A raman spectroscopic study of Al-Si ordering in synthetic magnesium cordierite   总被引：1，自引：0，他引：1  

Paul McMillan  Andrew Putnis  Michael A. Carpenter 《Physics and Chemistry of Minerals》1984,10(6):256-260

A number of previous investigations have examined the ordering behavior of magnesium cordierite using X-ray diffraction, transmission electron microscopy, infrared spectroscopy and solution calorimetry. In the present investigation, one series of samples from the above studies has been examined by Raman spectroscopy. Systematic modifications in the spectra with annealing time at 1,200° C are consistent with a continuous ordering of the average Al/Si distribution from 4 h to at least 64 h, and which may begin earlier. Spectral changes are first definitely observed when the ordered domains are around 100 Å across, suggesting that Raman spectroscopy is sensitive to this distance scale. The spectra of samples annealed at 1,200° C are compared with samples annealed at 1,400°; C where ordering proceeds much faster, and the possible use of Raman spectroscopy in characterization of Al/Si order in cordierite is discussed. Finally, the Raman spectrum of Mg₂Al₄Si₅O₁₈ with a stuffed β-quartz structure has been obtained. Comparison of its spectrum with that of cordierite glass suggests similar structures for both, which seem different to that of disordered cordierite.  相似文献   

Vibrational spectra of olivine composition glasses: The Mg-Mn join     

Quentin Williams  Paul McMillan  Thomas F. Cooney 《Physics and Chemistry of Minerals》1989,16(4):352-359

The vibrational frequencies of a series of splatquenched, olivine glasses spanning the compositional range from Mg₂SiO₄ to Mn₂SiO₄ have been determined using both infrared and Raman spectroscopies. The spectra of all glasses show evidence of tetrahedral coordination of silicon (possibly with some slight distortions), and largely octahedral coordination of magnesium. Spectra of Mn-rich glasses indicate that there is some manganese in 4 or 5-fold coordination. The frequencies observed for the fundamental vibrations of the silica tetrahedra are similar to those previously observed for SiO₄ groups in both crystalline and glassy orthosilicates. Additionally, there is evidence for a small amount of silicate polymerization in all glasses characterized: vibrations attributable to Si₂O₇ groups are visible in both infrared and Raman spectra.  相似文献   

Black Hole Mergers in the Universe     

Portegies Zwart SF  McMillan SL 《The Astrophysical journal》2000,535(1):L17-L20

We present the first grating-resolution X-ray spectra of the Seyfert 1 galaxy NGC 3783, obtained with the High Energy Transmission Grating Spectrometer on the Chandra X-Ray Observatory. These spectra reveal many narrow absorption lines from the H-like and He-like ions of O, Ne, Mg, Si, S, and Ar as well as Fe xvii-Fe xxi L-shell lines. We have also identified several weak emission lines, mainly from O and Ne. The absorption lines are blueshifted by a mean velocity of approximately 440+/-200 km s-1 and are not resolved, indicating a velocity dispersion within the absorbing gas of a few hundred kilometers per second or less. We measure the lines' equivalent widths and compare them with the predictions of photoionization models. The best-fitting model has a microturbulence velocity of 150 km s-1 and a hydrogen column density of 1.3x1022 cm-2. The measured blueshifts and inferred velocity dispersions of the X-ray absorption lines are consistent with those of the strongest UV absorption lines observed in this object. However, simple models that propose to strictly unify the X-ray and UV absorbers have difficulty explaining simultaneously the X-ray and UV absorption-line strengths.  相似文献   

Genetic and meristic variation in black and smooth oreos in the New Zealand exclusive economic zone     

P. J. Smith  P. J. McMillan  B. Bull  S. M. McVeagh  P. M. Gaffney  S. Chow 《新西兰海洋与淡水研究杂志》2013,47(4):737-750

Meristic and genetic methods were used to determine the stock relationships of black Allocytus niger (James, Inada & Nakamura, 1988) and smooth oreo Pseudocyttus maculatus (Gilchrist, 1906) in the New Zealand Exclusive Economic Zone (EEZ). Samples were collected from four management areas—OEO 1 (south‐west), OEO 3A (Chatham Rise west), OEO 4 (Chatham Rise east), and OEO 6 (subantarctic) during the 1998 October‐December spawning period. Lateral line scale counts and pyloric caeca counts revealed differences between black oreo samples from OEO 6 and the other three OEO management areas. Lateral line scale counts in smooth oreo showed no significant differences between areas. Genetic analyses of four non‐coding regions of nuclear DNA and mitochondrial (mt) DNA haplotypes in black oreo showed no significant differentiation among the four management areas. Likewise for smooth oreo, genetic analyses of five non‐coding regions of nuclear DNA and mtDNA haplotypes showed no overall regional differentiation, although there was weak evidence at one locus for a difference between OEO 3A and OEO 6. The data do not reject the null hypothesis of a single genetic stock in New Zealand waters, and are typical of marine species with long pelagic juvenile stages.  相似文献   

Effect of spatial variability and seasonality in soil moisture on drainage thresholds and fluxes in a conceptual hydrological model     

H.K. McMillan 《水文研究》2012,26(18):2838-2844

This paper uses soil moisture data from 17 recording sensors within the 50 km² Mahurangi catchment in New Zealand to determine how measured variability in soil moisture affects simulations of drainage in a typical lumped conceptual model. The data show that variability smoothes the simulated field capacity threshold such that a proportion of the catchment contributes to drainage even when mean soil moisture content is well below field capacity. Spatial variability in soil moisture controls by extension the catchment drainage behaviour: the resulting smoothed shape of the catchment‐scale drainage function is demonstrated and is also determined theoretically under simplifying assumptions. The smoothing effect increases the total simulated discharge by 130%. The analysis explains previous findings that different drainage equations are required at point scale versus catchment scale in the Mahurangi. The spatial variability and hence the emergent drainage behaviour are found to vary with season, suggesting that time‐varying parameters would be warranted to simulate drainage. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Environmental education and learning communities: The case of Kaikorai Stream,Dunedin, New Zealand     

Simon G. McMillan  Tony Binns 《New Zealand geographer》2011,67(3):199-212

This paper discusses a secondary school education initiative focussing on environment and sustainability centred on a small urban stream. This initiative has passed through an engagement stage, involving the community and other schools, and is now being embedded in curriculum learning. A cross‐curricular learning programme has been trialled and points the way toward new types of educational models within secondary schools in accord with opportunities offered by the new school curriculum. Moreover, these opportunities have wider benefits across the primary, secondary and tertiary sectors as well as within the community. These benefits include vertically structured place‐based education, win‐win partnerships, rationalising of local resources and leadership and networking. Further developments within the context of integrated catchment management are ongoing.  相似文献   

Geological Applications of Laser‐Induced Breakdown Spectroscopy     

Nancy J. McMillan  Shannon Rees  Kristen Kochelek  Catherine McManus 《Geostandards and Geoanalytical Research》2014,38(3):329-343

Laser‐induced breakdown spectroscopy (LIBS) records light emitted from the decay of electrons to lower‐energy orbitals during cooling of laser‐induced ablation plasmas; the resultant spectra can be used in a variety of geoanalytical applications. Four aspects of LIBS analysis distinguish LIBS from traditional laboratory‐based analytical techniques: (i) the lack of necessary sample preparation, allowing rapid analysis of many samples, (ii) the ability to analyse both 20 to 100 μm‐diameter spots and whole rocks, (iii) the detailed chemical signature contained in a LIBS spectrum and (iv) the ability to take LIBS into the field in backpack portable instrumentation. Three case studies illustrate potential applications of LIBS in the geosciences. First, analysis of the Carrizozo basalt flow in New Mexico, USA, illustrated that LIBS spectra could discriminate between samples of similar composition within uncertainties typical of whole‐rock analysis by X‐ray fluorescence spectrometry. Second, spectra from four sets of rubies from Madagascar and Tanzania illustrate the use of LIBS and multivariate analysis to determine provenance with success rates of > 95%. This technique can also be applied to correlation of units. Finally, a chemical map of a copper ore from Butte, MT, USA, illustrates the use of spatially defined LIBS spectra to understand chemical variations within textural context.  相似文献   

The Astrometric Telescope Facility     

David Black  John Dyer  Kenji Nishioka  Jeffrey Scargle  Charlie Sobeck  Eugene Levy  Robert McMillan  Michael Castelaz  George Gatewood  Andrew Buffington 《Astrophysics and Space Science》1991,177(1-2):307-313

Summary The Astrometric Telescope Facility (ATF) proposed for use on NASA's planned Space Station is similar in form and data output to ground-based long focus astrometric instruments. With a focal plane scale of 12.7 arc seconds/mm, the strawman design has a field size of 10 arc min square and a limiting visual magnitude fainter than 16. Output from an observation includes the X and Y coordinates of each star and its relative brightness. The targeted precision for the AFT is 0.00001 arc seconds.Portions of the observing program will be made available to members of the astronomical community.  相似文献   

New experimental constraints on the composition and structure of tholins     

Eric Quirico  Gilles Montagnac  Paul F. McMillan  Guy Cernogora  Patrick Simon  Jean-Michel Bernard  Nicolas Fray  François Raulin  Bernard Schmitt 《Icarus》2008,198(1):218-231

Powdered samples of carbon-nitrogen-hydrogen “tholins” that mimic Titan's atmosphere aerosols were produced under levitation conditions in the laboratory with a dusty plasma (PAMPRE experiment) using different initial N₂:CH₄ gas mixtures and studied using UV Raman and infrared spectroscopy, X-ray diffraction and high resolution transmission electron microscopy (HRTEM). Comparison between the tholins produced in the PAMPRE experiments and samples prepared by other techniques reveal that they form a fairly homogeneous family of hydrogenated carbon nitride materials. Wall effects during the PAMPRE deposition experiments and other were found to have little effect on the chemical structure of tholins. The first-order UV Raman bands of the disordered carbonaceous materials point to a large contribution of sp² clusters present compared with olefinic CN or CC groupings, whereas features at 690 and 980 cm⁻¹ suggest C₃N₃ rings are present as a species inserted in the macromolecular network. Diffraction techniques do not indicate the presence of large polyaromatic species in any of the tholins studied, whatever their nitrogen concentration, in disagreement with certain previous observations. This precludes the idea that the nature and degree of absorption in the visible range is controlled by the size of polyaromatic species, as has been observed in series of carbon-based materials obtained via thermal processing. Infrared spectroscopy analysis of the tholins has confirmed earlier identifications of chemical groups present including primary amines, nitriles, and alkyl moieties such as CH₂/CH₃, but has ruled out CH₂/CH₃ branches appearing on secondary or tertiary amines. Similar analyses were also performed on a polymeric (HCN)_x material, which was found to present several similarities with the tholins, hence suggesting similar polymerization processes.  相似文献   

松辽盆地营城组中基性火山岩成岩作用:矿物晶出序列、杏仁体充填和储层效应   总被引：6，自引：1，他引：5  

刘万洙  黄玉龙  庞彦明  王璞珺 《岩石学报》2010,26(1):158-164

利用露头和钻井资料,通过显微镜观测、化学分析和电子探针分析,研究营城组中基性火山岩的矿物晶出系列和杏仁体充填及其储层效应。本区中基性火山岩包括玄武岩、安山岩、玄武安山岩、粗面玄武岩、玄武粗安岩和粗安岩。斑晶矿物的晶出顺序为:橄榄石最早并几乎全部蚀变为蛇纹石、伊丁石和磁铁矿,仅保留橄榄石假象;辉石被斜长石包含或与之交生,说明辉石晶出有的略早于斜长石、有的与之同时。基质呈间隐间粒结构,为比斑晶偏酸性/碱性的板条状微晶长石堆积搭成格架、内充填玻璃质及微晶粒状矿物(橄榄石、辉石和磁铁矿)。基质结晶晚于斑晶,晶出序列为微晶粒状矿物→微晶长石→玻璃质。有单成分和复成分两种杏仁体。单成分者主要见硅质和钙质,具结晶世代性,为后生流体沉淀充填形成,可作为储层变差或非储层的标志。复成分杏仁体是原生火山玻璃固态下水合与蚀变作用的结果:包括蛇纹石/绿泥石-火山玻璃、石英-方解石-皂石/方解石和石英-绿泥石-方解石等组合类型,通常可作为储层改善或有效性增加的标志。中基性火山玻璃蚀变分为四个阶段:新鲜火山玻璃(折光率1.57)→水合火山玻璃(折光率降至1.53)→橙玄玻璃(铁镁质微晶矿物集合体)→新生矿物(石英、方解石、蛇纹石、绿泥石、皂石);由火山玻璃变为新生矿物的体积减小或孔隙增加效应为7%～10%。  相似文献