Unterwasserbeobachtungen im sublitoralen Solfatarenfeld von Vulcano (Äolische Inseln,Italien)     

Oskar Schulz 《Mineralium Deposita》1970,5(3):315-319

Zusammenfassung Unterwasserbeobachtungen im sublitoralen Solfatarenfeld von Vulcano brachten Einzelheiten über die verschiedene Gestaltung des Meeresbodenreliefs im Bereich der Gasaustritte und über die Anlagerung von kolloidalem Schwefel. Die Befunde werden anhand mehrerer Unterwasserphotographien erläutert und es wird auf die Ähnlichkeit der rezenten Bodengestaltung mit gewissen aus triadischen Pb-Zn-Erzlagerstätten bekannten Gefügen hingewiesen. Hinweise auf Flora und Fauna im Bereich der submarinen Vulkanexhalationen ergänzen die Untersuchungen.

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Underwater studies in the sublitoral field of solfataras of Vulcano revealed details on the relief of the sea bottom in areas with volcanic exhalations and on the deposition of colloidal sulphur. The observations made are illustrated by several underwater photographs. The similarity between the recent shape of the ground and certain fabrics known from Triassic Pb-Zn- ore deposits is pointed out. These studies are supplemented by short data on the abundant flora and fauna in the area of the submarine volcanic exhalations.

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Paleomagnetism of Late Cretaceous Poços de Caldas alkaline complex,Southern Brazil     

Neil D. Opdyke  William D. MacDonald 《Earth and Planetary Science Letters》1973,18(1):37-44

The paleomagnetism of the Late Cretaceous Poços de Caldas alkaline complex (46.6°W, 21.9°S) was investigated through 42 oriented cores from seven sites. Six sites, reversed relative to the present magnetic field of the Earth, yield a pole at 127°W, 82°S (dp = 8°,dm = 13°). This pole is located close to other Late Cretaceous poles for South America obtained by Creer [1] from untreated paleomagnetic samples. The results are significantly different from those for the nearby Early Cretaceous Serra Geral basalt but close to the Triassic pole for South America. The polar wandering path for South America for the Mesozoic seems to be more complicated than anticipated. The available paleomagnetic information may not yet be precise enough to determine the time of opening of the Atlantic.  相似文献   

Discussion of paper by Mörner and Lanser concerning the paleomagnetism of deep-sea core A179-15     

Neil D. Opdyke 《Earth and Planetary Science Letters》1976,29(1):238-239

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A Saturnian gas ring and the recycling of Titan's atmosphere     

Thomas R. McDonough  Neil M. Brice 《Icarus》1973,20(2):136-145

Atoms which escape Titan's atmosphere are unlikely to possess escape velocity from Saturn, and can orbit the planet until lost by ionization or collision with Titan. It is predicted that a toroidal ring of between ～1 and ～10³ atoms or molecules cm^?3 exists around Saturn at a distance of about 10 times the radius of the visible rings. This torus may be detectable from Earth-orbit and detection of nondetection of it may provide some information about the presence or absence of a Saturnian magnetic field, and the exospheric temperature and atmospheric escape rate of Titan. It is estimated that, if Titan has a large exosphere, ～97% or more of the escaping atoms can be recaptured by Titan, thereby decreasing the effective net atmospheric loss rate by up to two orders of magnitude. With such a reduction in atmospheric loss rates, it becomes more plausible to suggest that satellites previously thought too small to retain an atmosphere may have one. It is suggested that Saturn be examined by Lyman-α and other observations to search for the gaseous torus of Titan. If successful, these could then be extended to other satellites.The effect of a hypothetical Saturnian magnetosphere on the atmosphere of Titan is investigated. It is shown that, if Saturn has a magnetic field comparable to Jupiter's (～10 G at the planetary surface), the magnetospheric plasma can supply Titan with hydrogen at a rate comparable to the loss rates in some of the models of Trafton (1972) and Sagan (1973). A major part of the Saturnian ionospheric escape flux (～ 10²⁷ photoelectrons sec^?1) could perhaps be captured by Titan. At the upper limit, this rate of hydrogen input to the satellite could total ～0.1 atm pressure over the lifetime of the solar system, an amount comparable to estimates of the present atmospheric pressure of Titan.  相似文献   

Quasi-exospheric heat flux of solar-wind electrons     

Aharon Eviatar  Michael Schulz 《Astrophysics and Space Science》1976,39(1):65-73

Density, bulk-velocity, and heat-flow moments are calculated for truncated maxwellian distributions representing the cool and hot populations of solar-wind electrons, as realized at the base of a hypothetical exosphere. The electrostatic potential is thus calculated by requiring charge quasineutrality and the absence of electrical current. Plasma-kinetic coupling of the cool-electron and proton bulk velocities leads to an increase in the electrostatic potential and a decrease in the heat-flow moment. If the velocities differ by the Alfvén speed along the magnetic field, for example, the potential rises to 72.6 V and the heat flux falls to 2.72×10^–2 erg cm^–2 s^–1. In each case the heat flux is carried mainly by the quasi-exospherichot electrons.  相似文献   

Mapping of Ozone and Water in the Atmosphere of Mars near the 1997 Aphelion     

Robert E. NovakMichael J. Mumma  Michael A. DiSanti  Neil Dello Russo  Karen Magee-Sauer 《Icarus》2002,158(1):14-23

We present absolute abundances and latitudinal variations of ozone and water in the atmosphere of Mars during its late northern spring (L_s=67.3°) shortly before aphelion. Long-slit maps of the a¹Δ_g state of molecular oxygen (O₂) and HDO, an isotopic form of water, were acquired on UT January 21.6 1997 using a high-resolution infrared spectrometer (CSHELL) at the NASA Infrared Telescope Facility. O₂(a¹Δ_g) is produced by ozone photolysis, and the ensuing dayglow emission at 1.27 μm is used as a tracer for ozone. Retrieved vertical column densities for ozone above ∼20 km ranged between 1.5 and 2.8 μm-atm at mid- to low latitudes (30°S-60°N) and decreased outside that region. A significant decrease in ozone density is seen near 30°N (close to the subsolar latitude of 23.5°N). The rotational temperatures retrieved from O₂(a-X) emissions show a mean of 172±2.5 K, confirming that the sensed ozone lies in the middle atmosphere (∼24 km). The ν₁ fundamental band of HDO near 3.67 μm was used as a proxy for H₂O. The retrieved vertical column abundance of water varies from 3 precipitable microns (pr-μm) at ∼30°S to 24 pr-μm at ∼60°N. We compare these results with current photochemical models and with measurements obtained by other methods.  相似文献   

Arsenic and presumed resistate trace element geochemistry of the Lincolnshire (UK) sedimentary ironstones,as revealed by a regional geochemical survey using soil,water and stream sediment sampling     

Neil Breward 《Applied Geochemistry》2007

A regional geochemical survey using soils, stream sediment and stream water sampling revealed multi-element geochemical anomalies, though of low environmental mobility, associated with Mesozoic sedimentary ironstones in Lincolnshire, UK. The most prominent of these anomalies were of As and V in soils and sediments, but elevated levels of elements such as Cr, La, Ce and Th were also observed. These were initially thought to be part of a residual resistate element or heavy-mineral suite, but careful examination suggests that these too may be primarily associated with the process of Fe oxide precipitation during the initial formation of the ironstones.  相似文献   

Interpreting the Ca isotope record of marine biogenic carbonates     

Neil G. Sime  Edward T. Tipper  Albert Galy 《Geochimica et cosmochimica acta》2007,71(16):3979-3989

An 18 million year record of the Ca isotopic composition (δ^44/42Ca) of planktonic foraminiferans from ODP site 925, in the Atlantic, on the Ceara Rise, provides the opportunity for critical analysis of Ca isotope-based reconstructions of the Ca cycle. δ^44/42Ca in this record averages +0.37 ± 0.05 (1σ SD) and ranges from +0.21‰ to +0.52‰. The record is a good match to previously published Neogene Ca isotope records based on foraminiferans, but is not similar to the record based on bulk carbonates, which has values that are as much as 0.25‰ lower. Bulk carbonate and planktonic foraminiferans from core tops differ slightly in their δ^44/42Ca (i.e., by 0.06 ± 0.06‰ (n = 5)), while the difference between bulk carbonate and foraminiferan values further back in time is markedly larger, leaving open the question of the cause of the difference. Modeling the global Ca cycle from downcore variations in δ^44/42Ca by assuming fixed values for the isotopic composition of weathering inputs (δ^44/42Ca_w) and for isotope fractionation associated with the production of carbonate sediments (Δ_sed) results in unrealistically large variations in the total mass of Ca²⁺ in the oceans over the Neogene. Alternatively, variations of ±0.05‰ in the Ca isotope composition of weathering inputs or in the extent of fractionation of Ca isotopes during calcareous sediment formation could entirely account for variations in the Ca isotopic composition of marine carbonates. Ca isotope fractionation during continental weathering, such as has been recently observed, could easily result in variations in δ^44/42Ca_w of a few tenths of permil. Likewise a difference in the fractionation factors associated with aragonite versus calcite formation could drive shifts in Δ_sed of tenths of permil with shifts in the relative output of calcite and aragonite from the ocean. Until better constraints on variations in δ^44/42Ca_w and Δ_sed have been established, modeling the Ca²⁺ content of seawater from Ca isotope curves should be approached cautiously.  相似文献   

Alternative Validation of a LC-MS/MS-Multi-Method for Pesticides in Drinking Water     

Alexander Müller  Dirk Flottmann  Wolfgang Schulz  Wolfram Seitz  Walter H. Weber 《洁净——土壤、空气、水》2007,35(4):329-338

The development of instrumental analytics such as the LC-MS/MS has made it possible to quickly determine many component concentrations in a single chromatogram. However, the validation of such multi-methods needs new strategies for robustness and optimization. Statistical execution of analytical tests is one tool that can be utilized to meet this requirement. A Central Composite Design (CCD) was utilized for the validation of an LC-MS/MS multi-method for 84 analytes. The experimental design includes six design variables and two non-design variables (response variables). Concentration, ionization temperature, dwell time, gradient, flow (of eluent), and spraying/curtain gas (continuous design variables) were varied on five different levels; the whole design encompassed 91 runs. To investigate the robustness of a LC-MS/MS method both peak sensitivity and chromatographic separation had to be verified. Therefore, two non-design variables were necessary. The distribution of the peaks over analysis time was applied to describe the quality of the chromatographic separation. The sensitivity was described with the signal to noise ratio (S/N). The evaluation of the measured data was accomplished with the Analysis of Variance (ANOVA) and the Response Surface Methodology (RSM). Three main effects (concentration, ionization temperature, dwell time) and no significant interaction effect were found for the response variable “S/N”. The variables of concentration, ionization temperature, and dwell time had no significant effects for the response variable “S/N”. The ANOVA of the response variable chromatographic separation abandoned no significant effects as well. Therefore, robustness of the method can be guaranteed for all non significant design variables.  相似文献   

An SEM study of porosity and grain boundary microstructure in quartz mylonites, Simplon Fault Zone, Central Alps     

Neil S. Mancktelow  Djordje Grujic  Eric L. Johnson 《Contributions to Mineralogy and Petrology》1998,131(1):71-85

A backscattered and secondary electron SEM study of the grain boundary microstructure in quartz mylonites sampled along the length of the retrograde Simplon Fault Zone established three characteristic components. (1) Fine isolated pores (≤?1?μm diameter) are scattered across two-grain interfaces, preferentially concentrated on surfaces in extension. Pores are uncommon on three-grain junctions and there is no evidence for fluid interconnectivity along three- and four-grain junctions. The fine porosity may develop by accumulation of original, mainly intragranular fluid inclusions to the grain boundary during deformation and recrystallization and by cavitation of grain boundaries during grain boundary sliding. Dynamic cavitation implies that the “ductile” mylonitic deformation is at least locally dilatant and therefore pressure sensitive. (2) Large “vug”-like pores (up to mm-scale) extend along multi-grain boundaries. Observed in all samples, they are most common in the higher initial temperature, coarse-grained samples with a microstructure dominated by grain boundary migration recrystallization. Grains bordering this connected porosity develop perfect crystal faces, undecorated by fine pores or pits. The irregular “lobate” optical microstructure of many migrating grain boundaries actually consists of a series of straight crystal faces. The coarse porosity is probably due to accumulation during dynamic recrystallization of (CO₂-rich ?) fluid with a high wetting angle against quartz. (3) In one sample, interconnected sinuous ridges, ≤?0.2?μm high, are observed to follow three- and four-grain junctions and disjoint into more isolated worms and spheroidal globules. On two-grain interfaces, these are transitional to more branching vein-like or convoluted brain-like forms. The brain-like and globular forms have been observed, with varying frequency, through the range of samples, with the globules attaining sizes of up to 60?μm. Vein structures have also been observed on intragranular fractures. These topologies do not match across adjoining surfaces and must have developed into free space. The ridge-vein-brain-spheroid structure is distinctly different to that previously observed on experimentally healed microcracks and its origin is not unequivocally established. They could represent unstable meniscus necking of a thin grain-boundary phase of low viscosity, developed due to quasi-adiabatic shear and/or local stress-induced dilatancy during microcracking.  相似文献