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91.
A major plan for Portugal Mainland is being envisaged to use old open pits from abandoned uranium mining sites as “Waste Containment Deposits”. These areas will store mining waste from other adjacent mines. The old mining sites classification to this kind of usage is carried out accordingly to its location, accessibility, geological and hydrogeological conditions. Mining waste deposition in the open pits may however cause environmental problems related with geological and hydrogeological features that must be predicted and prevented before a particular site is chosen. Therefore, the identification of faults and conductive zones that may promote groundwater circulation and the spread of contaminated waters is of great importance, since the surrounding area is highly populated. The possible negative environmental impacts of the presence of such potential waste disposal sites are therefore being assessed using geophysical methods and geological outcrop studies in several geological and hydrogeological critical areas. The abandoned Quinta do Bispo uranium mine is one of such places. This old open pit, chosen as one of the sites to be used in the near future as a “Waste Containment Deposit” (accordingly to the above mentioned criteria), needs to be characterized at depth to prevent any possible negative environmental impacts. Thus, the acquisition, processing and interpretation of electromagnetic, electrical and both seismic refraction and reflection have been carried out. 2D schematic models have been constructed, showing alteration and faults zones at depth. These fault zones control groundwater circulation and therefore, future water circulation problems with negative environmental impact may be predicted and prevented.  相似文献   
92.
We relate fish biological and ecological characteristics to total and organic mercury concentrations to determine whether accumulation is influenced by trophic level, Hg concentration in the diet, and vertical distribution. Levels of total mercury and methylmercury were determined in the muscle tissue of eight species of fish: Pagellus acarne, Trachurus picturatus, Phycis phycis, P. blennoides, Polyprion americanus, Conger conger, Lepidopus caudatus and Mora moro, caught in the Azores. All such fishes are commercially valuable and were selected to include species from a wide range of vertical distributions from epipelagic (<200 m) to mesopelagic (>300 m) environments. Methylmercury was the major form accumulated in all species, comprising an average of 88.1% of total mercury. Concentrations of mercury (total and methylmercury) increased with age, length and weight. Based on data from other studies, mercury concentrations in fish diet were estimated. Mercury levels in food ranged from 0.08 to 0.32 ppm, dry weight. Hg concentrations in the food and in muscle tissue from different species were positively correlated. Total Hg levels in the muscles were approximately nine times those estimated in food. Total mercury concentrations in muscle were positively correlated with both trophic level and median depth. Such enhanced mercury bioaccumulation in relation to depth appears to be determined primarily by concentrations in food and ultimately by water chemistry, which controls mercury speciation and uptake at the base of the food chain.  相似文献   
93.
The rainfall-runoff modeling is very useful for forecasting purposes. A good methodology for forecasting the future stream flow is a key requirement for designers and operators of water resources systems. A compromise between conceptual and classical time series modeling is applied to model the relationship between rainfall and runoff. The dynamic nonlinear model is composed of a probability distribution describing the observation, a link function relating its mean to the so called state parameters and a system of equations defining the evolution of these parameters. Its Bayesian nature permits to take into account subjective information, making forward intervention, defining monitoring schemes and introducing smoothing facilities. An application using the data of Fartura river's basin is reported. The assessment of the prior distribution is discussed and the predictive performance of the linear and the non-linear models is reported.  相似文献   
94.
The chronic effects of polycyclic aromatic hydrocarbons (PAHs) on ovary development, total hepatic lipids and plasma sex- and corticosteroid levels in female flounder (Platichthys flesus) were examined. Sexually mature feral female flounder were exposed via the diet to phenanthrene (0.5, 2.5 or 12.5 nmol/g food) or chrysene (0.4 nmol/g food) for 12 weeks, during the previtellogenic phase of the annual reproductive cycle. PAH exposure did not directly affect germ cell development since no structural and/or developmental differences were observed between control and exposed fish. On the contrary, all treatments resulted in altered plasma steroid levels. The most pronounced effect was the significant decrease in plasma 17 beta-estradiol to 19 +/- 11%, 27 +/- 7%, 63 +/- 20% and 61 +/- 12% in relation to control fish, respectively, in flounders exposed to 12.5, 2.5 or 0.5 nmol phenanthrene/g food and 0.4 nmol chrysene/g food. Impaired ovarian growth was not observed, most likely because experiments were ended before the period of vitellogenesis, even though a non-significant general decline in total hepatic lipids could be observed. Moreover, all exposed flounders, except fish fed with the highest amount of phenanthrene, showed a negative correlation between plasma 17 beta-estradiol and 17 alpha-hydroxyprogesterone levels (r = -0.46). One possible explanation is that PAH action may be mediated by a specific inhibition of steroidogenic enzymes. These findings provide evidence that selected PAHs are antiestrogenic xenobiotics with the capability to impair female teleost reproductive function.  相似文献   
95.
Sepetiba Bay is located at 23 degrees S, 44 degrees W in Rio de Janeiro State, Brazil. Water samples were taken at eight locations adjacent to the north shore of the Bay, near to villages and towns without sewage treatment provision. The samples were analysed and total and faecal coliform concentrations determined. A hydrodynamic model of the Bay was used together with a species dispersion model based on an adaptive quadtree mesh to predict faecal concentrations in the Bay. Effluent sources used in the model were defined using population data from census returns with flow and concentration values estimated using standard values recommended by the World Bank (WB) and the World Health Organisation (WHO). Sufficient agreement was obtained between the measured and predicted concentrations to support the use of WB and WHO summary statistics to estimate sources of sewage.  相似文献   
96.
97.
Seismic reflection and well stratigraphic data are used to investigate the post‐Jurassic evolution of the Northern Lusitanian Basin, offshore west Iberia. Stratigraphic correlations between 11 exploration wells were attained in order to characterize the variations in depositional facies associated with salt tectonics. Latest Triassic–Hettangian salt, which generated multiple salt pillows during the Jurassic rifting, was reactivated after the early Aptian in two main phases. The first phase stretches from the late Turonian to the Maastrichtian. The second relates to Miocene tectonic inversion. The compression of the post‐salt overburden caused the amplification of Jurassic detachment folds, forming barriers to the westward progradation of sediment into distinct salt‐withdrawal sub‐basins. Particularly during the Miocene, thin‐skinned overburden shortening was accommodated by growing salt structures that suffered thrusting and extrusion. This structural style contrasts with that of salt‐scarce areas where a simple westerly tilted, fault‐bounded monocline was generated.  相似文献   
98.
Rare earth elements (REEs) are very important to technological development as well as to geochemical and environmental studies. In this work, hydrofluoric acid (HF) was replaced by condensed phosphoric acid (CPA) in the digestion of geological samples, and the quantification of REEs was performed by inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Six international reference materials (RMs), named DC86318, CGL 111, CGL 124, CGL 126, OKA‐2 and COQ‐1 and three Brazilian ore samples, named Araxá, Catalão and Pitinga were analysed. Only zircon and xenotime, which are potential REE‐bearing minerals, were not completely dissolved. Nevertheless, no REE associated with zircon was detected. The investigated digestion method presented many advantages: It was relatively fast (3 h), avoided fluoride precipitation, it was less hazardous because handling diluted H3PO4 is safer than HF, NH4F or NH4HF2 aqueous solutions, it preserved the quartz fittings of the measurement equipment and the final solution contained lower levels of total dissolved solids than those produced by the fusion method.  相似文献   
99.
The possibility of observing solar-type oscillations on other stars is of great relevance to investigating the uncertain aspects of the internal structure of stars. One of these aspects is the convective overshoot that takes place at the borders of the envelopes of stars of mass similar to, or lower than, the Sun. It affects the temperature stratification, mixing, rotation and magnetic-field generation. Asteroseismology can provide an observational test for the studies of the structure of such overshoot regions.
The seismic study of the transition in the Sun, located at the base of the convection zone, has been successful in determining the characteristics of this layer in the Sun. In this work we consider the extension of the analysis to other solar-type stars (of mass between 0.85 and 1.2 M) in order to establish a method for determining the characteristics of their convective envelopes. In particular, we hope to be able to establish seismologically that a star does indeed possess a convective envelope, to measure the size of the convective region and also to constrain the properties of an overshoot layer at the bottom of the envelope. The limitations in terms of observational uncertainties and stellar characteristics, and the detectability of an overshoot layer, are discussed.  相似文献   
100.
The Capanema Mine, an iron ore deposit, is located in the central portion of the Quadrilátero Ferrífero, State of Minas Gerais, southeastern Brazil. Mine development data from approximately 7000 drillholes were used for a comparative study between kriging variance and interpolation variance as uncertainty measurements associated with ordinary kriging estimates. As known, the traditional kriging variance does not depend on local data and, therefore, does not measure the actual dispersion of data. On the other hand, the interpolation variance measures adequately the local dispersion of data used for an ordinary kriging estimate. This paper presents an application of the concept of interpolation variance for measuring uncertainties associated with ordinary kriging estimates of Fe and silica grades. These data were selected for their distinct statistical characteristics with Fe presenting a negatively skewed distribution and, consequently, a low dispersion, and silica a positively skewed distribution and, therefore, a high variability. Comparative studies between the two uncertainty measurements associated with ordinary kriging estimates of Fe and silica proved the superiority of the interpolation variance as a reliable and precise alternative to the kriging variance.  相似文献   
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