Geology and volcanic stratigraphy of the Canatuan and Malusok volcanogenic massive sulfide deposits,southwestern Mindanao,Philippines     

Ross?L.?SherlockEmail author  Timothy?J.?Barrett 《Mineralium Deposita》2004,39(1):1-20

The Canatuan and Malusok massive sulfide deposits are located near Siocon, Zamboanga del Norte, in southwestern Mindanao, Philippines. The Canatuan–Malusok area is underlain by the Jurassic–Cretaceous Tungauan schists, which form much of the Zamboanga Peninsula. The volcanic strata at Canatuan and Malusok can be traced for >7 km along strike and is host to at least three discrete massive sulfide bodies: Canatuan, Malusok and SE Malusok. Basal basaltic andesite volcanic rocks are generally chemically uniform and show only moderate alteration. The massive sulfide deposits occur in overlying rhyolitic to rhyodacitic volcanic rocks that are altered to a schistose assemblage of quartz, sericite, chlorite and pyrite. The alteration is texturally destructive but graded clastic beds are locally observed. Despite tropical saprolitic weathering, four lithogeochemical subunits of the felsic package are identified. Stratigraphic interleaving, however, has made correlation of these units over any significant distance difficult. The sulfide lenses are overlain by a few metres of felsic schists which locally contain manganese-bearing silicates and oxides that serve as a stratigraphic marker. Hangingwall andesitic volcaniclastic rocks are discontinuously preserved, although where present, they consist of regularly bedded mafic volcanic sandstones. The lateral continuity of a manganese-bearing marker and flanking felsic volcaniclastic intervals indicate that locally the volcanic strata form a homoclinal sequence. The Canatuan Au–Ag–Cu–Zn deposit consists of a gossan overlying a massive sulfide lens. The sulfides and gossan are flat lying and hosted within felsic volcanic rocks. The gossan is gold–silver-rich, and was formed by a combination of oxidation and volume collapse of the original sulfide lens. The sulfide minerals present below the current water table, are auriferous massive pyrite with base metal sulfides, with some supergene chalcocite. The transition from gossan to sulfides is very sharp, occurring at the water table. Massive sulfide deposits at Malusok are hosted in the same felsic sequence as Canatuan and they have similar base and precious metal contents. Only limited gossan has been found at Malusok. The bimodal nature of the volcanic rocks at Canatuan, together with their low HFSE contents, near-flat REE patterns and tholeiitic affinities, suggest that they formed in an intra-oceanic arc setting above a depleted mantle source. Mafic and felsic volcanic rocks of similar composition have been recovered from the Tonga-Kermadec and Izu-Bonin-Marianas island-arc systems in the western Pacific. Mafic rocks at Canatuan show no evidence for LILE enrichment that characterizes melts derived from metasomatized mantle under more mature arcs, suggesting that they are the product of a nascent, rather than a mature arc. There is no evidence from the REE, or other incompatible trace elements, that continental crust or evolved arc crust was involved in the generation of the Canatuan-Malusok volcanic rocks. Although it has been proposed that the Zamboanga metamorphic complex comprises microcontinental fragments of Eurasian affinity, our data do not support an evolved crustal setting for the Canatuan-Malusok volcanic rocks, which we suggest were derived from an intra-oceanic arc and subsequently accreted to the eastern Mindanao terrane.Electronic Supplementary Material Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s00126-003-0350-7Editorial handling: R.R. Large  相似文献   

A search for forward scattering of sunlight from lunar libration clouds     

R.H. Munro  J.T. Gosling  E. Hildner  R.M. MacQueen  A.I. Poland  C.L. Ross  A. Hopfield 《Planetary and Space Science》1975,23(9):1313-1319

An attempt to determine the radiance of forward scattered sunlight from particles in lunar libration regions was made with the white light coronagraph on Skylab. The libration regions could not be distinguished against the solar K + F coronal background; an upper limit to the libration cloud radiance is determined to be $\text{2·5 × 10}{}^{\mathrm{?11}}\text{B}{}_{\mathrm{?}}$, where $\text{B}{}_{\mathrm{?}}$ is the mean radiance of the solar disk. Employing a model of the particle composition and size distribution which has been proposed for the interplanetary medium, we determine upper limits for the density enhancements in the libration region from the upper limit of the forward scattered radiance presented herein. Similarly, the actual spatial density enhancement is calculated using the earlier observations of the libration region backscattered radiance (Roach, 1975). Enhancements of a factor of 10²–10³ are thus determined, depending upon material composition and size distribution used. By combining the forward and backscatter observations, it is possible to eliminate from consideration clouds whose power law particle size distribution exponent k is 2·5 and complex index of refraction m is 1·33?0.05i and 1·50?0.05i (i.e. absorbing ice and quartz particles, respectively). Finally, the radiance contrast of a possible model libration cloud is calculated with respect to the K- and F-corona/zodiaal light background and is shown to be a maximum in the vicinity of solar elongation angle ～30 deg.  相似文献   

The speeds of coronal mass ejection events   总被引：2，自引：0，他引：2  

J. T. Gosling  E. Hildner  R. M. MacQueen  R. H. Munro  A. I. Poland  C. L. Ross 《Solar physics》1976,48(2):389-397

The outward speeds of mass ejection events observed with the white light coronagraph experiment on Skylab varied over a range extending from less than 100 km s^–1 to greater than 1200 km s^–1. For all events the average speed within the field of view of the experiment (1.75 to 6 solar radii) was 470 km s^–1. Typically, flare associated events (Importance 1 or greater) traveled faster (775 km s^–1) than events associated with eruptive prominences (330 km s^–1); no flare associated event had a speed less than 360 km s^–1, and only one eruptive prominence associated event had a speed greater than 600 km s^–1. Speeds versus height profiles for a limited number of events indicate that the leading edges of the ejecta move outward with constant or increasing speeds.Metric wavelength type II and IV radio bursts are associated only with events moving faster than about 400 km s^–1; all but two events moving faster than 500 km ^–1 produced either a type II or IV radio burst or both. This suggests that the characteristic speed with which MHD signals propagate in the lower (1.1 to 3 solar radii) corona, where metric wavelength bursts are generated, is about 400 to 500 km s^–1. The fact that the fastest mass ejection events are almost always associated with flares and with metric wavelength type II and IV radio bursts explains why major shock wave disturbances in the solar wind at 1 AU are most often associated with these forms of solar activity rather than with eruptive prominences.The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   

Electrical conductivity models for the continental crust based on laboratory measurements on high-grade metamorphic rocks   总被引：1，自引：0，他引：1  

C. D. Lee  F. J. Vine  R. G. Ross 《Geophysical Journal International》1983,72(2):353-371

Summary. Deep electrical conductivity soundings are increasingly being used as an additional source of information regarding the nature of the lower continental crust. However, a lack of relevant laboratory-based conductivity measurements makes interpretation of such soundings difficult. Laboratory measurements have been made on saturated and unsaturated samples of possible lower crustal rock types subjected to confining pressures up to 0.4 GPa, temperatures up to 300°C, and with variable pore fluid pressure up to the confining pressure. Extrapolation of these results suggests that the surprisingly high conductivities deduced for depths of approximately 20 km in certain stable continental areas may result from a combination of basic rock type and high pore fluid pressures, for whereas the conductivities measured in acid rock types can be explained in terms of conduction through the pore fluid alone, the conductivities measured in basic rock types imply enhanced conduction presumably through the matrix or along grain boundaries. The lower conductivities deduced from field experiments for the upper crust may be due to more acid rock types and/or lower pore fluid pressures, perhaps due to hydration reactions. In areas where the high conductivity layer is coincident with a low velocity layer an explanation in terms of changing pore fluid pressure, i.e. low to high, with increasing depth seems more likely.  相似文献   

A mapping of the electron localization function for earth materials     

G. V. Gibbs  D. F. Cox  N. L. Ross  T. D. Crawford  J. B. Burt  K. M. Rosso 《Physics and Chemistry of Minerals》2005,32(3):208-221

The electron localization function, ELF, generated for a number of geometry-optimized earth materials, provides a graphical representation of the spatial localization of the probability electron density distribution as embodied in domains ascribed to localized bond and lone pair electrons. The lone pair domains, displayed by the silica polymorphs quartz, coesite and cristobalite, are typically banana-shaped and oriented perpendicular to the plane of the SiOSi angle at ~0.60 Å from the O atom on the reflex side of the angle. With decreasing angle, the domains increase in magnitude, indicating an increase in the nucleophilic character of the O atom, rendering it more susceptible to potential electrophilic attack. The Laplacian isosurface maps of the experimental and theoretical electron density distribution for coesite substantiates the increase in the size of the domain with decreasing angle. Bond pair domains are displayed along each of the SiO bond vectors as discrete concave hemispherically-shaped domains at ~0.70 Å from the O atom. For more closed-shell ionic bonded interactions, the bond and lone pair domains are often coalesced, resulting in concave hemispherical toroidal-shaped domains with local maxima centered along the bond vectors. As the shared covalent character of the bonded interactions increases, the bond and lone pair domains are better developed as discrete domains. ELF isosurface maps generated for the earth materials tremolite, diopside, talc and dickite display banana-shaped lone pair domains associated with the bridging O atoms of SiOSi angles and concave hemispherical toroidal bond pair domains associated with the nonbridging ones. The lone pair domains in dickite and talc provide a basis for understanding the bonded interactions between the adjacent neutral layers. Maps were also generated for beryl, cordierite, quartz, low albite, forsterite, wadeite, åkermanite, pectolite, periclase, hurlbutite, thortveitite and vanthoffite. Strategies are reviewed for finding potential H docking sites in the silica polymorphs and related materials. As observed in an earlier study, the ELF is capable of generating bond and lone pair domains that are similar in number and arrangement to those provided by Laplacian and deformation electron density distributions. The formation of the bond and lone pair domains in the silica polymorphs and the progressive decrease in the SiO length as the value of the electron density at the bond critical point increases indicates that the SiO bonded interaction has a substantial component of covalent character.  相似文献   

U/Th dating by SHRIMP RG ion-microprobe mass spectrometry using single ion-exchange beads     

James L. Bischoff  Joe Wooden  Ross W. Williams 《Geochimica et cosmochimica acta》2005,69(7):1841-1846

We present a new analytical method for U-series isotopes using the SHRIMP RG (Sensitive High mass Resolution Ion MicroProbe) mass spectrometer that utilizes the preconcentration of the U-series isotopes from a sample onto a single ion-exchange bead. Ion-microprobe mass spectrometry is capable of producing Th ionization efficiencies in excess of 2%. Analytical precision is typically better than alpha spectroscopy, but not as good as thermal ionization mass spectroscopy (TIMS) and inductively coupled plasma multicollector mass spectrometry (ICP-MS). Like TIMS and ICP-MS the method allows analysis of small samples sizes, but also adds the advantage of rapidity of analysis. A major advantage of ion-microprobe analysis is that U and Th isotopes are analyzed in the same bead, simplifying the process of chemical separation. Analytical time on the instrument is ∼60 min per sample, and a single instrument-loading can accommodate 15-20 samples to be analyzed in a 24-h day. An additional advantage is that the method allows multiple reanalyses of the same bead and that samples can be archived for reanalysis at a later time. Because the ion beam excavates a pit only a few μm deep, the mount can later be repolished and reanalyzed numerous times. The method described of preconcentrating a low concentration sample onto a small conductive substrate to allow ion-microprobe mass spectrometry is potentially applicable to many other systems.  相似文献   

The creation and conduct of the Guatemalan Commission for Historical Clarification     

Amy Ross 《Geoforum》2006,37(1):69-81

As in other Latin American nations, Guatemala established a truth commission as a part of a negotiated transition from war to peace. The establishment of a particular truth commission arises out of the unique circumstances of that nation’s conflict and its negotiated resolution. As with other examples of truth commissions, the Guatemalan experience demonstrates the dilemmas of answering the demands for accountability, within the precarious context of a negotiated transition. Once established, a truth commission is subjected to the struggles within sectors of society striving to control the truth commission, and make it respond to certain interests. These struggles influence the practices, powers, and potential of the truth commissions.This article analyses the context in which the Guatemalan Commission for Historical Clarification emerged, the conditions in which it operated, and the potential consequences of the truth-seeking process. I argue that the Guatemalan truth commission became a site of struggle in which battles concerning impunity versus accountability occurred. This article first traces the phenomenon of truth commissions in Latin America, and locates the Guatemalan case within this regional context. Next, the negotiations that led to the formation of the truth commission are examined, in order to highlight the particular powers and interests at stake. Finally, I describe the operations of the Guatemalan truth commission in practice (1997-1999), and discuss the ways in which the commission developed a life of its own, despite the politics of its birth.  相似文献   

Chemical evidence for advection of hydrothermal solutions in the sediments of the Galapagos Mounds Hydrothermal Field     

Cynthia R.P. Maris  Michael L. Bender  Philip N. Froelich  Ross Barnes  Nile A. Luedtke 《Geochimica et cosmochimica acta》1984,48(11):2331-2346

Pore water profiles of Ca, Mg, F, PO₄^?3 and Mn in the Galapagos Mounds Hydrothermal Field are believed to reflect, in part, upwelling of hydrothermal solutions through the sediments. Concentration-depth profiles in a low heat flow area just north of the Mounds Field display diagenetic changes typical of those found in pore waters underlying highly productive surface waters, consistent with the inference of no water flow or very slow downwelling ($\text{w < 5}\text{cm/yr}$) of bottom water through these sediments. Rates of upward advection calculated from Mounds Field pore water profiles of Ca, Mg, and F profiles agree well with each other, averaging about 1 cm/yr in the pelagic sediments near the mounds and 15–30 cm/yr within the hydrothermal mounds themselves. The upward advection also modifies the shape of PO₄^?3 and Mn profiles.Advection rates inferred from the pore water data are generally in reasonable agreement with those made from heat flow data.The higher Ca and lower Mg, F, PO₄^?3 and Mn concentrations in Mounds Field pore waters (compared with those of the low heat flow area) suggest chemical exchange between the solution and basalt prior to upwelling. Li⁺, K⁺, Rb⁺, Sr⁺⁺ and SO₄^? concentrations are indistinguishable from bottom water. This suggests very high effective water/rock ratios during the reactions which produced the upwelling solutions, perhaps due to extensive prior alteration of basalt adjacent to the flow path of water through the crust Inferred reaction temperatures are between 70–150°C.  相似文献   

Chronology of the Black Sea over the last 25,000 years     

Egon T. DegensDavid A. Ross 《Chemical Geology》1972

Deep-water sediments of the Black Sea deposited during Late Pleistocene and Holocene time are distinguished by three sedimentary units: (1) a microlaminated coccolith ooze mainly consisting of Emiliania huxleyi; (2) a sapropel; and (3) a banded lutite. The base of the first unit lies at 3,000 years B.P., that of the second at 7,000 years B.P., and that of the third at least at about 25,000 years B.P. Fossils and geochemical criteria are used to decipher the environmental events of this time period. Beginning with the base of the section dated at about 25,000 years B.P. we witness the final stage of metamorphosis from anoxic marine to oxic freshwater conditions. By the time this stage ended, about 22,000 years B.P., the Black Sea had become a truly freshwater habitat. The lake phase lasted about 12,000 to 13,000 years. Sedimentation rates were in the order of 1 m/10³ years, but began to decrease as sea level rose during the last 5,000 years of this phase (9,000–15,000 years B.P.). Starting at about 9,000 years B.P. and continuing to 7,000 years B.P., Mediterranean waters occasionally spilled over the Bosporus as a consequence of ice retreat and sea level rise. This marked the beginning of a gradual shift from freshwater to marine, and from well aerated to stagnant conditions. At about 7,000 years B.P. when deposition of unit 2 started, the H₂S zone was well established. Sedimentation rates dropped to 10 cm/10³ years. Environmental conditions similar to those of today finally became established around 3,000 years B.P., almost exactly the time when Jason and the Argonauts sailed through the Bosporus in search of the Golden Fleece.  相似文献   

Occurrence and infrared spectra of holmquistite and hornblende from Mt. Marion,near Kalgoorlie,Western Australia     

R. W. T. Wilkins  L. R. Davidson  J. R. Ross 《Contributions to Mineralogy and Petrology》1970,28(4):280-287

Coexisting holmquistite and hornblende are described from an amphibolite associated with a spodumene pegmatite at Mt. Marion, near Kalgoorlie, Western Australia. Analytical, optical and infrared absorption data are presented. The distribution of cations in the holmquistite structure is readily determined by study of hydroxyl ion vibrations.  相似文献