Hydrogen sites in the dense hydrous magnesian silicate phase E: a pulsed neutron powder diffraction study     

Naotaka Tomioka  Takuo Okuchi  Narangoo Purevjav  Jun Abe  Stefanus Harjo 《Physics and Chemistry of Minerals》2016,43(4):267-275

Hydrogen site positions and occupancy in the crystal structure of dense hydrous magnesium silicate (DHMS) phase E were determined for the first time by pulsed neutron powder diffraction. A fully deuterated pure phase E powder sample, which had space group \(R\overline{3} m\) and lattice parameters of a = 2.97065(8) Å and c = 13.9033(4) Å, was synthesized at 15 GPa and 1100 °C. Through quantitative evaluation of refined structure parameters obtained with sufficient spatial resolution and very high signal-to-background ratio, we conclude that the O–D dipoles in the refined phase E structure are tilted by 24° from the direction normal to the layers of edge-shared MgO₆ octahedra (octahedral layers). The tilted dipole structure of phase E is in remarkable contrast to that of brucite, Mg(OH)₂, which has dipoles exactly normal to the octahedral layer. This contrast exists because the O–Si–O bonding unique in the phase E structure connects two adjacent octahedral layers and thereby reduces the interlayer O···O distance. This shrinkage of the interlayer distance induces the tilting of the O–D dipole and also generates unique O–D···O hydrogen bonding connecting all the layers in the phase E structure.  相似文献   

Internal Microanatomy and Zoological Affinity of the Early Cambrian Olivooides     

HAN Jian  LI Guoxiang  Kubota Shin  Ou Qiang  Toshino Sho  Wang Xing  Yang Xiaoguang  Uesugi Kentaro  Masato Hoshino  Sasaki Osamu  Kano Harumas  Sato Tomohiko  Komiya Tsuyoshi 《《地质学报》英文版》2016,90(1):38-65

The early Cambrian pentamerous microfossil Olivooides/Punctatus in South China, which is characterized by a diagnostic stellate tubular apex, has been well-known for its almost complete development sequence that can be confidently traced from embryos and hatched juveniles, to conical adults. However, its zoological affinity remains highly controversial. Here we describe the internal microanatomic structures of the soft-body inside the peridermal theca of Olivooides multisulcatus Qian, 1977, including interradial pairs of tentacles, adradial and perradial frenula, perradial oral marginal lappets and twins of perradial gastric saccule-like humps as well as a circular velarium with striated coronal muscles. Particularly, one specimen shows bifurcated velarial canals along the bell aperture. Both the components of the soft-body and the external theca (or cyst) are arranged in perfect pentaradial symmetry. These characteristics are more compatible with those of living cubomedusans and co-occurring Cambrian athecate embryonic cubozoans. Concerning the presence of peridermal theca, Olivooides most likely represents an extinct thecate stem-group cubomedusae but devoid of both perradial eyes and specialized pedalia. The well-grown soft body inside the peridermal tube displays a set of mixed features of both polyp and medusa.  相似文献   

Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific     

Yoshihisa?MinoEmail author  Chiho?Sukigara  Makio?C.?Honda  Hajime?Kawakami  Kazuhiko?Matsumoto  Masahide?Wakita  Minoru?Kitamura  Tetsuichi?Fujiki  Kosei?Sasaoka  Osamu?Abe  Jan?Kaiser  Toshiro?Saino 《Journal of Oceanography》2016,72(6):819-836

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.  相似文献   

Nucleation,growth and stability of CaAl2Si2O8 polymorphs     

Toshiya Abe  Katsuo sukamoto  Ichiro Sunagawa 《Physics and Chemistry of Minerals》1991,17(6):473-484

By means of in situ observation, the nucleation and growth of triclinic, pseudo-orthorhombic and pseudo-hexagonal CaAl₂Si₂O₈ were investigated and their relative stabilities established. Pseudo-hexagonal and pseudo-orthorhombic CaAl₂Si₂O₈ nucleate prior to anorthite and grow in a supercooled anorthite melt before the latter appears. They either dissolve or transform to anorthite once the latter nucleates and starts to grow. Corundum and mullite also nucleate metastably prior to anorthite in this melt. The liquidus temperatures of the four metastably nucleated phases were determined precisely by in situ measurements of the transformation temperatures from a polyhedral to a rounded morphology. On the basis of the supercooling thus determined, the growth rate versus supercooling relations were measured and analysed for the respective phases. The growth rate of the stable phase is one order of magnitude higher than those of any metastable phases. However, the growth rates of the three CaAl₂Si₂O₈ polymorphs normalized by the viscosities are nearly the same.  相似文献   

Re-evaluation of the large deep earthquake of January 21, 1906     

Katsuyuki Abe 《Physics of the Earth and Planetary Interiors》1985,39(3):157-166

The large deep earthquake of January 21, 1906 is re-evaluated using old seismogram data and updated analysis techniques. From the P and pP-P time data the hypocentre parameters are determined as follows: origin time, 13h 49min 35s; latitude, 33.8°N; longitude, 137.5°E; depth, 340 km. The body-wave magnitude m_B is re-evaluated from the amplitude and periods of P, PP and S waves. The average value of 7.4 is obtained. This value is the smallest among any values assigned previously to this shock, and it is denied that the earthquake is the world's largest deep shock in this century. The focal mechanism is estimated from the P-wave first motions and amplitude distribution of P and S waves. Synthetic body waves are used to constrain the mechanism and to determine the seismic moment. The mechanism solution suggests the down-dip compression typical of this region. A seismic moment of 1.5 × 10²⁷ dyn · cm is obtained. This value and the re-evaluated value of m_B are consistent with the moment-_B relation obtained for other deep earthquakes.  相似文献   

Hypocenter distribution and focal mechanism of AE events during two stress stage creep in Yugawara andesite     

Osamu Nishizawa  Kaoru Onai  Kinichro Kusunose 《Pure and Applied Geophysics》1984,122(1):36-52

More than a thousand acoustic-emission (AE) hypocenters were determined in a cylindrical andesite specimen under two-stage uniaxial creep at stresses of 204 and 214 MPa. Strains were monitored for 6 peripheral points at the middle part of the cylindrical specimen's wall. The strain data indicate gradual increase of nonuniform deformation during steady creep and strong intensification of the nonuniformity during acceleration creep and, therefore, biased stress distribution within the specimen. The correlation between dilatant strain and AE hypocenters was investigated for whether or not tensile cracks emit AE. The region with high AE activity shows only a small dilatant strain. This negative correlation between AE and the dilatant region may eliminate tensile cracks as possible AE sources. A composite focal-mechanism solution of local AE events, covering a wide solid angle of the focal hemisphere, indicates that shear fractures emit AE waves. The direction of the compressional axis in this solution shows a significant deviation from that inferred from the applied external force, suggesting that the local stress field is governed by preexisting weak zones that are, presumably, produced by tensile cracks within the specimen. AE hypocenters tended to form clusters during steady creep under the constant compressional stress. During acceleration creep caused by a small step increase of the external stress, the preceding clusters disappeared while a new cluster appeared in an incipient fault plane. This suggests that changes in seismicity pattern such as migrations or quiescences of swarm—important clues for earthquake predictions—may be caused by an instantaneous change in the tectonic-stress levels.  相似文献   

Modeling of the runup heights of the Hokkaido-Nansei-Oki tsunami of 12 July 1993     

Katsuyuki Abe 《Pure and Applied Geophysics》1995,144(3-4):735-745

The Hokkaido-Nansei-Oki earthquake (M _w 7.7) of July 12, 1993, is one of the largest tsunamigenic events in the Sea of Japan. The tsunami magnitudeM _t is determined to be 8.1 from the maximum amplitudes of the tsunami recorded on tide gauges. This value is larger thanM _w by 0.4 units. It is suggested that the tsunami potential of the Nansei-Oki earthquake is large forM _w . A number of tsunami runup data are accumulated for a total range of about 1000 km along the coast, and the data are averaged to obtain the local mean heightsH _n for 23 segments in intervals of about 40 km each. The geographic variation ofH _n is approximately explained in terms of the empirical relationship proposed byAbe (1989, 1993). The height prediction from the available earthquake magnitudes ranges from 5.0–8.4 m, which brackets the observed maximum ofH _n , 7.7 m, at Okushiri Island.  相似文献   

Antiferromagnetic transition of fayalite under high pressure studied by Mössbauer spectroscopy     

Mitsuhiko Hayashi  Ichiro Tamura  Osamu Shimomura  Hiroshi Sawamoto  Haruki Kawamura 《Physics and Chemistry of Minerals》1987,14(4):341-344

Néel temperature (Tm _N of α-Fe₂SiO₄ (fayalite) was measured as a function of pressure by means of Mössbauer spectroscopy in the pressure range 0–16 Gpa. High pressure was generated using a clamp-type miniature diamond anvil cell which was inserted into a cryostat. The Néel temperature increased linearly with increasing pressure at a rate of dT _N /dp=2.2±0.2 K/GPa. The result is discussed on the basis of the model proposed for the magnetic structure of fayalite by Santoro et al. (1966). The observed dT _N /dp suggests that the superexchange interactions vary as the ?10/3 power of the volume while the volume dependence of the direct exchange interactions is positive and small.  相似文献   

Microprobe mineralogy of plagioclase, clinopyroxene and amphibole as records of cooling rate in the Shirotori—Hiketa dike swarm, northeastern Shikoku, Japan     

Osamu Ujike 《Lithos》1982,15(4):281-287

A compositional gap between hypersolidus plagioclase and subsolidus plagioclase, most of which must have formed by devitrification, decreases in An % with decreasing cooling rate, probably reflecting a melt composition derived by in situ differentiation. Augitic pyroxenes, crystallized from a quickly cooling magma, tend to contain more Al, Ti, Na(+K) and Fe³⁺, and less Si and Mn. Compositional breaks between hypersolidus and subsolidus amphiboles with respect to the components of edenite and titanoamphibole, decrease in width with decreasing cooling rate. Subcalcic hornblende seems to grow from differentiated magmas in the course of moderate to rapid cooling.  相似文献   

Revision of magnitudes of large shallow earthquakes, 1897–1912     

Katsuyuki Abe  Shin&#x;ichi Noguchi 《Physics of the Earth and Planetary Interiors》1983,33(1):1-11

In previous research, trace amplitudes of surface wave maxima recorded by undamped Milne seismographs were used to determine the surface-wave magnitudes M_s of large shallow earthquakes which occurred prior to 1912. For this purpose, the effective gain of these instruments was calibrated by using the surface-wave magnitudes M_s(GR) which were calculated from the unpublished worksheets for Seismicity of the Earth of Gutenberg and Richter. In this paper, the real quality of M_s(GR) is critically re-evaluated by using independent sets of data. It is found that M_s(GR) for the period 1904–1909 is considerably overestimated. The average excess from the real M_s is 0.5 units for 1904–1906, 0.4 for 1907, 0.3 for 1908–1909 and 0.0 for 1910–1912. This overestimation is so systematic and large that the previous results are all redetermined. The average effective gain of Milne instruments is revised to be 21.9; previously, the gain depended on M_s. This revision results in systematic reduction in the previously assigned magnitudes. The revised values of M_s for 264 shallow earthquakes, with M_s=6.8 and over in the period 1897–1912 inclusive, are listed. The present revision is large enough to preclude the possibility of the high activity of large shallow earthquakes around the turn of the century. The present results have a direct effect on all the magnitude catalogues of shallow earthquakes which occurred prior to 1909.  相似文献