Single-crystal polarized FTIR spectroscopy and neutron diffraction refinement of cancrinite     

Giancarlo Della Ventura  G. Diego Gatta  Gunter J. Redhammer  Fabio Bellatreccia  Anja Loose  Gian Carlo Parodi 《Physics and Chemistry of Minerals》2009,36(4):193-206

We relate a single-crystal FTIR (Fourier transform infrared) and neutron diffraction study of two natural cancrinites. The structural refinements show that the oxygen site of the H₂O molecule lies off the triad axis. The water molecule is almost symmetric and slightly tilted from the (0001) plane. It is involved in bifurcated hydrogen bridges, with Ow···O donor–acceptor distances >2.7 Å. The FTIR spectra show two main absorptions. The first at 3,602 cm^?1 is polarized for E ⊥ c and is assigned to the ν₃ mode. The second, at 3,531 cm^?1, is also polarized for E ⊥ c and is assigned to ν₁ mode. A weak component at 4,108 cm^?1 could possibly indicate the presence of additional OH groups in the structure of cancrinite. Several overlapping bands in the 1,300–1,500 cm^?1 range are strongly polarized for E ⊥ c, and are assigned to the vibrations of the CO₃ group.  相似文献   

Rock slope response to strong earthquake shaking   总被引：1，自引：1，他引：0  

C. Massey  F. Della Pasqua  C. Holden  A. Kaiser  L. Richards  J. Wartman  M. J. McSaveney  G. Archibald  M. Yetton  L. Janku 《Landslides》2017,14(1):249-268

The 2010–2011 Canterbury earthquakes triggered many mass movements in the Port Hills including rockfalls, debris avalanches, slides and slumps, and associated cliff-top cracking. The most abundant mass movements with the highest risk to people and buildings were rockfalls and debris avalanches sourced from up to 100 m high cliffs inclined at angles >65°. Cliffs lower than 10 m in height generally remained stable during the strong shaking, with only isolated release of a few individual boulders. We used site-specific data to investigate the factors that controlled the response of the cliffs to the main earthquakes of the Canterbury sequence, adopting two-dimensional finite element seismic site response and stability modeling that was calibrated using the field observations and measurements. Observations from the assessed cliffs in response to the earthquakes show the taller cliffs experienced larger amounts of permanent cliff-top displacement and produced larger volumes of debris than the smaller cliffs. Results indicated a mean K_MAX amplification ratio for all sites under study of 1.6 (range of 1.1–3.8). Field data and numerical modeling results, however, show that amplification of shaking does not necessarily increase linearly with increasing cliff height. Instead, our results show that accelerations are amplified mainly due to the impedance contrasts between the geological materials, corresponding to where strong differences in rock mass shear wave velocity exist. The resulting acceleration contrasts and rock mass strength control cliff stability. However, the amount of permanent slope displacement and volume of debris leaving the cliffs varied between the sites, due to site-specific geometry and rock mass strength.  相似文献   

Combination of GIS and mathematical modeling to predict floods in semiarid areas: case of Rheraya watershed (Western High Atlas,Morocco)     

Abdelhafid El Alaoui El Fels  Ali Bachnou  Noureddine Alaa 《Arabian Journal of Geosciences》2017,10(24):554

The Tinitine sub-watershed of Rheraya is renowned for its semiarid climate, irregular supply of water flow, and its historical floods; for these reasons, it is classified as vulnerable areas during a rainfall event. We conducted this study to propose flood prediction models adapted to this risky zone. For this, a hydrological method of flood forecasting rainfall-runoff used to determine a model conforms to the semiarid basin. This model is based on the articulation of the series production and transfer function. The goal of the production function is to determine the portion of the rainfall runoff, which is performed by two approaches that differ in their structures: (1) the first approach is based on the mathematical model of Horton; (2) the second approach is based on the determination of the part of the rain contributes to runoff and obtained by a spatial map of runoff coefficient (GIS). The transfer function is based on the two models of Clark and Nash, rainy efficient routes to the catchment outlet from a unit hydrograph. The characteristic parameters of these models are obtained through the application of mathematical optimization methods such as genetic algorithms. Thereby, the coupling function producing Horton (identified by the parameters: initial infiltration?=?15.03, final infiltration?=?0.3, and phi?=?0.45) and Clark transfer function (identified by the parameters C_A?=?0.21 and C_B?=?0.79) was given very satisfying results, mainly the low difference between observed and simulated hydrograph and Nash coefficient which is about 85%. This shows the interest of this coupling model in flood forecasting.  相似文献   

Infrared characterization of (OH, F)-pargasites     

J.- L. Robert  G. Della Ventura  F. C. Hawthorne 《Physics and Chemistry of Minerals》1996,23(4-5):307-307

  相似文献   

Répartition des minéraux argileux et contrôle tectono-eustatique dans les bassins de la marge tunisienne     

Fakher Jamoussi  Mourad Bédir  Noureddine Boukadi  Samir Kharbachi  Fouad Zargouni  Alberto López-Galindo  Hélène Paquet 《Comptes Rendus Geoscience》2003,335(2):175-183

We have studied the clay assemblages found in the different palaeogeographic domains located at the several Tunisian margin basins, ranging in age from Palaeozoic to Neogene. This study has allowed us to characterize and highlight the relationship between the clay distribution in time and space and the geodynamic and eustatic events. Marine regressions, with the intensification of erosion, seem to be responsible for illite increases, whereas transgressions, in concordance with a warm and dry climate, coincide with the smectite dominance. The minimum marine level coincides with the abundance of palygorskite. Mineralogic changes in the clay assemblages as well as in the proportion of the different clay minerals will tentatively be related to erosive tectonic events and/or to subsiding and rifting events, marked by the inheritance or the neoformation of the several clays.  相似文献   

Depositional facies and stratal geometry of an Upper Carboniferous prograding and aggrading high-relief carbonate platform (Cantabrian Mountains, N Spain)   总被引：1，自引：0，他引：1  

Giovanna Della Porta  Jeroen A. M. Kenter  Juan R. Bahamonde† 《Sedimentology》2004,51(2):267-295

Seismic‐scale continuous exposures of an Upper Carboniferous (Bashkirian–Moscovian) carbonate platform (N Spain) provide detailed information about the lithofacies and stratal geometries (quantified with differential global positioning system measurements) of microbial boundstone‐dominated, steep prograding and aggrading platform margins. Progradational and aggradational platform‐to‐slope transects are characterized by distinct lithological features and stratal patterns that can be applied to the understanding of geometrically comparable, high‐relief depositional systems. The Bashkirian is characterized by rapid progradation at rates of 415–970 m My^?1. Characteristic outer‐platform facies are high‐energy grainstones with coated intraclasts, ooids and pisoids, moderate‐energy algal‐skeletal grainstones to packstones and lower energy algal packstone and boundstone units. The Moscovian aggradational phase is characterized by aggradation rates of 108 m My^?1. Coated‐grain shoals are less common, whereas crinoidal bars nucleated in well‐circulated settings below wave‐base. Boundstones form a belt (30–300 m wide) at the platform break and interfinger inwards with massive algal‐skeletal wackestones (mud‐rich banks). The progradational phase has divergent outer‐platform strata with basinward dips of 12° to 2°. Steep clinoforms with dips of 20–28° are 650–750 m in relief and possibly sigmoidal to concave in the lower part. The basinward‐dipping outer‐platform strata might be depositional for less than 6°, consistent with lithofacies deepening seaward. The basinward dip is attributed to the downward shift of upper‐slope boundstone, forced by late highstand and relative sea‐level fall, and to compaction‐induced differential subsidence during progradation. The aggradational phase is characterized by horizontally layered platform strata. Clinoforms steepen to 30–45° reaching heights of 850 m and are planar to concave. The evolution from progradation to aggradation, at the Bashkirian–Moscovian boundary, is attributed to increased foreland‐basin subsidence and decreased boundstone accumulation rates. Progradation was primarily controlled by boundstone growth rather than by highstand shedding from the platform top. Within the major phases, aggradational–progradational increments are produced by third‐ to fourth‐order relative sea‐level fluctuations.  相似文献   

The single-crystal,polarized-light,FTIR spectrum of stoppaniite,the Fe analogue of beryl     

Giancarlo Della Ventura  Fabio Bellatreccia  Paolo Rossi 《Physics and Chemistry of Minerals》2007,34(10):727-731

We report here a single-crystal polarized-light study of stoppaniite, ideally (Fe,Al,Mg)₄(Be₆Si₁₂O₃₆)(H₂O)₂(Na,□), from Capranica (Viterbo). Polarized-light FTIR spectra were collected on an oriented (hk0) section, doubly polished to 15 μm. The spectrum shows two main bands at 3,660 and 3,595 cm⁻¹; the former is strongly polarized for E ⊥c, while the latter is polarized for E //c. A sharp and very intense band at 1,620 cm⁻¹, plus minor features at 4,000 and 3,228 cm⁻¹ are also polarized for E //c. On the basis of literature data and considering the pleochroic behavior of the absorptions, the 3,660 cm⁻¹ band is assigned to the ν₃ stretching mode and the 1,620 cm⁻¹ (associated with an overtone 2*ν₂ at 3,230 cm⁻¹) band to the ν₂ bending mode of “type II” water molecules within the structural channels of the studied beryl. The sharp band at 3,595 cm⁻¹ is not associated with a corresponding ν₂ bending mode; thus it is assigned to the stretching vibration of O–H groups in the sample. The minor 4,000 cm⁻¹ feature can be assigned to the combination of the O–H bond parallel to c with a low-frequency metal-oxygen mode such as the Na–O stretching mode. The present results suggest that the interpretation of the FTIR spectrum of Na-rich beryl needs to be carefully reconsidered.  相似文献   

Seasonal variation of particulate organic compounds in atmospheric PM₁₀ in the biggest municipal waste landfill of Algeria   总被引：1，自引：0，他引：1  

Riad Ladji  Noureddine Yassaa  Angelo Cecinato  Brahim Youcef Meklati 《Atmospheric Research》2007,86(3-4):249-260

The average composition and seasonal variations of atmospheric organic particulates with respect to n-alkanes, n-alkanoic acid, polycyclic aromatic hydrocarbon (PAHs), and nitrated polycyclic aromatic hydrocarbons (N-PAHs) were determined at the biggest municipal waste landfill in Algeria located in Oued Smar, 13 km east of downtown Algiers. Samplings were carried out from August 2002 to February 2003, and organic compounds adsorbed in air particles having an aerodynamic diameter lower than 10 μm (PM₁₀) were characterized using gas chromatography coupled with mass spectrometric detection (GC/MSD). Total concentrations ranged from 828 to 11,068 ng per cubic meter of air for n-alkanes, from 1714 to 21,710 ng per cubic meter of air for n-alkanoic acids, from 13 to 212 ng per cubic meter of air for PAHs and from 93 to 205 pg per cubic meter of air for N-PAHs. n-Alkanoic acids accounted for 85 and 56% of the total organic composition of the aerosol measured in summer and winter, respectively, were the biggest fraction. The distribution profiles and the diagnostic ratios of some marker compounds allowed to identify the combustion and microbial activity as the major sources of particulate organic pollutants associated with direct emission. The year-time dependence of organic fraction content of aerosol in Oued Smar appeared to be related to average meteorological conditions as well as variability of rate and nature of materials wasted into the landfill.  相似文献   

Experimental investigation on the effect of the mode of deposition on the pore-access size distribution of sand     

Noureddine Della  Sadok Feia 《Geomechanics and Geoengineering》2018,13(1):33-41

It is well known that the specimen preparation method and the resulting sand fabric significantly affect sand behaviour and sand liquefaction resistance. In this study, a simple experimental method namely tensiometric method is presented for evaluation of the effect of the samples reconstituting methods on microstructure and the pore-access size distribution of sands. Specimens were prepared using dry funnel pluviation (DFP) and wet deposition (WD) at two densities Dr = 40% (loose state) and Dr = 80% (dense state). The water-retention curve of a sand specimen is evaluated using a technique similar to the hanging column method by application of a step-by-step variation of suction and measure of the corresponding changes in water content. The pore-access size distribution is then evaluated from the water-retention curve. In this experimental study the effects of the mode of deposition and the uniformity coefficient on the pore-access size distribution are investigated. It was found that the specimen generated by the WD method contained a higher percentage of pore size, contrary to the specimen prepared by the DFP which contained a limited percentage of pore size, causing a great influence on the mechanical behaviour of the specimens.  相似文献   

A re-evaluation of Late Devensian glacial Lake Humber levels in the Vale of York,UK     

Della K. Murton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(4):561-576

Proglacial Lake Humber formed in the Vale of York and Ancholme Valley during the Late Devensian (Weichselian) glaciation, but its lake levels and their precise ages are uncertain. Three-dimensional geological modelling, based on 193 borehole sediment logs from the eastern part of the Vale of York, indicates that glaciolacustrine sediments extend no higher than 10?m O.D. By contrast, recent palaeoenvironmental reconstructions for the region that suggest Lake Humber had eight recessional shorelines, extending from 42?m to 5?m O.D. Above 10?m O.D., the sediments become more discontinuous, and comprise clay with occasional chalk and flint gravel, and matrix-rich diamicton interdigitated with sands and gravels. Sedimentary and geochemical analyses of sands and gravels from one of the putative shorelines, at 25?m O.D., indicate an easterly provenance for these sediments. They are interpreted here as colluvial deposits, sourced largely by periglacial weathering of Jurassic and chalk bedrock. Collectively, the geological evidence suggests that the highest level of Lake Humber during the Late Devensian did not exceed 10?m O.D., and therefore reconstructions invoking higher lake levels are thought to be unlikely.  相似文献