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11.
David A. McKeown Charles C. Kim Michael I. Bell 《Physics and Chemistry of Minerals》1995,22(3):137-144
The normal modes of vibration and their frequencies are calculated for dioptase, a mineral whose crystal structure (space group R
or C
3i
2
) consists of puckered six-membered silicate rings (Si6O18) linked by Cu2+ ions and H2O groups. The calculation employs a valence force potential consisting of central interactions between nearest neighbors and bond-bending interactions centered at the Si4+ and Cu2+ ions. The force constants are determined by fitting the calculated frequencies to values obtained by measuring the single-crystal Raman spectra. The calculated frequencies are in reasonable agreement with experiment, permitting assignment of normal modes to the observed spectral frequencies. Considerable mixing of Cu and H2O motions with those of the ring is found for the Raman-active modes below 430 cm-1. The normal modes and frequencies of the hypothetical isolated ring with C
3i
symmetry are determined by neglecting all interactions between the rings and the surrounding Cu and H2O. The identification of normal modes characteristic of the puckered six-membered silicate rings and the effect of the environment on these modes may prove useful in the interpretation of the Raman spectra of amorphous silicates. 相似文献
12.
A vertical current sheet is a crucial element in many flare/coronal mass ejection (CME) models. For the first time, Liu et al. reported a vertical current sheet directly imaged during the flare rising phase with the EUV Imaging Telescope (EIT) onboard the Solar and Heliospheric Observatory (SOHO). As a follow-up study, here we present the comprehensive analysis and detailed physical interpretation of the observation. The current sheet formed due to the gradual rise of a transequatorial loop system. As the l... 相似文献
13.
Cetacean-oriented tourism has experienced rapid growth in the last two decades, accompanied by increasing concerns about the effects of tourism on target species. Here, we used shore-based observations of dusky dolphin (Lagenorhynchus obscurus) groups near Kaikoura, New Zealand, and generalised additive models to quantify changes in group speed, reorientation and linearity relative to natural and anthropogenic factors. Summer months were characterised by slower speeds and more changes in direction than winter months. Group speeds were higher at the beginning and end of the day, with slower speeds at midday. Speeds were slower when vessels were present, and dolphin groups changed direction more often when aircraft circled overhead. Effects were positively correlated with number of vessels present within 300 m. Short-term changes have potential to lead to long-term impacts, and further acoustic and energetic studies are proposed to elucidate whether these effects are likely to reduce individual fitness. 相似文献
14.
Gerardo Herrera Rosa María Mateos Juan Carlos García-Davalillo Gilles Grandjean Eleftheria Poyiadji Raluca Maftei Tatiana-Constantina Filipciuc Mateja Jemec Auflič Jernej Jež Laszlo Podolszki Alessandro Trigila Carla Iadanza Hugo Raetzo Arben Kociu Maria Przyłucka Marcin Kułak Michael Sheehy Xavier M. Pellicer Charise McKeown Graham Ryan Veronika Kopačková Michaela Frei Dirk Kuhn Reginald L. Hermanns Niki Koulermou Colby A. Smith Mats Engdahl Pere Buxó Marta Gonzalez Claire Dashwood Helen Reeves Francesca Cigna Pavel Liščák Peter Pauditš Vidas Mikulėnas Vedad Demir Margus Raha Lídia Quental Cvjetko Sandić Balazs Fusi Odd Are Jensen 《Landslides》2018,15(2):359-379
Landslides are one of the most widespread geohazards in Europe, producing significant social and economic impacts. Rapid population growth in urban areas throughout many countries in Europe and extreme climatic scenarios can considerably increase landslide risk in the near future. Variability exists between European countries in both the statutory treatment of landslide risk and the use of official assessment guidelines. This suggests that a European Landslides Directive that provides a common legal framework for dealing with landslides is necessary. With this long-term goal in mind, this work analyzes the landslide databases from the Geological Surveys of Europe focusing on their interoperability and completeness. The same landslide classification could be used for the 849,543 landslide records from the Geological Surveys, from which 36% are slides, 10% are falls, 20% are flows, 11% are complex slides, and 24% either remain unclassified or correspond to another typology. Most of them are mapped with the same symbol at a scale of 1:25,000 or greater, providing the necessary information to elaborate European-scale susceptibility maps for each landslide type. A landslide density map was produced for the available records from the Geological Surveys (LANDEN map) showing, for the first time, 210,544 km2 landslide-prone areas and 23,681 administrative areas where the Geological Surveys from Europe have recorded landslides. The comparison of this map with the European landslide susceptibility map (ELSUS 1000 v1) is successful for most of the territory (69.7%) showing certain variability between countries. This comparison also permitted the identification of 0.98 Mkm2 (28.9%) of landslide-susceptible areas without records from the Geological Surveys, which have been used to evaluate the landslide database completeness. The estimated completeness of the landslide databases (LDBs) from the Geological Surveys is 17%, varying between 1 and 55%. This variability is due to the different landslide strategies adopted by each country. In some of them, landslide mapping is systematic; others only record damaging landslides, whereas in others, landslide maps are only available for certain regions or local areas. Moreover, in most of the countries, LDBs from the Geological Surveys co-exist with others owned by a variety of public institutions producing LDBs at variable scales and formats. Hence, a greater coordination effort should be made by all the institutions working in landslide mapping to increase data integration and harmonization. 相似文献
15.
Immediate impacts and recovery trajectories of macrofaunal communities following hydraulic clam dredging on Banquereau, eastern Canada 总被引：2，自引：0，他引：2
16.
B. A. McKeown 《Marine environmental research》1978,1(2):119-123
Chlorine-labelled Bunker C oil was used to measure the differential accumulation in various fish tissues between a hydrocarbon and a hydrocarbon/oil dispersant mixture. There is an increased movement of the emulsified oil across the gill structure although accumulation by this tissue is similar for both test conditions. The liver and kidney showed significantly higher levels of the oil/dispersant mixture whereas muscle accumulations were less dramatic. The amounts of Bunker C found in the gills, liver and kidney were considerably higher than that found in the muscle. Consideration was given to the varying capability of the blood to carry polar, compared with non-polar, compounds. 相似文献
17.
Raman spectra and lattice dynamics calculations are presented for the silicate mineral gillespite, BaFeSi4O10, which contains sheets of linked four-membered silicate rings. The results are analyzed in relation to earlier work done
on the isolated four-membered ring silicate BaCuSi2O6 and to published claims that vibrational modes of four-membered rings are responsible for the sharp D
1“defect line” observed in the Raman spectra of SiO2 glass. The crystal structure of gillespite (space group P4/ncc or D
) consists of puckered Si4O12 rings, where each SiO4 tetrahedron is linked to two neighboring tetrahedra within a ring and to a third tetrahedron within a different ring. The
rings are linked to each other in a staggered configuration to form sheets, which are also bonded together by Ba2+ and Fe2+. The calculation adjusts the bond bending and bond stretching force constants so that calculated fundamental mode frequencies
best fit observed fundamental frequencies in the Raman spectra; eigenmodes associated with each calculated fundamental mode
are then generated. Some eigenmodes calculated are unique to the gillespite structure, but many of the more localized four-membered
ring modes are similar to those calculated for the four-membered rings in BaCuSi2O6 and for the three- and six-membered rings in the cyclosilicates studied earlier. The results for gillespite indicate that
the Raman-active A
1g
mode at 450 cm−1 is a four-membered ring bridging oxygen breathing mode that is mixed with other minor ring deformation displacements; because
of this mixing, the calculated frequency of this mode is 45 to 61 cm−1 lower than that calculated for bridging oxygen binding breathing modes of puckered four-membered rings in BaCuSi2O6 and in simulated glass structures.
Received: 9 April 1997 / Revised, accepted: 19 August 1997 相似文献
18.
Sellafield in West Cumbria was a potential site for the location of the UK's first underground repository for radioactive, intermediate level waste (ILW). The repository was to lie around 650 m beneath the ground surface within rocks of the Borrowdale volcanic group (BVG), a thick suite of SW dipping, fractured, folded and metamorphosed Ordovician meta-andesites and ignimbrites. These are overlain by an onlapping sequence of Carboniferous and Permo-Triassic sediments. In situ borehole measurements showed that upward trending fluid pressure gradients exist in the area of the potential repository site, and that there are three distinct fluid types in the subsurface; fresh, saline and brine (at depth, to the west of the site). Simulations of fluid flow in the Sellafield region were undertaken with a 2D, steady-state, coupled fluid and heat flow simulation code (OILGEN). In both simplified and geologically complex models, topographically driven flow dominated the regional hydrogeology. Fluids trended persistently upwards through the potential repository site. The dense brine to the west of the site promoted upward deflection of topographically driven groundwaters. The inclusion in hydrogeological models of faults and variably saline sub-surface fluids was essential to the accurate reproduction of regional hydraulic head variations. Sensitivity analyses of geological variables showed that the rate of groundwater flow through the potential repository site was dependent upon the hydraulic conductivity of the BVG, and was unaffected by the hydraulic conductivity of other hydrostratigraphic units. Calibration of the model was achieved by matching simulated subsurface pressures to those measured in situ. Simulations performed with BVG hydraulic conductivity 100 times the base case median value provided the “best-fit” comparison between the calculated equivalent freshwater head and that measured in situ, regardless of the hydraulic conductivity of other hydrostratigraphic units. Transient mass transport simulations utilising the hydraulic conductivities of this “best fit” simulation showed that fluids passing through the potential repository site could reach the surface in 15 000 years. Simple safety case implications drawn from the results of the study showed that the measured BVG hydraulic conductivity must be less than 0.03 m year−1 to be simply declared safe. Recent BVG hydraulic conductivity measurements showed that the maximum BVG hydraulic conductivity is around 1000 times this safety limit. 相似文献