Coupling spatial geochemical and lithological information to distinguish silicate and non-silicate chemical weathering fluxes     

Jens Hartmann  Nils Moosdorf 《Applied Geochemistry》2011

Lithological maps have been proved to be a useful tool to evaluate regional and global matter fluxes from chemical weathering. However, lithological classes provide aggregated information of mineralogical, geochemical, sedimentary or diagenetic properties. Thus, using a limited number of lithological classes introduces by their definition a bias to the analysis of weathering fluxes, specifically in the case of multilithological catchments. Here it is shown that the coupling of geochemical with lithological information may help to better identify the sources of the weathering fluxes, using the example of dissolved Ca to better distinguish weathering rates of silicate and non-silicate minerals.  相似文献   

Chromite oxidation by manganese oxides in subseafloor basalts and the presence of putative fossilized microorganisms     

Ivarsson M  Broman C  Holm NG 《Geochemical transactions》2011,12(1):5-10

Chromite is a mineral with low solubility and is thus resistant to dissolution. The exception is when manganese oxides are available, since they are the only known naturally occurring oxidants for chromite. In the presence of Mn(IV) oxides, Cr(III) will oxidise to Cr(VI), which is more soluble than Cr(III), and thus easier to be removed. Here we report of chromite phenocrysts that are replaced by rhodochrosite (Mn(II) carbonate) in subseafloor basalts from the Koko Seamount, Pacific Ocean, that were drilled and collected during the Ocean Drilling Program (ODP) Leg 197. The mineral succession chromite-rhodochrosite-saponite in the phenocrysts is interpreted as the result of chromite oxidation by manganese oxides. Putative fossilized microorganisms are abundant in the rhodochrosite and we suggest that the oxidation of chromite has been mediated by microbial activity. It has previously been shown in soils and in laboratory experiments that chromium oxidation is indirectly mediated by microbial formation of manganese oxides. Here we suggest a similar process in subseafloor basalts.  相似文献   

Atmospheric winter response to a projected future Antarctic sea-ice reduction: a dynamical analysis     

Jürgen Bader  Martin Flügge  Nils Gunnar Kvamstø  Michel D. S. Mesquita  Aiko Voigt 《Climate Dynamics》2013,40(11-12):2707-2718

Several studies have analysed the atmospheric response to sea-ice changes in the Arctic region, but only few have considered the Antarctic. Here, the atmospheric response to sea-ice variability in the Southern Hemisphere is investigated with the atmospheric general circulation model ECHAM5. The model is forced by the present and a projected future seasonal cycle of Antarctic sea ice. In September, the mean atmospheric response exhibits distinct similarities to the structure of the negative phase of the Southern Annular Mode, the leading mode of Southern Hemisphere variability. In the reduced Antarctic sea-ice integration, there is an equatorward shift of the Southern Hemisphere mid-latitude jet and the storm tracks. In contrast to a recent previous study, our findings indicate that a substantial impact of Southern Hemispheric future sea-ice reduction on the mid-latitude circulation cannot be ruled out.  相似文献   

Forecasts of hydrological parameters over the Mackenzie River Basin: Sensitivity to initial conditions,horizontal resolution and forecast range     

Nils Ek  Harold Ritchie 《大气与海洋》2013,51(4):675-710

Abstract

As part of the Global Energy and Water Cycle Experiment, Canadian global spectral forecast model predictions of surface water and energy fluxes over the Mackenzie River basin are examined. Two nine‐member ensemble forecasts of one month duration are produced with the operational model, for a spring and a summer case, at a horizontal resolution of about 100 km (T95). The sensitivity to initial conditions is measured by the degree to which the individual forecasts in the ensembles vary one from another. The evolution in time of this estimated error (ensemble standard deviation) is determined for the surface energy and water accumulations, averaged over the basin. For comparison the calculations are repeated for the Mississippi basin and over North America. The greatest sensitivity is found for the net accumulation of precipitation minus evaporation. The spring ensemble is redone at a coarser horizontal resolution (T47), and the results are similar. The forecast uncertainty (ensemble standard deviation) of the area‐averages over the basin appear to be unaffected by this change, although the ensemble mean values are sensitive to the change in resolution. The ensemble standard deviation makes a significant, abrupt increase toward the end of the second week into the forecasts. This investigation suggests a need for an improved model, if the forecasts’ useful range is to extend to one month. Available upgrades to the land‐surface, precipitation and evaporation schemes will be used in subsequent work, and the forecasts reported here will serve as a baseline for comparison.  相似文献   

The spin evolution of nascent neutron stars     

Anna L. Watts  Nils Andersson 《Monthly notices of the Royal Astronomical Society》2002,333(4):943-951

The loss of angular momentum owing to unstable r-modes in hot young neutron stars has been proposed as a mechanism for achieving the spin rates inferred for young pulsars. One factor that could have a significant effect on the action of the r-mode instability is fallback of supernova remnant material. The associated accretion torque could potentially counteract any gravitational-wave-induced spin-down, and accretion heating could affect the viscous damping rates and hence the instability. We discuss the effects of various external agents on the r-mode instability scenario within a simple model of supernova fallback on to a hot young magnetized neutron star. We find that the outcome depends strongly on the strength of the magnetic field of the star. Our model is capable of generating spin rates for young neutron stars that accord well with initial spin rates inferred from pulsar observations. The combined action of r-mode instability and fallback appears to cause the spin rates of neutron stars born with very different spin rates to converge, on a time-scale of approximately 1 year. The results suggest that stars with magnetic fields ≤10¹³ G could emit a detectable gravitational wave signal for perhaps several years after the supernova event. Stars with higher fields (magnetars) are unlikely to emit a detectable gravitational wave signal via the r-mode instability. The model also suggests that the r-mode instability could be extremely effective in preventing young neutron stars from going dynamically unstable to the bar-mode.  相似文献   

Evolving turbulence and magnetic fields in galaxy clusters     

Kandaswamy Subramanian  Anvar Shukurov  Nils Erland L. Haugen 《Monthly notices of the Royal Astronomical Society》2006,366(4):1437-1454

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Fluid–Rock Interactions in Geothermal Reservoirs,Germany: Thermal Autoclave Experiments Using Sandstones and Natural Hydrothermal Brines     

Schäffer  Rafael  Götz  Emilia  Schlatter  Nils  Schubert  Gabriela  Weinert  Sebastian  Schmidt  Stefanie  Kolb  Ute  Sass  Ingo 《Aquatic Geochemistry》2022,28(2):63-110

As renewable energy, geothermal can contribute substantially to the energy transition. To generate electricity or to harvest heat, high-saline fluids are tapped by wells of a few kilometres and extracted from hydrothermal reservoirs. After the heat exchanger units have been passed by, these fluids are reinjected into the reservoir. Due to the pressure and temperature differences between the subsurface and the surface, as well as the cooling of the fluids in the power plant, unwanted chemical reactions can occur within the reservoir, in the borehole, and within the power plant itself. This can reduce the permeability of the reservoir as well as the output of the geothermal power plant. This study aims to simulate real subsurface reactions using batch and leaching experiments with sandstone or sandstone powder as solid phase, and deionised water or natural brine as liquid phase. It is demonstrated that fluid composition changes after only a few days. In particular, calcite, aragonite, clay minerals, and zinc phases precipitate from the natural brine. In contrast, in particular minerals containing potassium, arsenic, barium, and silica are dissolved. Due to the experimental set-up, these mineral reactions mainly took place on the surface of the samples, which is why no substantial changes in petrophysical properties could be observed. However, it is assumed that the observed reactions on the reservoir scale have a relevant influence on parameters such as permeability.

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Recolonisation by Macrobenthos Mobilises Organic Phosphorus from Reoxidised Baltic Sea Sediments     

Nils Ekeroth  Magnus Lindstr?m  Sven Blomqvist  Per O. J. Hall 《Aquatic Geochemistry》2012,18(6):499-513

In recent decades, eutrophication has increased the extent of hypoxic and anoxic conditions in many coastal marine environments. In such conditions, the nutrient flux across the sediment?Cwater interface is a key process controlling the biogeochemical dynamics, and thereby the level and character of biological production. In some areas, management attempts to drive the ecosystem towards phosphorus (P) limitation, which calls for reliable knowledge on the mechanisms controlling P-cycling. We report a well-controlled laboratory experiment on benthic fluxes of P, when shifting from a state of hypoxic and azoic sediments to oxic and zoic bottom conditions. Adding any of three types of macrobenthic fauna (mysid shrimp, pontoporeid amphipod and tellinid clam) to oxygenated aquarium sections resulted in benthic P fluxes that differed consistently from the azoic control sections. All species caused liberation of dissolved organically bound P (DOP) from the sediment, in contrast to the azoic systems. The shrimp and the amphipod also resuspended the sediment, which resulted in a release of P bound to particles (>0.45???m). Dissolved inorganic phosphate (DIP) was released during hypoxic conditions, but was taken up after oxygenation, irrespective of the presence or absence of bottom fauna. In the presence of fauna, the uptake of DIP roughly equalled the release of DOP, suggesting that the benthic efflux of DOP following oxygenation and bottom fauna (re)colonisation might be considerable. This is an hitherto overlooked animal-controlled nutrient flux, which is missing from coastal marine P budgets.  相似文献   

Preferential perihelion and aphelion distances,and planetary formation     

Barricelli  Nils Aall 《Earth, Moon, and Planets》1986,34(1):1-33

An interpretation of a series of precise relationships (Barricelli, 1972a) between planetary perihelion and aphelion distances, leading to the definition of preferential perihelion and aphelion distances, designated as meeting distances is outlined. The interpretation is based on Alfvén's (1969) jet stream theory and the hypothesis of harmonic resonance between intersecting jet streams.  相似文献   

Hydrogeochemical Processes in the Kafue River upstream from the Copperbelt Mining Area, Zambia     

Ulf T. Pettersson  Johan Ingri  Per S. Andersson 《Aquatic Geochemistry》2000,6(4):385-411

Frequent sampling during an annual cycle of dissolved(<0.45 m) and suspended (>0.45 m) elementshas been conducted in the Kafue River at Raglan'sFarm, upstream from the mining activities within theCopperbelt Province, Zambia. Additional sampling ofsediment and interstitial pore water was conductedduring low water discharge. The presence of carbonateswithin the drainage basin naturally gives rise to highelement concentrations in the dissolved phase(Ca = 626, Mg = 494, Na = 360 and K = 24 mmol l^-1).During the rainy season the relative composition ofthe dissolved elements indicated a wash out ofaccumulated weathering products and mineralisedorganic material from the unsaturated zone of the soilprofile. High concentrations of dissolved Al, Fe andMn were measured during high water discharge. At lowwater discharge the sediment was a major source of Fe,Mn and associated Co and Cu to the water column.Enhanced concentrations of dissolved and suspended S,Co and Cu during the rainy season indicated thatatmospheric deposited particles from the mining areawere washed out into the river. Autochthonousformation of particles rich in Si indicated diatomproduction during low water discharge.  相似文献