Mobility of arsenic in a Bangladesh aquifer: Inferences from geochemical profiles, leaching data, and mineralogical characterization   总被引：3，自引：0，他引：3  

Christopher H. Swartz  Nicole Keon Blute  Borhan Badruzzman  Daniel Brabander  Jenny Jay  James Besancon  Harold F. Hemond 《Geochimica et cosmochimica acta》2004,68(22):4539-4557

Aquifer geochemistry was characterized at a field site in the Munshiganj district of Bangladesh where the groundwater is severely contaminated by As. Vertical profiles of aqueous and solid phase parameters were measured in a sandy deep aquifer (depth >150 m) below a thick confining clay (119 to 150 m), a sandy upper aquifer (3.5 to 119 m) above this confining layer, and a surficial clay layer (<3.5 m). In the deep aquifer and near the top of the upper aquifer, aqueous As levels are low (<10 μg/L), but aqueous As approaches a maximum of 640 μg/L at a depth of 30 to 40 m and falls to 58 μg/L near the base (107 m) of the upper aquifer. In contrast, solid phase As concentrations are uniformly low, rarely exceeding 2 μg/g in the two sandy aquifers and never exceeding 10 μg/g in the clay layers. Solid phase As is also similarly distributed among a variety of reservoirs in the deep and upper aquifer, including adsorbed As, As coprecipitated in solids leachable by mild acids and reductants, and As incorporated in silicates and other more recalcitrant phases. One notable difference among depths is that sorbed As loads, considered with respect to solid phase Fe extractable with 1 N HCl, 0.2 M oxalic acid, and a 0.5 M Ti(III)-citrate-EDTA solution, appear to be at capacity at depths where aqueous As is highest; this suggests that sorption limitations may, in part, explain the aqueous As depth profile at this site. Competition for sorption sites by silicate, phosphate, and carbonate oxyanions appear to sustain elevated aqueous As levels in the upper aquifer. Furthermore, geochemical profiles are consistent with the hypothesis that past or ongoing reductive dissolution of Fe(III) oxyhydroxides acts synergistically with competitive sorption to maintain elevated dissolved As levels in the upper aquifer. Microprobe data indicate substantial spatial comapping between As and Fe in both the upper and deep aquifer sediments, and microscopic observations reveal ubiquitous Fe coatings on most solid phases, including quartz, feldspars, and aluminosilicates. Extraction results and XRD analysis of density/magnetic separates suggest that these coatings may comprise predominantly Fe(II) and mixed valence Fe solids, although the presence of Fe(III) oxyhydroxides can not be ruled out. These data suggest As release may continue to be linked to dissolution processes targeting Fe, or Fe-rich, phases in these aquifers.  相似文献   

Characterisation of the seismological pattern in a slowly deforming intraplate region: Central and western France     

Yves Mazabraud  Nicole Bthoux  Sbastien Deroussi 《Tectonophysics》2005,409(1-4):175-192

We analyzed the seismicity of central and western France, using historical data, a compilation of all recorded earthquakes from 1962 to 2002 (4574 events, relocated), and all published focal mechanisms (119 focal solutions). The aim is to understand what are the causes of earthquakes and stress accumulation in a slowly deforming intraplate region. The distribution of earthquakes and focal mechanisms is first correlated with recognized faults, geological structures and tomographic images. Then, in order to better understand the distribution of hypocenters and seek deeper crustal sources for stress accumulation, Euler solutions are computed from the available Bouguer anomaly data. The analysis of the obtained pattern for heat flow values, provides a better understanding of the concentration of seismicity in some particular zones.Two different behaviors of this slowly deforming intraplate region are evidenced. One is linked to the presence of a hot spot under the Massif Central, the other to reactivation of the Hercynian structural heritage. Our results highlight that several possible sources for earthquake clustering can be invoked in central–western France.  相似文献   

长白山天池火山千年大喷发岩浆含水量研究——熔融包裹体含水量的红外光谱测试   总被引：1，自引：0，他引：1  

李霓  Nicole  METRICH  樊祺诚 《岩石学报》2006,22(6):1465-1472

长白山天池火山在公元一千年左右曾发生过大规模喷发，其产物为大面积分布的灰白色碱流质浮岩和碎屑流，在其斑晶矿物橄榄石、钙铁辉石和碱性长石中均可见到熔融包裹体。在最主要的斑晶矿物——碱性长石中含有数量众多且个体也较大的熔融包裹体，多数含有一个以上的气泡，其中部分含有子晶，根据形貌特征的不同可分为截然不同的两组包裹体。这些熔融包裹体带有大量喷发前地下岩浆的信息，成为研究地下深部的岩浆在复杂的溢流-爆炸喷发中所发生变化的最好媒介。也是本文的研究对象，通过其中挥发份尤其是水的含量，可以推知天池火山发生大喷发的原因。经Nicolet Magna-IR 550红外光谱仪测定，这些熔融包裹体的含水量较高，达1．6％-3．6％，为当时天池火山发生了巨大规模爆炸喷发的原因提供了强有力的证据。但目前红外光谱仪的应用范围还比较有限，有待今后拓宽其应用领域。  相似文献   

Dust in Hostile Environments     

Jean-Pierre J. Lafon  Nicole Berruyer 《Astrophysics and Space Science》1998,260(1-2):265-268

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Sediment accumulation along a glacially impacted mountainous coastline: north-east Gulf of Alaska   总被引：2，自引：0，他引：2  

John M. Jaeger  Charles A. Nittrouer  Nicole D. Scott  & John D. Milliman 《Basin Research》1998,10(1):155-173

Tectonically active coastal regions of the world recently have been suggested to supply the bulk of sediment from land to the oceans. Seabed sampling on the continental shelf and in coastal embayments of the north-east Gulf of Alaska (Alsek River to Prince William Sound) was performed to examine the temporal and spatial variability of sediment accumulation in a mountainous coastal setting. Cores of varying lengths (30–300 cm) were collected at 84 stations to provide information on sedimentary processes using radiochemical (²¹⁰Pb and ¹³⁷Cs) techniques. Four types of ²¹⁰Pb activity profiles were observed, dominantly reflecting steady-state sediment accumulation. However, nonsteady-state profiles also were measured, resulting in part from episodic deposition near glacier-fed rivers and on the Copper River Delta. Sediment accumulation rates in the eastern half of the study area are highest at midshelf depths (≈100 m) (≥10 mm yr^?1) and near rivers draining the Bering Glacier (≈20 mm yr^?1). On the Copper River Delta, sediment accumulation rates are highest for the delta front (> 20 mm yr^?1) and decrease westward along the sediment dispersal route. Total annual sediment accumulation is 90–140×10⁶ tons yr^?1 on the shelf in the study area. Annual sediment accumulation for the total marine environment in the study area (including Icy and Yakutat Bays) exceeds 250×10⁶ tons yr^?1, potentially making this region the largest sink for sediment in North America. Spatial patterns in sediment accumulation on the shelf are similar between centennial and Holocene time-scales, reflecting the dominance of the Copper River and Bering and Malaspina glaciers as sediment sources. Temporal variability in accumulation rates between centennial and Holocene time-scales exists for portions of the study area near fiords and demonstrates the considerable changes that occur in sediment supply during glacial advances and retreats.  相似文献   

Archean adakites from the Ashuanipi complex,eastern Superior Province,Canada: geochemistry,geochronology and tectonic significance   总被引：1，自引：0，他引：1  

Percival  John A.  Stern  Richard A.  Rayner  Nicole 《Contributions to Mineralogy and Petrology》2003,145(3):265-280

Contributions to Mineralogy and Petrology - Adakitic geochemical features characterize the Desliens suite of pre-tectonic diorite to tonalite sills intruded into volcanogenic greywackes of the...  相似文献   

Holocene paleoenvironmental change inferred from two sediment cores collected in the Tibetan lake Taro Co     

Laug  Andreas  Haberzettl  Torsten  Pannes  Andre  Schwarz  Anja  Turner  Falko  Wang  Junbo  Engels  Stefan  Rigterink  Sonja  Börner  Nicole  Ahlborn  Marieke  Ju  Jianting  Schwalb  Antje 《Journal of Paleolimnology》2021,66(3):171-186

Journal of Paleolimnology - The Tibetan Plateau, also known as the “Water Tower of Asia” because of its function as a water storage and supply region, responds dramatically to modern...  相似文献   

The influence of sampling design on spatial data quality in a geographic citizen science project     

Greg Brown  Jonathan Rhodes  Daniel Lunney  Ross Goldingay  Kelly Fielding  Nicole Garofano  Scott Hetherington  Marama Hopkins  Jo Green  Skye McNamara  Angie Brace  Lorraine Vass  Linda Swankie  Clive McAlpine 《Transactions in GIS》2019,23(6):1184-1203

Geographic citizen science has much potential to assist in wildlife research and conservation, but the quality of observation data is a key concern. We examined the effects of sampling design on the quality of spatial data collected for a koala citizen science project in Australia. Data were collected from three samples—volunteers (n = 454), an Internet panel (n = 103), and landowners (n = 35)—to assess spatial data quality, a dimension of citizen science projects rarely considered. The locational accuracy of koala observations among the samples was similar when benchmarked against authoritative data (i.e., an expert‐derived koala distribution model), but there were differences in the quantity of data generated. Fewer koala location data were generated per participant by the Internet panel sample than the volunteer or landowner samples. Spatial preferences for land uses affecting koala conservation were also mapped, with landowners more likely to map locations for residential and tourism development and volunteers less likely. These spatial preferences have the potential to influence the social acceptability of future koala conservation proposals. With careful sampling design, both citizen observations and land use preferences can be included within the same project to augment scientific assessments and identify conservation opportunities and constraints.  相似文献   

Insights about the formation of a complex impact structure formed in basalt from numerical modeling: The Vista Alegre structure,southern Brazil     

Marcos Alberto Rodrigues Vasconcelos  Fernanda Farias Rocha  Alvaro Penteado Crsta  Kai Wünnemann  Nicole Güldemeister  Emilson Pereira Leite  Júlio Csar Ferreira  Wolf Uwe Reimold 《Meteoritics & planetary science》2019,54(10):2373-2383

We present the outcomes of simulations of the formation of the Vista Alegre impact structure, Paraná Basin, Brazil. The target comprised a thick sequence of volcanic rocks of predominantly basaltic composition of the Serra Geral Formation that had been deposited on top of sedimentary rocks (sandstones) of the Pirambóia/Botucatu formations. The cratering process was modeled using the iSALE shock physics code. Our best‐fit model suggests that (1) the crater was originally ~10 km in size; (2) it was formed in ~115 s by a stony projectile of 1000 m in diameter, for an assumed impact velocity of 12 km s^?1; (3) target rocks underwent a peak pressure of ~20 GPa, in agreement with previous petrographic investigations of shock deformation. Furthermore, the model points out that the sedimentary strata below the layer of volcanic rocks were raised by ~650 meters at the central part of the crater, which resulted in the current partial exposure of the sandstones at the surface. The outcomes of our modeling suggest that parameters like cohesion and strength of the target rocks, after shock compression, determined the final morphology of the crater, especially the absence of a topographically prominent central peak. Finally, the results of the numerical modeling are roughly in agreement with gravity data over the structure, in particular with respect to the presence of the uplifted sedimentary strata, which are responsible for a low gravity signature at the center of the structure.  相似文献   

Dacite formation on Vesta: Partial melting of the eucritic crust          下载免费PDF全文

Timothy M. Hahn Jr.  Nicole G. Lunning  Harry Y. McSween Jr.  Robert J. Bodnar  Lawrence A. Taylor 《Meteoritics & planetary science》2017,52(6):1173-1196

The Dominion Range 2010 howardite pairing group contains an evolved lithic clast of dacite composition. The dacite contains an assemblage of plagioclase, quartz, and augite, with minor pigeonite, troilite, ilmenite, FeNi metal, K‐feldspar, and phosphates. Primary augite occurs as >1 mm oikocrysts enclosing plagioclase. Quartz is abundant, comprising approximately 30% of the clast. Textural and geochemical characteristics support the hypothesis that the dacite is a primary igneous lithology, and represents a partial melt of the eucritic crust. Numerical modeling (MELTS) suggests 10–20% partial melting of a Juvinas source could have produced the dacite lithology; quantitative trace element modeling further supports crustal partial melting as the magma source for the dacite. The dacite likely formed as evolved‐melt pockets, and thus represents a volumetrically minor lithology in the Vestan crust, although its formation provides direct support for a genetic relationship between Stannern and residual trend eucrites, and is the first identification of residual eucrite complementary melts. We propose the dacite clast is the first characterized sample of tertiary crust on Vesta.  相似文献