Measurements in N2-CH4(C2H2) discharges of reaction rates and thermochemical constants for Titan atmosphere study     

Ricard A  Cernogora G  Fitaire M  Hochard L  Kouassi N  Speller C  Vacher JR 《Planetary and Space Science》1995,43(1-2):41-46

The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K.  相似文献   

Chemical abundances in cold, dark interstellar clouds     

Irvine WM  Ohishi M  Kaifu N 《Icarus》1991,91(1):2-6

The Sun may well have formed in the type of interstellar cloud currently referred to as a cold, dark cloud. We present current tabulations of the totality of known interstellar molecules and of the subset which have been identified in cold clouds. Molecular abundances are given for two such clouds which show interesting chemical differences in spite of strong physical similarities, Taurus Molecular Cloud 1 (TMC-1) and Lynd's 134N (L134N, also referred to as L183). These regions may be at different evolutionary stages.  相似文献   

亚利桑那州的巨型干裂缝     

Raymond  C．Harris  于小芳 《水文地质工程地质技术方法动态》2006,(6):33-35

自1998年以来，亚利桑那州地质调查局就收到许多州周边大范围多个分散地点出现新裂缝的有关报告。此前90年代中期，报告的大部分裂缝均是人们所熟悉的类型，即开采地下水造成地面塌陷引发的地裂缝。然而，这些新裂缝大部分被证明具有不同的诱因——富含粘土的土壤或沉积物的干燥或被烘干。通过绘制这些被报道裂缝的地图及观察其航空照片，结果显示，这些“巨型干裂缝（GDC）”要比预先想象的普遍的多，并且比由开采地下水引起的地裂缝广泛的多。通过绘制亚利桑那州这些巨型干裂缝的地图，最近完成的一项研究证明了勘测的结果。这篇文章概述了那篇报道。  相似文献   

拉斯维加斯谷地下水开采引起的地面沉降和地裂缝     

John  W．Bell  吴洪涛 《水文地质工程地质技术方法动态》2006,(6):36-39

美国西南干旱半干旱地区人口增长非常快。水不仅要满足基本的需求（饮用水、污水系统等），而且还要维持乡村潮湿地区生活方式的改变（郊区的草地、高尔夫球场、庭院的游泳池等）。这些水的使用，既能满足供水系统所在区域地表水供水的需求，又可以满足最基本的地下水开采。然而，地下水的开采对沉积含水层有不利的影响，这些含水层是特有的沙漠区地下水流域的承载。这些影响包括含水层不同程度的压实、旧断层的重新复活、地表的裂缝，还能对人为的基础设施有相当大的影响。  相似文献   

Permeable Reactive Barrier for the treatment of contaminated surface water in Katedan industrial development area, Hyderabad, India     

Savitri Tripathi Vandana Parth Phani Homeshwari M. Vittal Babu N. Murthy N.N. Sorlie J.E. Govil P.K. 《中国地球化学学报》2006,25(B08):117-118

Permeable Reactive Barrier （PRB） is an emplacement of inert material （s） in the subsurface, designed to intercept a contaminated plume, provides a preferential flow path through the reactive media, and transforms the contaminant into environmentally acceptable forms to attain concentration remediation goals at the discharge of the barrier. The phenomena, which help in remediation within PRB, are adsorption/sorption, precipitation, oxidation/reduction and biodegradation. Various materials like zero-valent iron, zero-valent bi-metals, natural zeolites, organic carbon, fly ash, zeolites, limestone, activated alumina, apatites, etc. have been tried by many researchers to remove organic and inorganic contaminants. In USA, Canada, and many European countries commercial full-scale and pilot scale PRBs are successfully working. The design and installation of full scale PRBs needs laboratory treatability and dynamic flow column experiments？ The concept of PRB is being applied to treat contaminated surface water in the Katedan industrial area, Hyderabad, India. National Geophysical Research Institute （NGRI）, Hyderabad, India, conducted systematic studies in collaboration with Norwegian Geotechnical Institute （NGI）, Norway, to develop PRB technique to decontaminate the surface water pollution due to industrial effluent. A site assessment study in the Katedan Industrial Area, were carried out and water, soil and sediment from the lakes of the area were found to be polluted with high concentrations of heavy metals like As, Pb, Cr, Cd, Ni, etc. Adsorption studies at NGRI with synthetic samples and in-situ industrial effluent using different reactive media for removing contaminants like arsenic, chromium, cadmium, copper, nickel, lead and zinc have been carried out and yielded satisfactory results. The performance of zero-valent iron and limestone is encouraging in removing As,  相似文献   

Petrogenesis and geotectonic setting of the PanAfrican basement rocks in Bamenda Massif, Obudu Plateau, southeastern Nigeria： Evidence from trace element geochemistry     

UKAEGBU V. U. EKWUEME B. N. 《中国地球化学学报》2006,25(2):122-131

1 IntroductionThe study area is part of the Obudu Plateau,which forms part of the Precambrian Pan-African tec-tonothermal belt, lying between the West African Cra-ton and the Gabon-Congo Craton ( Fig. 1). It isbounded by the Benue Trough, in the NE-SW axi…  相似文献   

美国通量科学计划中的美国长期通量观测网（2／98）     

S．C．Wofsy D．Y．Hollinger 《辽宁气象》2002,(2):45-48

  相似文献   

成像雷达干涉测量数据相关性与干旱-半干旱地区地表类型特征的关系     

廖静娟  邵芸  郭华东  N.Veneziani 《地球科学进展》2002,17(5):648-652

利用欧洲资源卫星1号和2号获取的重轨干涉测量雷达数据，首先进行干涉测量数据相关性估测，并结合干涉测量数据的振幅信息，开展新疆喀什试验区地表土地类型的识别与分类，区分和识别出裸土、盐碱地、灌丛、裸岩/戈壁、沼泽和水体 6类土地类型。最后通过对不同土地类型的后向散射特性和相关性的分析，探讨了干涉测量数据相关性与干旱-半干旱地区地表特征的关系。  相似文献   

由兰德斯和赫克托矿地震的地震波触发的地震     

J．Gomberg P．A．Reasenberg P．Bodin R．A．Harris王宝善  阮爱国许忠淮 《世界地震译丛》2002,(3):23-27

加州1992年兰德斯7.3级地震和1999年赫克托矿7．1级地震的接近和相似允许人们对触发地震的假设进行检验，而这在以前是不可能的。赫克托矿地震证实了对兰德斯地震所提出的推断：瞬时、振荡的“动态”形变以地震波的形式辐射，能触发地震活动速率的增加(Hill，et al，1993；Anderson，et al，1994；Gomberg and Bodin，1994；Spudich，et al，1995；Gomberg，1996；Gomberg and Davis，1996)。在本文中，我们对地震活动速率的空间和时间变化(Matthews and Reasenberg，1988)进行了量化。在兰德斯地震的北部地震活动速率增加，而对赫克托矿地震这种增加主要发生在震中以南。我们认为破裂方向性分别使兰德斯和赫克托矿断层的北方和南方动态形变提高，这可以由地震波速度场的不对称性得到证明。对于触发作用，动态和静态应力变化都很重要，距离较远处动态应力变化起主要作用。峰值波速证明了动态触发闽值的存在，并约束了动态触发闽值的范围。在大多数地区，这个阈值依赖当地的条件，从零点几到几MPa变化，超过静态闽值一个量级以上。在某些地点触发过程直到动态形变平息了之后才开始。这些观测现象的物理机制可能与导致液化和循环疲劳的机理相似。  相似文献   

三分向台阵数据的偏振分析     

A．Jurkevics贺冬梅  钟南才张伯明 《世界地震译丛》2002,(3):59-72

给出了一种三分向地震台阵数据偏振分析的技术，并应用于挪威南部NORESS台阵三分向拾震器记录到的一大组区域事件。仔细分析了区域震相Pn、Sn和Lg的偏振性质。该技术基于Flinn(1965)最先提出的一种时域算法，通过解协方差矩阵的本征值问题，在滑动时间窗内计算偏振椭圆，由运动椭圆导出表征质点运动的各种属性。通过对不同拾震器的协方差矩阵求平均，把上述方法扩展到了由多个三分向拾震器组成的台阵情况，这样，当噪声和地方散射效应不相关时，可使方差估计减小1／M(M为拾震器数)。此方法的一个重要特点是穿过台阵相干波前的相速度不需要有很高精度。数据分析的重要结果为：在整个短周期频带内，很好地确定了Pn和Sn的偏振；由Pn和Lg波动获得了源方位的估计及Sn和Lg波独特的偏振属性使得在多数情形下能把这些震相区别出来。  相似文献