High precision SIMS oxygen three isotope study of chondrules in LL3 chondrites: Role of ambient gas during chondrule formation     

Noriko T. Kita  Hiroko Nagahara  Shin Tomomura  John H. Fournelle 《Geochimica et cosmochimica acta》2010,74(22):6610-6635

We report high precision SIMS oxygen three isotope analyses of 36 chondrules from some of the least equilibrated LL3 chondrites, and find systematic variations in oxygen isotope ratios with chondrule types. FeO-poor (type I) chondrules generally plot along a mass dependent fractionation line (Δ¹⁷O ∼ 0.7‰), with δ¹⁸O values lower in olivine-rich (IA) than pyroxene-rich (IB) chondrules. Data from FeO-rich (type II) chondrules show a limited range of δ¹⁸O and δ¹⁷O values at δ¹⁸O = 4.5‰, δ¹⁷O = 2.9‰, and Δ¹⁷O = 0.5‰, which is slightly ¹⁶O-enriched relative to bulk LL chondrites (Δ¹⁷O ∼ 1.3‰). Data from four chondrules show ¹⁶O-rich oxygen isotope ratios that plot near the CCAM (Carbonaceous Chondrite Anhydrous Mineral) line. Glass analyses in selected chondrules are systematically higher than co-existing minerals in both δ¹⁸O and Δ¹⁷O values, whereas high-Ca pyroxene data in the same chondrule are similar to those in olivine and pyroxene phenocrysts.Our results suggest that the LL chondrite chondrule-forming region contained two kinds of solid precursors, (1) ¹⁶O-poor precursors with Δ¹⁷O > 1.6‰ and (2) ¹⁶O-rich solid precursors derived from the same oxygen isotope reservoir as carbonaceous chondrites. Oxygen isotopes exhibited open system behavior during chondrule formation, and the interaction between the solid and ambient gas might occur as described in the following model. Significant evaporation and recondensation of solid precursors caused a large mass-dependent fractionation due to either kinetic or equilibrium isotope exchange between gas and solid to form type IA chondrules with higher bulk Mg/Si ratios. Type II chondrules formed under elevated dust/gas ratios and with water ice in the precursors, in which the ambient H₂O gas homogenized chondrule melts by isotope exchange. Low temperature oxygen isotope exchange may have occurred between chondrule glasses and aqueous fluids with high Δ¹⁷O (∼5‰) in LL the parent body. According to our model, oxygen isotope ratios of chondrules were strongly influenced by the local solid precursors in the proto-planetary disk and the ambient gas during chondrule melting events.  相似文献   

The Northwest Africa 1500 meteorite: Not a ureilite,maybe a brachinite     

Cyrena Anne GOODRICH  Noriko T. KITA  Michael J. SPICUZZA  John W. VALLEY  Jutta ZIPFEL  Takashi MIKOUCHI  Masamichi MIYAMOTO 《Meteoritics & planetary science》2010,45(12):1906-1928

Abstract– The Northwest Africa (NWA) 1500 meteorite is an olivine‐rich achondrite containing approximately 2–3 vol% augite, 1–2 vol% plagioclase, 1 vol% chromite, and minor orthopyroxene, Cl‐apatite, metal and sulfide. It was originally classified as a ureilite, but is currently ungrouped. We re‐examined the oxygen three‐isotope composition of NWA 1500. Results of ultra‐high precision (～0.03‰ for Δ¹⁷O) laser fluorination analyses of two bulk chips, and high precision (～0.3‰) secondary ion mass spectrometry (SIMS) analyses of olivine and plagioclase in a thin section, show that the oxygen isotope composition of NWA 1500 (Δ¹⁷O = ?0.22‰ from bulk samples and ?0.18 ± 0.06‰ from 16 mineral analyses) is within the range of brachinites. We compare petrologic and geochemical characteristics of NWA 1500 with those of brachinites and other olivine‐rich primitive achondrites, including new petrographic, mineral compositional and bulk compositional data for brachinites Hughes 026, Reid 013, NWA 5191, NWA 595, and Brachina. Modal mineral abundances, texture, olivine and pyroxene major and minor element compositions, plagioclase major element compositions, rare earth element abundances, and siderophile element abundances of NWA 1500 are within the range of those in brachinites and, in most cases, well distinguished from those of winonaites/IAB silicates, acapulcoites/lodranites, ureilites, and Divnoe. NWA 1500 shows evidence of internal reduction, in the form of reversely zoned olivine (Fo ～65–73 core to rim) and fine‐grained intergrowths of orthopyroxene + metal along olivine grain margins. The latter also occur in Reid 013, Hughes 026, NWA 5191, and NWA 595. We argue that reduction (olivine→enstatite + Fe⁰ + O₂) is the best hypothesis for their origin in these samples as well. We suggest that NWA 1500 should be classified as a brachinite, which has implications for the petrogenesis of brachinites. Fe‐Mn‐Mg compositions of brachinite olivine provide evidence of redox processes among bulk samples. NWA 1500 provides evidence for redox processes on a smaller scale as well, which supports the interpretation that these processes occurred in a parent body setting. SIMS data for ²⁶Al‐²⁶Mg isotopes in plagioclase in NWA 1500 show no ²⁶Mg excesses beyond analytical uncertainties (1–2‰). The calculated upper limit for the initial ²⁶Al/²⁷Al ratio of the plagioclase corresponds to an age younger than 7 Ma after CAI. Compared to ⁵³Mn‐⁵³Cr data for Brachina ( Wadhwa et al. 1998b ), this implies either a much younger formation age or a more protracted cooling history. However, Brachina is atypical and this comparison may not extend to other brachinites.  相似文献   

Verification of predicted non-linear site response during the 1995 Hyogo-Ken Nanbu earthquake     

M. Kawano  K. Asano  H. Dohi  S. Matsuda 《Soil Dynamics and Earthquake Engineering》2000,20(5-8):493-507

The linear and non-linear responses of surface soil layers have been predicted through the simultaneous simulation test against the observed ground motions at the six sites in Kobe City during the 1995 Hyogo-ken Nanbu earthquake. The total stress analysis method and the effective stress analysis method have been applied for the rough and detailed verification of the predicted non-linear dynamic behavior at the PIS and RKI sites including the liquefaction phenomenon. The shear strain distribution along depth, the ratio of excess pore water pressure to initial effective stress, the liquefaction strength parameters to initial effective stress, and the stress–strain curve during the earthquake at the PIS site have been investigated when the predicted ground motion could simulate successfully the observed acceleration time histories and response spectra in the non-linear range.  相似文献   

Transit time evaluation using a chloride concentration input step shift after forest cutting in a Japanese headwater catchment     

Tomoki Oda  Yuko Asano  Masakazu Suzuki 《水文研究》2009,23(19):2705-2713

Mean transit times were estimated for a small headwater catchment in Japan (the Fukuroyamasawa Experimental Watershed) using the step shift in input chloride (Cl^?) concentrations that occurred immediately after an episode of forest clear‐cutting. Measured Cl^? concentrations in stream water began to decrease immediately after clear‐cutting, and this trend continued for 6 years. Before clear‐cutting, the input Cl^? concentrations were controlled by wet and dry deposition processes, and most of the dry Cl^? deposition was collected by the forest canopy and reached the ground as throughfall and stemflow. After clear‐cutting, dry deposition was no longer collected by the canopy in this way, thus causing a sharp decrease in input Cl^? concentrations. By comparing measured Cl^? concentrations in stream water with estimates based on the input and evaporative Cl^? concentrations, it was shown that the decrease in stream water Cl^? concentrations was caused mainly by this step shift in the Cl^? input. It was proposed that the change in Cl^? concentrations after forest cutting could be used to represent the replacement of ‘old’ water that existed before cutting by ‘new’ water that was supplied after cutting. The breakthrough curve for the new water fraction gave an approximately exponential distribution of transit times in flow‐corrected time. The mean flow‐corrected transit time was estimated as 1068 days (runoff: 3497 mm). It was therefore concluded that the step change in input Cl^? concentrations immediately following forest clear‐cutting could be successfully used to estimate transit times for the entire catchment. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Characterization of the Heterogeneous Source Model of Intraslab Earthquakes Toward Strong Ground Motion Prediction     

Tomotaka Iwata  Kimiyuki Asano 《Pure and Applied Geophysics》2011,168(1-2):117-124

We characterize the heterogeneous source slip model of intraslab earthquakes to compare source scaling properties with those of inland crustal and subduction-zone plate-boundary earthquakes. We extracted rupture area (S), total area of asperity (S _a), average slip (D) and average slip on asperity (D _a) of eleven intraslab earthquakes following the procedure proposed by Somerville et al. (Seism Res Lett 70:59?C80, 1999) and proposed the empirical scaling relationship formula of S, S _a, and D for intraslab earthquakes. Under the same seismic moment, an intraslab earthquake has a smaller rupture area and total area of asperity, and smaller average slip than an inland crustal earthquake. The area ratio of asperity area and total rupture area of intraslab earthquakes are similar to those of inland crustal earthquakes. The strong motion generation area (SMGA) scaling of intraslab earthquakes appears self-similar, and those results support the idea the characterized source model of intraslab earthquakes can be modeled in a manner similar to that of inland crustal earthquakes.  相似文献   

Origin of the Tongbai-Dabie-Sulu Neoproterozoic low-δ 18O igneous province, east-central China     

Bin Fu  Noriko T. Kita  Simon A. Wilde  Xiaochun Liu  John Cliff  Alan Greig 《Contributions to Mineralogy and Petrology》2013,165(4):641-662

Zircons from 71 diverse rocks from the Qinling-Tongbai-Dabie-Sulu orogenic belt in east-central China and, for comparison, eight from adjoining areas in the South China and North China blocks, have been analyzed for in situ ¹⁸O/¹⁶O ratio and/or U–Pb age to further constrain the spatial distribution and genesis of Neoproterozoic low-δ ¹⁸O magmas, that is, δ ¹⁸O(zircon) ≤4 ‰ VSMOW. In many metaigneous rock samples from Tongbai-Dabie-Sulu, including high-pressure and ultrahigh-pressure eclogites and associated granitic orthogneisses, average δ ¹⁸O values for Neoproterozoic “igneous” zircon cores (i.e., 800–600 Ma) vary from ?0.9 to 6.9 ‰, and from ?9.9 to 6.8 ‰ for Triassic metamorphic rims (i.e., 245–200 Ma). The former extend to values lower than zircons in primitive magmas from the Earth’s mantle (ca. 5–6 ‰). The average Δ ¹⁸O (metamorphic zircon ? “igneous” zircon) values vary from ?11.6 to 0.9 ‰. The large volume of Neoproterozoic low-δ ¹⁸O igneous protoliths at Tongbai-Dabie-Sulu is matched only by the felsic volcanic rocks of the Snake River Plain hotspot track, which terminates at the Yellowstone Plateau. Hence, the low-δ ¹⁸O values at Tongbai-Dabie-Sulu are proposed to result from shallow subcaldera processes by comparison with Yellowstone, where repeated caldera-forming magmatism and hydrothermal alteration created similar low-δ ¹⁸O magmas. However, the possibility of involvement of meltwaters from local continental glaciations, rather than global Neoproterozoic glaciations, cannot be precluded. Our data indicate that Neoproterozoic low-δ ¹⁸O magmas that are either subduction- or rift-related are present locally along the western margin of the South China Block (e.g., Baoxing Complex). It appears that Neoproterozoic ¹⁸O-depletion events in the South China Block as the result of hydrothermal alteration and magmatism affected a much larger area than was previously recognized.  相似文献   

Mg and Si isotopic fractionation patterns in types B1 and B2 CAIs: Implications for formation under different nebular conditions     

Emma S. Bullock  Kim B. Knight  Frank M. Richter  Noriko T. Kita  Takayuki Ushikubo  Glenn J. MacPherson  Andrew M. Davis  Ruslan A. Mendybaev 《Meteoritics & planetary science》2013,48(8):1440-1458

Magnesium and silicon isotopic profiles across melilite grains in two type B1 and two type B2 calcium‐aluminum‐rich inclusions (CAIs) reveal differing but constant enrichments in heavy isotopes everywhere except ≤1000 μm from the CAI margins. There is no close correlation in the B1s or the B2s between isotopic composition and åkermanite content of the melilite, a measure of progressive igneous crystallization, yet such a correlation might be expected in a type B2: without a melilite mantle (as in B1s) to seal the interior off and prevent further evaporation, the melt would have maintained communication with the external gas. These observations indicate a model in which B1s and B2s solidified under differing conditions. The B2s solidified under lower hydrogen pressures ( ≤ 10^?4 – 10^?5 bars) than did B1s ( > 10^?4 bars), so surface volatilization was slower in the B2s and internal chemical and isotopic equilibrium was maintained over the interval of melilite crystallization. The outermost zones of the CAIs (≤1000 μm from the edge) are not consistently enriched in heavy isotopes relative to the interiors, as might be expected from diffusion‐limited surface evaporation of the melt. In all cases, the magnesium in the CAI margins is lighter than in the interiors. In one case, silicon in the margin also is lighter, but locally in some CAIs, it is isotopically heavier near the surface. If melt evaporation played a role in the formation of these outer zones, a later event in many cases caused isotopic re‐equilibration with an external and isotopically near‐normal reservoir.  相似文献   

Fall,classification, and exposure history of the Mifflin L5 chondrite     

Noriko T. Kita  Kees C. Welten  John W. Valley  Michael J. Spicuzza  Daisuke Nakashima  Travis J. Tenner  Takayuki Ushikubo  Glenn J. MacPherson  Linda Welzenbach  Philipp R. Heck  Andrew M. Davis  Matthias M. M. Meier  Rainer Wieler  Marc W. Caffee  Matthias Laubenstein  Kunihiko Nishiizumi 《Meteoritics & planetary science》2013,48(4):641-655

The Mifflin meteorite fell on the night of April 14, 2010, in southwestern Wisconsin. A bright fireball was observed throughout a wide area of the midwestern United States. The petrography, mineral compositions, and oxygen isotope ratios indicate that the meteorite is a L5 chondrite fragmental breccia with light/dark structure. The meteorite shows a low shock stage of S2, although some shock‐melted veins are present. The U,Th‐He age is 0.7 Ga, and the K‐Ar age is 1.8 Ga, indicating that Mifflin might have been heated at the time of the 470 Ma L‐chondrite parent body breakup and that U, Th‐He, and K‐Ar ages were partially reset. The cosmogenic radionuclide data indicate that Mifflin was exposed to cosmic rays while its radius was 30–65 cm. Assuming this exposure geometry, a cosmic‐ray exposure age of 25 ± 3 Ma is calculated from cosmogenic noble gas concentrations. The low ²²Ne/²¹Ne ratio may, however, indicate a two‐stage exposure with a longer first‐stage exposure at high shielding. Mifflin is unusual in having a low radiogenic gas content combined with a low shock stage and no evidence of late stage annealing; this inconsistency remains unexplained.  相似文献   

Evolution of protoplanetary disk inferred from 26Al chronology of individual chondrules     

Noriko T. KITA  Takayuki USHIKUBO 《Meteoritics & planetary science》2012,47(7):1108-1119

Abstract– We review the ²⁶Al ages of chondrules in various type 3.0 chondrites. The ²⁶Al ages of chondrules are 1–3 Myr after calcium‐aluminum‐rich inclusion (CAI) for LL3.0, CO3.0, and Acfer 094 (Ungrouped C 3.0). Available data for chondrules in CR chondrites indicate that many chondrules are relatively younger (≥3 Myr), although data from chondrules in CR3.0 are not yet available to confirm their younger ages. The total ranges for the ²⁶Al ages of chondrules in a single chondrite group are more than 0.5–1 Myr. However, most chondrules show relatively narrow range of ages in a single chondrite group (0.2–0.4 Myr, 1 SD), which might be short enough to preserve the group‐specific chemical and isotope signatures against radial diffusion of solid in the disk. Distinct oxygen isotope reservoirs might exist in the protoplanetary disk simultaneously, which could be spatially separated.  相似文献   

Source Scaling of Inland Crustal Earthquake Sequences in Japan Using the S-Wave Coda Spectral Ratio Method     

Kazuhiro Somei  Kimiyuki Asano  Tomotaka Iwata  Ken Miyakoshi 《Pure and Applied Geophysics》2014,171(10):2747-2766

We estimate corner frequencies and stress drops for 298 events ranging from M _w 3.2–7.0 in 17 inland crustal earthquake sequences in Japan to investigate the source scaling and variation in stress drops. We obtain the source spectral ratio from observed records by the S-wave coda spectral ratio method. The advantage of using the S-wave coda is in obtaining much more stable source spectral ratios than using direct S-waves. We carefully examine the common shape of the decay of coda envelopes between event pair records. The corner frequency and stress drop are estimated by modeling the observed source spectral ratio with the omega-square source spectral model. We investigate the dependences of stress drops on some tectonic effects such as regionality, focal mechanism, and source depth. The principal findings are as follows: (1) a break in self-similar source scaling is found in our dataset. Events larger than M _w 4.5 show larger stress drops than those of smaller events. (2) Stress drops of aftershocks are mostly smaller than those of mainshocks in each sequence. (3) There are no systematic differences between stress drops of events occurring inside and outside the Niigata-Kobe Tectonic Zone in Japan. (4) Clear dependence of the faulting type on stress drops cannot be seen. (5) Stress drops of aftershocks depend on their source depth. (6) The crack size obtained from the corner frequency corresponds to the total rupture area of heterogeneous slip models for large events.  相似文献