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91.
The redox state of the surface environment of the early Earth is still controversial, and a detailed and quantitative estimate is still lacking. We carried out in-situ analyses of major, trace, and rare-earth elements of carbonate minerals in rocks with primary sedimentary structures in shallow and deep sea-deposits, in order to eliminate secondary carbonate and contamination of detrital materials, and to estimate the redox condition of seawater through time. Based on the Ce content and anomalies of the carbonate minerals at given parameters of atmospheric CO2 content (pCO2) and Ca content of seawater, we calculated the oxygen contents of shallow and deep seawater, respectively. The results show that the oxygen content of the deep sea was low and constant until at least 1.9 Ga. The oxygen content of shallow seawater increased after 2.7 Ga, but fluctuated. It became quite high at 2.5 and 2.3 Ga, but eventually increased after the Phanerozoic. In addition, the calculation of a high pCO2 condition shows that seawater was more oxic even in the Archean than at present, suggesting a relatively low pCO2 through geologic time.Our detailed calculations from compositions of carbonate minerals in Three Gorge area, south China show a low oxygen content of seawater after the Snowball Earth until the late Ediacaran, an increase in the late Ediacaran, and a significant decrease around the Precambrian–Cambrian and Nemakit/Daldynian–Tommotian boundaries. These variations were possibly caused by global regression and dissolution of methane hydrates.  相似文献   
92.
93.
The effect of a non-trivial topology on the temperature correlations of the cosmic microwave background (CMB) in a small compact hyperbolic universe with volume comparable to the cube of the curvature radius is investigated. Because the bulk of large-angle CMB fluctuations are produced at the late epoch in low-Ω0 models, the effect of a long-wavelength cut-off owing to the periodic structure does not lead to significant suppression of large-angle power as in compact flat models. The angular power spectra are consistent with COBE data for Ω00.1.  相似文献   
94.
New U–Pb ages of zircons from migmatitic pelitic gneisses in the Omuta district, northern Kyushu, southwest Japan are presented. Metamorphic zonation from the Suo metamorphic complex to the gneisses suggests that the protolith of the gneisses was the Suo metamorphic complex. The zircon ages reveal the following: (i) a transformation took place from the high‐P Suo metamorphic complex to a high‐T metamorphic complex that includes the migmatitic pelitic gneisses; (ii) the detrital zircon cores in the Suo pelitic rocks have two main age components (ca 1900–1800 Ma and 250 Ma), with some of the detrital zircon cores being supplied (being reworked) from a high‐grade metamorphic source; and (iii) one metamorphic zircon rim yields 105.1 ±5.3 Ma concordant age that represents the age of the high‐T metamorphism. The high‐P to high‐T transformation of metamorphic complexes implies the seaward shift of a volcanic arc or a landward shift of the metamorphic complex from a trench to the sides of a volcanic arc in an arc–trench system during the Early Cretaceous. The Omuta district is located on the same geographical trend as the Ryoke plutono‐metamorphic complex, and our estimated age of the high‐T metamorphism is similar to that of the Ryoke plutono‐metamorphism in the Yanai district of western Chugoku. Therefore, the high‐T metamorphic complex possibly represents the western extension of the Ryoke plutono‐metamorphic complex. The protolith of the metamorphic rocks of the Ryoke plutono‐metamorphic complex was the Jurassic accretionary complex of the inner zone of southwest Japan. The high‐P to high‐T transformation in the Omuta district also suggests that the geographic trend of the Jurassic accretionary complex was oblique to that of the mid‐Cretaceous high‐T metamorphic field.  相似文献   
95.
Zircon U–Pb ages of two acidic tuff and two turbidite sandstone samples from the Nakanogawa Group, Hidaka Belt, were measured to estimate its depositional age and the development of the Hokkaido Central Belt, northeast Japan. In the northern unit, homogeneous zircons from pelagic acidic tuff from a basal horizon dated to 58–57 Ma, zircons from sandstone from the upper part of the unit dated to 56–54 Ma, and zircons from acidic tuff from the uppermost part dated to 60–56 Ma and 69–63 Ma. Both of the tuff U–Pb ages are significantly older than the youngest radiolarian fossil age (66–48 Ma). Therefore, the maximum depositional age of the turbidite facies in the northern unit is 58 Ma and the younger age limit, estimated from the fossil age, is 48 Ma. In the southern unit, homogeneous zircons from turbidite sandstone dated to 58–57 Ma. Thus the depositional age of this turbidite facies was interpreted to be 66–56 Ma from the fossil age, probably close to 57 Ma. Most of the zircon U–Pb ages from the Nakanogawa Group are younger than 80 Ma, with a major peak at 60 Ma. This result implies that around Hokkaido volcanic activity occurred mainly after 80 Ma. Older zircon ages (120–80 Ma, 180–140 Ma, 340–220 Ma, 1.9 Ga, 2.2 Ga, and 2.7 Ga) give information about the provenance of other rocks in the Hidaka Belt. It is inferred that the Nakanogawa Group comprises protoliths of the upper sequence of the Hidaka Metamorphic Zone, which therefore has the same depositional age as the Nakanogawa Group (66–48 Ma). The depositional ages of the lower sequence of the Hidaka Metamorphic Zone and the Nakanogawa Group are probably the same.  相似文献   
96.
We present a new LA–ICP–MS system for zircon fission‐track (FT) and U–Pb double dating, whereby a femtosecond laser combined with galvanometric optics simultaneously ablates multiple spots to measure average surface U contents. The U contents of zircon measured by LA–ICP–MS and standardized with the NIST SRM610 glass are comparable to those measured by the induced FT method, and have smaller analytical errors. LA–ICP–MS FT dating of seven zircon samples including three IUGS age standards is as accurate as the external detector method, but can give a higher‐precision age depending on the counting statistics of the U content measurement. Double dating of the IUGS age standards gives FT and U–Pb ages that are in agreement. A chip of the Nancy 91500 zircon has a homogeneous U content of 84 ppm, suggesting the possibility of using this zircon as a matrix‐matched U‐standard for FT dating. When using the Nancy 91500 zircon as a U‐standard, a zeta calibration value of 42–43 year cm2 for LA–ICP–MS FT dating is obtained. While this value is strictly valid only for the particular session, it can serve as a reference for other studies.  相似文献   
97.
The opening of the Japan Sea led to the separation of southwest Japan from the Eurasian continent. Subsequent to this event, a diverse range of igneous activities occurred in southwest Japan. On the back-arc side of the region, igneous activity commenced at approximately 22 Ma and persisted for an extended period. In the trench-proximal region of southwest Japan, magmatism initiated around 15.6 Ma, immediately following the cessation of the Japan Sea opening, in correlation with the subduction of the Philippine Sea plate beneath southwest Japan. The Amakusa Islands in western Kyushu host felsic to intermediate igneous rocks with Miocene radiometric ages. There has been a debate regarding the attribution of the igneous rocks in Amakusa Island among the Miocene igneous rocks in southwest Japan. To address this issue, we conducted zircon U–Pb dating and analyzed the major- and trace-element compositions of felsic igneous rocks in the Amakusa Islands to elucidate their characteristics. The obtained U–Pb ages range from 14.5 to 14.8 Ma, suggesting contemporaneity between magmatism in the Amakusa Islands and the Setouchi Volcanic Rocks in the trench-proximal region of southwest Japan. The major and trace element compositions of the felsic igneous rocks exhibit similarities to the dacites of the Setouchi Volcanic Rocks. These findings support previous suggestions that the magmatism in the Amakusa Islands can be correlated with the Setouchi Volcanic Rocks, based on the discovery of a high-Mg andesite dike and paleo-stress analysis utilizing the direction of dikes and sills. Therefore, the Setouchi Volcanic Belt is proposed to extend further west than the previously identified Ohno volcanic rocks in eastern Kyushu. The subduction of the Shikoku Basin of the Philippine Sea plate toward western Kyushu supports the hypothesis that the Kyushu-Palau Ridge was positioned west of Kyushu at ~15 Ma.  相似文献   
98.
Tephra fingerprinting techniques contributing to volcanology and palaeoenvironmental studies have been developed using a combination of laser-ablation inductively coupled-plasma mass spectrometry (LA-ICP-MS) and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS). In particular, femtosecond LA-ICP-MS can determine major- and trace element abundances in individual glass shards. On the basis of the major oxide and trace element composition of the glass shards, using those methods, we re-examined the identification of four lower Pleistocene tephras originating from north-east Japan. All trace element abundances exhibited the typical pattern of tephras from the Hokkaido–Tohoku area, and major element concentrations were distinct. As a result, we re-examined the correlation of the widespread Tmg-R4 tephra (2.0 Ma), and newly defined the widespread Kd44-Naka tephra (1.968–1.781 Ma), both originating from the Sengan geothermal region. Furthermore, we re-examined identifications of Sr-Asn-Kd8 (1.219 Ma) and Sr-Kc-U8 (0.922–0.910 Ma) in central Japan, both derived from the Aizu volcanic region. The extensive distributions of the former two tephras suggest the occurrence of two large caldera-forming eruptions (Volcanic Explosivity Index 7) during a short period. Also, the distributions and volumes of the latter two tephras are broader and larger than those previously assumed. The results provide insight into large volcanic eruption history and terrestrial and marine palaeoenvironmental history.  相似文献   
99.
The geophysical methods are effective tools for determining changes in physical parameters of the geological environment, as soil or groundwater in the presence of contamination. This work consisted on analyzing the natural electric potential obtained over domestic solid waste ditches with controlled closure dates. The interpretation data suggest the generation of electric potential predominantly through the redox phenomenon, as opposed to the flow potential phenomenon. The statistical data analysis indicates a correlation between residence time of the waste and growing variations of voltage. In addition highlights that eight years are required to achieve the reported values for the area with absence of waste, time estimated for decomposition of most organic matter contained in the buried waste.  相似文献   
100.
By comparing detrital zircon U–Pb age spectra of coeval fore‐arc and back‐/intra‐arc basin sandstones, we identified the overall distributary pattern of terrigenous clastic material within the Cretaceous arc system of SW Japan. Abundant Proterozoic (c. 1500–2500 Ma) detrital grains from the interior of East Asia are present in the Cretaceous intra‐arc basin. However, after a barrier mountain range formed during batholith emplacement, Proterozoic clastics were rarely transported into the fore‐arc domain. Episodic batholith formation in Pacific‐type orogens likely played a major role in controlling terrigenous supply routes between coeval back‐arc and fore‐arc domains. The Cretaceous orogen in Japan thus provides a good template for analysing the tectono‐sedimentary development of other arc‐related basins.  相似文献   
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