Effect of divalent cations on the kinetics of Fe(III) complexation by organic ligands in natural waters     

Manabu Fujii  Andrew L. Rose  Tatsuo Omura 《Geochimica et cosmochimica acta》2008,72(5):1335-1349

We have investigated the kinetics of Fe(III) complexation by several organic ligands including fulvic acid, citrate and ethylenediaminetetraacetic acid (EDTA). Particular attention was given to examination of the effect of competitive divalent cations (Me: Ca²⁺ and Mg²⁺) at concentrations typical of seawater on the complexation rate. All experiments were conducted in 0.5 M NaCl solution buffered with 2 mM bicarbonate at pH 8.0 in the absence and presence of Me (25 μM-250 mM). The rate constants of complex formation determined by using the competitive ligand (5-sulfosalicylic acid) method combined with visible spectrophotometry ranged from 3.3 × 10⁴ to 3.2 × 10⁶ M⁻¹ s⁻¹. The mechanism of complexation was then examined based on a kinetic model. When EDTA was used as a ligand, Me at concentrations comparable to the ligand markedly retarded the rate of iron complex formation due to the predominance of an adjunctive pathway (where iron-ligand complex is formed via direct association of iron to Me-ligand complex). In contrast, the competing effect of Me on iron complexation by citrate and fulvic acid was observed only when the Me concentration was in excess of the ligand by more than a factor of 10-1000. The kinetic model suggests that iron complexation by fulvic acid occurs predominantly via a disjunctive pathway (where iron complexation by ligand occurs after dissociation of Me from Me-ligand complex) at concentrations of divalent cations and natural organic matter typical of natural waters including seawater and freshwater.  相似文献   

Local time variation of geomagnetic transfer functions   总被引：1，自引：0，他引：1  

Masahiko Takeda 《Geophysical Journal International》1997,130(3):765-770

The local time (LT) variation of the geomagnetic transfer function at the 32-min period was examined for observatories distributed worldwide. Two distinct variation types (types 1 and 2) were found in the real part of A. Type 1 is conspicuous at lower latitudes and its seasonal variation is small, whereas type 2 is found at higher latitudes and has its maximum in summer. These two types of LT variation are seen globally and are conspicuous when solar activity is high. The amplitudes of both types of variation vary from 0.018 to 0.078, and are independent of the mean values at each observatory. These values are relatively small, but the amplitude of Chambon la Foret is larger than the mean value, which shows that Au changes its sign in local time. The amplitudes of type 1 and 2 variations decrease and increase with geomagnetic latitude, respectively. These features suggest that they are generated by some global external fields. The most probable cause is the Sq field, although the Dp field may contribute to type 1 variation. On the other hand, for the islands of the Pacific Ocean at low latitudes, such as Honolulu and Chichijima, the type 1 variation appears not in the real but in the imaginary part of A, which suggests that currents induced in the ocean also contribute to the local time variation.  相似文献   

II-1 On the cross flow turbine for wave power plant (1st report, the characteristics of the turbine in steady air flow)     

Masahiko Akabane  Haruyuki Suzuki  Kunihiko Yamauchi 《Ocean Engineering》1985,12(6):562

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Development of an ROV operated both as towed and self-propulsive vehicle   总被引：1，自引：0，他引：1  

Masahiko Nakamura  Hiroyuki Kajiwara  Wataru Koterayama 《Ocean Engineering》2001,28(1):406

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Effects of fixation and storage on flow cytometric analysis of marine bacteria     

Eriko Kamiya  Shinji Izumiyama  Masahiko Nishimura  James G. Mitchell  Kazuhiro Kogure 《Journal of Oceanography》2007,63(1):101-112

Flow cytometry (FCM) is now becoming a routine tool for the enumeration and optical characterization of bacteria in marine environments. We investigated the effects of sample fixation and storage upon flow cytometric determination of marine bacteria. Fixed and unfixed seawater samples were analyzed by FCM immediately aboard ship and/or later in the laboratory, and the appearances of the fluorescence signals and bacterial counts of these samples were compared. Fixation and storage led to the formation of multiple peaks in fluorescence histograms; this was also seen in 22 out of 36 samples frozen in liquid nitrogen. Fixation did not, but storage did induce a decrease of bacterial counts: a rapid decrease during the first 3 days followed by a slower decline. The decline of cell numbers in stored samples was expressed by a regression model. Our studies indicate that precaution is necessary when interpreting the data from fixed and/or stored marine bacterial samples analyzed by FCM. The possibility that the procedure of fixation and storage leads to the appearance of high DNA and low DNA bacterial groups should be considered.  相似文献   

Induction of female‐to‐male sex change in a large protogynous fish,Choerodon schoenleinii          下载免费PDF全文

Taku Sato  Masato Kobayashi  Takayuki Takebe  Narisato Hirai  Koichi Okuzawa  Sayumi Sawaguchi  Takahiro Matsubara  Tomofumi Yamaguchi  Rihito Shinoda  Masahiko Koiso  Kazuhisa Teruya 《Marine Ecology》2018,39(1)

Most behavioral studies on hermaphroditic fishes have focused on small‐sized species, which are tractable for research. Although many species of large hermaphroditic fishes are important fishery resources, their proximate mechanisms (visual, chemical and/or behavioral cues) in the social regulation of sex change have not been determined. Determination of these would inform resource management and aquaculture. In order to get closer to understanding the proximate mechanisms underlying the social regulation of female‐to‐male sex change in large hermaphroditic fishes, this study reports situations that induced female‐to‐male sex change in black‐spot tuskfish, Choerodon schoenleinii, a species of large protogynous fish, in massive laboratory tanks. The situations differed in the possibility of male‐to‐female tactile contact and in the group sex ratio, enabling us to infer plausible proximate mechanisms underlying sex change induction. Tactile contact between individuals is suspected to be closely related to the incidence of female‐to‐male sex change in C. schoenleinii. Visual and chemical cues alone may be insufficient to inhibit such sex changes. Male‐to‐female tactile contact may have an important influence on female‐to‐male sex change, i.e., inhibition of this sex change, in this species. The effect of sex ratio of a social group on the incidence of sex change may be due to the relative frequency and intensity of male tactile contact with each female, which may vary with the number of females. In the absence of a dominant male, tactile contact among females may affect the incidence of sex change, as well as determine which individuals change sex.  相似文献   

Changes in the lower limit of mountain permafrost between 1973 and 2004 in the Khumbu Himal, the Nepal Himalayas   总被引：2，自引：0，他引：2  

Kotaro Fukui  Yoshiyuki Fujii  Yutaka Ageta  Katsuhiko Asahi 《Global and Planetary Change》2007,55(4):251-256

Because the Khumbu Himal of the Nepal Himalayas lacks long-term climate records from weather stations, mountain permafrost degradation serves as an important indicator of climate warming. In 1973, the permafrost lower limit was estimated to be 5200–5300 m above sea level (ASL) on southern-aspect slopes in this region. Using ground-temperature measurements, we examined the mountain permafrost lower limit on slopes with the same aspect in 2004. The results indicate that the permafrost lower limit was 5400–5500 m ASL in 2004. The permafrost lower limit was estimated to be 5400 to 5500 m on slopes with a southern aspect in the Khumbu Himal in 1991 using seismic reflection soundings. Thus, it is possible that the permafrost lower limit has risen 100–300 m between 1973 and 1991, followed by a stable limit of 5400 to 5500 m over the last decade. An increase in mean annual air temperature of approximately 0.2 to 0.4 °C from the 1970s to the 1990s has indicated a rise in the permafrost lower limit of 40 to 80 m at the Tibetan Plateau. The rise in the mountain permafrost lower limit in the Khumbu Himal exceeds that of the Tibetan Plateau, suggesting the possibility of greater climate warming in the Khumbu Himal.  相似文献   

Estrogenic activity in sediments contaminated by nonylphenol in Tokyo Bay (Japan) evaluated by vitellogenin induction in male mummichogs (Fundulus heteroclitus)     

Kurihara R  Watanabe E  Ueda Y  Kakuno A  Fujii K  Shiraishi F  Hashimoto S 《Marine pollution bulletin》2007,54(9):1315-1320

Estrogenic activity was determined in sediments collected from Tokyo Bay. Sampling was performed at five stations including the site near the sewage treatment plant. The most estrogenic sediment collected near the sewage treatment plant was fractionated into ten fractions using normal-phase high-performance liquid chromatography. Chemical analysis was carried out for each fraction and nonylphenol (NP, 20,700 ng g⁻¹ dry wt) was detected at a higher concentration than estron (2.39 ng g⁻¹ dry wt) and 17β-estradiol (<0.7 ng g⁻¹ dry wt). Furthermore, each fraction was administered to male mummichogs (Fundulus heteroclitus), and vitellogenin (Vtg) was measured after two weeks. The induction of Vtg was observed; this estrogenic potency could be attributed to the NP content in this fraction. This is the first report to suggest that the high NP concentration in the sediments from Tokyo Bay has the potential to induce Vtg in wild fish.  相似文献   

Compaction and fragmentation of porous gypsum targets from low-velocity impacts     

Yuichi Fujii 《Icarus》2009,201(2):795-801

We performed low-velocity impact experiments of gypsum spheres with porosity ranging from 0 to 61% and diameter ranging from 25 to 83 mm. The impact velocity was from 0.2 to 22 m/s. The target was an iron plate. The outcome of gypsum spheres with porosity 31-61% was different from those of non-porous ice [Higa M., Arakawa, M., Maeno, N., 1996. Planet. Space Sci. 44, 917-925; Higa M., Arakawa, M., Maeno, N., 1998. Icarus 133, 310-320] and non-porous gypsum. In between the intact and fragmentation modes, the outcome of the non-porous ice and gypsum was crack growth at the impact point. However, the outcome of the porous gypsum was compaction. We found that the restitution coefficients of the porous gypsum spheres were all in a similar range, in spite of the difference of the porosity and size at impact velocities up to about 10 m/s where they begin to be fragmented in pieces. Moreover, there is not a large difference between the restitution coefficient of porous and non-porous gypsum. These results collectively indicate that restitution coefficient of gypsum spheres of cm-size is not strongly dependent upon the porosity and compaction process.  相似文献   

Nuclear field shift effect as a possible cause of Te isotopic anomalies in the early solar system—An alternative explanation of Fehr et al. (2006 and 2009)     

Frédéric Moynier  Toshiyuki Fujii  Francis Albarède 《Meteoritics & planetary science》2009,44(11):1735-1742

Abstract— We explore the possibility that Te isotopic anomalies measured in Ca‐Al‐rich inclusions (Fehr et al. 2009) and in leachates of carbonaceous chondrites (Fehr et al. 2006) may be due to mass‐independent effects controlled by nuclear field shift rather than to nucleosynthetic processes. Fehr et al.'s spectrum of mass‐independent anomalies of Te isotopes shows a smooth correlation with mass number and nuclear charge distribution. Ratios of even to odd isotopes, as the ¹²⁵Te/¹²⁶Te ratio used by these authors for normalization are particularly prone to nuclear field shift effects. We show that the alternative normalization of isotopic ratios to ¹³⁰Te/¹²⁶Te strongly reduces the trend of isotopic fractionation with mass number, leaving only ¹²⁵Te as truly anomalous. For both normalizations (¹²⁵Te/¹²⁶Te and ¹³⁰Te/¹²⁶Te), Fehr et al.'s results fit the theory of Bigeleisen (1996), which suggests that the nuclear field shift effect can potentially account for the observed Te isotope abundances, as an alternative to nucleosynthetic processes. We propose that these mass‐independent effects may be acquired during accretion of sulfides from the solar nebula.  相似文献