Intense pyrite formation under low-sulfate conditions in the Achterwasser lagoon, SW Baltic Sea   总被引：1，自引：0，他引：1  

Thomas Neumann  Nicole Rausch  Thomas Leipe  Zsolt Berner 《Geochimica et cosmochimica acta》2005,69(14):3619-3630

In comparison to similar low-sulfate coastal environments with anoxic-sulfidic sediments, the Achterwasser lagoon, which is part of the Oder estuary in the SW Baltic Sea, reveals unexpectedly high pyrite concentrations of up to 7.5 wt%. Pyrite occurs mainly as framboidal grains variable in size with diameters between 1 and 20 μm. Pyritization is not uniform down to the investigated sediment depth of 50 cm. The consumption of reactive-Fe is most efficient in the upper 20 cm of the sediment column, leading to degrees of pyritization (DOP) as high as 80 to 95%.Sediment accumulation in the Achterwasser takes place in high productivity waters. The content of organic carbon reaches values of up to 10 wt%, indicating that pyrite formation is not limited by the availability of organic matter. Although dissolved sulfate concentration is relatively low (<2 mmol/L) in the Achterwasser, the presence of H₂S in the pore water suggests that sulfate is unlikely to limit pyrite authigenesis. The lack of free Fe(II) in the pore waters combined with the possibility of a very efficient transformation of Fe-monosulfides to pyrite near the sediment/water interface suggests that pyrite formation is rather controlled by (i) the availability of reactive-Fe, which limits the FeS formation, and by (ii) the availability of an oxidant, which limits the transformation of FeS into pyrite. The ultimate source for reactive-Fe is the river Oder, which provides a high portion of reactive-Fe (∼65% of the total-Fe) in the form of suspended particulate matter. The surficial sediments of the Achterwasser are reduced, but are subject to oxidation from the overlying water by resuspension. Oxidation of the sediments produces sulfur species with oxidation states intermediate between sulfide and sulfate (e.g., thiosulfate and polysulfides), which transform FeS to FeS₂ at a significant rate. This process of FeS-recycling is suggested to be responsible for the formation of pyrite in high concentrations near the sediment surface, with DOP values between 80 and 95% even under low sulfate conditions.A postdepositional sulfidization takes place in the deeper part of the sediment column, at ∼22 cm depth, where the downward diffusion of H₂S is balanced by the upward migration of Fe(II). The vertical fluctuation of the diffusion front intensifies the pyritization of sediments. We suggest that the processes described may occur preferentially in shallow water lagoons with average net-sedimentation rates close to zero. Such environments are prone to surficial sediment resuspension, initiating oxidation of Fe-sulfides near the sediment/water interface. Subsequent FeS₂ formation as well as postdepositional sulfidization leads to a major pyrite spike at depth within the sediment profile.  相似文献   

Designing Service Architectures for Distributed Geoprocessing: Challenges and Future Directions   总被引：5，自引：0，他引：5  

Anders Friis-Christensen  Nicole Ostländer  Michael Lutz  Lars Bernard 《Transactions in GIS》2007,11(6):799-818

In this paper we study the feasibility of using services offered by a Spatial Data Infrastructure as a basis for distributed service oriented geoprocessing. By developing a prototype we demonstrate that a Spatial Data Infrastructure facilitates rapid development of applications that solve typical problems for an existing risk management application. The prototype provides users with a distributed application that enables the assessment of fire damage areas based on land cover data in a given area. The services involved in the application include: Web Feature Services, Web Map Services, a Gazetteer Service, a Catalogue Service, and Geoprocessing Services. We present the architecture of the application and describe details about implementation‐specific issues. We conclude that current OGC specifications provide a sound basis for developing service oriented architectures for geographic applications; however, in particular for geoprocessing applications, we question the feasibility of the use of Web Feature Services as data sources for larger amounts of data and call for further research in this direction.  相似文献   

Molecular environment of iodine in naturally iodinated humic substances: Insight from X-ray absorption spectroscopy     

Michel L. Schlegel  Pascal Reiller  Nicole Barré  Valérie Moulin 《Geochimica et cosmochimica acta》2006,70(22):5536-5551

The molecular environment of iodine in reference inorganic and organic compounds, and in dry humic and fulvic acids (HAs and FAs) extracted from subsurface and deep aquifers was probed by iodine L₃-edge X-ray absorption spectroscopy. The X-ray absorption near-edge structure (XANES) of iodine spectra from HAs and FAs resembled those of organic references and displayed structural features consistent with iodine forming covalent bonds with organic molecules. Simulation of XANES spectra by linear combination of reference spectra suggested the predominance of iodine forming covalent bonds to aromatic rings (aromatic-bound iodine). Comparison of extended X-ray absorption fine structure (EXAFS) spectra of reference and samples further showed that iodine was surrounded by carbon shells at distances comparables to those for references containing aromatic-bound iodine. Quantitative analysis of EXAFS spectra indicated that iodine was bound to about one carbon at a distance d (I-C) of 2.01(4)-2.04(9) Å, which was comparable to the distances observed for aromatic-bound iodine in references (1.99(1)-2.07(6) Å), and significantly shorter than that observed for aliphatic-bound iodine (2.15(2)-2.16(2) Å). These results are in agreement with previous conclusions from X-ray photoelectron spectroscopy and from electrospray ionization mass spectrometry. These results collectively suggest that the aromatic-bound iodine is stable in the various aquifers of this study.  相似文献   

Factors Controlling Phytoplankton Biomass in a Subtropical Coastal Lagoon: Relative Scales of Influence     

Nicole Dix  Edward Phlips  Peter Suscy 《Estuaries and Coasts》2013,36(5):981-996

Patterns in phytoplankton biomass are essential to understanding estuarine ecosystem structure and function and are the net result of various gain and loss processes. In this study, patterns in phytoplankton biomass were explored in relation to a suite of potentially regulating factors in a well-flushed, subtropical lagoon, the Matanzas River Estuary (MRE) in northeast Florida. We examined temporal variability in water temperature, light availability, nutrient concentrations, phytoplankton productivity, and phytoplankton standing stock over 8 years (2003–2010) and explored relationships among variables through correlation analysis. Laboratory experiments in the spring and summer of 2009 quantified phytoplankton growth rates, nutrient limitation potential, and zooplankton grazing rates. The potential influence of oyster grazing was also examined by scaling up population metrics and filtration rate estimates. Results indicated that phytoplankton biomass in the study area was relatively low mainly due to a combination of low temperature and light availability in the winter and consistent tidal water exchange and bivalve grazing throughout the year. Relatively low levels of phytoplankton standing stock and small inter-annual variability within the MRE reflect a balance between gain and loss processes which provide a degree of resilience of the system to natural and anthropogenic influences.  相似文献   

Saturn’s F ring as seen by Cassini UVIS: Kinematics and statistics     

Nicole Albers  Miodrag Sremčević  Joshua E. Colwell  Larry W. Esposito 《Icarus》2012,217(1):367-388

We present a new orbital model of Saturn’s F ring core based on 93 occultations by the Cassini Ultraviolet Imaging Spectrograph (UVIS) and the Voyager radio and stellar occultations. We demonstrate that the core, despite its intrinsic variability, is well-described as an inclined, freely precessing ellipse. We find that post-fit residuals with a root-mean-square of 24 km are genuine, representing the well-known non-Keplerian features observed in the ring. Over the nearly 4 years of UVIS observations we find the residual variance to increase, coincident with the apse anti-alignment of Prometheus and F ring core in December 2009. This increase in dynamical F ring core temperature most likely reflects the ever-stronger perturbations by Prometheus. Our results are in good agreement with Earth-based and HST observations as well as Voyager imaging.Cassini UVIS stellar occultations resolve the F ring at unprecedented resolutions of a few meters and we identify the F ring core and inner and outer strands. We infer their normal optical depth and full width at half maximum (FWHM) and show that core and strands form distinct morphological groups. Typically, a strand is about ten times wider than the core (average FWHM is ～10 km) while having a ten times smaller optical depth. Unlike in pre-Cassini occultations the F ring core displays significant optical depth with in some cases >3. In many cases we find a narrow optically thick component (～ few km and τ > 0.5) embedded in the F ring core. Entertaining the possibility that this is the actual, “true” F ring core then UVIS results suggest that this “true” core is highly non-continuous. In addition, we report the detection of a previously unknown structure – dubbed the “secondary” as it visually resembles the F ring core. Its morphology is similar to that of the core in optical depth and FWHM and it displays individual opaque features. Despite its core-like appearance, we show that its kinematics is consistent with that of strands. We conclude that it is the most prominent strand seen to date. It represents a striking example of strand creation resulting in what could be called a morphological “small-scale” version of the F ring core. This extraordinary object should be one of the prime targets of future F ring studies.  相似文献   

Micro-arcsecond Celestial Reference Frames: definition and realization - Impact of the recent IAU Resolutions     

Nicole Capitaine 《中国天文和天体物理学报》2012,12(8)

The adoption of the International Celestial Reference System (ICRS),based on Very Long Baseline Interferometry (VLBI) observations of extragalactic radiosources by the International Astronomical Union ...  相似文献   

Geophysical applications across the US Critical Zone Observatories (CZO) and future CZOs for the pan-Canadian EON-ROSE research initiative     

Katherine Boggs  Nicole West  Pamela Sullivan  Edward Johnson 《《地质学报》英文版》2018,92(Z1):154-155

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Erratum to: The year-long unprecedented European heat and drought of 1540 – a worst case     

Oliver Wetter  Christian Pfister  Johannes P. Werner  Eduardo Zorita  Sebastian Wagner  Sonia I. Seneviratne  Jürgen Herget  Uwe Grünewald  Jürg Luterbacher  Maria-Joao Alcoforado  Mariano Barriendos  Ursula Bieber  Rudolf Brázdil  Karl H. Burmeister  Chantal Camenisch  Antonio Contino  Petr Dobrovolný  Rüdiger Glaser  Iso Himmelsbach  Andrea Kiss  Oldřich Kotyza  Thomas Labbé  Danuta Limanówka  Laurent Litzenburger  Øyvind Nordli  Kathleen Pribyl  Dag Retsö  Dirk Riemann  Christian Rohr  Werner Siegfried  Johan Söderberg  Jean-Laurent Spring 《Climatic change》2014,125(3-4):365-367

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The year-long unprecedented European heat and drought of 1540 – a worst case     

Oliver Wetter  Christian Pfister  Johannes P. Werner  Eduardo Zorita  Sebastian Wagner  Sonia I. Seneviratne  Jürgen Herget  Uwe Grünewald  Jürg Luterbacher  Maria-Joao Alcoforado  Mariano Barriendos  Ursula Bieber  Rudolf Brázdil  Karl H. Burmeister  Chantal Camenisch  Antonio Contino  Petr Dobrovolný  Rüdiger Glaser  Iso Himmelsbach  Andrea Kiss  Oldřich Kotyza  Thomas Labbé  Danuta Limanówka  Laurent Litzenburger  Øyvind Nordl  Kathleen Pribyl  Dag Retsö  Dirk Riemann  Christian Rohr  Werner Siegfried  Johan Söderberg  Jean-Laurent Spring 《Climatic change》2014,125(3-4):349-363

The heat waves of 2003 in Western Europe and 2010 in Russia, commonly labelled as rare climatic anomalies outside of previous experience, are often taken as harbingers of more frequent extremes in the global warming-influenced future. However, a recent reconstruction of spring–summer temperatures for WE resulted in the likelihood of significantly higher temperatures in 1540. In order to check the plausibility of this result we investigated the severity of the 1540 drought by putting forward the argument of the known soil desiccation-temperature feedback. Based on more than 300 first-hand documentary weather report sources originating from an area of 2 to 3 million km², we show that Europe was affected by an unprecedented 11-month-long Megadrought. The estimated number of precipitation days and precipitation amount for Central and Western Europe in 1540 is significantly lower than the 100-year minima of the instrumental measurement period for spring, summer and autumn. This result is supported by independent documentary evidence about extremely low river flows and Europe-wide wild-, forest- and settlement fires. We found that an event of this severity cannot be simulated by state-of-the-art climate models.  相似文献   

Mapping Benthic Habitats in Delaware Bay and the Coastal Atlantic: Acoustic Techniques Provide Greater Coverage and High Resolution in Complex, Shallow-Water Environments     

Nicole A. Raineault  Arthur C. Trembanis  Douglas C. Miller 《Estuaries and Coasts》2012,35(2):682-699

Accurate benthic habitat maps are critical for resource management in coastal waters with competing uses. We used a 500 kHz phase-measuring bathymetric sonar (PMBS) and 900 kHz side-scan sonar to acquire seafloor data in estuarine and shelf environments. Grab samples and remotely operated vehicle video created geological and biological classifications for segmented maps produced by a backscatter clustering program. PMBS improves regional map resolution (<1 m), reduces the need for direct sampling, extends information on sediment–biological relationships to larger areas, and allows measurements of bedforms. Auto-segmentation was successful in environments with highly contrasting acoustic signatures and meters-scale homogeneity. Patchier communities are identifiable in PMBS data. Species preferences for sediment (i.e., tubeworm preference for sediment without shell hash) allowed us to determine potential habitat without identifying individual organisms in acoustic data. PMBS with sufficient ground-truthing offers an efficient way to map seafloor characteristics, which is critical in marine spatial planning efforts.  相似文献