The rheology of olivine and spinel magnesium germanate (Mg2GeO4): TEM study of the defect microstructures     

Catherine Dupas-Bruzek  Tracy N. Tingle  Harry W. Green II.  Nicole Doukhan  Jean-Claude Doukhan 《Physics and Chemistry of Minerals》1998,25(7):501-514

Synthetic polycrystals of α-Mg₂GeO₄ (with the olivine structure) and γ-Mg₂GeO₄ (with the spinel structure) deformed at high temperature and pressure in their respective stability fields were investigated by analytical transmission electron microscopy. Specimens with a mean grain size of 20–30 µm deform by dislocation glide and/or climb. The predominance of glide versus climb depends on stress and grain orientation. The defect microstructures of both polymorphs are very similar to those observed in their respective silicate analogues, α- and γ-(Mg,Fe)₂SiO₄, and, in the case of the spinel phase, very similar to those observed in magnesium aluminate spinels. These observations suggest that Mg₂GeO₄ is a good rheological analogue for the Earth’s upper mantle. A spinel specimen deformed under the same conditions of temperature and strain rate as an olivine specimen was approximately three times stronger than olivine. In specimens of both phases deformed at or above 1400 K, a thin amorphous film composed of Mg, Ge, and O was detected along some grain boundaries. Grains ≤10 µm diameter surrounded by a film of amorphous phase (>10 nm thick) exhibited low dislocation densities, and deformation appeared to have occurred by grain boundary sliding.  相似文献   

Electron Temperature in the Solar Wind From a Kinetic Collisionless Model: Application to High-Latitude Ulysses Observations     

Karine Issautier  Nicole Meyer-Vernet  Viviane Pierrard  Joseph Lemaire 《Astrophysics and Space Science》2001,277(1-2):189-193

We use a kinetic collisionless model of the solar wind to calculate the radial variation of the electron temperature and obtain analytical expressions at large radial distances. In order to be compared with Ulysses observations, the model, which initially assumed a radial magnetic field, has been generalized to a spiral magnetic field. We present a preliminary comparison with Ulysses observations in the fast solar wind at high heliospheric latitudes. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Total Effect of any Nearly-Diurnal Wobble of the Earth's Axis of Rotation in Latitude and Time Observations. Application to the Paris Astrolabe Observations from 1956.6 to 1973.8     

Nicole Capitaine 《Geophysical Journal International》1975,43(2):573-588

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Vertical hydraulic exchange and the contribution of hyporheic community respiration to whole ecosystem respiration in the River Lahn (Germany)     

Detlev Ingendahl  Dietrich Borchardt  Nicole Saenger  Peter Reichert 《Aquatic Sciences - Research Across Boundaries》2009,71(4):399-410

To quantify the contribution of hyporheic community respiration to whole running-water ecosystem respiration in a cultural landscape setting, we studied the vertical hydraulic exchange in riffle–pool sequences of the River Lahn (Germany). We used flow through curves from four tracer experiments to estimate flow velocities in the surface and subsurface water. Generally, vertical exchange velocities were higher in riffle sections and a high temporal variability was observed (range of values 0.11–1.08 m day⁻¹). We then used (1) the exchange velocities and (2) time series of dissolved oxygen concentration in surface and subsurface water to calculate hyporheic respiration. Hyporheic respiration was estimated in a range of 10–50 mg O₂ m⁻³ day⁻¹ for the upper sediment layer (first 20 cm). It was much lower in the deeper sediment layer (20–40 cm), ranging from 0 to 10 mg O₂ m⁻³ day⁻¹ (volumes are volumes of interstitial water; the average porosity was 20%). We determined primary production and respiration of the biofilm growing on the sediment by modelling dissolved oxygen concentration time series for a 2,450 m long stream reach (dissolved oxygen concentrations with diurnal variations from 8 to 16 mg L⁻¹). Modelled respiration rates ranged from 2 to 21 g O₂ m² day⁻¹. All information was integrated in a system analysis with numerical simulations of respiration with and without sediments. Results indicated that hyporheic respiration accounted for 6 to 14% of whole ecosystem respiration. These values are much lower than in other whole system respiration studies on more oligotrophic river systems.  相似文献   

Institutional design propositions for the governance of adaptation to climate change in the water sector     

Patrick Huntjens  Louis Lebel  Claudia Pahl-Wostl  Jeff Camkin  Roland Schulze  Nicole Kranz 《Global Environmental Change》2012,22(1):67-81

This paper provides an evidence-based contribution to understanding processes of climate change adaptation in water governance systems in the Netherlands, Australia and South Africa. It builds upon the work of Ostrom on institutional design principles for local common pool resources systems. We argue that for dealing with complexities and uncertainties related to climate change impacts (e.g. increased frequency and intensity of floods or droughts) additional or adjusted institutional design propositions are necessary that facilitate learning processes. This is especially the case for dealing with complex, cross-boundary and large-scale resource systems, such as river basins and delta areas in the Netherlands and South Africa or groundwater systems in Western Australia. In this paper we provide empirical support for a set of eight refined and extended institutional design propositions for the governance of adaptation to climate change in the water sector. Together they capture structural, agency and learning dimensions of the adaptation challenge and they provide a strong initial framework to explore key institutional issues in the governance of adaptation to climate change. These institutional design propositions support a “management as learning” approach to dealing with complexity and uncertainty. They do not specify blueprints, but encourage adaptation tuned to the specific features of local geography, ecology, economies and cultures.  相似文献   

Arsenic release from chlorine-promoted alteration of a sulfide cement horizon: Evidence from batch studies on the St. Peter Sandstone,Wisconsin, USA     

Nicole West  Madeline Schreiber  Madeline Gotkowitz 《Applied Geochemistry》2012

Elevated As concentrations have been measured in wells in the St. Peter Sandstone aquifer of eastern Wisconsin, USA. The primary source is As-bearing sulfide minerals (pyrite and marcasite) within the aquifer. There is concern that well disinfection by chlorination may facilitate As release to groundwater by increasing the rate and extent of sulfide oxidation. The objective of this study was to examine the abiotic processes that mobilize As from the aquifer solids during controlled exposure to chlorinated solutions. Thin sections made from sulfidic aquifer material were characterized by quantitative electron probe micro-analysis before and after 24 h exposure to solutions of different Cl₂ concentrations. Batch experiments using crushed aquifer solids were also conducted to examine changes in solution chemistry over 24 h. Results of the combined experiments indicate that Cl₂ addition affects As release and uptake in two ways. First, Cl₂ increases oxidation of sulfide minerals, releasing more As from the mineral structure. Chlorine addition also increases the rate of Fe(II) oxidation and subsequent hydrous ferric oxide (HFO) precipitation, allowing for increased uptake of As onto the mineral surface. Although HFOs can act as sinks for As, they can release As if biogeochemical conditions (e.g. redox, pH) change. These results have implications not only for disinfection of drinking water wells in the study area, but also suggest that introduction of oxidants may adversely affect water quality during aquifer storage and recovery programs in aquifers containing As-bearing minerals.  相似文献   

Micro-arcsecond Celestial Reference Frames： definition and realization Impact of the recent IAU Resolutions     

Nicole Capitaine 《天体物理学报》2012,(8):1162-1184

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Nano dust impacts on spacecraft and boom antenna charging     

Filippo Pantellini  Soraya Belheouane  Nicole Meyer-Vernet  Arnaud Zaslavsky 《Astrophysics and Space Science》2012,341(2):309-314

High rate sampling detectors measuring the potential difference between the main body and boom antennas of interplanetary spacecraft have been shown to be efficient means to measure the voltage pulses induced by nano dust impacts on the spacecraft body itself (see Meyer-Vernet et al. in Sol. Phys. 256:463, 2009). However, rough estimates of the free charge liberated in post impact expanding plasma cloud indicate that the cloud’s own internal electrostatic field is too weak to account for measured pulses as the ones from the TDS instrument on the STEREO spacecraft frequently exceeding 0.1 V/m. In this paper we argue that the detected pulses are not a direct measure of the potential structure of the plasma cloud, but are rather the consequence of a transitional interruption of the photoelectron return current towards the portion of the antenna located within the expanding cloud.  相似文献   

On the driving force of cation exchange in clays: Insights from combined microcalorimetry experiments and molecular simulation     

Benjamin Rotenberg  Jean-Pierre Morel  Pierre Turq  Nicole Morel-Desrosiers 《Geochimica et cosmochimica acta》2009,73(14):4034-20527

We study the origin of the ionic exchange enthalpy in montmorillonite clays using microcalorimetry measurements and molecular simulation. We first determine the standard reaction enthalpy for well-defined interlayer water contents. We then show by a detailed analysis based on thermodynamic cycles that replacing Na⁺ ions by Cs⁺ in the interlayer of montmorillonite clays is an endothermic process, and that the overall exchange is exothermic only because it is dominated by the exothermic replacement of Cs⁺ by Na⁺ in the aqueous phase. This conclusion from ionic exchange enthalpies supports the one of a recent study of the ionic exchange free energy by Teppen and Miller [Teppen B. J. and Miller D. M. (2006) Hydration energy determines isovalent cation exchange selectivity by clay minerals. Soil Sci. Soc. Am. J.70(1), 31-40] and contradicts long-held views on the role of ion-clay interactions in determining the ionic exchange thermodynamics. This calls for a paradigm shift for the origin of this exchange: The driving force is the “hydrophobicity” of Cs⁺ compared to Na⁺ and not its affinity for clay surfaces.  相似文献   

The oxidation state of sulfur in synthetic and natural glasses determined by X-ray absorption spectroscopy   总被引：1，自引：0，他引：1  

Nicole Métrich  Andrew J. Berry  Jean Susini 《Geochimica et cosmochimica acta》2009,73(8):2382-7631

Sulfur K-edge X-ray absorption near edge structure (XANES) spectra were recorded for experimental glasses of various compositions prepared at different oxygen fugacities (fO₂) in one-atmosphere gas-mixing experiments at 1400 °C. This sample preparation method only results in measurable S concentrations under either relatively reduced (log fO₂ < −9) or oxidised (log fO₂ > −2) conditions. The XANES spectra of the reduced samples are characterised by an absorption edge crest at 2476.4 eV, typical of S²⁻. In addition, spectra of Fe-bearing compositions exhibit a pronounced absorption edge shoulder. Spectra for all the Fe-free samples are essentially identical, as are the spectra for the Fe-bearing compositions, despite significant compositional variability within each group. The presence of a sulfide phase, such as might exsolve on cooling, can be inferred from a pre-edge feature at 2470.5 eV.The XANES spectra of the oxidised samples are characterised by an intense transition at 2482.1 eV, typical of the sulfate anion SO₄²⁻. Sulfite (SO₃²⁻) has negligible solubility in silicate melts at low pressures. The previous identification of sulfite species in natural glass samples is attributed to an artefact of the analysis (photoreduction of S⁶⁺). S⁴⁺ does, however, occur unambiguously with S⁶⁺ in Fe-free and Fe-poor compositions prepared in equilibrium with CaSO₄ at 4-16 kbar, and when buffered with Re/ReO₂ at 10 kbar. Solubility of S⁴⁺ thus requires partial pressures of SO₂ considerably in excess of 1 bar. A number of experiments were undertaken in an attempt to access intermediate fO₂s more applicable to terrestrial volcanism. Although these were largely unsuccessful, S²⁻ and S⁶⁺ were found to coexist in some samples that were not in equilibrium with the imposed fO₂.The XANES spectra of natural olivine-hosted melt inclusions and submarine glasses representative of basalts at, or close to, sulfide saturation show mainly dissolved S²⁻, but with minor sulfate, and additionally a peak at 2469.5 eV, which, although presumably due to immiscible sulfide, is 1 eV lower than that typical of FeS. These sulfate and sulfide-related peaks disappear with homogenisation of the inclusions by heating to 1200 °C followed by rapid quenching, suggesting that both these features are a result of cooling under natural conditions. The presence of small amounts of sulfate in otherwise reduced basaltic magmas may be explained by the electron exchange reaction: S²⁻ + 8Fe³⁺ = S⁶⁺ + 8Fe²⁺, which is expected to proceed strongly to the right with decreasing temperature. This reaction would explain why S²⁻ and S⁶⁺ are frequently found together despite the very limited fO₂ range over which they are thermodynamically predicted to coexist. The S XANES spectra of water-rich, highly oxidised, basaltic inclusions hosted in olivine from Etna and Stromboli confirm that nearly all S is dissolved as sulfate, explaining their relatively high S contents.  相似文献