P‐O‐rich sulfide phase in CM chondrites: Constraints on its origin on the CM parent body          下载免费PDF全文

Ai‐Cheng Zhang  Shoichi Itoh  Hisayoshi Yurimoto  Wei‐Biao Hsu  Ru‐Cheng Wang  Lawrence A. Taylor 《Meteoritics & planetary science》2016,51(1):56-69

CM chondrites are a group of primitive meteorites that have recorded the alteration history of the early solar system. We report the occurrence, chemistry, and oxygen isotopic compositions of P‐O‐rich sulfide phase in two CM chondrites (Grove Mountains [GRV] 021536 and Murchison). This P‐O‐rich sulfide is a polycrystalline aggregate of nanometer‐size grains. It occurs as isolated particles or aggregates in both CM chondrites. These grains, in the matrix and in type‐I chondrules from Murchison, were partially altered into tochilinite; however, grains enclosed by Ca‐carbonate are much less altered. This P‐O‐rich sulfide in Murchison is closely associated with magnetite, FeNi phosphide, brezinaite (Cr₃S₄), and eskolaite (Cr₂O₃). In addition to sulfur as the major component, this sulfide contains ~6.3 wt% O, ~5.4 wt% P, and minor amounts of hydrogen. Analyses of oxygen isotopes by SIMS resulted in an average δ¹⁸O value of ?22.5 ‰ and an average Δ¹⁷O value of 0.2 ± 9.2 ‰ (2σ). Limited variations in both chemical compositions and electron‐diffraction patterns imply that the P‐O‐rich sulfide may be a single phase rather than a polyphase mixture. Several features indicate that this P‐O‐rich sulfide phase formed at low temperature on the parent body, most likely through the alteration of FeNi metal (a) close association with other low‐temperature alteration products, (b) the presence of hydrogen, (c) high Δ¹⁷O values and the presence in altered mesostasis of type‐I chondrules and absence in type‐II chondrules. The textural relations of the P‐O‐rich sulfide and other low‐temperature minerals reveal at least three episodic‐alteration events on the parent body of CM chondrites (1) formation of P‐O‐rich sulfide during sulfur‐rich aqueous alteration of P‐rich FeNi metal, (2) formation of Ca‐carbonate during local carbonation, and (3) alteration of P‐O‐rich sulfide and formation of tochilinite during a period of late‐stage intensive aqueous alteration.  相似文献   

XANES and Mg isotopic analyses of spinels in Ca‐Al‐rich inclusions: Evidence for formation under oxidizing conditions     

J. M. Paque  S. R. Sutton  S. B. Simon  J. R. Beckett  D. S. Burnett  L. Grossman  H. Yurimoto  S. Itoh  H. C. Connolly Jr. 《Meteoritics & planetary science》2013,48(10):2015-2043

Ti valence measurements in MgAl₂O₄ spinel from calcium‐aluminum‐rich inclusions (CAIs) by X‐ray absorption near‐edge structure (XANES) spectroscopy show that many spinels have predominantly tetravalent Ti, regardless of host phases. The average spinel in Allende type B1 inclusion TS34 has 87% Ti⁺⁴. Most spinels in fluffy type A (FTA) inclusions also have high Ti valence. In contrast, the rims of some spinels in TS34 and spinel grain cores in two Vigarano type B inclusions have larger amounts of trivalent titanium. Spinels from TS34 have approximately equal amounts of divalent and trivalent vanadium. Based on experiments conducted on CAI‐like compositions over a range of redox conditions, both clinopyroxene and spinel should be Ti⁺³‐rich if they equilibrated with CAI liquids under near‐solar oxygen fugacities. In igneous inclusions, the seeming paradox of high‐valence spinels coexisting with low‐valence clinopyroxene can be explained either by transient oxidizing conditions accompanying low‐pressure evaporation or by equilibration of spinel with relict Ti⁺⁴‐rich phases (e.g., perovskite) prior to or during melting. Ion probe analyses of large spinel grains in TS34 show that they are enriched in heavy Mg, with an average Δ²⁵Mg of 4.25 ± 0.028‰, consistent with formation of the spinel from an evaporating liquid. Δ²⁵Mg shows small, but significant, variation, both within individual spinels and between spinel and adjacent melilite hosts. The Δ²⁵Mg data are most simply explained by the low‐pressure evaporation model, but this model has difficulty explaining the high Ti⁺⁴ concentrations in spinel.  相似文献   

Partitioning and lateral transport of iron to the Canada Basin     

Ana M. Aguilar-Islas  Robert Rember  Shigeto Nishino  Takashi Kikuchi  Motoyo Itoh 《Polar Science》2013,7(2):82-99

The concentration of dissolved iron (DFe) and suspended leachable particulate iron (LPFe) in the water column of the western Beaufort Sea were investigated during the late summer of 2010. Elevated concentrations of surface DFe (0.49–1.42 nM) were similar to those reported in resent studies, likely reflecting input from melting sea ice and river discharge. The rapid decrease in DFe (5.20–0.48 nM) and LPFe (88.2–1.83 nM) values observed from inshore to offshore in Pacific influenced waters, suggest scavenging processes limit the input of DFe from the shelf to the deep basin. However, frequent eddies found in this region are likely important in promoting lateral advection, as suggested by higher surface DFe concentrations at an offshore station in the vicinity of a warm-core eddy. Within the Atlantic layer, relatively homogeneous DFe (0.69–0.80 nM) and LPFe (1.18–2.13 nM) concentrations were observed at all the stations, reflecting a balance in the interplay between input and removal processes within this watermass. An input of DFe east of the Lomonosov Ridge was inferred by comparing DFe values within the core of Atlantic water between the Eastern and Western Arctic.  相似文献   

Experimental studies on debris flow with logs focusing on specific weight difference of log species     

Haruki WATABE  Takahiro ITOH  Kazuhiko KAITSUKA  Shigeki NISHIMURA 《山地科学学报》2013,10(2):315-325

There are many experimental approaches,field investigations and numerical calculations for movements of woods in a clear water and debris flow.However,kinematic conditions for accumulated logs and the interactions between a main flow and logs have not been fully evaluated.Mitigations for woods need taking into account the characteristics of tree species such as conifer and broad-leaf trees and of shapes such as root swells and crown.In the present study,we focus on the differences in specific weight of conifer and broad-leaf trees with some moisture in a sediment-water mixture flow with narrow flow width,and consider that conifer and broad-leaf tree are floating and submerged solid phase,respectively.Flume tests are conducted in steady flow of clear and debris flow over a rigid bed in order to evaluate conifer and broad-leaf tree movement in clear water and debris flow.Experimental data indicates that dimensionless transverse diffusion coefficient can be 0.1 to 0.4 and 0.3 to 0.9 in flow direction.Those diffusive characteristics seem to be independent of Reynolds number and Froude number,but dependent of bed slope,i.e.,gravity,though detailed considerations are needed to discuss about flow characteristics such as spatial eddy structures,momentum transfer induced by interactions of logs and so on.  相似文献   

Influence of the Oyashio Current and Tsugaru Warm Current on the circulation and water properties of Otsuchi Bay,Japan     

Miho Ishizu  Sachihiko Itoh  Kiyoshi Tanaka  Kosei Komatsu 《Journal of Oceanography》2017,73(1):115-131

Mooring and hydrographic observations were conducted from September 2012 to May 2014 at the mouth of Otsuchi Bay, a ria along the Pacific coast of Japan. Our observations quantitatively demonstrated that the circulation and the water properties of Otsuchi Bay are strongly influenced by the Tsugaru Warm Current (TWC) and Oyashio Current (OY) at seasonal and subseasonal time scales. Two bottom-mounted velocity profilers and temperature and salinity measurements beneath the near-surface halocline showed a counterclockwise lateral circulation pattern related to the TWC, which was enhanced from summer to autumn. From winter to early spring, the lateral circulation patterns related to the TWC weakened and the influence of the OY occasionally increased. When the OY was weak, surface flows became an overturning structure, with outflows in the upper layer and inflows in the lower layer. When the OY was strong and passed close to the Sanriku coast, the circulation became highly variable and intermittent. Intrusions of the markedly low-salinity OY water were observed on two occasions and persisted for periods of several weeks to several months. Salinity was sometimes less than 33.7, the lower limit of the typical TWC from late summer to autumn even when the TWC dominates. We suggested that this is the seasonal fluctuations of the TWC itself, as the upstream current of the Tsushima Warm Current is freshened in summer as a result of the influence of the Changjiang River. The surface water was generally fresher in the south of the bay than in the north, suggesting the Coriolis deflection of the river plume.  相似文献   

Geochemical modeling of sedimentary rocks in the central Hokkaido,Japan: Episodic deformation and subsequent confined basin-formation along the eastern Eurasian margin since the Cretaceous     

Machiko Tamaki  Kunihiro Tsuchida  Yasuto Itoh 《Journal of Asian Earth Sciences》2009,34(2):198-208

Late Cretaceous to Paleogene tectonic episodes around the eastern Eurasian margin are described utilizing one-dimensional (1D) basin modeling technique on the basis of organic maturation; vitrinite reflectance and T_max parameter values of the Rock-Eval pyrolysis. Fine-grained marine sediment of the Yezo Supergroup in central Hokkaido is one of the most extensive Cretaceous constituents along the plate margin. To evaluate organic maturation within the Yezo Supergroup, a surface section (Hakkin-zawa) and a deep borehole (MITI Yubari) were selected, from which quite different maturation trends were obtained. Notably low and constant maturation was suggested throughout the thick Hakkin-zawa section, and it was confirmed on the basis of various biomarker analyses. It requires anomalously rapid burial, probably related to thrust-stacking or large-scale slumping, followed by prompt tilting/exhumation event. In sharp contrast, Late Cretaceous strata in the MITI Yubari do not indicate coeval tectonic disturbances in a short period. A wider view of the ancient convergent margin suggests that deformation of the forearc propagated westward during the Cretaceous. High maturation levels in the uppermost thrust sheet around the MITI Yubari are optimized in 1D geochemical modeling on the assumption that a thick missing Paleogene unit has been eroded out as a result of thrust-forming contraction scheme emerged during the Neogene. A similar Cenozoic burial pattern is adopted for the once tilted and exhumed Hakkin-zawa section in order to match the present maturation levels. Although such an active subsidence of a ‘forearc’ is generally interpreted as an effect of the subduction erosion, heavy mineral composition of the shallow marine to fluvial Paleogene implies uplift and exhumation of ultramafic rocks to the east (trench-side). Thus the confined basin-formation in central Hokkaido is to be understood in a different tectonic framework that may reflect transcurrent motions on the plate margin.  相似文献   

Paleogene and Plio-Pleistocene basin formation around northwestern Kyushu, Japan     

Yasuto Itoh  Kazumi Matsuoka  & Keiji Takemura 《Island Arc》1999,8(1):56-65

Cenozoic basin-forming processes in northwestern Kyushu were studied on the basis of geological and geophysical data. Gravity anomaly analysis delineated four sedimentary basins in the study area: Goto-nada, Nishisonogi, Amakusa-nada, and Shimabara. Borehole stratigraphy and reflection seismic interpretation suggest that the Goto-nada Basin was subdivided into the Paleogene and Plio-Pleistocene depocenters (Goto-nada 1 and 2). In the Paleogene, Amakusa-nada Basin was rapidly subsiding together with the Shimabara Basin as part of a large graben. Goto-nada 1 and Nishisonogi basins belonged to another depositional area. After stagnant subsidence stage in the early Miocene, the study area became a site of basaltic activity (since 10 Ma) and vigorous subsidence in the Plio-Pleistocene. Goto-nada 2 Basin is accompanied with numerous east–west active faults, and separated from the Amakusa-nada Basin by a northeast– southwest basement high, Nomo Ridge. Plio-Pleistocene subsidence of the Amakusa-nada Basin is related with low-angle normal faulting on the eastern flank of the Nomo Ridge. Shimabara Basin is a composite volcano-tectonic depression which is studded by east–west faults. Focal mechanism on active faults suggests transtensional stress regime in the study area.  相似文献   

Influence of bedrock groundwater on streamflow characteristics in a volcanic catchment          下载免费PDF全文

Masamitsu Fujimoto  Nobuhito Ohte  Masatoshi Kawasaki  Ken'ichi Osaka  Masayuki Itoh  Izumi Ohtsuka  Masami Itoh 《水文研究》2016,30(4):558-572

Groundwater movements in volcanic mountains and their effects on streamflow discharge and representative elementary area (REA) have remained largely unclear. We surveyed the discharge and chemical composition of spring and stream water in two catchments: the Hontani river (NR) catchment (6.6 km²) and the Hosotani river (SR) catchment (4.0 km²) at the southern part of Daisen volcano, Japan. Daisen volcano is a young volcano (17 × 10³ years) at an early stage of erosion. Our study indicated that deep groundwater that moved through thick lava and pyroclastic flows and that could not be explained by shallow movements controlled by surface topography contributed dominantly to streamflow at larger catchment areas. At the NR catchment, the deep groundwater contribution clearly increased at a catchment boundary defined by an area of 3.0 km² and an elevation of 800 m. At the SR catchment, the contribution deep groundwater to the stream also increased suddenly at a boundary threshold of 2.0 and 700 m. Beyond these thresholds, the contributions of deep bedrock groundwater remained constant, indicating that the REA is between 2 and 3 km² at the observed area. These results indicate that the hydrological conditions of base flow were controlled mainly by the deep bedrock groundwater that moved through thick lava and pyroclastic flows in the undissected volcanic body of the upper part of the catchment. Our study demonstrates that deep and long groundwater movements via a deep bedrock layer including thick deposits of volcanic materials at the two catchments on Daisen volcano strongly determined streamflow discharge instead of the mixing of small‐scale hydrological conditions. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Back analyses of rainfall-induced slope failure in Northland Allochthon formation     

S. J. Harris  R. P. Orense  K. Itoh 《Landslides》2012,9(3):349-356

To verify numerical models used for the development of an early warning system for rainfall induced landslides, a back analysis of a roadway embankment adjacent to State Highway 1 in Silverdale, New Zealand has been undertaken. The embankment collapsed in June 2008 as a result of prolonged rainfall. The failure occurred in a cut slope through the landslide-prone Northland Allochthon formation. Using volumetric water content sensors and a rainfall gauge, recordings were made of the field response of the soil due to rainfall events during the 2010 winter. Saturated/unsaturated seepage analyses were undertaken using empirically obtained soil parameters to simulate the variation in the monitored volumetric water contents in conjunction with a slope stability analysis to determine the factor of safety of the slope. The rainfall record that caused the slope failure was then applied as an influx to this model to determine the factor of safety against slope failure. If modelled correctly, this factor of safety should reach a minimum at the same time the landslide occurred. If a good agreement between the models and the field observations is reached, the models can be used to create a cost-effective early warning system.  相似文献   

High-resolution imaging polarimetry of HL Tau and magnetic field structure     

P. W. Lucas  Misato Fukagawa  Motohide Tamura  A. F. Beckford  Yoichi Itoh  Koji Murakawa  Hiroshi Suto  Saeko S. Hayashi  Yumiko Oasa  Takahiro Naoi  Yoshiyuki Doi  Noboru Ebizuka  Norio Kaifu 《Monthly notices of the Royal Astronomical Society》2004,352(4):1347-1364

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