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21.
The variability of Quaternary landforms preserved in the Tabernas basin of southeast (SE) Spain raises numerous questions concerning the roles of external forcing mechanisms (e.g. tectonics and/or climate) and internal landscape properties (e.g. lithological controls) in the evolution of the basin‐wide fluvial system over Late Quaternary timescales. In this study, we apply the FLUVER2 numerical model to investigate the significance of these landscape controls upon patterns of landscape evolution. We highlight the complications of generating realistic input datasets for use in the modelling of long‐term landscape evolution (e.g. discharge and runoff datasets). Model outputs are compared to extensive field mapping of fluvial terraces, their sedimentary architecture and optically stimulated luminescence dating results of the terraces. The results demonstrate the significance of non‐linear rates of flexural tectonic uplift towards the west of the Tabernas Basin which have controlled base levels throughout the Quaternary and promoted the formation of a series of diverging fluvial terraces. Our numerical model results further highlight the importance of climate cycles upon river terrace formation. Basin‐wide aggradation events were modelled during the transition from Marine Isotope Stage (MIS) 6 to 5 and the Last Glacial Maximum (LGM) as supported by field evidence. This aggradational pattern supports the regional hypothesis of terrace formation during global glacial cycles and cold‐to‐warm stage transitions and supports the use of sea surface temperature climate proxy data in the modelling exercise. The availability of sediments derived from the surrounding hillslopes and adjacent alluvial fans explains the generation of substantial terrace aggradations. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
22.
The distribution of arsenic (As(III), As(V)) and iron (Fe(II), Fe(III)) species was monitored during 1 year in a borehole drilled in the Carnoulès tailings impoundment which contains As-rich pyrite. The concentrations of total As and Fe in subsurface waters exhibited strong variations over one year, which were controlled by dissolved oxygen concentrations. At high oxygen levels, extremely high As (up to 162 mM) and Fe (up to 364 mM) concentrations were reached in the borehole, with the oxidised species predominant. As and Fe concentrations decreased 10-fold under oxygen-deficient conditions, as a result of pH increase and subsequent precipitation of As(V) and Fe(III). From drill core sections, it appeared that at low dissolved oxygen levels, As(III) was primarily released into water by the oxidation of As-rich pyrite in the unsaturated zone. Subsequent As and Fe precipitation was promoted during transport to the saturated zone; this reaction resulted in As enrichments in the sediment below the water table compared to the original content in pyrite, together with the formation of As-rich (up to 35 wt% As) ferruginous material in the unsaturated zone. High amounts of As(V) were released from these secondary phases during leaching experiments with oxygenated acid sulfate-rich waters; this process is believed to contribute to As(V) enrichment in the subsurface waters of the Carnoulès tailings during periods of high dissolved oxygen level.  相似文献   
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Eleven monthly estuarine profiles of dissolved inorganic germanium (Gei) and silica (Si) in a natural, pristine river/bay system demonstrate that Ge-removal and -input parallel the seasonal silica cycle, reflecting Ge-uptake by and -dissolution from diatoms. The Ge/Si atom ratio of the river is 0.6 ± 0.15 × 10?6, which is near the average value for continental granites and for uncontaminated, remote, natural rivers (0.7 ± 0.3 × 10?6). The GeSi ratio escaping this estuary to the ocean is 0.8 × 10?6, reflecting some estuarine enhancement of the fluvial Ge-flux, probably due to release of Gei from fluvial particulates. Nevertheless, the post-estuarine GeSi ratio is not significantly different from the continental crustal ratio but is very different from the ratio in sea-floor hot springs and mid-ocean ridge hydrothermal plumes (4 ± 2 × 10?6) and in oceanic basalts (2.6 × 10?6). Thus natural estuarine processes do not obscure the contrasting GeSi signatures entering the ocean from dissolution of continental and sea-floor silicates.  相似文献   
24.
The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.  相似文献   
25.
An objective method for the assignment of pollen spectra to appropriate biomes has been published recently. The aim of this paper is to improve the distinction between warm and cool steppes, thus refining vegetation and climate reconstruction, particularly during the Last Glacial Maximum. A set of modern pollen spectra from the Mediterranean and Kazakhstan regions, dominated today by open vegetation types, has been analysed statistically in order to relate pollen taxa abundances to warm and cool grass/shrub plant functional types (PFTs). A statistical test using modern pollen data shows that the method is able to distinguish between cool and warm steppe biomes with a high degree of confidence. The method has been applied to two fossil pollen records. The results of this exercise showed that cool steppe dominated in central Greece between 18 000 and 13 000 yr BP, while in western Iran the vegetation was at the boundary between cool and warm steppes. These vegetation types were replaced by warm mixed forest in Greece and warm steppe in Iran after that time span. © 1998 John Wiley & Sons, Ltd.  相似文献   
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27.
We propose an analytic model that allows rapid computation of the secondary ion production due to electron impact from the primary photo-production in the ionosphere of Titan. The model parameters are given for each of the 5 major ion productions (N+2, CH+4, N+, CH+3, N++2) as well as for the electron production.  相似文献   
28.
This paper presents an event stratigraphy based on data documenting the history of vegetation cover, lake‐level changes and fire frequency, as well as volcanic eruptions, over the Last Glacial–early Holocene transition from a terrestrial sediment sequence recovered at Lake Accesa in Tuscany (north‐central Italy). On the basis of an age–depth model inferred from 13 radiocarbon dates and six tephra horizons, the Oldest Dryas–Bølling warming event was dated to ca. 14 560 cal. yr BP and the Younger Dryas event to ca. 12 700–11 650 cal. yr BP. Four sub‐millennial scale cooling phases were recognised from pollen data at ca. 14 300–14 200, 13 900–13 700, 13 400–13 100 and 11 350–11 150 cal. yr BP. The last three may be Mediterranean equivalents to the Older Dryas (GI‐1d), Intra‐Allerød (GI‐1b) and Preboreal Oscillation (PBO) cooling events defined from the GRIP ice‐core and indicate strong climatic linkages between the North Atlantic and Mediterranean areas during the last Termination. The first may correspond to Intra‐Bølling cold oscillations registered by various palaeoclimatic records in the North Atlantic region. The lake‐level record shows that the sub‐millennial scale climatic oscillations which punctuated the last deglaciation were associated in central Italy with different successive patterns of hydrological changes from the Bølling warming to the 8.2 ka cold reversal. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
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The stakes for alleviating poverty and avoiding unbridled climate change are inextricably linked. Climate change impacts will slow down and may even reverse trends in poverty reduction. The pathways consistent with global warming of no more than 2?°C require strategies for poverty alleviation to make allowance for the constraint of low-carbon development. Existing climate funds have failed to target poverty alleviation as a high-priority strategy for adaptation or as a component of low-carbon development. This article proposes a funding window as part of the Green Climate Fund in order to foster synergies targeting greater satisfaction of basic needs, while making allowance for adaptation and mitigation. This financial mechanism is based on indicators of the satisfaction of basic needs and could respond to the claims of the developing countries, which see alleviating poverty as the first priority in climate negotiations. It defines a country continuum, given that there are poor people everywhere; all developing countries are therefore eligible with a mechanism of this sort.

Policy relevance

The Intergovernmental Panel on Climate Change (IPCC) calls for substantial emissions reductions and adaptation strategies over the next decades to reduce the high risks of severe impacts of climate change over the 21st century. Industrialized countries and developing countries alike recognize the need to mitigate climate change and to adapt to it. But they face many challenges that lead to an ‘emissions gap’ between an emissions level consistent with the 2?°C increase limit and the voluntary pledges that they have made thus far in the climate negotiations (United Nations Environment Programme. (2014). The Emissions Gap Report 2014. A UNEP synthesis report). In this arena, many developing countries underline that their first domestic priority is the satisfaction of basic needs. In the run-up to the next climate negotiations at the 21st Conference of the Parties (COP 21) in Paris, the proposed poverty-adaptation-mitigation funding window could contribute to alleviate the conflict between development and climate goals in developing countries. In this sense, it could spur developing countries to integrate more ambitious emissions limitations pledges into their Intended Nationally Determined Contributions. This could in turn entice industrialized countries to act similarly. In the end, it could pave the way to an ambitious climate agreement in Paris at COP 21.  相似文献   
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