The Cathedral of S. Giorgio in Ragusa Ibla (Italy): characterization of construction materials and their chromatic alteration     

Germana Barone  Mauro Francesco La Russa  Antonino Lo Giudice  Paolo Mazzoleni  Antonino Pezzino 《Environmental Geology》2008,55(3):499-504

The Cathedral of St. Giorgio in Ragusa Ibla (Sicily) is one of the most important Baroque monuments of eastern Sicily. The restoration of the monument underway has put forward notable questions regarding the stone materials used and their state of degradation. The façade appears to be made mainly of a creamy white calcarenite, and of mortars and plasters. However, detailed analysis has highlighted a more complex use of the raw material. The mortar and plaster have a different composition in regards to their architectural use while the natural stone material is distinguished not only by a creamy-white calcarenite but also by a dark coloured bituminous calcarenite (pitch rock), which now appears whiter because of superficial chromatic alterations. This process was reproduced in the laboratory using an accelerated aging technique on samples of bituminous calcarenite, which allowed the cause of the alternation to be identified as photo-oxidation of the asphaltenes. Following this process of photo-oxidation, other forms of chromatic alterations affected the façade (brown–orange-coloured patinas). FTIR, Scanning Electron Microscope and thin section microscopic observation allowed the characterization of also the products of this process to be carried out, highlighting the complex mechanism which the processes underwent.  相似文献   

The Contribution of Geoelectrical Investigations in the Analysis of Periglacial and Glacial Landforms in Ice Free Areas of the Northern Foothills (Northern Victoria Land, Antarctica)     

Mauro Guglielmin  Alessandro Biasini  & Claudio Smiraglia 《Geografiska Annaler: Series A, Physical Geography》1997,79(1-2):17-24

All periglacial and glacial landforms investigated in the Northern Foothills have a very thin active layer (0.1–0.3 m thickness) overlying a thin permafrost layer, characterised by electrical resistivities ranging between 13 and 50 kΩm and by different thicknesses. Below this surficial layer, different types of ground ice (with a resistivity range from 8000 to 0.1 kΩm) were detected. These different types of ground ice permitted ice-cored rock glaciers to be distinguished from ice-cemented rock glaciers, subsea permafrost to be identified in some raised beaches, and other interpretations to be suggested about a debris-covered glacier. These results have been obtained by vertical electrical soundings (VES) carried out in ice-free areas of the Northern Foothills, near Terra Nova Bay Station during the tenth national Italian expedition in Antarctica (1994–1995). In these areas on the basis of previous geomorphological research, some landforms such as rock glaciers, raised beaches with patterned ground and debris-covered glaciers were chosen to carry out the VES. The electrical prospection can be considered a good means for understanding the origins of landforms in ice-free areas of Antarctica and for making a contribution to the palaeoenvironmental reconstruction of this continent.  相似文献   

Permeability distribution in the Lahendong geothermal field: A blind fault captured by thermal–hydraulic simulation     

Maren Brehme  Guido Blöcher  Mauro Cacace  Yustin Kamah  Martin Sauter  Günter Zimmermann 《Environmental Earth Sciences》2016,75(14):1088

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Temporal changes in pelagic copepod assemblages off Ubatuba,Brazil          下载免费PDF全文

Mauro Melo Júnior  Catarina R. Marcolin  Leonardo K. Miyashita  Rubens M. Lopes 《Marine Ecology》2016,37(4):877-890

The inner shelf waters off Southeastern Brazil are periodically enriched by bottom intrusions of the cold and nutrient‐rich South Atlantic Central Water (SACW), which is transported offshore by the Brazil Current. This study examined the temporal contrasts in abundance and structure of pelagic copepod assemblages in a neritic station off Ubatuba, in relation to hydrography and phytoplankton biomass, to investigate the effects of SACW bottom intrusions on copepod population dynamics during three consecutive years. The water‐column characteristics shifted from a well‐mixed, more turbid and phytoplankton‐poor scenario during subsidence conditions to a stratified, less turbid and high Chl‐a concentration scenario during SACW bottom intrusions, leading to increased copepod diversity, abundance, and biomass. The rise in copepod diversity during SACW intrusions was related to the contribution of oceanic species in addition to coastal water species. The copepod community was numerically dominated by small‐sized species, such as Oncaea waldemari, Oithona plumifera, and clausocalanid and paracalanid copepodids, regardless of seasonality and SACW intrusions. Some large calanoid species contributed considerably to the total copepod biomass during intrusions. In addition to confirming that SACW seasonal intrusions play a key role in pelagic processes off Southeast Brazil, this study showed that the multiannual variability of SACW seasonal intrusions is important in regulating the structure and dynamics of copepod communities in this subtropical area.  相似文献   

Reconstruction of itineraries from annotated text with an informed spanning tree algorithm     

Ludovic Moncla  Mauro Gaio  Javier Nogueras-Iso  Sébastien Mustière 《International journal of geographical information science》2016,30(6):1137-1160

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Metal fluxes to the sediments of the northern Venice Lagoon     

Mauro Frignani  Luca G. Bellucci  Leonardo Langone  Herbert Muntau 《Marine Chemistry》1997,58(3-4)

Eighteen short cores were analyzed for major and trace metals (Al, Fe, Ca, Mg, Mn, Si, K, Ti, Pb, Zn, Cu, Ni, Cr), ²¹⁰Pb, ¹³⁷Cs, and other sediment characteristics, so as to describe the chronology of pollution and calculate metal concentration factors and fluxes. Substantial evidence was found that trace metal profiles are influenced by anthropogenic sources and by changes in sediment composition. Only Zn presents concentrations (up to 13.1 μmol g⁻) and concentration factors (1.3 to 13.2) that can be attributed to heavy contamination. Pb, Cu and Ni, in this order, are less significant. The areal distribution of concentrations and inventories reflects the importance of direct sources, in particular the industrial area of Porto Marghera and the Dese river. The inventories of excess metals, above pre-industrial levels, were determined for each core and the three different parts of the study area, the amounts of Zn accumulated in sediments are 11.0 Mmol, 5.1 Mmol and 0.37 Mmol in the Campalto, S. Erasmo, and Palude di Cona areas, respectively. Ruxes were also calculated and compared with those suggested for the atmospheric delivery by Cochran et al. [(1995)b. Atmospheric fluxes of heavy metal contaminants to the Venice Lagoon, Rapp. Comm. Int. Mer Médit., 34, 136.], the atmospheric contribution is predominant or significant in many cases, especially at sites far from the major local inputs. Concentrations and fluxes show a significant increase in the anthropogenic metal supply starting from the second decade of this century, with maximum inputs in the period between the (1930)s and the (1970)s. At some stations a decrease in heavy metal contamination of surficial sediments was found and this could be ascribed to a reduced input of pollutants in recent years.  相似文献   

Decadal Climatic Anomalies in the Northern Adriatic Sea Inferred from a New Oceanographic Data Set   总被引：1，自引：0，他引：1  

Aniello Russo  Sandro Rabitti  Mauro Bastianini 《Marine Ecology》2002,23(S1):340-351

Abstract. In 1997, Artegiani et al. depicted for the first time the seasonal climatology of the Adriatic Sea; they used the ATOS data set, formed by 5540 oceanographic stations sampled over this continental basin from 1911 to 1980. Lately, two Italian institutes working on the Adriatic Sea for long time, IBM and IRPEM, merged their recent data sets for the northernmost part of the basin. This yielded 3600 new oceanographic stations, concentrated in an area where 809 ATOS stations were located. The new data were quality checked, and then a seasonal climatology was drawn up as a first analysis step. The new climatology differed significantly from the ATOS results; this could be explained, at least partially, by the climatic changes that have occurred on this area. For example, air temperature increased significantly over northern Italy starting from 1988. Variations of the observed air temperature and Po River runoff qualitatively agree with sea surface temperature and salinity variations. A preliminary computation of heat fluxes based on ECMWF reanalysis confirms an increased heat flux to the Northern Adriatic Sea starting from 1988.  相似文献   

Bioaccumulation and depuration of Zn and Cd in mangrove oysters (Crassostrea rhizophorae, Guilding, 1828) transplanted to and from a contaminated tropical coastal lagoon   总被引：2，自引：0，他引：2  

Rebouças do Amaral MC  de Freitas Rebelo M  Torres JP  Pfeiffer WC 《Marine environmental research》2005,59(4):277-285

In order to study Zn and Cd accumulation and depuration, a set of oysters, Crassostrea rhizophorae, were transplanted to a metal contaminated coastal lagoon and another one was harvested there and transplanted to a non-polluted site. C. rhizophorae oysters and Perna perna mussels native from both sites were collected in order to monitor variability of metal concentration in resident populations. After three months exposure, oysters transplanted to the polluted site accumulated fourfold Zn (307-1319 microgg(-1)) without reaching the concentration level of resident oysters (9770 microgg(-1)). Cadmium concentrations had a slight but significant decrease during the same period (1.25-0.54 microgg(-1)). Oysters transplanted to the non-polluted site, showed threefold Zn depuration (6727-2404 microgg(-1)), while Cd had no significant variation (0.90-1.45 microgg(-1)). Results showed that transplanted oysters do not reach heavy metal concentrations in indigenous populations suggesting transplanted organisms would be better used to evaluate bioavailability instead of environmental concentrations.  相似文献   

Meiofauna of the deep Eastern Mediterranean Sea: distribution and abundance in relation to bacterial biomass, organic matter composition and other environmental factors     

Roberto Danovaro  Norberto Della Croce  Anastasios Eleftheriou  Mauro Fabiano  Nadia Papadopoulou  Chris Smith  Anastasios Tselepides 《Progress in Oceanography》1995,36(4)

Quantitative information on the abundance and biomass of metazoan meiofauna was obtained from samples collected at 15 deep-sea stations in the Eastern Mediterranean Sea (533–2400m). Meiofaunal abundance was compared to bacterial biomass and other environmental factors such as the total sedimentary organic matter content, the concentrations of the main biochemical classes of organic compounds (i.e. proteins, carbohydrates and lipids) and to ATP. To estimate the sedimentation potential of primary organic matter, sediment bound chloroplastic pigment equivalents (CPE) were assayed. Meiofaunal density was very low ranging from 4 ind.10cm⁻² (Station A4, 1658m depth) to 290 ind.10cm⁻² (Station A12, 636m depth). Nematodes were the numerically dominant taxon (68% of total meiofauna) and were usually confined to the top 6cm of the sediments. Total meiofaunal biomass ranged from 2.78μgC 10cm⁻² (Station A4) to 598.34μgC 10cm⁻² (Station 15A). There was a significant decrease in the density of metazoan meiofauna with water depth. Bacterial biomass largely dominated the total biomass (as the sum of bacterial and meiofaunal biomass) with an average of 73.2% and accounted for 35.8% of the living biomass (as ATP carbon) whereas meiofaunal biomass accounted only for 6.56%. Bacterial biomass was significantly related to the DNA concentrations of the sediment. A significant correlation between ATP concentration and CPE content was also found. No correlations were found between meiofauna, ATP and CPE, or between meiofauna and bacterial parameters. The significant relationship between meiofaunal density and the ratio of labile organic matter/total organic matter indicates that deep-sea meiofauna inhabiting an extremely oligotrophic environment (such as the Eastern Mediterranean) may be more nutritionally dependent upon the quality than on the quantity of sedimentary organic matter.  相似文献   

Comparison of different methods describing the peak runoff contributing areas during floods          下载免费PDF全文

Andrea Gioia  Vito Iacobellis  Salvatore Manfreda  Mauro Fiorentino 《水文研究》2017,31(11):2041-2049

In the last few years, the scientific community has developed several hydrological models aimed at the simulation of hydrological processes acting at the basin scale. In this context, the portion of peak runoff contributing areas represents a critical variable for a correct estimate of surface runoff. Such areas are strongly influenced by the saturated portion of a river basin (influenced by antecedent conditions) but may also evolve during a specific rainfall event. In the recent years, we have developed 2 theoretically derived probability distributions that attempt to interpret these 2 processes adopting daily runoff and flood‐peak time series. The probability density functions (PDFs) obtained by these 2 schematisations were compared for humid river basins in southern Italy. Results highlighted that the PDFs of the peak runoff contributing areas can be interpreted by a gamma distribution and that the PDF of the relative saturated area provides a good interpretation of such process that can be used for flood prediction.  相似文献