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31.
X-PEEM images and XPS were collected on isolated layers of three synthetic swelling clays, one hectorite and two saponites with various charge, recording the Si(2p), Al(2p) and Mg(2p) core level spectra from the clay sheets. Spectra were fitted to determine the different components of the core levels. Due to their large full width at half maximum, Si XPS spectra were fitted using two to three doublets. It appears that, for a given clay mineral, Si, Al and Mg binding energies (BE) were constant, for all the observed layers. However, variations of the Si BE were observed depending on the nature of the mineral investigated. The various components obtained from the fit of Si spectra could be assigned to different substitution rates; binding energy shifting to lower values with substitution increase in the layer. Furthermore, variations in Si BE according to charge location were assigned to the influence of exchangeable cation.  相似文献   
32.
Being a laborious approach, manual calibration of hydrologic model in a semi-arid context requires in-depth knowledge of the watershed and as much as possible field input data to obtain reliable simulations. In this study, manual calibration and relative sensitivity analysis approaches of the SWAT model (Soil and Water Assessment Tool) were applied for water balance in a 1993 km2 watershed (on the R’dom river) located in North-western Morocco. The watershed is located in a semi-arid area dominated by agro-forestry activities. The objectives of this study were (i) to perform a local sensitivity analysis of the SWAT model taking into consideration the watershed characteristics and (ii) to implement a detailed methodology of manual calibration and validation of the model in a semi-arid context. Sensitivity analysis has been carried out on 12 different SWAT input parameters, and has revealed that 4 input parameters only were the most influential ones on flow components of the R’dom watershed. Model manual calibration was conducted along 2006 and 2007 by comparing measured and predicted monthly and daily discharges and taking Nash-Sutcliffe coefficient (NSE), determination coefficient (R 2), and percent bias (PBIAS) as goodness-of-fit indicators. Validation has been performed by the same approach through 2008 and 2009 period. All final NSE values were above 0.5, R 2 values exceeded 0.7, and PBIAS lower than 25% demonstrating satisfactory model performances over the study watershed conditions. The SWAT model set-up with measured input data, manually calibrated and validated, reflects well the real hydrologic processes occurring in the R’dom watershed and can be used to assess current and future conditions and to evaluate alternative management practices.  相似文献   
33.
The Middle Anisian has been palynologically characterized for the first time, at the whole Moroccan scale, in the High Atlas of Marrakech. The stratigraphic, tectonic and paleogeographic implications of this discovery are analysed. To cite this article: E.H. El Arabi et al., C. R. Geoscience 338 (2006).  相似文献   
34.
The structurally controlled Au–Pd mineralization at Bleïda Far West occurs in a volcano-sedimentary rock sequence in altered amphibolites and chlorite schists of the Neoproterozoic Bou Azzer–El Graara inlier. The Au–Pd mineralization is virtually sulfide-free; instead, gold is associated with hematite, barite, quartz, and calcite. The gold grains are silver- and palladium-bearing (up to 19 wt% Ag and 6.3 wt% Pd) and are intergrown with a distinct suite of mainly Pd-dominated platinum group minerals, namely mertieite-I/isomertieite, merenskyite, keithconnite, kotulskite, palladseite, and sperrylite, defining a Au–Pd–As–Sb–Se–Te chemical signature. Stable isotope and fluid inclusion studies indicate a wide range of fluid compositions with a prominent saline component. In conjunction with the mineral association, oxidizing fluids are indicated, and Au and PGE transport and deposition likely took place by chloride complexes in the epithermal range, at elevated f O2 and/or low pH. It is still speculative whether the mineralization is late Pan-African (~600–550 Ma) in age, or connected with the Variscan orogeny (~330–300 Ma), or related to some other hydrothermal event. Common to all Au–Pd mineralizations worldwide (Brazil, Australia, UK), including Bleïda Far West, is their formation in the epithermal (<300°C) range; deposition mainly in brittle structures; sulfide-poor mineral assemblages comprising hematite, sulfate minerals, and selenides; and metal transport by, and deposition from, oxidized, chloride-rich fluids. These deposits are further characterized by noble metal abundances in the order Au>Pd>Pt and the chemical signature Au–Pd–Se–Te (±As, Sb, Bi). As such, the Au–Pd association represents a discrete style of gold mineralization distinct from other classes of gold deposits.  相似文献   
35.
36.
New geochronological analyses (U–Pb SIMS zircon ages) have yielded ages of 552 ± 5 Ma for the Bou Madine rhyolitic dome (Ougnat, eastern Anti-Atlas), 543 ± 9 Ma for the Tachkakacht rhyolitic dyke (Saghro–Imiter, eastern Anti-Atlas), and 531 ± 5 Ma for the Aghbar trachytic sill (Bou Azzer, central Anti-Atlas). Inherited zircon cores from the Aghbar trachytic sill and from the Bou Madine rhyolitic dome have been shown to be of Statherian age (ca. 1600–1800 Ma) and Palæoproterozoic (>2100 Ma) age, respectively, suggesting that a significantly older protolith underlies the Pan-African rocks in the Central and Eastern Anti-Atlas. Granodiorites and rhyolites from the Saghro–Imiter area have similar low 87Sr/86Sr (0.702–0.706) and 143Nd/144Nd (0.5116–0.5119) initial ratios, suggesting a mixture of mantle and lower crust sources. This can also be inferred from the low 187Os/188Os ratios obtained on pyrite crystals from the rhyolites.A recently published lithostratigraphic framework has been combined with these new geochemical and geochronological data, and those from the literature to produce a new reconstruction of the complex orogenic front that developed at the northern edge of the Eburnian West African craton during Pan-African times. Three Neoproterozoic magmatic series can be distinguished in the Anti-Atlas belt, i.e., high-K calc-alkaline granites, high-K calc-alkaline to shoshonitic rhyolites and andesites, and alkaline-shoshonitic trachytes and syenites, which have been dated at 595–570, 570–545 and 530 Ma, respectively.The accretion of the Pan-African Anti-Atlas belt to the West African super continent (WAC) was a four-stage event, involving extension, subduction, moderate collision and extension. The calc-alkaline magmatism of the subduction stage was associated with large-scale base metal and gold mineralisation. Metallogenic activity was greatest during the final extensional stage, at the Precambrian–Cambrian boundary. It is characterised by world-class precious metal deposits, base–metal porphyry and SEDEX-type occurrences.  相似文献   
37.
The submarine sewage outfall of Santos (SSOS) is situated in the Santos Bay (São Paulo, Brazil) and is potentially a significant source of contaminants to the adjacent marine ecosystem. The present study aimed to assess the influence of SSOS on the sediment toxicity and contamination at Santos Bay. At the disposal site, sediments tended to be finer, organically richer and exhibited higher levels of surfactants and metals, sometimes exceeding the “Threshold Effect Level” values. The SSOS influence was more evident toward the East, where the sediments exhibited higher levels of TOC, total S and metals during the summer 2000 sampling campaign. Sediment toxicity to amphipods was consistently detected in four of the five stations studied. Amphipod survival tended to correlate negatively to Hg, total N and % mud. This work provides evidence that the SSOS discharge affects the quality of sediments from Santos Bay, and that control procedures are warranted.  相似文献   
38.
The convective atmospheric vortex models of Kuo (1966) and Kendall (1978) are extended to allow the formulation of similarity equations for the unsteady vortex arising from an ambient flow with unstable stratification and rotation. In particular, a new analytical solution is found which allows flow at large radius that is more physically realistic than in any earlier solutions. Additional unsteady solutions are obtained numerically but at large radius these are subject to the limitations of earlier solutions.  相似文献   
39.
Planktonic foraminifera and pollen data from core GNS84-C106 (Gulf of Salerno, Tyrrhenian Sea) were analysed through the Modern Analogue Technique, Constrained Cluster Analysis and relative variation biplots. A long period of mild climate, centred around 25 ka BP, is evident in both marine and continental reconstructions. The cooling phase from 17 to 14.7 ka BP, correlated to the H1 Heinrich event, is indicated by a sea surface temperature (SST) decrease, which roughly coincides with the cold-arid phase identified by annual and January temperatures. A rapid increase in atmospheric temperatures and precipitation, culminating at 13.8 ka BP, marks the BA cronozone. The corresponding increase in summer and winter SSTs, of 11 and 6.5 °C, respectively, occurred over 600 years. The beginning of the YD, centred around 12.5 ka BP, is marked by a decrease in summer and winter SSTs of, respectively, 4.5 and 3.5 °C in one century. The atmospheric evidence of the YD is primarily reflected in low January temperatures, reaching −6 °C, the lowest values ever experienced in the analysed time interval. The Late Glacial–Holocene transition is clearly recorded in both the continental and marine realms. From 11.5 to 9 ka BP, atmospheric temperatures record a period of substantial stability followed by a drop at 8.9 ka BP, which chronologically fall within the first RCC event (9–8 ka BP) of Mayewski et al. [2004. Holocene climate variability. Quaternary Research 62, 243–255], in correspondence with a phase of relatively high seasonality, indicated by foraminifera.  相似文献   
40.
During the last earthquake that occurred in Chlef (El Asnam 1980, Algeria), a significant decrease in the shear strength has caused major damages to several civil and hydraulic structures (earth dams, embankments, bridges, slopes and buildings), especially for the saturated sandy soil of the areas near Chlef valley. This paper presents a laboratory study of drained compression triaxial tests conducted on sandy soil reinforced with horizontal layers of geotextile, in order to study the influence of geotextile layer characteristics both on shear stress–strain and on volumetric change–strain. Tests were carried out on medium and dense sand. The experimental programme includes some drained compression tests performed on reinforced sand samples, for different values of the geotextile layers number (N g), of confining pressure (\( \sigma_{\text{c}}^{\prime } \)) and relative density (D r). The test results have shown that the contribution of the geotextile at low values of the axial strain (ε 1) is negligible, for higher values of (ε 1); geotextile induces a quasi-linear increase in the deviator stress (q) and leads to an increase in the volume contractiveness within the reinforced samples. A negligible influence of geotextile layers number (N g) on the stress–strain behaviour and the volumetric change has been shown, when normalized with N g. The results indicate that the contribution of geotextile to the stress–strain mobilization increases with increasing confining pressure, while its contribution to the volume contraction decreases with the increase in the confining pressure.  相似文献   
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