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61.
The hydraulic and transfer response of karst aquifers is complex and often highly nonlinear: due to their high transmissivity and connection with the surface, such systems are very sensitive to modifications of their boundary conditions. The aim of this study was to assess the variation of the response depending on both upstream and downstream parameters, and propose a methodology to simulate the response of the karst system depending on those parameters. The impact of the variations of multiple environmental parameters on the response of a karstic system submitted to tidal variations (Normandy, France) was investigated after a campaign of artificial tracer tests acquired in very different hydrologic conditions (rainfall events, low tide, high tide, low/high piezometric level, and low/high waters). Principal components analysis and hierarchical clustering were applied on both environmental variables and karstic system response variables (parameters of the residence time distribution [RTD] curves). Equations between the RTD parameters and the most relevant variables were established using a symbolic regression algorithm. It appeared that the variations of the RTD parameters depend mainly on the cumulated rainfall preceding the injection, the piezometric level of the aquifer, and on the tide parameters. The hydraulic conditions downstream of the aquifer have a strong influence on the hydraulic and transfer response of the aquifer. The response of the aquifer in various and extreme conditions has been simulated using the equations resulting from the symbolic regression algorithm. Such relationships can be useful for management of water resources in karst media, and support decision making.  相似文献   
62.
Clastic sedimentary features of beachrocks and unconsolidated deposits of parent beaches were investigated along the northern Aegean coastline(Greece) to assess their suitability in palaeo-environmental reconstruction.Twelve paired datasets were collected in the Thermaikos,Toroneos,Siggitikos and lerissos gulfs of the Chalkidiki Peninsula,the adjoining Kavala Gulf and Thassos Island,comprising beachrock cores and companion beach subsurface sediments.Particle size analyses based on univariate and bivariate statistics suggest that,during the time period of beachrock formation,depositional conditions differed distinctly from those of the modern parent beaches.The results imply difference of maturity level of beach evolution from the time of cementation(coarser materials-early stage of beach formation) to modern situation(finer materials-reworked and ’mature’ beach sediments).Furthermore,the findings indicate increasing coastal protection due to beachrock exposure in the modern swash zone.In conclusion,it is suggested that textural analysis of beachrocks in comparison with unconsolidated sediments of the parent beach might provide information regarding differences of coastal depositional regimes and future research could focus on specific-layer analysis and comparison.  相似文献   
63.
The objective of this study was to characterize the behavior of a groundwater contaminant (trichloroethene, TCE) plume after implementation of a source‐containment operation at a site in Arizona. The plume resides in a quasi‐three‐layer system comprising a sand/gravel unit bounded on the top and bottom by relatively thick silty clayey layers. The system was monitored for 60 months beginning at start‐up in 2007 to measure the change in contaminant concentrations within the plume, the change in plume area, the mass of the contaminant removed, and the integrated contaminant mass discharge (CMD). The concentrations of TCE in groundwater pumped from the plume extraction wells have declined significantly over the course of operation, as have concentrations for groundwater sampled from 40 monitoring wells located within the plume. The total CMD associated with operation of the plume extraction wells peaked at 0.23 kg/d, decreased significantly within 1 year, and thereafter began an asymptotic decline to a current value of approximately 0.03 kg/d. Despite an 87% reduction in contaminant mass and a comparable 87% reduction in CMD for the plume, the spatial area encompassed by the plume has decreased by only approximately 50%. This is much less than would be anticipated based on ideal flushing and mass‐removal behavior. Simulations produced with a simplified three‐dimensional (3D) numerical model matched reasonably well to the measured data. The results of the study suggest that permeability heterogeneity, back diffusion, hydraulic factors associated with the specific well field system, and residual discharge from the source zone are all contributing to the observed persistence of the plume, as well as the asymptotic behavior currently observed for mass removal and for the reduction in CMD.  相似文献   
64.
This study describes the main circulation patterns (CP) in the Amazonian Basin over the 1975–2002 period and their relationship with rainfall variability. CPs in the Amazonian Basin have been computed for each season from the ERA-40 daily 850?hPa winds using an approach combining artificial neural network (Self Organizing Maps) and Hierarchical Ascendant Classification. A 6 to 8 cluster solutions (depending on the season considered) is shown to yield an integrated view of the complex regional circulation variability. For austral fall, winter and spring the temporal evolution between the different CPs shows a clear tendency to describe a cycle, with southern wind anomalies and their convergence with the trade winds progressing northward from the La Plata Basin to the Amazon Basin. This sequence is strongly related to eastward moving extra tropical perturbations and their incursion toward low latitude that modulate the geopotential and winds over South America and its adjoining oceans. During Austral summer, CPs are less spatially and temporally organized compared to other seasons, principally due to weaker extra tropical perturbations and more frequent shallow low situations. Each of these CPs is shown to be associated with coherent northward moving regional rainfall patterns (both in in situ data and ERA-40 reanalysis) and convective activity. However, our results reveals that precipitation variability is better reproduced by ERA-40 in the southern part of the Amazonian Basin than in the northern part, where rainfall variability is likely to be more constrained by local and subdaily processes (e.g. squall lines) that could be misrepresented in the reanalysis dataset. This analysis clearly illustrates the existing connections between the southern and northern part of the Amazonian Basin in terms of regional circulation/rainfall patterns. The identification of these CPs provide useful information to understand local rainfall variability and could hence be used to better understand the influence of these CPs on the hydrological variability in the Amazonian Basin.  相似文献   
65.
Antibiotic-resistant (pathogenic and non-pathogenic) organisms and genes are now acknowledged as significant emerging aquatic contaminants with potentially adverse human and ecological health impacts, and thus require monitoring. This study is the first to investigate levels of resistance among Irish groundwater (private wells) samples; Escherichia coli isolates were examined against a panel of commonly prescribed human and veterinary therapeutic antibiotics, followed by determination of the causative factors of resistance. Overall, 42 confirmed E. coli isolates were recovered from a groundwater-sampling cohort. Resistance to the human panel of antibiotics was moderate; nine (21.4%) E. coli isolates demonstrated resistance to one or more human antibiotics. Conversely, extremely high levels of resistance to veterinary antibiotics were found, with all isolates presenting resistance to one or more veterinary antibiotics. Particularly high levels of resistance (93%) were found with respect to the aminoglycoside class of antibiotics. Results of statistical analysis indicate a significant association between the presence of human (multiple) antibiotic resistance (p?=?0.002–0.011) and both septic tank density and the presence of vulnerable sub-populations (<5 years). For the veterinary antibiotics, results point to a significant relationship (p?=?<0.001) between livestock (cattle) density and the prevalence of multiple antibiotic resistant E. coli. Groundwater continues to be an important resource in Ireland, particularly in rural areas; thus, results of this preliminary study offer a valuable insight into the prevalence of antibiotic resistance in the hydrogeological environment and establish a need for further research with a larger geological diversity.  相似文献   
66.
With a paroxysmal ash eruption on 4 September 2007 and the highly explosive activity continuing in 2008, Oldoinyo Lengai (OL) has dramatically changed its behavior, crater morphology, and magma composition after 25 years of quiet extrusion of fluid natrocarbonatite lava. This explosive activity resembles the explosive phases of 1917, 1940–1941, and 1966–1967, which were characterized by mixed ashes with dominantly nephelinitic and natrocarbonatitic components. Ash and lapilli from the 2007–2008 explosive phase were collected on the slopes of OL as well as on the active cinder cone, which now occupies the entire north crater having buried completely all earlier natrocarbonatite features. The lapilli and ash samples comprise nepheline, wollastonite, combeite, Na-åkermanite, Ti-andradite, resorbed pyroxene and Fe–Ti oxides, and a Na–Ca carbonate phase with high but varying phosphorus contents which is similar, but not identical, to the common gregoryite phenocrysts in natrocarbonatite. Lapilli from the active cone best characterize the erupted material as carbonated combeite–wollastonite–melilite nephelinite. The juvenile components represent a fundamentally new magma composition for OL, containing 25–30 wt.% SiO2, with 7–11 wt.% CO2, high alkalies (Na2O 15–19%, K2O 4–5%), and trace-element signatures reminiscent of natrocarbonatite enrichments. These data define an intermediate composition between natrocarbonatite and nephelinite, with about one third natrocarbonatite and two thirds nephelinite component. The data are consistent with a model in which the carbonated silicate magma has evolved from the common combeite–wollastonite nephelinite (CWN) of OL by enrichment of CO2 and alkalies and is close to the liquid immiscible separation of natrocarbonatite from carbonated nephelinite. Material ejected in April/May 2008 indicates reversion to a more common CWN composition.  相似文献   
67.
On September 4, 2007, after 25 years of effusive natrocarbonatite eruptions, the eruptive activity of Oldoinyo Lengai (OL), N Tanzania, changed abruptly to episodic explosive eruptions. This transition was preceded by a voluminous lava eruption in March 2006, a year of quiescence, resumption of natrocarbonatite eruptions in June 2007, and a volcano-tectonic earthquake swarm in July 2007. Despite the lack of ground-based monitoring, the evolution in OL eruption dynamics is documented based on the available field observations, ASTER and MODIS satellite images, and almost-daily photos provided by local pilots. Satellite data enabled identification of a phase of voluminous lava effusion in the 2 weeks prior to the onset of explosive eruptions. After the onset, the activity varied from 100 m high ash jets to 2–15 km high violent, steady or unsteady, eruption columns dispersing ash to 100 km distance. The explosive eruptions built up a ∼400 m wide, ∼75 m high intra-crater pyroclastic cone. Time series data for eruption column height show distinct peaks at the end of September 2007 and February 2008, the latter being associated with the first pyroclastic flows to be documented at OL. Chemical analyses of the erupted products, presented in a companion paper (Keller et al. 2010), show that the 2007–2008 explosive eruptions are associated with an undersaturated carbonated silicate melt. This new phase of explosive eruptions provides constraints on the factors causing the transition from natrocarbonatite effusive eruptions to explosive eruptions of carbonated nephelinite magma, observed repetitively in the last 100 years at OL.  相似文献   
68.
Boriskino is a poorly studied CM chondrite with numerous millimeter‐ to centimeter‐scale clasts exhibiting sharp boundaries. Clast textures and mineralogies attest to diverse geological histories with various degrees of aqueous alteration. We conducted a petrographic, chemical, and isotopic study on each clast type of the breccia to investigate if there exists a genetic link between brecciation and aqueous alteration, and to determine the controlling parameter of the extent of alteration. Boriskino is dominated by CM2 clasts for which no specific petrographic type could be assigned based on the chemical compositions and modal abundances of constituents. One clast stands out and is identified as a CM1 lithology, owing to its lack of anhydrous silicates and its overall abundance of dolomite‐like carbonates and acicular iron sulfides. We observe that alteration phases near clast boundaries exhibit foliation features, suggesting that brecciation postdated aqueous alteration. We measured the O‐isotopic composition of Ca‐carbonates and dolomite‐like carbonates to determine their precipitation temperatures following the methodology of Verdier‐Paoletti et al. (2017). Both types of carbonates yield similar ranges of precipitation temperatures independent of clast lithology, ranging from ?13.9 ± 22.4 (2σ) to 166.5 ± 47.3 °C, precluding that temperature alone accounts for the differences between the CM1 and CM2 lithologies. Instead, we suggest that initial water/rock ratios of 0.75 and 0.61 for the CM1 and CM2 clasts, respectively, might control the extent of aqueous alteration. Based on these estimates, we suggest that Boriskino clasts originated from a single parent body with heterogeneous distribution of water either due to local differences in the material permeability or in the initial content of ice available. These conditions would have produced microenvironments with differing geochemical conditions thus leading to a range of degrees of aqueous alteration.  相似文献   
69.
Currently, monitoring tools can be deployed in observation boreholes to better assess groundwater flow, flux of dissolved contaminants and their mass discharge in an aquifer. The relationship between horizontal water velocity in observation boreholes and Darcy fluxes in the surrounding aquifer has been studied for natural flow conditions (i.e., no pumping). Interpretation of measurements taken with dilution tests, the colloidal borescope, the Heat Pulse Flowmeter, and other techniques require the conversion of observed borehole velocity u to aquifer Darcy flux q . This conversion is typically done through a proportionality factor α = u/q . In experimental studies as well as in theoretical developments, reported values of α vary almost three orders of magnitude (from 0.5 to 10). This large variability in reported values of α could be explained by: (1) unclear distinction between Darcy flux and water seepage velocity, (2) unclear definition of water velocity in the borehole, (3) effects of well screen and the presence of the measurement device itself on the observable velocities, and (4) hydraulic conditions in the borehole annulus. We address (1), (2) from a conceptual/theoretical perspective, and (3) by means of numerical simulations. We show that issue (1) in low porosity aquifers can yield to order-of-magnitude discrepancies in estimates of q ; (2) may result in discrepancies of up to 50%, and (3) can cause differences up to 20% of water velocity in the borehole void space compared to the theoretical case of an open borehole.  相似文献   
70.
Peruvian anchovy (Engraulis ringens) stock abundance is tightly driven by the high and unpredictable variability of the Humboldt Current Ecosystem. Management of the fishery therefore cannot rely on mid- or long-term management policy alone but needs to be adaptive at relatively short time scales. Regular acoustic surveys are performed on the stock at intervals of 2 to 4 times a year, but there is a need for more time continuous monitoring indicators to ensure that management can respond at suitable time scales. Existing literature suggests that spatially explicit data on the location of fishing activities could be used as a proxy for target stock distribution. Spatially explicit commercial fishing data could therefore guide adaptive management decisions at shorter time scales than is possible through scientific stock surveys. In this study we therefore aim to (1) estimate the position of fishing operations for the entire fleet of Peruvian anchovy purse–seiners using the Peruvian satellite vessel monitoring system (VMS), and (2) quantify the extent to which the distribution of purse–seine sets describes anchovy distribution. To estimate fishing set positions from vessel tracks derived from VMS data we developed a methodology based on artificial neural networks (ANN) trained on a sample of fishing trips with known fishing set positions (exact fishing positions are known for approximately 1.5% of the fleet from an at-sea observer program). The ANN correctly identified 83% of the real fishing sets and largely outperformed comparative linear models. This network is then used to forecast fishing operations for those trips where no observers were onboard. To quantify the extent to which fishing set distribution was correlated to stock distribution we compared three metrics describing features of the distributions (the mean distance to the coast, the total area of distribution, and a clustering index) for concomitant acoustic survey observations and fishing set positions identified from VMS. For two of these metrics (mean distance to the coast and clustering index), fishing and survey data were significantly correlated. We conclude that the location of purse–seine fishing sets yields significant and valuable information on the distribution of the Peruvian anchovy stock and ultimately on its vulnerability to the fishery. For example, a high concentration of sets in the near coastal zone could potentially be used as a warning signal of high levels of stock vulnerability and trigger appropriate management measures aimed at reducing fishing effort.  相似文献   
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