Study on the fate of petroleum-derived polycyclic aromatic hydrocarbons (PAHs) and the effect of chemical dispersant using an enclosed ecosystem,mesocosm     

Yamada M  Takada H  Toyoda K  Yoshida A  Shibata A  Nomura H  Wada M  Nishimura M  Okamoto K  Ohwada K 《Marine pollution bulletin》2003,47(1-6):105-113

Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant.  相似文献   

Double-planed deep seismic zone and upper-mantle structure in the Northeastern Japan Arc   总被引：6，自引：0，他引：6  

Akira Hasegawa  Norihito Umino  Akio Takagi 《Geophysical Journal International》1978,54(2):281-296

Summary. The ScSp wave converted from the ScS wave at the boundary between the descending lithospheric slab and the mantle above it was clearly observed from a nearby deep earthquake with magnitude 7.7 at some stations of the seismic network of Tohoku University which covers the Tohoku District, the northeastern part of Honshu, Japan. By applying the three-dimensional seismic-ray tracing method, the location of this boundary was determined from the difference in arrival time between the ScS and ScSp waves. The result shows that the upper boundary of the descending slab lies exactly on the upper plane of the double-planed deep seismic zone found in the Northeastern Japan Arc.
There is an additional evidence that the boundary is located on the upper plane of the double-planed deep seismic zone. The hypocentre distribution of intermediate-depth earthquakes located by the small-scale seismic-array observation is extremely different from that obtained by the relatively large-scale seismic network. The discrepancy in the distribution of hypocentres of the same earthquake independently located is well explained by the inclined lithospheric slab model derived from the difference in arrival time between the ScS and ScSp waves.
The earthquakes with reverse faulting or with down-dip compressional stresses occur at the upper boundary of the descending slab. Within the descending slab, the earthquakes with down-dip extensional stresses also occur in a very narrow zone from 30 to 40 km below the dipping boundary in the depth range from 50 to about 200 km, and these shocks form the lower plane of the double-planed deep seismic zone.  相似文献   

Noble gas elemental and isotopic abundances in deep-sea trenches in the western Pacific     

George Igarashi  Masako Kodera  Minoru Ozima  Yuji Sano  Hiroshi Wakita  Jacques Boulgue 《Earth and Planetary Science Letters》1987,86(1)

Noble gas elemental and isotopic abundances were measured in seven deep-sea water samples from five different sampling sites in the Nankai Trough, the Japan Trench and the Kuril Trench. The samples were obtained by the manned submersible “Nautile”. Most of the sampling sites are associated with clam colonies and/or fluid venting. Excesses both in³He/⁴He ratio and He concentration are observed in a seawater sample collected a few kilometers off the clam colonies which were found at a depth of 3830 m at the mouth of the Tenryu Canyon. Concentrations of noble gases (Ne, Ar, Kr and Xe) in this sample show progressive depletion from Ne to Xe relative to those in 1°C air-saturated seawater, which can be attributed to mixing of hot water ( 15°C) with cold ambient water ( 1°C). Isotopic compositions of Ne, Ar, Kr and Xe in this sample are atmospheric. These observations may reflect venting of hot pore water around the Tenryu Canyon. All the other samples show a significant excess in concentration of all noble gases relative to 1°C air-saturated seawater and the isotopic compositions are atmospheric. This excess of noble gas concentrations may appear to be air contamination in the samples. However, results of hydrocarbon analyses of the Kaiko samples imply that such large amount of air contamination is improbable. Decomposition of gas hydrate in deep-sea sediments is a more likely explanation for the observed excess of noble gas concentration.  相似文献   

Nature of volcanic gases and volcanic eruption     

Iwaji Iwasaki  Takejiro Ozawa  Minoru Yoshida  Takashi Katsura  Bunji Iwasaki  Masaakira Kamada 《Bulletin of Volcanology》1963,26(1):73-81

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Uranium isotopes in the Greenland ice-sheet     

Minoru Koide  Edward D. Goldberg 《Earth and Planetary Science Letters》1983,65(2):245-248

The²³⁴U/²³⁸U activity ratio was measured in dated strata of the Dye-3 Greenland ice-sheet. Values were generally less than unity indicating a source in weathered crustal rock debris. Three levels showed elevated ratios which are attributed to entry of debris from the aborted Russian satellite Cosmos 954 following residence in the stratosphere.  相似文献   

Characteristics of vertical land movement and microearthquake activity in the northeastern Japan arc     

Hiroshi Ishii  Yoichiro Komukai  Akio Takagi 《Tectonophysics》1981,77(3-4)

Methods have been devised for analyzing vertical land movement and seismicity data using two-dimensional Chebychev functions and oblique projections. A filtering operation in the space domain is made possible by use of a two-dimensional Chebychev function. The oblique projections give an intuitive understanding of land deformation. Characteristic aspects of vertical land movement obtained by precise levelling and of the energy release of microearthquakes with depths shallower than 20 km in the northeastern Japan arc were investigated in detail applying these methods.Lineations with wavelength of about 20–60km trending towards NE—SW were found for both the land deformation and the seismicity. It should be noted that this trend is almost perpendicular to the direction of the strain migration and is related to other geophysical information.  相似文献   

Comparison of carbon cycle between the western Pacific subarctic and subtropical time-series stations: highlights of the K2S1 project     

Makio C. Honda  Masahide Wakita  Kazuhiko Matsumoto  Tetsuichi Fujiki  Eko Siswanto  Kosei Sasaoka  Hajime Kawakami  Yoshihisa Mino  Chiho Sukigara  Minoru Kitamura  Yoshikazu Sasai  Sherwood L. Smith  Taketo Hashioka  Chisato Yoshikawa  Katsunori Kimoto  Shuichi Watanabe  Toru Kobari  Toshi Nagata  Koji Hamasaki  Ryo Kaneko  Mario Uchimiya  Hideki Fukuda  Osamu Abe  Toshiro Saino 《Journal of Oceanography》2017,73(5):647-667

A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms.  相似文献