Simultaneous use of geochemical and geophysical methods to characterise abandoned landfills     

José F. Noguera  Lluís Rivero  Xavier Font  Andrés Navarro  Francisco Martínez 《Environmental Geology》2002,41(8):898-905

. Groundwater sampling and geophysical methods determined a serious contamination problem associated with refilled exploitation sites at the Cal Dimoni area, Llobregat delta, Barcelona, Spain. To characterise this process, hydrogeochemical analyses were performed and showed the following modifications to groundwater chemical composition: increasing pH values, changing redox conditions, significant increases in total organic carbon (TOC) and certain trace elements, and high groundwater conductivity values. Major ion content accumulations were found under the refilled area. In contrast, elements involved in the oxidation–reduction processes, such as iron, manganese and nitrates, clearly diminished. Electromagnetic prospecting methods were also performed and delineated the contamination plume extent. These methods also showed separate sources of contamination, one clearly related to the groundwater–refilled zone leachate interaction, another as a consequence of the manure–accumulation surface site. Geochemical and geophysical methods have shown similar results for locating groundwater contamination sources, and for determining leachate generation mechanisms and flow paths.  相似文献   

The fall and rise of metropolitan government in Copenhagen     

Hans Thor Andersen  Frank Hansen  John Jørgensen 《GeoJournal》2002,58(1):43-52

In this paper it is argued that the re-establishment of a metropolitan government in the Greater Copenhagen Area in 2000 (Greater Copenhagen Authority) is not to be seen as a return to the kind of regional, coordinative authority (Greater Copenhagen Council) that was abolished in the Thatcherite climate of the 1980s. Throughout the 1980s and 1990s new forms of urban governance, entrepreneurialism and a higher national priority to the capital region were introduced, which changed the conditions under which the new metropolitan government is operating. This `contextualization' of the analysis of the two generations of metropolitan government points to the fact that typologies of metropolitan government, such as the one put forward by Sharpe (1995), often lacks analytical cogency. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Electrons in feldspar II: a consideration of the influence of conduction band-tail states on luminescence processes     

N. R. J. Poolton  K. B. Ozanyan  J. Wallinga  A. S. Murray  L. Bøtter-Jensen 《Physics and Chemistry of Minerals》2002,29(3):217-225

 Most natural feldspars contain many charged impurities, and display a range of bond angles, distributed about the ideal. These effects can lead to complications in the structure of the conduction band, giving rise to a tail of energy states (below the high-mobility conduction band) through which electrons can travel, but with reduced mobility: transport through these states is expected to be thermally activated. The purpose of this article is twofold. Firstly, we consider what kind of lattice perturbations could give rise to both localized and extended conduction band-tail states. Secondly, we consider what influence the band tails have on the luminescence properties of feldspar, where electrons travel through the sample prior to recombination. The work highlights the dominant role that 0.04–0.05-eV phonons play in both the luminescence excitation and emission processes of these materials. It also has relevance in the dating of feldspar sediments at elevated temperatures. Received: 11 May 2001 / Accepted: 6 September 2001  相似文献   

Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

Comparison of isotope pairing and N2:Ar methods for measuring sediment denitrification—Assumption, modifications, and implications     

Bradley D. Eyre  Søren Rysgaard  Tage Dalsgaard  Peter Bondo Christensen 《Estuaries and Coasts》2002,25(6):1077-1087

Denitrification has been measured during the last few years using two different methods in particular: isotope pairing measured on a triple-collector isotopic ratio mass spectrometer and N₂:Ar ratios measured on a membrane inlet mass spectrometer (MIMS). This study compares these two techniques in short-term batch experiments. Rates obtained using the original N₂∶Ar method were up to 3 to 4 times higher than rates obtained using the isotope pairing technique due to O₂ reacting with the N₂ during MIMS analysis. Oxygen combines with N₂ within the mass spectrometer ion source forming NO⁺ which reduces the N₂ concentration. The decrease in N₂ is least at lower O₂ concentrations and since oxygen is typically consumed during incubations of sediment cores, the result is often a pseudo-increase in N₂ concentration being interpreted as denitrification activity. The magnitude of this ocygen effect may be instrument specific. The reaction of O₂ with N₂ and the subsequent decrease in N₂ was only partly correctly using an O₂ correction curve for the relationship between N₂ and O₂ concentrations. The O₂ corrected N₂∶Ar denitrification rates were lower, but still did not match the isotope pairing rates and the variability between replicates was much higher. Using a copper reduction column heated to 600°C to remove all of the O₂ from the sample before MIMS analysis resulted in comparable rates (slightly lower), and comparable variability between replicates, to the isotope pairing technique. The N₂:Ar technique determines the net N₂ production as the difference between N₂ production by denitrification and N₂ consumption by N-fixation, while N-fixation has little effect on the isotope pairing technique which determines a rate very close to the gross N₂ production. When the two different techniques were applied on the same sediment, the small difference in rates obtained by the two methods seemed to reflect N-fixation as also supported from measurements of ethylene production in acetylene enriched sediment cores. The N₂:Ar and isotope pairing techniques may be combined to provide simultaneous measurements of denitrification and N-fixation. Both techniques have several assumptions that must be met to achieve accurate rates; a number of tests are outlined that can be applied to demonstrate that these assumptions are being meet.  相似文献   

Phytoplankton, nutrients, and transparency in Danish coastal waters     

Søren Laurentius Nielsen  Kaj Sand-Jensen  Jens Borum  Ole Geertz-Hansen 《Estuaries and Coasts》2002,25(5):930-937

We present a comparative analysis of 1400 data series of water chemistry (particularly nitrogen and phosphorus concentrations), phytoplankton biomass as chlorophylla (chla) concentrations, concentrations of suspended matter and Secchi depth transparency collected from the mid-1980s to the mid-1990s from 162 stations in 27 Danish fjords and coastal waters. The results demonstrate that Danish coastal waters were heavily eutrophied and had high particle concentrations and turbid waters. Median values were 5.1 μg chla 1⁻¹, 10.0 mg DW 1⁻¹ of suspended particles, and Secchi depth of 3.6 m. Chlorophyll concentration was strongly linked to the total-nitrogen concentration. The strength of this relationship increased from spring to summer as the concentration of total nitrogen declined. During summer, total nitrogen concentrations accounted for about 60% of the variability in chlorophyll concentrations among the different coastal systems. The relationship between chlorophyll and total phosphorus was more consistant over the year and correlations were much weaker than encountered for total nitrogen. Secchi depth could be predicted with good precision from measurements of chlorophyll and suspended matter. In a multiple stepwise regression model with In-transformed values the two variables accounted for most of the variability in water transparency for the different seasons and the period March–October as a whole (c. 80%). We were able to demonstrate a significant relationship between total nitrogen and Secchi depth, with important implications for management purposes.  相似文献   

Mesoscale transport of air pollution     

Jørgen Brandt  Torben Mikkelsen 《Physics and Chemistry of the Earth》2002,27(35):1467

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The importance of a small wall deformation in the three-dimensional acoustic logging results   总被引：1，自引：0，他引：1  

Luís Godinho  António Tadeu 《Geophysical Journal International》2002,151(2):403-415

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Sea cliffs resulting from late Miocene extensional tectonics: the Serra Gelada case study (Betic Cordillera, Spain)     

Alfonso Ybenes  Pedro Alfaro  Jos Delgado  Antonio Estvez  Jesús M. Soria 《Geomorphology》2002,42(3-4)

The Serra Gelada sea cliffs are carved in Mesozoic carbonate rocks belonging to the External Zones of the eastern Betic Cordillera (Alicante, SE Spain). Several normal faults with vertical slips of more than a hundred metres have played an important role in the origin of this coastline. Some previous studies propose that the present cliff morphology was mainly originated by Quaternary fault activity. However, the integration of geomorphological features, stratigraphical and sedimentological data, together with the results of the tectonic analysis of fractures occurring in Serra Gelada, and a detailed study of seismic reflection profiles carried out in the adjacent continental shelf, indicate that these normal faults were active mainly during the late Miocene. Therefore, the Serra Gelada sea cliffs represent a tectonically controlled long-term landscape. Thus, normal faults have not significantly modified the Serra Gelada relief since then. Furthermore, the northern part of the Serra Gelada cliff may be considered as an inherited pre-Quaternary relict palaeocliff since it has only undergone very little erosive recession.  相似文献   

Use of Noise to Augment Training Data: A Neural Network Method of Mineral–Potential Mapping in Regions of Limited Known Deposit Examples     

Warick M. Brown  Tamás D. Gedeon  David I. Groves 《Natural Resources Research》2003,12(2):141-152

One of the main factors that affects the performance of MLP neural networks trained using the backpropagation algorithm in mineral-potential mapping isthe paucity of deposit relative to barren training patterns. To overcome this problem, random noise is added to the original training patterns in order to create additional synthetic deposit training data. Experiments on the effect of the number of deposits available for training in the Kalgoorlie Terrane orogenic gold province show that both the classification performance of a trained network and the quality of the resultant prospectivity map increasesignificantly with increased numbers of deposit patterns. Experiments are conducted to determine the optimum amount of noise using both uniform and normally distributed random noise. Through the addition of noise to the original deposit training data, the number of deposit training patterns is increased from approximately 50 to 1000. The percentage of correct classifications significantly improves for the independent test set as well as for deposit patterns in the test set. For example, using ±40% uniform random noise, the test-set classification performance increases from 67.9% and 68.0% to 72.8% and 77.1% (for test-set overall and test-set deposit patterns, respectively). Indices for the quality of the resultant prospectivity map, (i.e. D/A, D × (D/A), where D is the percentage of deposits and A is the percentage of the total area for the highest prospectivity map-class, and area under an ROC curve) also increase from 8.2, 105, 0.79 to 17.9, 226, 0.87, respectively. Increasing the size of the training-stop data set results in a further increase in classification performance to 73.5%, 77.4%, 14.7, 296, 0.87 for test-set overall and test-set deposit patterns, D/A, D × (D/A), and area under the ROC curve, respectively.  相似文献