Chelation of divalent metal ions by brown algal polyphenols     

Mark A Ragan  Olav Smidsrød  Bjørn Larsen 《Marine Chemistry》1979,7(3):265-271

High-molecular-weight, nondialyzable polyphloroglucinols from the marine brown algae Ascophyllum nodosum and Fucus vesiculosus (Phaeophyceae, Fucales) chelate the divalent metal ions Sr²⁺, Mg²⁺, Ca²⁺, Be²⁺, Mn²⁺, Cd²⁺, Co²⁺, Zn²⁺, Ni²⁺, Pb²⁺ and Cu²⁺ in weakly acidic aqueous solution. Values of the relative selectivity coefficients k have been calculated relative to Mn²⁺; the ionotropic series with the algal polyphenols are similar to those with catechol and pyrogallol. These studies may serve as a guide for the examination of metal chelation by brown algal polyphenols both in situ and after exudation into seawater.  相似文献   

Progress in optical dating of guano-rich sediments associated with the Deep Skull, West Mouth of the Great Cave of Niah, Sarawak, Borneo     

Mark Stephens  Richard G. Roberts  Olav B. Lian  Hiroyuki Yoshida 《Quaternary Geochronology》2007,2(1-4):330-336

The West Mouth of the Great Cave of Niah is one of the major archaeological sites in Southeast Asia; the radiocarbon chronology of this site currently places the earliest presence of Homo sapiens (a Deep Skull find) in Southeast Asia at about 45 ka BP. An optical dating programme using sand-sized quartz was initiated in the West Mouth to complement the radiocarbon chronology. This paper reports on the progress in dating a key sample (sample 376r) that was taken from deposits containing the Deep Skull. A somewhat novel procedure was developed to separate and clean quartz grains from the unusual guano-rich deposits. From this, only a small quantity of quartz grains could be recovered and 36 aliquots (1 mm in diameter) were prepared, each consisting of 80 grains. This sample was dated by means of the single-aliquot regenerative-dose (SAR) method using the protocols of Murray and Wintle [2000. Luminescence dating of quartz using an improved single-aliquot regenerative-dose protocol. Radiation Measurements 32, 57–73], and of Choi et al. [2003. Luminescence dating of well-sorted marine terrace sediments on the southeastern coast of Korea. Quaternary Science Reviews 22, 407–421]. The results showed a wide distribution of equivalent doses; this distribution is inferred to be due to bioturbation, variable bleaching at deposition, and to local variations in the dose rate within the sample site. Dose rates were measured using both field (in-situ γ-ray spectrometry, IGRS) and laboratory (inductively coupled plasma mass spectrometry/atomic emission spectrometry, ICP-MS/AES; and isotope dilution, ID) methods. There was significant disagreement between the concentrations of radioisotopes found using laboratory and field measurements, indicating sediment heterogeneity and also possible disequilibrium in the ²³⁸U decay chain. Future work in the West Mouth should therefore concentrate on taking sediment samples of at least 500–600 cm³, improving the dose rate estimates (e.g. by high-resolution γ-ray spectrometry) and investigating other luminescence signals (e.g. red thermoluminescence) as potential geochronometers.  相似文献   

Preface     

Dr.  Olav Orheim Dr.  Helle V. Goldman 《Polar research》2001,20(2):125-126

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Cellular plagioclase intergrowths as a result of crystal-magma mixing in the Proterozoic Åland rapakivi batholith,SW Finland     

Ulf B. Andersson  Olav Eklund 《Contributions to Mineralogy and Petrology》1994,117(2):124-136

Finely cellular plagioclase intergrowths have been studied in xenocrystic andesine (An₃₂) and andesine mantled K-feldspars within mafic magmatic enclaves in a quartz-feldspar porphyry from the Proterozoic subvolcanic Hammarudda complex, Åland rapakivi batholith, SW Finland. The cellular intergrowths usually occur as 0.2–2.0 mm mantles around xenocrysts but also as entirely cellular grains, and are built up of a network of two distinct phases: one relatively Na-rich (An₃₁) and one relatively Ca-rich (An₅₀). The grains are also covered by a thin (0.08–0.12 mm), continuous, normally zoned rim outside the cellular mantle. Small inclusions (0.01–0.05 mm) of Fe–Mg minerals are concentrated in the Ca-rich part of the network. Compositionally, the Na-rich phase of the network is close to the inner non-cellular andesine of the xenocrysts. However, it has a lower Or- and a slightly lower An-content. The Ca-rich phase has the same composition as the inner part of the normally zoned rim, which outwards grades into lower An-contents that overlap the An-content of the matrix plagioclases. The cellular network was developed after the andesine xenocrysts (or andesine mantled K-feldspars) were engulfed in mafic magmatic enclaves during a mixing event. The xenocrysts became heated to a temperature just below the liquidus of the mafic magma. Dissolution of the xenocrysts developed a spongy cellular texture which was penetrated by enclave magma. Ca-rich plagioclase crystallized in the cells in equilibrium with the enclave magma, trapping Fe–Mg-rich melt. As the enclaves cooled the outermost thin rim and matrix plagioclases crystallized from the mafic melt. These processes operated in fairly large enclaves, as the one studied here, which has a diameter of 70cm. Smaller enclaves, on the other hand, were cooled more rapidly to temperatures close to the solidus of the enclave magma, and consequently had no time to dissolve the xenoxrysts.  相似文献   

The margin between Senja and Spitsbergen fracture zones: Implications from plate tectonics     

Annik M. Myhre  Olav Eldholm  Eirik Sundvor 《Tectonophysics》1982,89(1-3)

Analysis of multichannel seismic data from the continental margin off Svalbard between the Senja and Spitsbergen fracture zones suggests that the transition between continental and oceanic crust is located at or close to the Hornsund Fault Zone. In the Late Paleocene/Early Eoeene (57 m.y.) the region between Svalbard and Northeast-Greenland was subjected to regional shear movements associated with a transform system between the young Lofoten-Greenland Basin and the Arctic Ocean. Approximately 50 m.y. ago the spreading axis migrated to the northeast creating a deep basin north of the Greenland-Senja Fracture Zone forming the passive margin between Bear Island and 76.5°N. North of 76.5°N the regional transform was maintained. At the time of the main reorganization of relative plate motion (36 m.y.) the northern margin evolved. A continental fragment was possibly cut off from the Svalbard margin forming a small microcontinent. The microcontinent appears as the submarine ridge which has been associated with the Hovgaard Fracture Zone. It is suggested that the sediments west of the Hornsund Fault Zone are not older than Eocene in the south and mid-Oligocene in the north. The position of the spreading axis has greatly influenced the margin sedimentation.  相似文献   

Notiz überDidymium nigripes (Myxomycetes) aus einer Abwasserbiozönose     

Olav M. Skulberg 《Aquatic Sciences - Research Across Boundaries》1958,20(2):210-217

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Contemporary and Post-glacial Rates of Aeolian Deposition in the Coast Mountains of British Columbia, Canada     

Philip N. Owens  & Olav Slaymaker 《Geografiska Annaler: Series A, Physical Geography》1997,79(4):267-276

Contemporary and post-glacial rates of aeolian deposition are determined for three small catchments that straddle the alpine-subalpine ecotone in the Pacific Ranges of the Coast Mountains of British Columbia. From process measurement over a single year, the mean annual regional (allochthonous) rate of aeolian deposition for the catchments is estimated to be approximately 11 g m⁻². The average rate of annual deposition over the post-glacial period is calculated from the soil profiles to be c . 6 g m⁻², although fallout rates are likely to have varied significantly over the Holocene epoch due to changes in climate and catchment conditions. It would appear that the vegetated ground strata in these catchments are net receivers of aeolian dust fallout. Consequently, many of the soils are cumulic in nature and protect the bedrock in these catchments from subaerial weathering. These results have implications for sediment transfers in alpine and sub-alpine environments in southwestern British Columbia.  相似文献   

Learning from mistakes in climate research   总被引：1，自引：0，他引：1  

Rasmus E. Benestad  Dana Nuccitelli  Stephan Lewandowsky  Katharine Hayhoe  Hans Olav Hygen  Rob van Dorland  John Cook 《Theoretical and Applied Climatology》2016,126(3-4):699-703

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uTshani BuyaKhuluma––The Grass Speaks: the political space and capacity of the South African Homeless People’s Federation     

Marianne Millstein  Sophie Oldfield  Kristian Stokke   《Geoforum》2003,34(4):457-468

The point of departure for this article is the contemporary tendency towards localisation of politics in the context of neo-liberal globalisation. Mediated through institutional reforms, political discourses and localised struggles, this localisation of politics produce new and transformed local political spaces. The purpose of the article is to examine the capacity of popular movements to use and transform such political spaces within the South African housing sector. This analysis is done through a combination of conceptual examination of political space and actor capacity and a concrete case study of the political strategies and capacities of The South African Homeless People’s Federation. The article argues that the Federation has utilised political relations at different scales to mobilise resources such as land and subsidies for housing for its members. It has also influenced the formulation of housing policies through its discourses and practical experiences with people-driven housing processes. In consequence the Federation’s ability to function as a civil/political movement has granted them a certain capacity to participate in the complicated process of turning de jure rights to adequate shelter into de facto rights for the urban poor as citizens of a democratic South Africa.  相似文献   

Namibia volcanic margin     

Gladczenko  Tadeusz P.  Skogseid  Jakob  Eldhom  Olav 《Marine Geophysical Researches》1998,20(4):313-341

Two end members of passive margin types are present on the Namibia margin: volcanic and non-volcanic. The central and southern parts of the Namibia margin feature characteristic volcanic margin elements such as thickened initial oceanic crust, seaward dipping reflectors, and high-velocity/density lower crust that extends beneath the rift zone that was formed during initial seafloor spreading in Early Cretaceous. The margin north of the Walvis FZ is non-volcanic in character and probably formed as a result of a ridge jump that occurred after cessation of the initial magmatic activity. The Walvis Ridge forms the boundary between the two margin types and resulted from the persistent magmatism associated with the Tristan plume. MCS data in conjunction with gravity modeling reveal a Paleozoic rift zone beneath the Namibia margin south of the Walvis FZ. The Paleozoic rift zone partly overlaps the Jurassic/Early Cretaceous rift zone which produced the breakup between Africa and South America. We calculate an average stretching value of =1.4 for the Paleozoic rift, based on subsidence modeling. The rift is partly bounded by low-angle faults, related to the orogenic collapse of the Pan-African fold belt, which provided a major Paleozoic sediment source. The offshore continuity of onshore ophiolitic complexes is suggested by the coast parallel high-amplitude magnetic anomaly G, and low-angle detachment faults along the southern part of the margin. The average stretching value for the Jurassic/Early Cretaceous rift is =1.7, which implies a syn-rift displacement on this margin of 70 km. The minimum igneous volume of the South Atlantic LIP was found to be in excess of 3.62×106 km³.  相似文献