Lu–Hf garnet systematics of a polymetamorphic basement unit: new evidence for coherent exhumation of the Adula Nappe (Central Alps) from eclogite-facies conditions     

Sascha?SandmannEmail author  Thorsten?J.?Nagel  Daniel?Herwartz  Raúl?O.?C.?Fonseca  Robert?M.?Kurzawski  Carsten?Münker  Nikolaus?Froitzheim 《Contributions to Mineralogy and Petrology》2014,168(5):1075

The Adula Nappe in the Central Alps is a mixture of various pre-Mesozoic continental basement rocks, metabasics, ultrabasics, and Mesozoic cover rocks, which were pervasively deformed during Alpine orogeny. Metabasics, ultrabasics, and locally garnet–mica schists preserve eclogite-facies assemblages while the bulk of the nappe lacks such evidence. We provide garnet major-element data, Lu profiles, and Lu–Hf garnet geochronology from eclogites sampled along a north–south traverse. A southward increasing Alpine overprint over pre-Alpine garnets is observed throughout the nappe. Garnets in a sample from the northern Adula Nappe display a single growth cycle and yield a Variscan age of 323.8 ± 6.9 Ma. In contrast, a sample from Alpe Arami in the southernmost part contains unzoned garnets that fully equilibrated to Alpine high-pressure (HP) metamorphic conditions with temperatures exceeding 800 °C. We suggest that the respective Eocene Lu–Hf age of 34.1 ± 2.8 Ma is affected by partial re-equilibration after the Alpine pressure peak. A third sample from the central part of the nappe contains separable Alpine and Variscan garnet populations. The Alpine population yields a maximum age of 38.8 ± 4.3 Ma in line with a previously published garnet maximum age from the central nappe of 37.1 ± 0.9 Ma. The Adula Nappe represents a coherent basement unit, which preserves a continuous Alpine high-pressure metamorphic gradient. It was subducted as a whole in a single, short-lived event in the upper Eocene. Controversial HP ages and conditions in the Adula Nappe may result from partly preserved Variscan assemblages in Alpine metamorphic rocks.  相似文献   

Ensemble-based hierarchical multi-objective production optimization of smart wells     

R. M. Fonseca  O. Leeuwenburgh  P. M. J. Van den Hof  J. D. Jansen 《Computational Geosciences》2014,18(3-4):449-461

In an earlier study, two hierarchical multi-objective methods were suggested to include short-term targets in life-cycle production optimization. However, this earlier study has two limitations: (1) the adjoint formulation is used to obtain gradient information, requiring simulator source code access and an extensive implementation effort, and (2) one of the two proposed methods relies on the Hessian matrix which is obtained by a computationally expensive method. In order to overcome the first of these limitations, we used ensemble-based optimization (EnOpt). EnOpt does not require source code access and is relatively easy to implement. To address the second limitation, we used the Broyden-Fletcher-Goldfarb-Shanno (BFGS) algorithm to obtain an approximation of the Hessian matrix. We performed experiments in which water flood was optimized in a geologically realistic multilayer sector model. The controls were inflow control valve settings at predefined time intervals. Undiscounted net present value (NPV) and highly discounted NPV were the long-term and short-term objective functions used. We obtained an increase of approximately 14 % in the secondary objective for a decrease of only 0.2–0.5 % in the primary objective. The study demonstrates that ensemble-based hierarchical multi-objective optimization can achieve results of practical value in a computationally efficient manner.  相似文献   

Petrogenesis of alkaline basalt-hosted sapphire megacrysts. Petrological and geochemical investigations of in situ sapphire occurrences from the Siebengebirge Volcanic Field,Germany     

L.?C.?BaldwinEmail author  F.?Tomaschek  C.?Ballhaus  A.?Gerdes  R.?O.?C.?Fonseca  R.?Wirth  T.?Geisler  T.?Nagel 《Contributions to Mineralogy and Petrology》2017,172(6):43

Megacrystic sapphires are frequently associated with alkaline basalts, most notably in Asia and Australia, although basalt is not generally normative in corundum. Most of these sapphire occurrences are located in alluvial or eluvial deposits, making it difficult to study the enigmatic relationship between the sapphires and their host rocks. Here, we present detailed petrological and geochemical investigations of in situ megacrystic sapphires within alkaline basalts from the Cenozoic Siebengebirge Volcanic Field (SVF) in Germany. Markedly, the sapphires show several micrometer thick spinel coronas at the contact with the host basalt, indicating chemical disequilibrium between the sapphire and the basaltic melt, supporting a xenogenetic relationship. However, in situ U–Pb dating of a Columbite Group inclusion within one Siebengebirge sapphire using laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) indicates a close genetic relationship between sapphire crystallization and alkaline mafic volcanism in the SVF. The syngenetic mineral inclusion suite including carbonates, members of the Pyrochlore, Betafite and Columbite Groupe minerals, as well as a high abundance of HFSE and of gaseous low-density CO₂ inclusions support a parentage of a highly evolved, MgO and FeO deficient carbonatitic melt. We identified CO₂ to be the link between alkaline basaltic volcanism and the xenocrystic sapphires. Only alkaline volcanic suites can build up enough CO₂ in this magma chamber upon fractionation so that at high degrees of fractionation a carbonatitic melt exsolves which in turn can crystallize sapphires.  相似文献