The Banhad?o Alkaline Complex, Southeastern Brazil: source and evolution of potassic SiO2-undersaturated high-Ca and low-Ca magmatic series     

Excelso Ruberti  Gaston E. R. Enrich  Rogério G. Azzone  Piero Comin-Chiaramonti  Angelo De Min  Celso B. Gomes 《Mineralogy and Petrology》2012,104(1-2):63-80

The Cretaceous Banhad?o alkaline complex in southeastern Brazil presents two potassic SiO₂-undersaturated series. The high-Ca magmatic series consist of initially fractionated olivine (Fo_92-91) + diopside (Wo_48-43En_49-35Ae_0-7), as evidenced by the presence of xenocrysts and xenoliths. In that sequence, diopside (Wo_47-38En_46-37Ae_0-8) + phlogopite + apatite + perovskite (Prv_>92) crystallized to form the phlogopite melteigite and led to the Ca enrichment of the magma. Diopside (Wo_47-41En_32-24 Ae_3-14) continued to crystallize as an early mafic mineral, followed by nepheline (Ne_74.8-70.1Ks_26.3-21.2Qz_7.6-0.9) and leucite (Lc_65-56) and subsequently by melanite and potassic feldspar (Or_85-99Ab_1-7) to form melanite ijolites, wollastonite-melanite urtites and melanite-nepheline syenites. Melanite-pseudoleucite-nepheline syenites are interpreted to be a leucite accumulation. Melanite nephelinite dykes are believed to represent some of the magmatic differentiation steps. The low-Ca magmatic series is representative of a typical fractionation of aegirine-augite (Wo_36-29En_25-4Ae_39-18) + alkali feldspar (Or_57-96Ab_3-43) + nepheline (Ne_76.5-69.0Ks_19.9-14.4Qz_15.1-7.7) + titanite from phonolite magma. The evolution of this series from potassic nepheline syenites to sodic sodalite syenites and sodalitolites is attributed to an extensive fractionation of potassic feldspar, which led to an increase of the NaCl activity in the melt during the final stages forming sodalite-rich rocks. Phonolite dykes followed a similar evolutionary process and also registered some crustal assimilation. The mesocratic nepheline syenites showed interactions with phlogopite melteigites, such as compatible trace element enrichments and the presence of diopside xenocrysts, which were interpreted to be due to a mixing/mingling process of phonolite and nephelinite magmas. The geochemical data show higher TiO₂ and P₂O₅ contents and lower SiO₂ contents for the high-Ca series and different LILE evolution trends and REE chondrite-normalized patterns as compared to the low-Ca series. The ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ²⁰⁶Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb initial ratios for the high-Ca series (0.70407–0.70526, 0.51242–0.51251, 17.782–19.266 and 38.051–39.521, respectively) were slightly different from those of the low-Ca series (0.70542–0.70583, 0.51232–0.51240, 17.758–17.772 and 38.021–38.061, respectively). For both series, a CO₂-rich potassic metasomatized lithospheric mantle enriched the source with rutile-bearing phlogopite clinopyroxenite veins. Kamafugite-like parental magma is attributed to the high-Ca series with major contributions from the melting of the veins. Potassic nephelinite-like parental magma is assigned to the low-Ca series, where the metasomatized wall-rock played a more significant role in the melting process.  相似文献   

Fault Roughness at Seismogenic Depths from LIDAR and Photogrammetric Analysis     

Andrea Bistacchi  W. Ashley Griffith  Steven A. F. Smith  Giulio Di Toro  Richard Jones  Stefan Nielsen 《Pure and Applied Geophysics》2011,168(12):2345-2363

Fault surface roughness is a principal factor influencing earthquake mechanics, and particularly rupture initiation, propagation, and arrest. However, little data currently exist on fault surfaces at seismogenic depths. Here, we investigate the roughness of slip surfaces from the seismogenic strike-slip Gole Larghe Fault Zone, exhumed from ca. 10 km depth. The fault zone exploited pre-existing joints and is hosted in granitoid rocks of the Adamello batholith (Italian Alps). Individual seismogenic slip surfaces generally show a first phase of cataclasite production, and a second phase with beautifully preserved pseudotachylytes of variable thickness. We determined the geometry of fault traces over almost five orders of magnitude using terrestrial laser-scanning (LIDAR, ca. 500 to <1 m scale), and 3D mosaics of high-resolution rectified digital photographs (10 m to ca. 1 mm scale). LIDAR scans and photomosaics were georeferenced in 3D using a Differential Global Positioning System, allowing detailed multiscale reconstruction of fault traces in Gocad^®. The combination of LIDAR and high-resolution photos has the advantage, compared with classical LIDAR-only surveys, that the spatial resolution of rectified photographs can be very high (up to 0.2 mm/pixel in this study), allowing for detailed outcrop characterization. Fourier power spectrum analysis of the fault traces revealed a self-affine behaviour over 3–5 orders of magnitude, with Hurst exponents ranging between 0.6 and 0.8. Parameters from Fourier analysis have been used to reconstruct synthetic 3D fault surfaces with an equivalent roughness by means of 2D Fourier synthesis. Roughness of pre-existing joints is in a typical range for this kind of structure. Roughness of faults at small scale (1 m to 1 mm) shows a clear genetic relationship with the roughness of precursor joints, and some anisotropy in the self-affine Hurst exponent. Roughness of faults at scales larger than net slip (>1–10 m) is not anisotropic and less evolved than at smaller scales. These observations are consistent with an evolution of roughness, due to fault surface processes, that takes place only at scales smaller or comparable to the observed net slip. Differences in roughness evolution between shallow and deeper faults, the latter showing evidences of seismic activity, are interpreted as the result of different weakening versus induration processes, which also result in localization versus delocalization of deformation in the fault zone. From a methodological point of view, the technique used here is advantageous over direct measurements of exposed fault surfaces in that it preserves, in cross-section, all of the structures which contribute to fault roughness, and removes any subjectivity introduced by the need to distinguish roughness of original slip surfaces from roughness induced by secondary weathering processes. Moreover, offsets can be measured by means of suitable markers and fault rocks are preserved, hence their thickness, composition and structural features can be characterised, providing an integrated dataset which sheds new light on mechanisms of roughness evolution with slip and concomitant fault rock production.  相似文献   

Principal Slip Zones in Limestone: Microstructural Characterization and Implications for the Seismic Cycle (Tre Monti Fault, Central Apennines, Italy)     

Steven A. F. Smith  Andrea Billi  Giulio Di Toro  Richard Spiess 《Pure and Applied Geophysics》2011,168(12):2365-2393

Earthquakes in central Italy, and in other areas worldwide, often nucleate within and rupture through carbonates in the upper crust. During individual earthquake ruptures, most fault displacement is thought to be accommodated by thin principal slip zones. This study presents detailed microstructural observations of the slip zones of the seismically active Tre Monti normal fault zone. All of the slip zones cut limestone, and geological constraints indicate exhumation from <2?km depth, where ambient temperatures are ?100°C. Scanning electron microscope observations suggest that the slip zones are composed of 100% calcite. The slip zones of secondary faults in the damage zone contain protocataclastic and cataclastic fabrics that are cross-cut by systematic fracture networks and stylolite dissolution surfaces. The slip zone of the principal fault has much more microstructural complexity, and contains a 2?C10?mm thick ultracataclasite that lies immediately beneath the principal slip surface. The ultracataclasite itself is internally zoned; 200?C300???m-thick ultracataclastic sub-layers record extreme localization of slip. Syn-tectonic calcite vein networks spatially associated with the sub-layers suggest fluid involvement in faulting. The ultracataclastic sub-layers preserve compelling microstructural evidence of fluidization, and also contain peculiar rounded grains consisting of a central (often angular) clast wrapped by a laminated outer cortex of ultra-fine-grained calcite. These ??clast-cortex grains?? closely resemble those produced during layer fluidization in other settings, including the basal detachments of catastrophic landslides and saturated high-velocity friction experiments on clay-bearing gouges. An overprinting foliation is present in the slip zone of the principal fault, and electron backscatter diffraction analyses indicate the presence of a weak calcite crystallographic preferred orientation (CPO) in the fine-grained matrix. The calcite c-axes are systematically inclined in the direction of shear. We suggest that fluidization of ultracataclastic sub-layers and formation of clast-cortex grains within the principal slip zone occurred at high strain rates during propagation of seismic ruptures whereas development of an overprinting CPO occurred by intergranular pressure solution during post-seismic creep. Further work is required to document the range of microstructures in localized slip zones that cross-cut different lithologies, and to compare natural slip zone microstructures with those produced in controlled deformation experiments.  相似文献   

Seismic response of L��Aquila downtown from comparison between 2D synthetics spectral ratios of SH, P-SV and Rayleigh waves and observations of the 2009 earthquake sequence     

Paola Bordoni  John Haines  Giuliano Milana  Sandro Marcucci  Fabrizio Cara  Giuseppe Di Giulio 《Bulletin of Earthquake Engineering》2011,9(3):761-781

This is the first part of a study on the seismic response of the L’Aquila city using 2D simulation and experimental data. We have studied two velocity-depth models with the aim of outlining the behavior of a velocity reversal in the top layer, which is associated with the stiff Brecce de L’Aquila unit (BrA). In this setting, the SMTH model is topped by a layer with about 2:1 impedance contrast with the underlying layer while the NORV model has no velocity reversal. We have simulated the propagation of SH and P-SV wavefields in the range 0–10 Hz for incidence 0°–90°. Earthquake spectral ratios of the horizontal and vertical components at six sites in L’Aquila downtown are compared to corresponding synthetics spectral ratios. The vertical component of P-SV synthetics enables us to investigate a remarkable amplification effect seen in the vertical component of the recorded strong motion. Sites AQ04 and AQ05 are best matched by synthetics from the NORV model while FAQ5 and AQ06 have a better match with synthetics spectral ratios from the SMTH model. All simulations show this behavior systematically, with horizontal and near-horizontal incident waves predicting the overall pattern of matches more clearly than vertical and near-vertical incidence. The model inferences are in agreement with new geological data reporting lateral passages in the top layer from the stiff BrA to softer sediments. Matches are good in terms of frequency of the first amplification peak and of spectral amplitude: the horizontal components have spectral ratio peaks predominantly at 0.5 Hz in the simulations and at 0.7 Hz in the data, both with amplitudes of 4, while the vertical component spectral ratios reach values of 6 at frequencies of about 1 Hz in both data and simulations. The vertical component spectral ratios are very well matched using Rayleigh waves with incidence at 90°. The NORV model without the velocity reversal predicts spectral ratio peaks for the horizontal components at frequencies up to 6 Hz. The reversal of velocity acts as a low-pass frequency filter on the horizontal components reducing the amplification effect of the sediment filled valley.  相似文献   

Site effects of the Roio basin, L��Aquila     

E. Bertrand  A.-M. Duval  J. R��gnier  R. M. Azzara  F. Bergamashi  P. Bordoni  F. Cara  G. Cultrera  G. Di Giulio  G. Milana  J. Salichon 《Bulletin of Earthquake Engineering》2011,9(3):809-823

During the microzonation studies of the April 6th, 2009 L??Aquila earthquake, we observed local seismic amplifications in the Roio area??a plane separated from L??Aquila city center by mount Luco. Six portable, digital instruments were deployed across the plain from 15 April to mid-May 2009. This array recorded 152 aftershocks. We analyzed the ground motion from these events to determine relative site amplification within the plain and on surrounding ridges. Horizontal over vertical spectral ratio on noise data (HVSRN), aftershock recordings (HVEQ) and standard spectral ratio (SSR) showed amplifications at 1.3 and 4.0?Hz on quaternary deposits. Seismic amplifications in the frequency range of 4 and 6?Hz were also observed on a carbonate ridge of Colle di Roio, on the northwestern border of the plateau. A small amplification was noticed near the top of mount Luco, another rocky site. Large discrepancies in the amplification levels between methods have been observed for these sites, but the HVSRN, HVEQ and SSR gave similar results at the stations located in the Roio plain. On the rocky sites, the SSR was more reliable than the HVSRN at estimating the transfer function of the site, even if the resonance frequency seemed to be well detected by the latter method.  相似文献   

Time and space dependency in impact damage evaluation of a sub-Plinian eruption at Mount Vesuvius     

Giulio Zuccaro  Daniela De Gregorio 《Natural Hazards》2013,68(3):1399-1423

The volcanic eruptions have produced death and devastation along the ages; the victims caused by the documented events are about 260,000. Today, people subjected to volcanic risk are 500 million. They live predominantly in large conurbations, such as Tokyo, Mexico City, Seattle and Naples, which are located in the proximity of volcanoes with a high probability to erupt. Further, cause of concern is the elevated growth rates of the urban populations in the developing countries, seeing that many cities are located just above the tectonic belts where are predominantly situated the World’s most explosive volcanoes. Therefore, the volcanic risk mitigation of these areas requires a careful territorial planning together with an adequate knowledge of the behaviour of constructions under the eruption effects. The problem is very complex considering that a several number of actions (such as lavas, earthquakes, ash fall, pyroclastic flows, ballistics, landslides, tsunami and lahars) with a peculiar time–space distribution are produced by an eruptive event. Moreover, for the impact evaluation of a volcanic eruption, the time–space effect acquires a great importance, differently by the case of single catastrophic event (such as tectonic earthquakes, debris flows, etc.), since the sequence of the several exceptional actions which occur during an eruptive event, that modify the resistance characteristics of the struck constructions, in consequence, the impact damage evaluation requires analyses, step by step, of the eruptive process, the damage accumulated on the buildings and the distribution of the damage on the territory. All these aspects are examined in this paper which furnishes a useful compendium relating to the impact damage assessment produced on buildings by an explosive volcanic eruption, through the time–space variability analysis. This document organically summarizes the results of about 15 years of researches conducted by the PLINIVS Study Centre (Study Centre for the Hydrogeological, Volcanic and Seismic Engineering) with reference to the volcanic risk assessment, in the framework of the scientific literature on the topic. The paper analyses the probabilistic approaches used these days to treat Hazard, Vulnerability and Exposure in risk and impact evaluation of volcanic eruptions. Reliability of the model available is discussed; open problems and future improvement of the research in progress are highlighted. In conclusion, recommendations to follow for impact estimation studies in volcanology are reported.  相似文献   

Vitellogenin-associated maternal transfer of exogenous and endogenous ligands in the estuarine fish, Fundulus heteroclitus     

G. H. Monteverdi  R. T. Di Giulio 《Marine environmental research》2000,50(1-5)

Sequestration of large quantities of vitellogenin (VTG) is critical for proper oocyte development in most oviparous vertebrates. While previous studies have shown a general correlation between oocyte growth and the accumulation of various exogenous and endogenous ligands, few studies have attempted to elucidate the role VTG plays in this maternal transfer. In the present study, we have demonstrated that oocytic accumulation of [³H]-2,3,7,8-tetrachlorodibenzo-p-dioxin (³H-TCDD) and [¹⁴C]-benzo(a)pyrene (¹⁴C-BaP) by gravid Fundulus heteroclitus is directly correlated with oocyte maturational status. A positive correlation was observed between oocyte maturational state (size) and both total quantity (total pmoles) as well as concentration (pmoles/g tissue) of TCDD and BaP. Further, the bi-phasic accumulation of both TCDD and BaP mirrors that previously observed for protein sequestration by cultured Fundulus oocytes. Additionally, both TCDD and BaP were associated with VTG in vivo. HPLC analysis of serum extracts has shown that VTG associates with both parent BaP and BaP metabolites. Studies with ¹²⁵I-T₄ (thyroxine) also suggest that this critical hormone also associates with VTG in vivo. Ongoing studies are examining the VTG-associated transport and oocytic sequestration of ¹²⁵I-T₄ in gravid Fundulus.  相似文献   

Nonequilibrium Processes in the Solar Corona,Transition Region,Flares, and Solar Wind <Emphasis Type="Italic">(Invited Review)</Emphasis>     

Jaroslav Dudík  Elena Dzifčáková  Nicole Meyer-Vernet  Giulio Del Zanna  Peter R. Young  Alessandra Giunta  Barbara Sylwester  Janusz Sylwester  Mitsuo Oka  Helen E. Mason  Christian Vocks  Lorenzo Matteini  Säm Krucker  David R. Williams  Šimon Mackovjak 《Solar physics》2017,292(8):100

We review the presence and signatures of the non-equilibrium processes, both non-Maxwellian distributions and non-equilibrium ionization, in the solar transition region, corona, solar wind, and flares. Basic properties of the non-Maxwellian distributions are described together with their influence on the heat flux as well as on the rates of individual collisional processes and the resulting optically thin synthetic spectra. Constraints on the presence of high-energy electrons from observations are reviewed, including positive detection of non-Maxwellian distributions in the solar corona, transition region, flares, and wind. Occurrence of non-equilibrium ionization is reviewed as well, especially in connection to hydrodynamic and generalized collisional-radiative modeling. Predicted spectroscopic signatures of non-equilibrium ionization depending on the assumed plasma conditions are summarized. Finally, we discuss the future remote-sensing instrumentation that can be used for the detection of these non-equilibrium phenomena in various spectral ranges.  相似文献   

Systematic conservation planning in the Mediterranean: a flexible tool for the identification of no-take marine protected areas     

Maiorano  Luigi; Bartolino  Valerio; Colloca  Francesco; Abella  Alvaro; Belluscio  Andrea; Carpentieri  Paolo; Criscoli  Alessandro; Jona Lasinio  Giovanna; Mannini  Alessandro; Pranovi  Fabio; Reale  Bruno; Relini  Giulio; Viva  Claudio; Ardizzone  Gian Domenico 《ICES Journal of Marine Science》2009,66(1):137-146

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Chemical and tectonic controls on the formation of sparry magnesite deposits — the deposits of the northern Greywacke Zone (Austria)     

Giulio Morteani  Horst Neugebauer 《International Journal of Earth Sciences》1990,79(2):337-344

The sparry magnesite deposits of the northern Greywacke Zone are situated at the base of thrust sheets. Model calculations and natural examples suggest that an inverse temperature gradient can only be established at the base of a thrust sheet if thrusting is so rapid as to be geologically unrealistic. Independently of this thrusting induces a fluid flow from the lower units to the front of the moving thrust sheet. Stability data of magnesite and dolomite in contact with fluids with different Ca/(Ca+Mg) ratios suggest that this tectonically induced fluid flow produce magnesite from preexisting dolomite by metasomatism.

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Zusammenfassung Die Spatmagnesitvorkommen der Nördlichen Grauwackenzone liegen innerhalb von Deckengrenzen. Modellberechnungen zeigen, daß ein inverser Temperaturgradient sich nur dann an der Basis von Decken einstellen kann, wenn die Überschiebungsgeschwindigkeit so groß wird, daß sie geologisch unglaubwürdig ist. Deckenüberschiebungen erzeugen aber in jedem Fall in der überschobenen Einheit einen zur Deckenfront hin gerichteten Fluidstrom. Eine Betrachtung der Stabilitätsdaten für Magnesit und Dolomit im Gleichgewicht mit einer fluiden Phase mit unterschiedlichen Ca/(Ca+Mg)-Verhältnissen zeigt, daß durch einen solchen Fluidstrom metasomatisch Magnesit aus Dolomit gebildet werden kann.

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Résumé Les dépôts de magnésite spathique de la Grauwacken Zone septentrionale sont situés à la base d'unités charriées. Un calcul de modélisation et des exemples naturels montrent qu'un gradient inverse de température ne peut s'établir à la base d'une unité charriée qu'à la condition d'admettre une vitesse de charriage tellement élevée qu'elle est irréaliste. D'autre part, le phénomene de charriage induit un déplacement de fluide depuis les unités inférieures vers le front de la nappe. Les données relatives aux conditions de stabilité de la magnésite et de la dolomite en présence de fluides de divers rapports Ca/Ca+Mg permettent de déduire que le flux ainsi engendré par la tectonique peut engendrer la magnésite par métasomatose à partir de dolomite préexistante.

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