Near-lithostatic pore pressure at seismogenic depths: a thermoporoelastic model     

Francesca Zencher  Maurizio Bonafede  Ragnar Stefansson 《Geophysical Journal International》2006,166(3):1318-1334

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Continuous in situ measurements of volcanic gases with a diode-laser-based spectrometer: CO<Subscript>2</Subscript> and H<Subscript>2</Subscript>O concentration and soil degassing at Vulcano (Aeolian islands: Italy)     

Maurizio De Rosa  Gianluca Gagliardi  Alessandra Rocco  Renato Somma  Paolo De Natale  Giuseppe De Natale 《Geochemical transactions》2007,8(1):5

We report on a continuous-measurement campaign carried out in Vulcano (Aeolian islands, Sicily), devoted to the simultaneous monitoring of CO₂ and H₂O concentrations. The measurements were performed with an absorption spectrometer based on a semiconductor laser source emitting around a 2-μm wavelength. The emitted radiation was selectively absorbed by two molecular ro-vibrational transitions specific of the investigated species. Data for CO₂ and H₂O concentrations, and CO₂ soil diffusive flux using an accumulation chamber configuration, were collected at several interesting sampling points on the island (Porto Levante beach- PLB, Fossa Grande Crater – FOG- and Valley of Palizzi, PAL). CO₂/H₂O values, measured on the ground, are very similar (around 0.019 (± 0.006)) and comparable to the previous discrete detected values of 0.213 (Fumarole F5-La Fossa crater rim) and 0.012 (Fumarole VFS – Baia Levante beach) obtaid during the 1977–1993 heating phase of the crater fumaroles.  相似文献   

Warmer early instrumental measurements versus colder reconstructed temperatures: shooting at a moving target     

David Frank  Ulf Büntgen  Reinhard Bhm  Maurizio Maugeri  Jan Esper 《Quaternary Science Reviews》2007,26(25-28):3298-3310

Comparison of tree-ring-based warm-season temperature reconstructions and their instrumental target data reveals substantial divergence between (warmer) early instrumental measurements and (colder) proxy estimates. Here we detail this systematic misfit for the Northern Hemisphere before 1900 and the European Alps before 1850. Five hypotheses related to both proxy and target uncertainties are presented towards explaining this phenomenon. These include: (1) tree-ring detrending methods, (2) biological persistence in the proxy time-series, (3) uncertainties and instabilities in the growth response to given climatic parameters, (4) reduced instrumental station availability back in time, and (5) instrumental data homogeneity. We suggest that uncertainties in the choice of instrumental targets at the hemispheric scale, and instrumental data inhomogeneities at the Alpine and possibly also the hemispheric-scale are the most important factors in explaining this offset. Assessment of homogeneity at larger scales remains challenging. Attention is drawn to possible warm biases in early thermometer shelters and the relevance of proxy/target discrepancies for understanding and quantifying the amplitude of both recent anthropogenic and past natural forced climate fluctuations.  相似文献   

Equivocal carbonatite markers in the mantle xenoliths of the Patagonia backarc: the Gobernador Gregores case (Santa Cruz Province,Argentina)     

Giorgio?RivalentiEmail author  Alberto?Zanetti  Maurizio?Mazzucchelli  Riccardo?Vannucci  Carlos?A.?Cingolani 《Contributions to Mineralogy and Petrology》2004,147(6):647-670

Amphibole ± phlogopite ± apatite-bearing mantle xenoliths at Gobernador Gregores display modal, bulk-rock and phase geochemical characteristics held as indicators of carbonatitic metasomatism. However, part of these xenoliths has high TiO₂/Al₂O₃ and those displaying the most pronounced carbonatitic geochemical markers modally trend towards harzburgite. Bulk-rock, clinopyroxene and amphibole show Zr, Hf and Ti negative anomalies, which increase at decreasing Na₂O and high field strength elements (HFSE) concentrations. Steady variation trends between xenoliths which have and do not have carbonatitic characteristics suggest a control by reactive porous flow of only one agent, inferred to be initially a ne-normative hydrous basalt (because of the presence of wehrlites) evolving towards silica saturation. Variation trends exhibit cusps when amphibole appears in the mode. Appearance of amphibole may explain the Ti anomaly variations, but not those of Zr and Hf. Numerical modelling [Plate Model (Vernières et al. in J Geophys Res 102:24771–24784, 1997)] gives results consistent with the observed geochemical features by assuming the presence of loveringite. Modest HFSE anomalies in the infiltrating melt may be acquired during percolation in the garnet-facies.In memory of Carlo Rivalenti  相似文献   

The effect of organic compounds in the oxidation kinetics of Cr(III) by H₂O₂     

Maurizio Pettine  Francesca Gennari  Frank J. Millero 《Geochimica et cosmochimica acta》2008,72(23):5692-5707

The oxidation of Cr(III) has been studied in NaCl solutions in the presence of two siderophore models, acetohydroxamic acid (Aha) and benzohydroxamic acid (Bha), the natural siderophore Desferal (DFOB) and the synthetic aminocarboxilate (ethylenedinitrilo)-tetra-acetic acid (EDTA) as a function of pH (8-9), ionic strength (0.01-2 M) and temperature (10-50 °C), at different Cr(III)-organic compound ratios. The addition of Aha and Bha caused the rates to increase at low ligand/Cr(III) ratios and decrease at high ratios. The variation of the pseudo first order rate constant (k₁) as a function of the ligand concentration has been attributed to the formation of three Cr(III)-organo species (1:1, 1:2, 1:3), which can form in the presence of monohydroxamic acids. A kinetic model has been developed that gives a value of 600 (min⁻¹) for the pseudo first order rate constant k_1CrAha²⁺ and values approaching zero for and k_1CrAha3. These kinetic results demonstrate that these monohydroxamic acids are able to bind with Cr(III) under experimental conditions that may occur in natural waters and can increase the oxidation rates of Cr(III) with H₂O₂ by a factor of 3.5 at an Aha/Cr(III) ratio of about 50-100.The monohydroxamic acids also affect the rates on aged products of Cr(III), suggesting that these ligands are able to affect the oxidation rates by releasing reactive Cr(III). DFOB and EDTA do not have a great effect on the oxidation of Cr(III) with H₂O₂. This is thought to be due to the much longer times they need to form complexes with Cr(III) compared to Aha and Bha. The rates for the formation of DFOB and EDTA complexes with Cr(III) are not competitive with the rates of the formation of aged Cr(III). After allowing Cr(III) and DFOB to react for 5 days to form the complex, reaction rates of Cr(III) with H₂O₂ appear to be lowered probably because of steric hindrance of the chelated Cr(III).  相似文献   

Depth and morphology of reflectors from the non-linear inversion of arrival-time and waveform semblance data. Part I: method and applications to synthetic data     

Maurizio Vassallo  Aldo Zollo 《Geophysical Prospecting》2008,56(4):527-540

We propose a two-dimensional, non-linear method for the inversion of reflected/converted traveltimes and waveform semblance designed to obtain the location and morphology of seismic reflectors in a lateral heterogeneous medium and in any source-to-receiver acquisition lay-out. This method uses a scheme of non-linear optimization for the determination of the interface parameters where the calculation of the traveltimes is carried out using a finite-difference solver of the Eikonal equation, assuming an a priori known background velocity model. For the search for the optimal interface model, we used a multiscale approach and the genetic algorithm global optimization technique. During the initial stages of inversion, we used the arrival times of the reflection phase to retrieve the interface model that is defined by a small number of parameters. In the successive steps, the inversion is based on the optimization of the semblance value determined along the calculated traveltime curves. Errors in the final model parameters and the criteria for the choice of the best-fit model are also estimated from the shape of the semblance function in the model parameter space. The method is tested and validated on a synthetic dataset that simulates the acquisition of reflection data in a complex volcanic structure. This study shows that the proposed inversion approach is a valid tool for geophysical investigations in complex geological environments, in order to obtain the morphology and positions of embedded discontinuities.  相似文献   

Flow analysis in a channel with flexible vegetation using double-averaging method     

Maurizio Righetti 《Acta Geophysica》2008,56(3):801-823

The paper addresses the problem of the resistance due to vegetation in an open channel flow, characterized by partially and fully submerged vegetation formed by colonies of bushes. The flow is characterized by significant spatial variations of velocity between vertical profiles that make the traditional approach based on time averaging of turbulent fluctuations inconvenient. A more useful procedure, based on time and spatial averaging (Double-Averaging Method) is applied for the flow field analysis and characterization. The vertical distribution of mean velocity and turbulent stresses at different spatial locations has been measured with a 3D Acoustic Doppler Velocimeter (ADV) for two different vegetation densities where fully submerged real bushes (salix pentandra) have been used. Velocity measurements were completed together with the measurements of drag exerted on the flow by bushes at different flow depths. The analysis of velocity measurements allows depicting the fundamental characteristics of both the mean flow field and turbulence. The experimental data show that the contribution of form-induced stresses to the momentum balance cannot be neglected. The mean velocity profiles and the spatially averaged turbulent intensity profiles allow inferring that the vegetation density is a driving parameter for the development of a mixing layer at the canopy top in the case of submerged vegetation. Moreover, the net upward turbulent momentum flux, evaluated with the methodology proposed by Lu and Willmarth (1973), appears to be damped for increased vegetation density; this finding can rationally explain the reduction of the suspended sediment transport capacity typically observed in free surface flows over a vegetated bed.  相似文献   

Gravity inversion by the Multi‐HOmogeneity Depth Estimation method for investigating salt domes and complex sources          下载免费PDF全文

Mahak Singh Chauhan  Maurizio Fedi  Mrinal K. Sen 《Geophysical Prospecting》2018,66(Z1):175-191

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Thorough wetting and drainage of a peat lysimeter in a climate change scenario     

Maurizio Previati  Davide Canone  Edoardo Iurato  Davide Gisolo  Stefano Ferrari  Pietro Teatini  Mario Putti  Stefano Ferraris 《水文研究》2020,34(5):1269-1284

A peat deposit (Zennare basin, Venice coastland, Italy) was monitored in previous field studies to investigate the hydrological response of organic soil to meteorological dynamics. Field tests and modelling predictions highlighted the risk of the complete loss of this peat layer during the next 50 years, due to oxidation enhanced by the increased frequency of warmer periods. Unfortunately, despite the considerable impacts that are expected to affect peat bogs (in this area and worldwide), only a few experimental studies have been carried out to assess the hydrologic response of peat to severe water scarcity. Because of that, an undisturbed 0.7 m³ peat monolith was collected, transferred to the laboratory and instrumented. The total weight (representative of the water content dynamics of the peat monolith as a whole), and two vertical profiles of matric potentials and water content were monitored in controlled water-scarce conditions. After an extended air-drying period, the monolith was used as an undisturbed peat lysimeter and a complete cycle of wetting and drainage was performed. Supplementary measurements of matric potential ψ and water content θ were collected by testing peat subsamples on a suction table apparatus. A set of water retention curves was determined in a range of matric potentials broader (ψ down to −7 m) than the current natural conditions in the field (minimum ψ = −1 m). While water content at saturation showed values similar to those in the original natural conditions (θ ≅ 0.8), a remarkable loss of water holding capacity (even for low potentials) has been highlighted, especially in deep layers that are now permanently below the water table. The retention curves changed shape and values, with a more pronounced hysteresis visible in an increasing distance between wetting and drying data. Hydraulic non-equilibrium between the water content and water potential could be a possible cause and it is worth modelling in future studies. The parameters of the van Genuchten retention curves were obtained for the wetting and the drying phases.  相似文献   

Insights on the spreading of the Tyrrhenian Sea from the magnetic anomaly pattern     

Giovanni Florio  Maurizio Fedi  Federico Cella 《地学学报》2011,23(2):127-133

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