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401.
402.
Knowing little about how porosity and permeability are distributed at depth, we commonly develop models of groundwater by treating the subsurface as a homogeneous black box even though porosity and permeability vary with depth. One reason for this depth variation is that infiltrating meteoric water reacts with minerals to affect porosity in localized zones called reaction fronts. We are beginning to learn to map and model these fronts beneath headwater catchments and show how they are distributed. The subsurface landscapes defined by these fronts lie subparallel to the soil-air interface but with lower relief. They can be situated above, below, or at the water table. These subsurface landscapes of reaction are important because porosity developed from weathering can control subsurface water storage. In addition, porosity often changes at the weathering fronts, and when this affects permeability significantly, the front can act like a valve that re-orients water flowing through the subsurface. We explore controls on the positions of reaction fronts under headwater landscapes by accounting for the timescales of erosion, chemical equilibration, and solute transport. One strong control on the landscape of subsurface reaction is the land surface geometry, which is in turn a function of the erosion rate. In addition, the reaction fronts, like the water table, are strongly affected by the lithology and water infiltration rate. We hypothesize that relationships among the land surface, reaction fronts, and the water table are controlled by feedbacks that can push landscapes towards an ‘ideal hill’. In this steady state, reaction-front valves partition water volumes into shallow and deep flowpaths. These flows dissolve low- and high-solubility minerals, respectively, allowing their reaction fronts to advance at the erosion rate. This conceptualization could inform better models of subsurface porosity and permeability, replacing the black box.  相似文献   
403.
In support of efforts to reconstruct relative sea level (RSL), we investigated the utility of foraminifera, diatoms and bulk‐sediment geochemistry (δ13C, C:N and parameters measured by Rock‐Eval pyrolysis) as sea‐level indicators in Eurasian sub‐Arctic salt marshes. At three salt marshes (<15 km apart) in Dvina Bay (White Sea, Russia), we collected surface sediment samples along transects from subtidal to Taiga forest environments. Foraminifera at all sites formed bipartite assemblages, where elevations below mean high higher water (MHHW) were dominated by Miliammina spp. and elevations between MHHW and the highest occurrence of foraminifera were dominated by Jadammina macrescens and Balticammina pseudomacrescens. Five high‐diversity groups of diatoms were identified and they displayed pronounced variability amongst the study sites. Bulk‐sediment geochemistry recognized two groups (clastic‐dominated environments below MHHW and organic‐rich environments above MHHW). As one group included subtidal elevations and the other included supratidal elevations, we conclude that the measured geochemical parameters are not stand‐alone sea‐level indicators. Core JT2012 captured a regressive sediment succession of clastic, tidal‐flat sediment overlain by salt‐marsh organic silt and freshwater peat. The salt‐marsh sediment accumulated at 2804±52 years before present and preserved foraminifera (Jadammina macrescens and Balticammina pseudomacrescens) with good analogy to modern assemblages indicating that RSL was +2.60±0.47 m at this time. Diatoms confirm that marine influence decreased through time, but the lack of analogy between modern and core assemblages limited their utility as sea‐level indicators. Geochemical parameters also indicate a reduction in marine influence through time. We conclude that RSL reconstructions derived from salt‐marsh sediment preserved beneath Eurasian sub‐Arctic peatlands can provide valuable insight into the spatio‐temporal evolution of the Fennoscandian and Eurasian ice sheets.  相似文献   
404.
Deep Earth dynamics impact so strongly on surface geological processes that we can use sediment palaeo‐markers as a window into the deeper Earth. Derived from climatic and tectonic erosive actions on the continents, and related to eustasy, subsidence and isostasy, the sediment in a deep basin is the main recorder of these processes. Nevertheless, defining and quantifying the relative roles of parameters that interact to give the final sedimentary architecture is not a simple task. Using a 3D‐grid of seismic and wide‐angle data, boreholes and numerical stratigraphic modelling, we propose here a quantification of post‐rift vertical movements in the Provençal Basin (West Mediterranean) involving three domains of subsidence: seaward tilting on the platform and the slope and purely vertical subsidence in the deep basin. These domains fit the deeper crustal domains highlighted by previous geophysical data. Post‐break‐up sedimentary markers may therefore be used to identify the initial hinge lines of the rifting phase and the subsidence laws.  相似文献   
405.
Detailed analyses of seismic profiles and boreholes in the Valencia Basin (VB) reveal a differentiated basin, the Minorca Basin (MB), lying between the old Mesozoic Valencia Basin sensu strico (VBss) and the young Oligocene Liguro‐Provençal Basin (LPB). The relationship between these basins is shown through the correlation of four Miocene‐to‐present‐day megasequences. The Central and North Balearic Fracture Zones (CFZ and NBFZ) that border the MB represent two morphological and geodynamical thresholds that created an accommodation in steps between the three domains. Little to no horizontal Neogene movements are found for the Ibiza and Majorca Islands. In contrast, the counterclockwise movement of the Corso‐Sardinian blocks induced a counterclockwise movement of the Minorca block towards the SE along the CFZ and NBFZ, during the exhumation of lower continental crust in the LPB. This new understanding implies pure Neogene vertical subsidence in the VBss and places the AlKaPeCa northeastward of the present‐day Alboran Area.  相似文献   
406.
After 33 years of repose, one of the most active volcanoes of the Kurile island arc—Sarychev Peak on Matua Island in the Central Kuriles—erupted violently on June 11, 2009. The eruption lasted 9 days and stands among the largest of recent historical eruptions in the Kurile Island chain. Satellite monitoring of the eruption, using Moderate Resolution Imaging Spectroradiometer, Meteorological Agency Multifunctional Transport Satellite, and Advanced Very High Resolution Radiometer data, indicated at least 23 separate explosions between 11 and 16 June 2009. Eruptive clouds reached altitudes of generally 8–16 km above sea level (ASL) and in some cases up to 21 km asl. Clouds of volcanic ash and gas stretched to the north and northwest up to 1,500 km and to the southeast for more than 3,000 km. For the first time in recorded history, ash fall occurred on Sakhalin Island and in the northeast sector of the Khabarovsky Region, Russia. Based on satellite image analysis and reconnaissance field studies in the summer of 2009, the eruption produced explosive tephra deposits with an estimated bulk volume of 0.4 km3. The eruption is considered to have a Volcanic Explosivity Index of 4. Because the volcano is remote, there was minimal risk to people or infrastructure on the ground. Aviation transport, however, was significantly disrupted because of the proximity of air routes to the volcano.  相似文献   
407.
Artificial macrophytes were experimentally deployed in Boadella Reservoir (NE Spain) and assessed for fish use throughout the first 3 months of the 2007 summer drawdown. In total, 1,832 individuals of seven fish species were recorded through visual censuses, with introduced perch Perca fluviatilis being the prevalent species. Fish richness and abundance were significantly higher in artificial macrophytes than in rocky shores and sandy beaches, displaying a unimodal variation through time. P. fluviatilis, Rutilus rutilus and Abramis brama were significantly more abundant in artificial macrophytes than in the other two naturally submersed habitats, where no individuals of these species were recorded. The abundances of Squalius laietanus, Lepomis gibbosus, Micropterus salmoides and Cyprinus carpio were overall greater in artificial macrophytes than in rocky shores but displayed significant habitat × time interactions. A decrease in predation risk was apparently the key-factor of the intensive use of artificial macrophytes by small fish (≤100 mm TL) in Boadella Reservoir, since most species reduced drastically or completely the use of submerged structures when body size increased. This study demonstrates that adding artificial structures mimicking aquatic macrophytes can be an interesting tool to mitigate the adverse effects of water level fluctuations on fish assemblages in structure-less and homogeneous ecosystems, and to understand the mechanisms affecting habitat use and species replacement.  相似文献   
408.
409.
Geodemographics offers the prospects of integrating, modelling and mapping health care needs and other health indicators that are useful for targeting neighbourhoods in public health campaigns. Yet reports about this application domain has to date been sporadic. The purpose of this paper is to examine the potential of a bespoke geodemographic system for neighbourhood targeting in an inner city public health authority, Southwark Primary Care Trust, London. This system, the London Output Area Classification (LOAC), is compared to six other geodemographic systems from both governmental and commercial sources. The paper proposes two new indicators for assessing the performance of geodemographic systems for neighbourhood targeting based on local hospital demand data. The paper also analyses and discusses the utility of age- and sex standardisation of geodemographic profiles of health care demand.  相似文献   
410.
Measurements of biogenic gases including enantiomeric monoterpenes and isoprene, and anthropogenic gases such as benzene, toluene, ethylbenzene, ortho-, meta- and para- xylene (BTEX) compounds were made by GC-MS in November and December 2008 within a stone pine (Pinus pinea L) forest located on the Southwest coast of Spain (37.10°N, 6.70°W). Mixing ratios of the biogenic species were found to be low (mean circa 10 pptv) consistent with previously observed low wintertime regional forest emission rates. In contrast, anthropogenic species were significantly higher (mean 10–156 pptv), the dominant emissions originating from the city of Huelva and associated petrochemical activities, located 25 km north west of the measurement site. In wintertime the monoterpene (?)-α-pinene was found to be in slight enantiomeric excess over (+)-α-pinene at night but by day the measured ratio was closer to one i.e. racemic. Samples taken the following summer in the same location showed much higher monoterpene mixing ratios and revealed a strong enantiomeric excess of (?)-α-pinene. This indicates a strong seasonal variance in the enantiomeric emission ratio which is not manifested in the day/night temperature cycles in wintertime. Mixing ratios of the xylene isomers (meta- and para-) and ethylbenzene, which are all well resolved on the beta-cyclodextrin column, were exploited to estimate average OH radical exposures to VOCs from the Huelva industrial area. These were compared to empirical estimates of OH based on JNO2 measured at the site. The deficiencies of each estimation method are discussed.  相似文献   
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