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131.
In this work, the recently developed “second-order” self-consistent method [Liu, Y., Ponte Castañeda, P., 2004a. Second-order estimates for the effective behavior and field fluctuations in viscoplastic polycrystals. J. Mech. Phys. Solids 52 467–495] is used to simulate texture evolution in halite polycrystals. This method makes use of a suitably optimized linear comparison polycrystal and has the distinguishing property of being exact to second order in the heterogeneity contrast. The second-order model takes into consideration the effects of hardening and of the evolution of both crystallographic and morphological texture to yield reliable predictions for the macroscopic behavior of the polycrystal. Comparisons of these predictions with full-field numerical simulations [Lebensohn, R.A., Dawson, P.R., Kern, H.M., Wenk, H.R., 2003. Heterogeneous deformation and texture development in halite polycrystals: comparison of different modeling approaches and experimental data. Tectonophysics 370 287–311], as well as with predictions resulting from the earlier “variational” and “tangent” self-consistent models, included here for comparison purposes, provide insight into how the underlying assumptions of the various models affect slip in the grains, and therefore the texture predictions in highly anisotropic and nonlinear polycrystalline materials. The “second-order” self-consistent method, while giving a softer stress-strain response than the corresponding full-field results, predicts a pattern of texture evolution that is not captured by the other homogenization models and that agrees reasonably well with the full-field predictions and with the experimental measures.  相似文献   
132.
Over the last decades, groundwater irrigation has become commonplace in many arid and semiarid regions worldwide, including Spain. This is largely a consequence of the advances in drilling and pumping technologies, and of the development of Hydrogeology. Compared with traditional surface water irrigation systems, groundwater irrigation offers more reliable supplies, lesser vulnerability to droughts, and ready accessibility for individual users. Economic forces influence the groundwater irrigation sector and its development. In Spain's Mediterranean regions, abstraction costs often amount to a very small fraction of the value of crops. In the inner areas, groundwater irrigation supports a more stable flow of farm income than rainfed agriculture. The social (jobs/m3) and economic (€/m3) value of groundwater irrigation generally exceeds that of surface water irrigation systems. However, poor groundwater management and legal controversies are currently at the base of Spain's social disputes over water. A thorough and transparent assessment of the relative socio-economic value of groundwater in relation to surface water irrigation might contribute to mitigate or avoid potential future conflicts. Enforcement of the European Union's Water Framework Directive may deliver better groundwater governance and a more sustainable use.
Resumen Durante las últimas décadas, la irrigación con agua subterránea se ha vuelto común en muchas regiones áridas y semiáridas alrededor del mundo, incluyendo a España. Ésta es en gran medida una consecuencia de los adelantos en las tecnologías de perforación y bombeo, y del desarrollo de la Hidrogeología. Comparada con los sistemas tradicionales de irrigación con agua superficial, la irrigación con agua subterránea ofrece suministros más fiables, la vulnerabilidad es menor a las sequías, y posee accesibilidad inmediata para los usuarios individuales. Las fuerzas económicas influyen el sector de irrigación con agua subterránea y su desarrollo. En las regiones mediterráneas de España, los costos de extracción suman a menudo una parte muy pequeña del valor de las cosechas. En las áreas internas, la irrigación con agua subterránea constituye un flujo más estable de ingresos para la granja, que la agricultura dependiente del agua lluvia. El valor social (empleos/m3) y económico (€/m3) de la irrigación con agua subterránea, generalmente excede a aquél con sistemas de irrigación de agua superficial. Sin embargo, la gestión pobre del agua subterránea y las controversias legales están actualmente en la base de las disputas sociales en España acerca del agua. Una evaluación completa y transparente del valor socio-económico relativo de agua subterránea respecto a la irrigación con agua superficial, podría contribuir mitigar o evitar los conflictos potenciales del futuro. La entrada en vigor del Marco Reglamentario de Agua de la Unión Europea, puede conllevar a una administración mejor del agua subterránea y a un uso más sostenible.

Résumé Depuis les dernières décennies, l’irrigation avec l’eau souterraine est devenue commune dans plusieurs régions arides et semi-arides, incluant l’Espagne. Ceci est largement une conséquence due à l’avancement aux technologies de forages et des pompages, et au développement de l’Hydrogéologie. Comparé avec des systèmes traditionnels d’irrigation utilisant l’eau de surface, l’irrigation avec l’eau souterraine offre une technique d’alimentation plus fiable, une vulnérabilité à la sécheresse moins grande, et une accessibilité plus aisée pour chaque utilisateur. Les forces économiques influencent le secteur de l’irrigation par l’eau souterraine et son développement. Dans les régions de l’Espagne Méditerranéenne, les coûts d’exploitation représentent toujours une petite fraction de la valeur des cultures. Dans les régions intérieures, l’irrigation par l’eau souterraine supporte une agriculture plus stable et continue qu’une agriculture reposant sur l’eau de pluie. La valeur sociale (emploi/m3) et économique (€/m3) de l’irrigation avec l’eau souterraine, excède généralement celle des systèmes d’irrigation avec l’eau de surface. Néanmoins, des gestions pauvres de l’eau souterraine et des controverses légales sont couramment à la base de disputes sociales sur l’eau. Un bilan transparent et minutieux des valeurs relatives socio-économiques de l’eau souterraine en relation avec l’eau de surface d’irrigation, devrait contribuer à éviter de potentiels et futurs conflits. Un renforcement de la Directive Cadre de l’Union Européenne devrait apporter une meilleure gouvernance et un usage plus durable.
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135.
Leach tests carried out on tektite specimens (indochinites and australites) under high-dilution conditions show a common behavior characterized by low leach rates (1.8 × 10?5g · m?2 · d?1or 7.2 × 10?12m · d?1 at 23°C) and an activation energy of (79.6 ± 0.7) × 103J · mol?1. The extent of selective leaching is very small, of the order of 10?8 m. Extrapolation of test results over the lifetime of the tektites gives an excellent agreement with field observations on the extent of corrosion, and this is an important step in establishing the validity of laboratory tests as a basis for the development of models and predictions concerning long-term durabilities at least in the limiting case of high dilution or rapid flow. The results are also shown to be in agreement with various previous observations on the corrosion resistance of tektites. The chemical durability of tektites is observed to be consistent with their composition, highlighting requirements for high corrosion resistance in glasses; these requirements include a silica content in excess of 67 mol%, an extremely low water content and an alkali content which is low both absolutely and relative to the di- and poly-valent metal oxide levels. It is shown that artificial glasses which fulfil these criteria are no less corrosion-resistant than the corresponding natural glasses. These conclusions have bearing on the development as well as on the evaluation of glasses intended for very long service, such as radioactive waste vitrification media.  相似文献   
136.
One of the most challenging technical issues associated with project-based mechanisms is that of leakage. A conceptual framework is proposed for the identification and analysis of leakage potentially generated by a project. The categorization of leakage based on the actors responsible for their manifestation is proposed, which divides sources of leakage into primary and secondary types. It is the actors or agents responsible for the baseline activities that cause primary leakage. Secondary leakage occurs when the project’s outputs create incentives for third parties to increase emissions elsewhere. This distinction, based on the source of leakage, provides a basis for the analysis outlined in the paper. The extent and type of leakage will vary depending on the project typology and design. Using a decision tree approach, the process of identifying potential sources of leakage is demonstrated for the case study of avoided deforestation projects. If the main elements determining a baseline are properly identified and understood, in particular the ‘baseline agents’, a combination of the decision tree approach and apportioning responsibility, can assist in the quantification and monitoring of primary leakage. An analysis at the project design stage can also assist in minimizing the risk of future leakage. Econometric methods may prove more useful in analyzing secondary leakage.  相似文献   
137.
1 INTRODUCTION Mathematical models to analyze the one-dimensional morphological evolution of alluvial rivers, induced either by natural events or anthropic actions, have been commonly applied since the original work of de Vries (1957, 1965, 1969). In the last decades much effort was made in developing suitable 2D horizontal and 3D time-depending mathematical models to study riverbed changes. In fact, full 2D-H hydro-morphological models (Olesen, 1987; Spasojevic and Holly, 1988) as w…  相似文献   
138.
Many oases(wet interdunes)are sedimentary systems characterized by high-frequency water-level oscillations,marked changes in salinity and intense biological activity at their margins.They are considered to be one of the most challenging environments on Earth for ecosystem development.These dynamic,depositional settings are usually unfavourable for fossilization and subsequent preservation of vegetal remains.This paper describes bryophyte(liverwort)assemblages occurring in three successive horizons interpreted to represent(i)recurrent early successional phases of biological soil crust colonization of wet interdune margins or(ii)exceptional preservation of floating or riparian liverworts in oasis pond waters associated with a progressive fall of the interdune water level.The record of in situ colonization surfaces characterized by delicate(e.g.lignin-free)three-dimensional structures represents an exceptional type of preservation herein associated with a rapid variation in phreatic interdune water level and the subsequent establishment of anoxic and reducing conditions.The occurrence of exceptionally preserved liverwort colonies coincides with the sedimentary record of,at least,three seismite levels in the oasis.Data gathered from the site suggests that the water table of the oasis was controlled by a combination of(i)a positive creation of accommodation space due to subsidence associated with movement on syn-sedimentary extensional faults,and(ii)the rise and fall of the oasis water table controlled by the oscillations of the groundwater system due to orbital changes which appear to drive the variability of the climate system.Rising groundwater levels flooded the oasis soil crusts and lead to the exceptional recurrent preservation of liverwort colonies at the oasis margins.Alternatively,considering the hypothesis of floating or riparian liverworts in the oasis pond waters,the fall in the level of the oasis water table placed the floating liverworts in contact with the oasis bottom sediments.This fall in the level of the oasis water table could indicate a cessation of accommodation space by syn-sedimentary extensional faults and/or a regional lowering of the groundwater system level associated with drought periods.Preliminary results indicate that oasis lamination between liverwort colonies records decadal and sub-decadal cyclicity,related with 11-year Schwabe sunspot and sub-decadal NAO cyclicities,conferring for every sedimentary cycle between liverwort colonies a duration of approximately 200 years,that otherwise matches the expected recurrence period for the De Vries cycle of solar activity.  相似文献   
139.
Global climate models have predicted a rise on mean sea level of between 0.18 m and 0.59 m by the end of the 21st Century, with high regional variability. The objectives of this study are to estimate sea level changes in the Bay of Biscay during this century, and to assess the impacts of any change on Basque coastal habitats and infrastructures. Hence, ocean temperature projections for three climate scenarios, provided by several atmosphere–ocean coupled general climate models, have been extracted for the Bay of Biscay; these are used to estimate thermosteric sea level variations. The results show that, from 2001 to 2099, sea level within the Bay of Biscay will increase by between 28.5 and 48.7 cm, as a result of regional thermal expansion and global ice-melting, under scenarios A1B and A2 of the Intergovernmental Panel on Climate Change. A high-resolution digital terrain model, extracted from LiDAR, data was used to evaluate the potential impact of the estimated sea level rise to 9 coastal and estuarine habitats: sandy beaches and muds, vegetated dunes, shingle beaches, sea cliffs and supralittoral rock, wetlands and saltmarshes, terrestrial habitats, artificial land, piers, and water surfaces. The projected sea level rise of 48.7 cm was added to the high tide level of the coast studied, to generate a flood risk map of the coastal and estuarine areas. The results indicate that 110.8 ha of the supralittoral area will be affected by the end of the 21st Century; these are concentrated within the estuaries, with terrestrial and artificial habitats being the most affected. Sandy beaches are expected to undergo mean shoreline retreats of between 25% and 40%, of their width. The risk assessment of the areas and habitats that will be affected, as a consequence of the sea level rise, is potentially useful for local management to adopt adaptation measures to global climate change.  相似文献   
140.
Seasonal monitoring was carried out to investigate the influence of extracellular enzymatic activity (EEA) on metal speciation and organic matter cycling in the rhizosediment of Spartina maritima . Heavy metal speciation was achieved by the Tessier scheme, and showed a similar pattern of variation of the organic-bound fraction, indicating a decomposition process in progress. Both humic acid and organic matter showed the same seasonal pattern. The basal respiration of the rhizosediments also presented a similar seasonal pattern, indicating a microbial degradation of organic matter. The high organic-bound fraction found in the summer gradually decreased towards the winter. This decrease was found to be related to the increase of activity of peroxidase, β- N -acetylglucosaminidase and protease. Also the activity of sulphatase was found to be related to the depletion on the exchangeable fraction, probably due to sulphide formation and consequent mobilization. The results show an interaction between several microbial activities, affecting metal speciation.  相似文献   
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