Geochemical processes underlying a sharp contrast in groundwater arsenic concentrations in a village on the Red River delta,Vietnam   总被引：1，自引：0，他引：1  

Elisabeth Eiche  Thomas Neumann  Michael Berg  Beth Weinman  Alexander van Geen  Stefan Norra  Zsolt Berner  Pham Thi Kim Trang  Pham Hung Viet  Doris Stüben 《Applied Geochemistry》2008

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Palaeo-hydrogeological control on groundwater As levels in Red River delta,Vietnam     

Søren Jessen  Flemming Larsen  Dieke Postma  Pham Hung Viet  Nguyen Thi Ha  Pham Quy Nhan  Dang Duc Nhan  Mai Thanh Duc  Nguyen Thi Minh Hue  Trieu Duc Huy  Tran Thi Luu  Dang Hoang Ha  Rasmus Jakobsen 《Applied Geochemistry》2008

To study the geological control on groundwater As concentrations in Red River delta, depth-specific groundwater sampling and geophysical logging in 11 monitoring wells was conducted along a 45 km transect across the southern and central part of the delta, and the literature on the Red River delta’s Quaternary geological development was reviewed. The water samples (n = 30) were analyzed for As, major ions, Fe²⁺, H₂S, NH₄, CH₄, δ¹⁸O and δD, and the geophysical log suite included natural gamma-ray, formation and fluid electrical conductivity. The SW part of the transect intersects deposits of grey estuarine clays and deltaic sands in a 15–20 km wide and 50–60 m deep Holocene incised valley. The NE part of the transect consists of 60–120 m of Pleistocene yellowish alluvial deposits underneath 10–30 m of estuarine clay overlain by a 10–20 m veneer of Holocene sediments. The distribution of δ¹⁸O-values (range −12.2‰ to −6.3‰) and hydraulic head in the sample wells indicate that the estuarine clay units divide the flow system into an upper Holocene aquifer and a lower Pleistocene aquifer. The groundwater samples were all anoxic, and contained Fe²⁺ (0.03–2.0 mM), Mn (0.7–320 μM), SO₄ (<2.1 μM–0.75 mM), H₂S (<0.1–7.0 μM), NH₄ (0.03–4.4 mM), and CH₄ (0.08–14.5 mM). Generally, higher concentrations of NH₄ and CH₄ and low concentrations of SO₄ were found in the SW part of the transect, dominated by Holocene deposits, while the opposite was the case for the NE part of the transect. The distribution of the groundwater As concentration (<0.013–11.7 μM; median 0.12 μM (9 μg/L)) is related to the distribution of NH₄, CH₄ and SO₄. Low concentrations of As (?0.32 μM) were found in the Pleistocene aquifer, while the highest As concentrations were found in the Holocene aquifer. PHREEQC-2 speciation calculations indicated that Fe²⁺ and H₂S concentrations are controlled by equilibrium for disordered mackinawite and precipitation of siderite. An elevated groundwater salinity (Cl range 0.19–65.1 mM) was observed in both aquifers, and dominated in the deep aquifer. A negative correlation between aqueous As and an estimate of reduced SO₄ was observed, indicating that Fe sulphide precipitation poses a secondary control on the groundwater As concentration.  相似文献   

Magmatism in the Iberian Pyrite Belt: petrological constraints on a metallogenic model     

D. Thiéblemont  E. Pascual  G. Stein 《Mineralium Deposita》1997,33(1-2):98-110

Igneous formations associated with massive sulphide deposits in the Iberian Pyrite Belt (IPB) are essentially composed of basic lavas and dolerites, and dacitic to rhyolitic volcanites; intermediate lavas are subordinate. The basic rocks show variable geochemical characteristics: lavas and dolerites comparable to recent within-plate alkaline basalts seem restricted to the western and southern parts of the IPB, whereas basic rocks comparable to continental tholeiites or arc-related basalts occur across the whole belt. The felsic rocks are classified as calc-alkaline and belong to the “low-Al₂O₃ and high-Yb type”. At given SiO₂, Al₂O₃ and TiO₂ contents, they show variable Zr, Nb, and HREE contents. Heavy-rare-earth element fractionation decreases from the dacites to the rhyolites ([Gd/Yb]_N ∼ 1), whereas the negative Eu-anomaly becomes more pronounced. The characteristics of the rhyolites are typical of sulphide-fertile volcanic packages. Trace-element modelling suggests that the felsic rocks evolved from a dacitic parent magma through fractional crystallization of hornblende and plagioclase. Partial melting of an amphibolite protolith, which appears as the most probable model for the origin of this dacitic magma, requires a high T/P gradient in the crust. The occurrence of alkaline basalts and continental tholeiites is consistent with formation of the IPB in a tensional tectonic setting. However, the associated island-arc tholeiites suggest a location in a domain of plate convergence. Emplacement in a fore-arc basin over a recently accreted crustal segment is envisaged as a possible hypothesis to account for the geological and petrological constraints. A high geothermal gradient and eruption in a submarine tensional basin could have been two key ingredients for the development of massive sulphide deposits within the IPB.

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Resumen (translated by E. Pascual) Las formaciones ígneas asociadas con los depósitos de sulfuros masivos de la Faja Pirítica Ibérica (IPB) se componen esencialmente de doleritas y lavas básicas y de rocas volcánicas dacíticas a riolíticas; las lavas intermedias son poco abundantes. Las rocas básicas muestran caracteres geoquímicos variables: lavas y doleritas comparables a basaltos alcalinos intraplaca recientes parecen hasta ahora restringidos a las partes W y S de la IPB, mientras que rocas básicas de caracteres comparables a las de toleítas continentales o basaltos relacionados con arcos aparecen en toda la zona. Las rocas ácidas se clasifican como calcoalcalinas del tipo “low-Al₂O₃, high-Yb”. Para un contenido dado en SiO₂, Al₂O₃ y TiO₂, muestran contenidos variables en Zr, Nb y REE. El contenido en tierras raras pesadas decrece de dacitas a riolitas ([Gd/Yb]_N ∼ 1), al tiempo que la anomalía de Eu se hace más pronunciada. La modelización de elementos trazas sugiere que las rocas evolucionaron a partir de un magma parental dacítico mediante cristalización fraccionada de hornblenda y plagioclasa. La fusión parcial de un protolito anfibolítico, que parece el modelo más plausible para el origen del magma dacítico, requiere un elevado gradiente T/P en la corteza. La existencia de basaltos alcalinos y de toleítas continentales es congruente con la formación de la IPB en un entorno tectónico distensivo. El emplazamiento en una cuenca “fore-arc”, en un segmento cortical de reciente acreción, se contempla como una hipótesis posible para explicar los caracteres geológicos y petrológicos. Un alto gradiente térmico, junto con la erupción en una cuenca submarina extensional, pueden haber sido los dos ingredientes clave en el desarrollo de los depósitos de sulfuros masivos en la IPB.

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Received: 3 March 1996 / Accepted: 7 April 1997  相似文献   

Applicability of CPT-based methods in predicting toe bearing capacities of driven piles in sand     

Le Chi Hung  Tien Dung Nguyen  Ju-Hyung Lee  Sung-Ryul Kim 《Acta Geotechnica》2016,11(2):359-372

This paper presents a study on applicability of predicting toe bearing capacities from cone penetration test (CPT) for PHC (pretensioned spun high-strength concrete) driven piles into deep sandy deposits in the Nakdong River deltaic area west of Busan City in South Korea. Using toe bearing capacities obtained from pile driving analyzer (PDA) tests as reference values, which were reliably calibrated by on-site O-cell tests, the applicability of the CPT-based methods was evaluated using a statistical rank index (RI). A total of 82 piezocone penetration test soundings and 190 PDA test piles were used for reliability analysis in this study. Three correction steps were applied to obtain reliable PDA and CPT data sets before ranking is carried out. The RI index is combined from four criteria: (1) the best-fit line, (2) the arithmetic mean and standard deviation, (3) the cumulative probabilities, and (4) the log-normal and histogram distributions. Based on these criteria the performance of some SPT-based methods in the literature is evaluated.  相似文献   

Analysis of sediment distribution and transport for mitigation of sand deposition hazard in Tam Quan estuary,Vietnam     

Do Minh Duc  Dinh Xuan Thanh  Dinh Thi Quynh  Patrick McLaren 《Environmental Earth Sciences》2016,75(9):741

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Spatial prediction of landslide susceptibility using integrated frequency ratio with entropy and support vector machines by different kernel functions     

Wei Chen  Jiale Wang  Xiaoshen Xie  Haoyuan Hong  Nguyen Van Trung  Dieu Tien Bui  Gang Wang  Xinrui Li 《Environmental Earth Sciences》2016,75(20):1344

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A new continuous measurement method for gaseous ammonia by counter-current flow tube sampling and indophenol reaction     

Duong Huu Huy  To Thi Hien  Norimichi Takenaka 《Journal of Atmospheric Chemistry》2016,73(3):223-240

Ammonia (NH₃) is the most abundant alkaline gas in the atmosphere and plays a key role in atmospheric chemistry. Reliable and high-time-resolution data for gaseous ammonia are necessary to understand the sources and sinks of ammonia gas in ambient air. In the present study, a sensitive and continuous instrument for measuring gaseous ammonia was developed. Ammonia gas in ambient air was collected in an aqueous solution using a counter-current flow tube (CCFT) sampler. Then, ammonium formed in the aqueous solution was detected by the indophenol method. Based on a CCFT length of 50 cm and air flow rate of 1 L/min, the collection efficiency exceeded 98.5 % at an ammonia mixing ratio of up to 120 ppbv. The detection limit of this method was 0.062 ppbv. Interferences from several gases were investigated, and the results showed that the present method was not affected by NO_x, O₃, SO₂, HONO, methylamine, formaldehyde, hydrogen sulfide or a mixture of these gases. The most important result was that only gaseous ammonia was detected in the present method without any interference from the particulate ammonium in ambient air. Comparisons with data based on the dry denuder method indicated that the present method showed good agreement with the denuder method.  相似文献   

A Continuous Mapping of Tidal Current Structures in the Kanmon Strait   总被引：1，自引：0，他引：1  

Keisuke?Yamaguchi  Ju?Lin  Arata?KanekoEmail author  Tokuo?Yayamoto  Noriaki?Gohda  Hong-Quang?Nguyen  Hong?Zheng 《Journal of Oceanography》2005,61(2):283-294

Tidal current structures at the Hayatomono-Seto of the Kanmon Strait are mapped continuously during March 17 to 20, 2003, including a spring tide, by the eight coastal acoustic tomography (CAT) systems distributed on both the sides of the strait. Detailed structures of strong tidal currents and their associated vortices are well reconstructed by the inverse analysis of travel-time difference data obtained from the reciprocal sound transmission between the paired CAT systems located at both sides of the strait mainly. The results are well compared to the shipboard acoustic Doppler current profiler (ADCP) data at the correlation rate of 0.84/0.82 and the RMS difference of 0.47/0.48 ms⁻¹ for the east-west/north-south current after the selection of good data. During the observation period, the maximum hourly mean volume transport for the upper 7 m layer across the strait reached 13,314 m³ s⁻¹ for the eastward and 5,547 m³ s⁻¹ for the westward. The daily mean transport is directed to the eastward and estimated 1,470 m³ s⁻¹ and 2,140 m³ s⁻¹ for March 18 and 19, respectively, when a spring tide occurs.  相似文献   

Anticipated changes in analysis accuracy with the removal of Ocean Weather Ship P     

H. Jean Thiébaux 《大气与海洋》2013,51(4):261-285

Abstract

Analysis error patterns have been established for the Pacific Weather Centre Experiment Area, and comparisons made between errors computed for meteorological observing arrays, including Ocean Weather Ship (OWS) P, and errors computed for several alternative arrays which excluded OWS P. These assessments of the impact of replacing the ocean weather ship with alternative observing equipment indicate that, above the 1000‐mb pressure surface, there will be a significant loss of accuracy in the forecast‐minus‐observation analyses regardless of proposed additional report systems. Near the surface, forecast error variances are estimated to decrease slightly with an increase of reports from buoys and ships of opportunity within the region.

The dependence of the assessments on the data selection procedure and on correlation representations for the region suggest that some loss may be compensated by more efficient use of available data. Refinements in the objective analysis scheme are seen to be especially important to analysis accuracy in regions lacking radiosonde coverage.  相似文献   

PGE geochemical constraints on the origin of the Ni-Cu-PGE sulfide mineralization in the Suoi Cun intrusion,Cao Bang province,Northeastern Vietnam     

Tatyana V. Svetlitskaya  Nadezhda D. Tolstykh  Andrey E. Izokh  Phuong Ngo Thi 《Mineralogy and Petrology》2015,109(2):161-180

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