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91.
Predicted allowed and forbidden EUV line intensities of Fe xv and Ni xvii are presented in explicit graphical form, clarifying and extending the earlier treatment of Bely and Blaha (1968). In the case of the former ion a detailed comparison with available observations leads to questioning or rejection of some presently accepted line identifications (323.57 Å, 317.61 Å), and on the other hand suggests that a quiet Sun line at 304.853 Å is due to Fe xv. For the little known ion Ni xvii estimates of level structure and line wavelengths are given and a preliminary comparison is made with recent flare observations.  相似文献   
92.
Hydrothermal sulfide-sulfate deposits were sampled from eight active and inactive vent sites along the East Pacific Rise at 21°N during the RISE expedition of April, 1979. The mineralogy of the samples has been determined by X-ray diffractometry, scanning electron microscopy, and X-ray energy dispersive analysis. Mounds of Zn, Fe, and Cu sulfides, dominated by sphalerite, pyrite, and lesser chalcopyrite, are topped by inactive and active chimneys, spouting fluids ≤350°C. The outer zones of active chimneys bear abundant anhydrite precipitated from heated ambient seawater, in addition to hydrothermal pyrite and sphalerite. Mg-hydroxysulfate-hydrate, a phase identified in seawater heating experiments, but previously not observed in nature, is intimately intergrown with anhydrite. Hottest chimneys contain massive chalcopyrite±bornite in their interior zones and belch fluids blackened by a presumably non-equilibrium assemblage of pyrrhotite plus minor sphalerite and pyrite. The early, outer walls of chimneys form from sulfates and the sulfide minerals in black smoke, but metastable pyrrhotite in outer zones is rapidly recrystallized to pyrite or marcasite. Reduction in the permeability of the outer walls permits a high-temperature (>~250°C), low-pH environment within chimneys that enhances precipitation of Cu-Fe sulfides in the central zones. Cooler, worm-covered chimneys emit white fluids bearing particulates of amorphous silica, barite, and pyrite. Amorphous silica and barite are also widely associated with fossilized worm-tubes. Two inactive chimneys are filled with sphalerite, wurtzite, sulfur, pyrite, and marcasite. Anhydrite has been dissolved from these dead chimneys, and the sulfate assemblage is dominated by barite and alteration products such as jarosite and natrojarosite. Silicates other than amorphous silica are not abundant in these deposits, although talc forms in hot chimneys from seawater Mg and hydrothermal silica, and nontronite is found in sediments on the crest of the East Pacific Rise. Other accessory phases identified include copper-rich sulfides such as cubanite, chalcocite, covellite, and digenite; galena; Fe-oxyhydroxides, including goethite; and gypsum. Chimney debris accumulates to form basal mounds, and the mineralogical differences between mounds and chimneys are attributable to weathering of mounds. Mn-oxyhydroxides form crusts within a few meters of the vents, but are not coprecipitating with the sulfide/sulfate minerals.  相似文献   
93.
The broad range of time over which ribbon bedded cherts were deposited does not extend into the present marine environment, and no ribbon cherts have been recovered from the sea floor by the Deep Sea Drilling Project. The depositional environment of bedded cherts is difficult to determine, but extra-silicic impurities in the rock may offer clues about the provenance of the non-biogenic component. To test the usefulness of relative abundances of the extra silicic components in extracting information on the depositional environment of the chert, I analyzed the major element chemistry of chert samples from a broad range of environments including ophiolite-associated chert from the Franciscan Formation of California, deep-sea chert and porcellanite from the northwest Pacific (DSDP Leg 32), shallow pelagic shelf chert nodules from the Chalk of Britain, continental marginal basin chert from the Monterey Formation of California, and continental marginal basin chert from the Pindos Zone of Greece. The ratios FeO/A12O3, TiO2/A12O3 and A1/A1+Fe+Mn were considered in detail. The interpretative logic is simple but empirically supported by observations of these ratio values at different depositional environments in the Pacific: A1 is concentrated most highly in continental material while Fe and Mn are more concentrated in pelagic sediments. FeO/A12O3 can be used to differentiate between ophiolite associated chert and chert associated only with other sediments. TiO2/A12O3 is not a useful indicator, possibly because of the equalizing effect of widespread eolian transport. The A1/A1+Fe+Mn ratio was measured in detail in one stratigraphic section in central continental Greece. This ratio varied with the type of sediment admixture, decreasing in value after the influx of ophiolite debris-bearing sediments, even when their presence was undetectable in hand sample or under petrographic microscope.To help clarify the paleogeography of the main study area, the Pindos Zone, and to identify sources and dispersal patterns of extra-basinal materials, isopach maps of sedimentary facies of the Pindos were constructed. Superimposed directly upon the series of imbricated thrust slices that comprise the Pindos Zone, the maps are at best compressed pictures of the Pindos Sea Floor. Persistent regional variation of facies thicknesses over time suggests the existence of several smaller depressions surrounded by submarine highs in the Pindos Basin.  相似文献   
94.
Deep Sea Drilling Hole 245 (31°32′S, 52° 18′E) in the southwest Indian Ocean shows pronounced linear concentration-depth gradients in interstitial dissolved Ca, Mg and Sr. Electrical conductivity tests enable us to make the estimate of a constant diffusion coefficient with depth of about 2 × 10?6 cm2/sec. The shapes of the concentration-depth gradients suggest that the major reaction sites in this hole are situated in the basal sediments and/or underlying basalts. It is proposed that observed interstitial water concentration changes in Ca and Mg are related to alteration of basaltic material, whereas those in Sr are due to calcium carbonate recrystallization processes. Support for the basaltic material alteration hypothesis comes from petrochemical and mineralogical data. Geochemical data also indicate that the high contents in Fe and Mn of the basal sediments can be related to low temperature alteration of basaltic glass and not necessarily to ‘hydrothermal’ activity.  相似文献   
95.
Some line identifications in solar disk and limb spectra are proposed on the basis of recent laboratory and theoretical results reported in the literature, including allowed lines of Mgi and Fexiv in the EUV spectrum and an expected forbidden line of Fexvii near 1190 Å.  相似文献   
96.
Oscillator strengths are calculated for resonance lines of some silicon and sulfur ions, which are present in the solar spectrum from about 160 Å to 380 Å. Spin-spin and spin-other orbit interactions are included. A comparison is made with Garstang's results for Six; agreement is good.  相似文献   
97.
The complex brecciation and shock history of amphoterite (LL-) chondrites is well reflected in their diverse natural magnetic remanence (NRM) behavior: Most LL-chondrites have a multicomponent, undemagnetizable NRM, analogous to that of lunar breccias. Only one meteorite among those studied, namely Dhurmsala (LL6), meets the criteria of NRM stability and directional coherence with progressive AF cleaning, indicative of a useful paleoremanence. Ancient field paleointensity determinations for Dhurmsala (LL6) of 0.03 and 0.1 Oe, agree well with our earlier estimates of 0.01 and 0.08 Oe for the LL6 Jelica and Vavilovka, respectively. In light of their petrographic structure, cooling rates, radiometric ages and shock indicators, it appears likely that the NRM may have been thermally imprinted, during cooling following shock-metamorphism. The closely similar saturation remanence (IRMs) behavior for LL-chondrites, in contrast to the intragroup scatter in NRM characteristics, implies that - although formed by similar process from the same starting material, - the LL-chondrites have suffered widely different degrees of shock/metamorphic reheating.  相似文献   
98.
In Northern Hemisphere deglaciation records, the transition from the last glacial to the Holocene indicates a rapid return to near-glacial conditions during the Younger Dryas, whereas their Southern Hemisphere ice core counterparts record two separate cooling events: the Antarctic Cold Reversal and the Oceanic Cold Reversal. Spatial distribution and relative timing of these events in both hemispheres are central for our understanding of causes and mechanisms of abrupt climate change. To date, no marine record from the southern mid-latitudes conclusively demonstrates that the Younger Dryas was a significant event in the Southern Ocean. Here, we present high-resolution oxygen isotope and iron content records of a radiocarbon-dated sedimentary sequence from the Great Australian Bight, which constrains oceanic and atmospheric changes during the last deglaciation. Oxygen isotopes from planktonic foraminifera indicate two rapid cold reversals (between 13.1 and 11.1 kyr BP) separated by a brief warming. The sedimentary iron content, interpreted as a proxy for wind strength, indicates a simultaneous change in atmospheric circulation pattern. Both records demonstrate the existence of cooling events in the Southern Hemisphere, which are synchronous with the Northern Hemisphere Younger Dryas cold reversal (between 12.9 and 11.5 kyr BP). Such evidence for the spatial distribution and timing of abrupt climatic fluctuations is essential data for groundtruthing results derived from global climate models.  相似文献   
99.
Mangroves are sensitive ecosystems of prominent ecological value that lamentably have lost much of their areas across the world. The vulnerability of mangroves grown in proximity to cities requires the development of new technologies for the remediation of acute oil spills and chronic contaminations. Studies on oil remediation are usually performed with in vitro microcosms whereas in situ experiments are rare. The aim of this work was to evaluate oil degradation on mangrove ecosystems using in situ microcosms seeded with an indigenous hydrocarbonoclastic bacterial consortium (HBC). Although the potential degradation of oil through HBC has been reported, their seeding directly on the sediment did not stimulate oil degradation during the experimental period. This is probably due to the availability of carbon sources that are easier to degrade than petroleum hydrocarbons. Our results emphasize the fragility of mangrove ecosystems during accidental oil spills and also the need for more efficient technologies for their remediation.  相似文献   
100.
Litter layers develop across a diverse array of vegetated ecosystems and undergo significant temporal compositional changes due to canopy phenological phases and disturbances. Past research on temporal dynamics of litter interception has focused primarily on litter thickness and leaf fall, yet forest phenophases can change many more litter attributes (e.g., woody debris, bark shedding, and release of reproductive materials). In this study, weekly changes in litter composition over 1 year were used to estimate litter water storage dynamics and model event‐based litter interception. Litter interception substantially reduced throughfall (6–43%), and litter water storage capacity ranged from 1 to 3 mm, peaking when megastrobili release and liana leaf senescence occurred simultaneously during fall 2015. Tropical storm disturbances occurred during the sampling period, allowing evaluation of how meteorological disturbances altered litter interception. High wind speeds and intense rainfall from 2 tropical storms increased litter interception by introducing new woody debris, which, in this study, stored more water than the pre‐existing woody debris. After 2 extreme weather events, a third (Hurricane Hermine) did not increase woody debris (or litter interception), suggesting that the canopy pool of branches susceptible to breakage had been largely depleted. Needle and bark shedding had minor effects on litter interception. Results suggest that the release of reproductive materials and meteorological disturbances appear to be the major compositional drivers of litter interception beyond their obvious contribution to litter thickness.  相似文献   
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