Selective Separation/Preconcentration of Silver Ion in Water by Multiwalled Carbon Nanotubes Microcolumn as a Sorbent     

Pourya Biparva  Mohammad Reza Hadjmohammadi 《洁净——土壤、空气、水》2011,39(12):1081-1086

The present paper proposes the application of multiwalled carbon nanotubes (MWCNTs) as a solid adsorbent for selective separation/preconcentration of silver(I) in water samples prior to flame atomic absorption spectrometry. The procedure is based on the solid phase extraction of Ag(I)–2‐mercaptobenzothiazole chelate on MWCNTs. The elution step is carried out with 5 mL of 2 mol L^?1 HNO₃ in acetone solution at a flow rate of 1.0 mL min^?1. The influences of the various analytical parameters including pH of the solution, eluent type, sample volume, flow rates of eluent, matrix ions were investigated for optimization of the presented procedure. Tests of addition/recovery for analyte ion in real samples were performed with satisfactory results. Preconcentration factor and limit of detection for Ag(I) were 160 and 0.21 µg L^?1, respectively. The synthesized MWCNT exhibited excellent stability in eluent solution and its adsorption capacity was 5.4 mg of silver per gram of sorbent. The proposed method was successfully applied to trace silver determination in a variety of environmental water samples.  相似文献   

Smoothing impact of isostatic crustal thickness models on local integral inversion of satellite gravity gradiometry data     

Mehdi Eshagh  Mohammad Bagherbandi 《Acta Geophysica》2011,59(5):891-906

The effects of topographic masses on satellite gradiometric data are large and in order to reduce the magnitude of these effects some compensation mechanisms should be considered. Here we use the isostatic hypotheses of Airy-Heiskanen and the recent Vening Meinesz-Moritz for compensating these effects and to smooth the data prior to their downward continuation to gravity anomaly. The second-order partial derivatives of extended Stokes’ formula are used for the continuations over a topographically rough territory like Persia. The inversions are performed and compared based on two schemes of the remove-compute-restore technique and direct downward continuation. Numerical results show that the topographic-isostatic effect based on Vening Meinesz-Mortiz’s hypothesis smoothes the data better than that based on Airy-Heiskanen’s hypothesis. Also the quality of inversions of the smoothed data by this mechanism is twice better than that of the nonsmoothed ones.  相似文献   

The Kharapeh orogenic gold deposit: geological,structural, and geochemical controls on epizonal ore formation in West Azerbaijan Province,Northwestern Iran     

Shojaeddin Niroomand  Richard J. Goldfarb  Farid Moore  Mohammad Mohajjel  Erin E. Marsh 《Mineralium Deposita》2011,46(4):409-428

The Kharapeh gold deposit is located along the northwestern margin of the Sanandaj–Sirjan Zone (SSZ) in the West Azerbaijan province, Iran. It is an epizonal orogenic gold deposit formed within the deformed zone between central Iran and the Arabian plate during the Cretaceous–Tertiary Zagros orogeny. The deposit area is underlain by Cretaceous schist and marble, as well as altered andesite and dacite dikes. Structural analysis indicates that the rocks underwent tight to isoclinal recumbent folding and were subsequently co-axially refolded to upright open folds during a second deformation. Late- to post-tectonic Cenozoic granites and granodiorites occur northeast of the deposit area. Mineralization mainly is recognized within NW-trending extensional structures as veins and breccia zones. Normal faults, intermediate dikes, and quartz veins, oriented subparallel to the axial surface of the Kharapeh antiform, indicate synchronous extension perpendicular to the fold axis during the second folding event. The gold-bearing quartz veins are >1 km in length and average about 6 m in width; breccia zones are 10–50 m in length and ≤1 m in width. Hydrothermal alteration mainly consists of silicification, sulfidation, chloritization, sericitization, and carbonatization. Paragenetic relationships indicate three distinct stages—replacement and silicification, brecciation and fracture filling, and cataclastic brecciation—with the latter two being gold-rich. Fluid inclusion data suggest mineral deposition at temperatures of at least 220–255°C and depths of at least 1.4–1.8 km, from a H₂O–CO₂±CH₄ fluid of relatively high salinity (12–14 wt.% NaCl equiv.), which may reflect metamorphism of passive margin carbonate sequences. Ore fluid δ¹⁸O values between about 7‰ and 9‰ suggest no significant meteoric water input, despite gold deposition in a relatively shallow epizonal environment. Similarities to other deposits in the SSZ suggest that the deposit formed as part of a diachronous gold event during the middle to late Tertiary throughout the SSZ and during the final stages of the Zagros orogeny. The proximity of Kharapeh to the main tectonic suture of the orogen, well-developed regional fold systems with superimposed complex fracture geometries, and recognition of nearby volcanogenic massive sulfide systems that suggest a region characterized by sulfur- and metal-rich crustal rocks, collectively indicate an area of the SSZ with high favorability for undiscovered gold resources.  相似文献   

Palaeoecology and biostratigraphy of early Cretaceous (Aptian) calcareous nannofossils and the δC_carb isotope record from NE Iran     

Azam Mahanipour  Jörg MutterloseAnoshiravan L. Kani  Mohammad Hosein Adabi 《Cretaceous Research》2011,32(3):331-356

Upper Barremian-Lower Aptian sediments of the Sarcheshmeh and Sanganeh formations in the Kopet Dagh area, northeast Iran were studied with regard to their calcareous nannofossil content and their δ¹³C_carb signal. The sediments are composed mainly of marlstones, argillaceous limestones and limestones. Based on the occurrence of biostratigraphic index taxa, the calcareous nannofossil zones NC5, NC6 and the NC7A Subzone were recognised. The calcareous nannofossils and the δ¹³C_carb data enable recognition of the early Aptian Oceanic Anoxic Event 1a (OAE 1a). The deposits of the OAE 1a interval are characterised by the rarity of nannoconids and a sharp negative δ¹³C_carb excursion (1.36‰), followed by an abrupt positive δ¹³C_carb excursion of 4-5‰; both events have been recognised elsewhere in OAE 1a deposits in the Tethys. In the OAE 1a interval, the relative abundance of Watznaueria barnesiae/Watznaueria fossacincta is higher (more than 40%) than that of Biscutum spp., Discorhabdus spp. and Zeugrhabdotus spp., which indicates dissolution. In the upper part of the section, the higher relative abundance of mesotrophic and oligotrophic taxa (Watznaueria spp. and nannoconids respectively) and the enhanced relative abundance of eutrophic taxa (Biscutum spp., Discorhabdus spp., Zeugrhabdotus spp.) is indicative of an environment with slightly increased nutrient content. The presence of warm water taxa (Rhagodiscus asper and nannoconids) and the absence of cool water taxa (Repagulum and Crucibiscutum) suggest warm surface-water conditions.  相似文献   

Investigation of meteorological extreme events over coastal regions of Iran   总被引：1，自引：0，他引：1  

Safar Marofi  Mohammad Mehdi Sohrabi  Kurosh Mohammadi  Ali Akbar Sabziparvar  Hamid Zare Abyaneh 《Theoretical and Applied Climatology》2011,103(3-4):401-412

In this study, in order to detect probable trends and effects of climatic extreme events of precipitation and temperature as well as maximum relative humidity, dew point temperature, sunshine hours, and wind speed, 12 stations on the northern and southern coastlines of Iran were investigated from 1977 to 2007. For this purpose, 27 indices of precipitation and temperature, which are specified by the Expert Team of the World Meteorological Organization and Climate Variability and Predictability, were calculated by using RClimDex software. The Mann?CKendall method was also used to detect possible trends in the data time series. The results indicate that temperature indices are absolutely consistent with warming. Warm nights, hot days, and hot day and night frequencies increased, while cold spell and cool day and night frequencies declined. The minimum temperature experienced a considerable rise both in its maximum and minimum values. The minimum temperature had a higher increase than the maximum temperature. Therefore, diurnal temperature ranges have experienced dramatic declines. In the northern coastal sites, hot day frequency and hottest day temperature showed higher magnitudes than those of the southern sites as a result of the significant increase in the maximum sunshine hours in northern stations. This enhancement led to a considerable increase in the maximum wind speed. Consequently, relative humidity declined in the northern sites. Precipitation indices indicate few significant trends over the studied period. Temporal precipitation distribution was different from station to station. Three precipitation patterns were detected at individual stations, although an overall regional rainfall pattern was not detectable. On the whole, the results of this study emphasize that the water resources in the studied area are going to become problematic.  相似文献   

Comparison of crustal thickness from two gravimetric-isostatic models and CRUST2.0     

Mohammad Bagherbandi  Lars E. Sjöberg 《Studia Geophysica et Geodaetica》2011,55(4):641-666

The Mohorovičić discontinuity is the boundary between the Earth’s crust and mantle. Several isostatic hypotheses exist for estimating the crustal thickness and density variation of the Earth’s crust from gravity anomalies.  相似文献   

Provenance, tectonics and source weathering of modern fluvial sediments of the Brahmaputra–Jamuna River, Bangladesh: Inference from geochemistry     

Mohammad Amir Hossain Bhuiyan  M. Julleh Jalalur Rahman  Samuel B. Dampare  Shigeyuki Suzuki 《Journal of Geochemical Exploration》2011,111(3):113-137

This present study describes the elemental geochemistry of fluvial sediments in the Kurigram (upstream) to Sirajganj–Tangail (downstream) section of the Brahmaputra–Jamuna River, Bangladesh, with the aim of evaluating their provenance, weathering and tectonic setting. Petrographically, the sediments are rich in quartz (68%), followed by feldspars (8.5%) and lithic grains (7%). The bulk sediment chemistry is influenced by grain size. Concentrations of TiO₂, Fe₂O₃, MgO, K₂O, P₂O₅, Rb, Nb, Cr, V, Y, and, Ce, Th and Ga slightly decrease with increasing SiO₂/Al₂O₃ and grain size, suggesting clay matrix control. In contrast, concentrations of CaO, Na₂O, Sr and Pb increase with increasing SiO₂/Al₂O₃ and grain size, suggesting residence of these substances in feldspar. Decrease in Zr as grain size increases is likely controlled both by clay matrix and heavy minerals. In addition, heavy minerals' sorting also influences Ce, Th, Y and Cr abundances in some samples. The sediments are predominantly quartzose in composition with abundant low-grade metamorphic and sedimentary lithics, low feldspars and trace volcanic detritus, indicating a quartzose recycled orogen province as a source of the sediments. Discriminant diagrams together with immobile element ratio plots show that, the Brahmaputra–Jamuna River sediments are mostly derived from rocks formed in an active continental margin. Moreover, the rare earth element ratios as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomalies indicate derivation of the sediments of Brahmaputra–Jamuna River from felsic rock sources of upper continental crust (UCC). The chemical indices of alteration suggest that Brahmaputra–Jamuna River sediments are chemically immature and experienced low chemical weathering effects. In the A–CN–K ternary diagram, most of the samples close to the plagioclase–K-feldspar join line and to the UCC plot, and in the field of various lithologies of Higher Himalayan Crystalline Series, suggesting that rocks in these series are likely source rocks. Therefore, the elemental geochemistry of the Brahmaputra–Jamuna River sediments is controlled mostly by mechanical breakdown of lithic fragments and subsequent preferential attrition of muscovite > albite > quartz.  相似文献   

Assessment of As and Cd contamination in topsoils of Northern Ghorveh (Western Iran): role of parent material, land use and soil properties     

Mohammad Tahsin Karimi Nezhad  Manijeh Ghahroudi Tali  Mohammad Hashemi Mahmoudi  Ebrahim Pazira 《Environmental Earth Sciences》2011,64(5):1203-1213

The aim of this study was to investigate the influences of land use, parent materials (rock types) and soil properties on total arsenic and cadmium concentrations in the agricultural soils. A total of 87 surface (0–20 cm) soil samples were collected from four types of land use: irrigated farming, rangeland, dry farming and orchard. The average concentrations of the analyzed elements in topsoil were 84.426 mg As/kg and 3.289 mg Cd/kg. In addition, the pH, organic matter (OM), cation exchange capacity (CEC), soil grain sizes and CaCO₃ were measured for each sample. The results indicated that land use had no significant effect on As and Cd concentrations. Our findings indicated that the Cd concentrations were influenced by bedrock composition, but for As there were no significant differences between various soil parent materials (bedrocks). Soil pollution was assessed on the basis of pollution index (PI), comprehensive pollution index (P _n ) and geoaccumulation index (I _geo). Calculated indices showed high-pollution levels for As and low- to moderate-pollution levels for Cd.  相似文献   

Using fuzzy TOPSIS method for mineral processing plant site selection     

Mohsen Safari  Reza Kakaei  Mohammad Ataei  Mohammad Karamoozian 《Arabian Journal of Geosciences》2011,5(5):1011-1019

Site selection for the mineral processing is the most important decision made by owner that has a significant impact on the efficiency of the whole process. This is a critical decision which involves considering a number of criteria and finding the best location among feasible alternatives. Therefore, a multicriteria decision-making method is necessary to apply site-selection process to find the best location that meet desired conditions set by the selection criteria. This paper presents an application of TOPSIS method based on fuzzy sets (fuzzy TOPSIS), which is one of the broader multicriteria decision making means, used to select an appropriate site for mineral processing plant for Sangan iron ore mine (phase 2). For this purpose, at first considering the geological, technical, economical, and environmental factors, three feasible alternatives were selected for the processing plant using Geographical Information System. Then, based on the technical and experimental experiences and through judgment of the decision makers and experts, 14 criteria were established and these alternatives were evaluated. Finally, the alternatives were ranked and the best location was recommended.  相似文献   

Geospatial modeling for assessing the nutrient load of a Himalayan lake   总被引：1，自引：0，他引：1  

Shakil Ahmad Romshoo  Mohammad Muslim 《Environmental Earth Sciences》2011,64(5):1269-1282

This research makes use of the remote sensing, simulation modeling and field observations to assess the non-point source pollution load of a Himalayan lake from its catchment. The lake catchment, spread over an area of about 11 km², is covered by different land cover types including wasteland (36%), rocky outcrops (30%), agriculture (12%), plantation (12.2%), horticulture (6.2%) and built-up (3.1%) The GIS-based distributed modeling approach employed relied on the use of geospatial data sets for simulating runoff, sediment, and nutrient (N and P) loadings from a watershed, given variable-size source areas, on a continuous basis using daily time steps for weather data and water balance calculations. The model simulations showed that the highest amount of nutrient loadings are observed during wet season in the month of March (905.65 kg of dissolved N, 10 kg of dissolved P, 10,386.81 kg of total N and 2,381.89 kg of total P). During the wet season, the runoff being the highest, almost all the excess soil nutrients that are trapped in the soil are easily flushed out and thus contribute to higher nutrient loading into the lake during this time period. The 11-year simulations (1994–2004) showed that the main source areas of nutrient pollution are agriculture lands and wastelands. On an average basis, the source areas generated about 3,969.66 kg/year of total nitrogen and 817.25 kg/year of total phosphorous. Nash–Sutcliffe coefficients of correlation between the daily observed and predicted nutrient load ranged in value from 0.80 to 0.91 for both nitrogen and phosphorus.  相似文献