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71.
Predicting runoff hot spots and hot‐moments within a headwater crop‐catchment is of the utmost importance to reduce adverse effects on aquatic ecosystems by adapting land use management to control runoff. Reliable predictions of runoff patterns during a crop growing season remain challenging. This is mainly due to the large spatial and temporal variations of topsoil hydraulic properties controlled by complex interactions between weather, growing vegetation, and cropping operations. This interaction can significantly modify runoff patterns and few process‐based models can integrate this evolution of topsoil properties during a crop growing season at the catchment scale. Therefore, the purpose of this study was to better constrain the event‐based hydrological model Limburg Soil Erosion Model by incorporating temporal constraints for input topsoil properties during a crop growing season (LISEM). The results of the temporal constraint strategy (TCS) were compared with a classical event per event calibration strategy (EES) using multi‐scale runoff information (from plot to catchment). The EES and TCS approaches were applied in a loess catchment of 47 ha located 30 km northeast of Strasbourg (Alsace, France). A slight decrease of the Nash–Sutcliffe efficiency criterion on runoff discharge for TCS compared to EES was counterbalanced by a clear improvement of the spatial runoff patterns within the catchment. This study showed that limited agronomical and climatic information added during the calibration step improved the spatial runoff predictions of an event‐based model. Reliable prediction of runoff source, connectivity, and dynamics can then be derived and discussed with stakeholders to identify runoff hot spots and hot‐moments for subsequent land use and crop management modifications.  相似文献   
72.
Abstract– We describe the geological, morphological, and climatic setting of the San Juan meteorite collection area in the Central Depression of the Atacama Desert (Chile). Our recovery activities yielded 48 meteorites corresponding to a minimum of 36 different falls within a 3.88 km2 area. The recovery density is in the range 9–12 falls km?2 depending on pairing, making it the densest among meteorite collection areas in hot deserts. This high meteorite concentration is linked to the long‐standing hyperaridity of the area, the stability of the surface pebbles (> Ma), and very low erosion rates of surface pebbles (approximately 30 cm Ma?1 maximum). The San Juan meteorite population is characterized by old terrestrial ages that range from zero to beyond 40 ka, and limited weathering compared with other dense collection areas in hot desert. Chemical weathering in San Juan is slow and mainly controlled by the initial porosity of meteorites. As in the Antarctic and other hot deserts, there is an overabundance of H chondrites and a shortage of LL chondrites compared with the modern falls population, suggesting a recent (< few ka) change in the composition of the meteorite flux to Earth.  相似文献   
73.
Preservation of cyclic steps contrasts markedly with that of subcritical‐flow bedforms, because cyclic steps migrate upslope eroding their lee face and preserving their stoss side. Such bedforms have not been described from turbidite outcrops and cores as yet. A conceptual block diagram for recognition of cyclic steps in outcrop has been constructed and is tested by outcrop studies of deep water submarine fan deposits of the Tabernas Basin in south‐eastern Spain. Experimental data indicate that depositional processes on the stoss side of a cyclic step are controlled by a hydraulic jump, which decelerates the flow and by subsequent waxing of the flow up to supercritical conditions once more. The hydraulic jump produces a large scour with soft‐sediment deformation (flames) preserved in coarse‐tail normal‐graded structureless deposits (Bouma Ta), while near‐horizontal, massive to stratified top‐cut‐out turbidite beds are found further down the stoss side of the bedform. The architecture of cyclic steps can best be described as large, up to hundreds of metres, lens‐shaped bodies that are truncated by erosive surfaces representing the set boundaries and that consist of nearly horizontal lying stacks of top‐cut‐out turbidite beds. The facies that characterize these bedforms have traditionally been described as turbidite units in idealized vertical sequences of high‐density turbidity currents, but have not yet been interpreted to represent bedforms produced by supercritical flow. Their large size, which is in the order of 20 m for gravelly and up to hundreds of metres for sandy steps, is likely to have hindered their recognition in outcrop so far.  相似文献   
74.
The Seine estuary, one of the largest estuaries of the European northwest continental shelf, is subjected to numerous anthropogenic influences. Here we present an assessment of the microbial faecal contamination of the estuary water. The most vulnerable areas were defined on the basis of the fluxes of indicator organisms and the occurrence of Salmonella and Cryptosporidium sp. and Giardia sp. (oo)cysts. The microbial quality of the water changes from upstream to downstream: in the upstream area, contamination by faecal-indicator bacteria and Salmonella occurs during periods of high flow; in the urbanized area, mid-way between the uppermost areas of the estuary and its mouth, discharge from a wastewater treatment plant and a tributary degrade water quality; at the estuary mouth, the accumulation of microorganisms attached to particles in the maximum turbidity zone, particularly Clostridium perfringens spores and oocysts of Cryptosporidium, is accompanied by inputs of ThC and Escherichia coli from tributaries. In some areas, significant strong relations are observed between Salmonella, (oo)cysts of protozoan, and levels of faecal indicators.  相似文献   
75.
A simple thermohydromechanical (THM) constitutive model for unsaturated soils is described. The effective stress concept is extended to unsaturated soils with the introduction of a capillary stress. This capillary stress is based on a microstructural model and calculated from attraction forces due to water menisci. The effect of desaturation and the thermal softening phenomenon are modelled with a minimal number of material parameters and based on existing models. THM process is qualitatively and quantitatively modelled by using experimental data and previous work to show the application of the model, including a drying path under mechanical stress with transition between saturated and unsaturated states, a heating path under constant suction and a deviatoric path with imposed suction and temperature. The results show that the present model can simulate the THM behaviour in unsaturated soils in a satisfactory way.  相似文献   
76.
We report in situ LA‐ICP‐MS trace element analyses of silicate phases in olivine‐bearing chondrules in the Sahara 97096 (EH3) enstatite chondrite. Most olivine and enstatite present rare earth element (REE) patterns comparable to their counterparts in type I chondrules in ordinary chondrites. They thus likely share a similar igneous origin, likely under similar redox conditions. The mesostasis however frequently shows negative Eu and/or Yb (and more rarely Sm) anomalies, evidently out of equilibrium with olivine and enstatite. We suggest that this reflects crystallization of oldhamite during a sulfidation event, already inferred by others, during which the mesostasis was molten, where the complementary positive Eu and Yb anomalies exhibited by oldhamite would have possibly arisen due to a divalent state of these elements. Much of this igneous oldhamite would have been expelled from the chondrules, presumably by inertial acceleration or surface tension effects, and would have contributed to the high abundance of opaque nodules found outside them in EH chondrites. In two chondrules, olivine and enstatite exhibit negatively sloped REE patterns, which may be an extreme manifestation of a general phenomenon (possibly linked to near‐liquidus partitioning) underlying the overabundance of light REE observed in most chondrule silicates relative to equilibrium predictions. The silicate phases in one of these two chondrules show complementary Eu, Yb, and Sm anomalies providing direct evidence for the postulated occurrence of the divalent state for these elements at some stage in the formation reservoir of enstatite chondrites. Our work supports the idea that the peculiarities of enstatite chondrites may not require a condensation sequence at high C/O ratios as has long been believed.  相似文献   
77.
Abstract— Using visual observations that were reported 140 years ago in the Comptes Rendus de l'Académie des Sciences de Paris, we have determined the atmospheric trajectory and the orbit of the Orgueil meteorite, which fell May 14, 1864, near Montauban, France. Despite the intrinsic uncertainty of visual observations, we were able to calculate a reasonably precise atmospheric trajectory and a moderately precise orbit for the Orgueil meteoroid. The atmosphere entry point was ?70 km high and the meteoroid terminal point was ?20 km high. The calculated luminous path was ?150 km with an entry angle of 20°. These characteristics are broadly similar to that of other meteorites for which the trajectory is known. Five out of six orbital parameters for the Orgueil orbit are well constrained. In particular, the perihelion lies inside the Earth's orbit (q ?0.87 AU), as is expected for an Earth‐crossing meteorite, and the orbital plane is close to the ecliptic (i ?0°). The aphelion distance (Q) depends critically on the pre‐atmospheric velocity. From the calculated atmospheric path and the fireball duration, which was reported by seven witnesses, we have estimated the pre‐atmospheric velocity to be larger than 17.8 km/sec, which corresponds to an aphelion distance Q larger than 5.2 AU, the semi‐major axis of Jupiter orbit. These results suggest that Orgueil has an orbit similar to that of Jupiter‐family comets (JFCs), although an Halley‐type comet cannot be excluded. This is at odds with other meteorites that have an asteroidal origin, but it is compatible with 140 years of data‐gathering that has established the very special nature of Orgueil compared to other meteorites. A cometary origin of the Orgueil meteorite does not contradict cosmochemistry data on CI1 chondrites. If CI1 chondrites originate from comets, it implies that comets are much more processed than previously thought and should contain secondary minerals. The forthcoming return of cometary samples by the Stardust mission will provide a unique opportunity to corroborate (or contradict) our hypothesis.  相似文献   
78.
The Mt Cameroon volcano is the highest and most active volcano of the Cameroon Volcanic Line. Little geological information is available for improving the understanding of the structure of this large volcanic system and its relationship to regional tectonics. After reviewing the tectonic evolution of the region, the analysis of a Digital Elevation Model and results from a field campaign dedicated to mapping geological structures in the summit area and at the SE base of Mt Cameroon are presented. Mt Cameroon is a lava-dominated volcano with long steep (over 30°) flanks. It is elongate parallel to its well defined rift zone. The summit plateau is bordered by 10 m high cliffs formed by summit subsidence along normal faults. Geological profiles were measured along rivers cutting through a topographic step at the SE base of Mt Cameroon. This step is associated with deformed Miocene sediments from the Douala basin that are overlain by volcanic products. Weak sediments of this area are deformed by 050°–060° and 020°–030° trending asymmetrical folds verging toward the SE, and thrusts faults related to the spreading of the volcano over its mechanically weak substratum. Combined remote sensing and field observations suggest that spreading is accommodated by summit subsidence and flanks sliding. Both slow spreading movements and catastrophic collapses of the steep flanks are interpreted to result from complex interactions between the growing edifice, repeated dyke intrusions, the weak sedimentary substratum and tectonic structures.  相似文献   
79.
Multiple pieces of geologic evidence suggest that interfaces between contrasted lithologies exert a strong control on the fate of volatiles in subduction zones. Here we present results from a contact between serpentinites and sediments, located in Corsica and metamorphosed in the blueschist facies during the alpine orogeny. It was shown previously that carbonates in the sediments have been reduced to graphitic carbonaceous material within a 5–10-cm-thick reaction zone at the contact with serpentinites. In an effort to investigate the mechanisms governing this unusual process, bulk rock geochemical analyses incorporating a statistical analysis of compositional data are presented. Observations show that the fate of C was decoupled from that of other elements such as O, H, and large-ion lithophile elements—e.g. K, Sr, Ba...,As—that were extensively leached from the reaction zone. Notably, Na is strongly enriched in the reaction zone and structurally linked to pectolite. Reducing conditions, manifested by the depletion of O in the reaction zone compared to the bulk metasediment, were likely maintained by the presence of Fe(II) in the serpentinite. Moreover, thermodynamic calculations show that the low solubility of carbon in COH fluids at high-pressure and low-temperature conditions was the main driver for graphite precipitation synchronously with carbonate destabilization. This may have been kinetically favored by the presence of already existing graphitized carbonaceous material and phengite in the metasediment. Limited lateral flow might have contributed as well to the geochemical and petrological patterns observed in these rocks.  相似文献   
80.
Abstract— A database of magnetic susceptibility (χ) measurements on different non‐ordinary chondrites (C, E, R, and ungrouped) populations is presented and compared to our previous similar work on ordinary chondrites. It provides an exhaustive study of the amount of iron‐nickel magnetic phases (essentially metal and magnetite) in these meteorites. In contrast with all the other classes, CM and CV show a wide range of magnetic mineral content, with a two orders of magnitude variation of χ. Whether this is due to primary parent body differences, metamorphism or alteration, remains unclear. C3–4 and C2 yield similar χ values to the ones shown by CK and CM, respectively. By order of increasing χ, the classes with well‐grouped χ are: R << CO < CK ≈ CI < Kak < CR < E ≈ CH < CB. Based on magnetism, EH and EL classes have indistinguishable metal content. Outliers that we suggest may need to have their classifications reconsidered are Acfer 202 (CO), Elephant Moraine (EET) 96026 (C4–5), Meteorite Hills (MET) 01149, and Northwest Africa (NWA) 521 (CK), Asuka (A)‐88198, LaPaz Icefield (LAP) 031156, and Sahara 98248 (R). χ values can also be used to define affinities of ungrouped chondrites, and propose pairing, particularly in the case of CM and CV meteorites.  相似文献   
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