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71.
Microscopic melt inclusions found in magmatic minerals are undoubtedly one of the most important sources of information on the chemical composition of melts. This paper reports on the successful application of near-infrared (NIR) femtosecond laser ablation (LA) - inductively coupled plasma-mass spectrometry to in situ determination of incompatible trace elements (Li, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Ta, Th, U) and ore metals (As, Mo, Pb) in individual melt inclusions hosted in quartz from the Mount Pinatubo dacites, Philippines. The determined elements cover a concentration range of five orders of magnitude. Femtosecond LA-ICP-MS analyses of twenty-eight individual melt inclusions demonstrate the efficiency of the microanalytical technique and suggests a spectacular homogeneity of the entrapped melt, at least with respect to the following incompatible trace elements: Rb, Sr, Nb, Cs, Ba, La, Ce, Pr, Nd, Pb, Th. The analytical precision (1s) for Na, Ca, Rb, Sr, Y, Nb, Ba and LREE ranged from 3 to 20%. Comparison of trace element concentrations in Mt. Pinatubo melt inclusions determined by femtosecond LA-ICP-MS with those of melt inclusions previously analysed by secondary ion mass spectrometry analysis (SIMS) and those of matrix glasses previously determined by nanosecond LA-ICP-MS showed an agreement typically within 30–40%. The homogeneity of trace element concentrations of the Mt. Pinatubo melt inclusions and the matrix glasses is consistent with the melt inclusion origin as homogeneous rhyolitic melt that was trapped in quartz phenocrysts at the final crystallisation stages of the host adakite (dacite) magma.  相似文献   
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The reducing emissions from deforestation and forest degradation (REDD+) initiative has emerged in recent years as a mechanism to simultaneously address climate change, biodiversity, and poverty reduction challenges at the margins of tropical forests. Congo Basin countries, including Cameroon, have embraced the opportunities that REDD+ provides, with great expectations. Yet, it needs to be investigated whether the enabling institutional environment, which is required for implementing REDD+, is present. Understanding is still limited on how to build adequate and strong institutional relations that could shape the reforms towards the establishment of efficient emissions reductions schemes. Furthermore, uncertainty remains on the operational mechanisms of REDD+, suggesting that, to catalyse effectiveness, there is a need to come up with a governance model nested in relevant policy frameworks. This study builds on a modified ‘4Is’ framework – Institutions, Interests, Ideas and Information – to analyse REDD+ and explore stakeholders' perceptions on the local forest governance potential. A structural implementation model to optimize the effectiveness of REDD+ is developed. Findings suggest that governments need to review existing policies to take into account participation, local people rights, and information access as a way to stimulate actors' willingness to contribute to emissions reductions and carbon stock increases under REDD+ regimes.  相似文献   
74.
From a large collection of Ethiopian flood basalts (~30  Myr old) sampled for magnetostratigraphy, 40Ar/39Ar geochronology and geochemical investigations, 47 samples were selected in order to test their suitability for Thellier palaeointensity experiments. Only 17 samples from eight individual flows yielded reliable palaeointensity estimates, with flow-mean virtual dipole moments ranging from 3.0 to 10.5 × 1022  A  m2 .
  A critical review of the Oligocene palaeointensity data set, including these new Ethiopian data, indicates an Oligocene mean virtual dipole moment of 5.1 ± 2.5 × 1022  A  m2 for the complete data set. After applying mild selection criteria, the reduced data set yields a mean value of only 4.6 ± 1.9 × 1022  A  m2 . This value is significantly lower than the present-day field strength but is higher than the Mesozoic dipole low mean field. This low Oligocene field might be in agreement with the high palaeosecular variation and rather high non-dipole field invoked around 30  Ma. However, the Oligocene data set is largely dependent on the palaeointensity determinations from Armenia, obtained mainly from baked contacts, which show amazingly low dispersion at both flow and between-flow levels. More data are needed to reduce the weight of these determinations on the mean value and avoid a possible bias.  相似文献   
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