Ultra‐reduced phases in Apollo 16 regolith: Combined field emission electron probe microanalysis and atom probe tomography of submicron Fe‐Si grains in Apollo 16 sample 61500          下载免费PDF全文

Phillip Gopon  Michael J. Spicuzza  Thomas F. Kelly  David Reinhard  Ty J. Prosa  John Fournelle 《Meteoritics & planetary science》2017,52(9):1941-1962

The lunar regolith contains a variety of chemically reduced phases of interest to planetary scientists and the most common, metallic iron, is generally ascribed to space weathering processes (Lucey et al. 2006 ). Reports of silicon metal and iron silicides, phases indicative of extremely reducing conditions, in lunar samples are rare (Anand et al. 2004 ; Spicuzza et al. 2011 ). Additional examples of Fe‐silicides have been identified in a survey of particles from Apollo 16 sample 61501,22. Herein is demonstrated the utility of low keV electron probe microanalysis (EPMA), using the Fe Ll X‐ray line, to analyze these submicron phases, and the necessity of accounting for carbon contamination. We document four Fe‐Si and Si⁰ minerals in lunar regolith return material. The new Fe‐Si samples have a composition close to (Fe,Ni)₃Si, whereas those associated with Si⁰ are close to FeSi₂ and Fe₃Si₇. Atom probe tomography of (Fe,Ni)₃Si shows trace levels of C (60 ppma and nanodomains enriched in C, Ni, P, Cr, and Sr). These reduced minerals require orders of magnitude lower oxygen fugacity and more reducing conditions than required to form Fe⁰. Documenting the similarities and differences in these samples is important to constrain their formation processes. These phases potentially formed at high temperatures resulting from a meteorite impact. Whether carbon played a role in achieving the lower oxygen fugacities—and there is evidence of nearby carbonaceous chondritic material—it remains to be proven that carbon was the necessary component for the unique existence of these Si⁰ and iron silicide minerals.  相似文献   

The loss of K,REE, Th,and U from a Martian and a terrestrial basalt by acidic leaching     

Gerlind DREIBUS  Reinhard HAUBOLD  Wolfgang HUISL  Bernhard SPETTEL 《Meteoritics & planetary science》2008,43(11):1895-1908

Abstract— The mobilization of K, rare earth elements (REE), Th, and U from Martian surface material upon contact with acidic solutions probably occurred extensively on Mars about 4 to 3.5 Ga ago and seems to have occurred locally in more recent times. We have studied the dissolution of these elements by leaching the basaltic shergottite Zagami and the terrestrial basalt BE‐N at constant pH values ranging from 5 to 1 in the absence and presence of added salts. Potassium is nearly immobile in Zagami and mobilized readily from BE‐N. The REE reside mostly in calcium phosphates and dissolve readily, with those in whitlockite of Zagami reacting slightly better than those in apatite of BE‐N. Thorium and U also reside mostly in calcium phosphates. Both dissolve similarly for both basalts and less readily than the REE. The experiments indicate the extent of the mobilization of K, REE, Th, and U, when acidic water leached the surface of Mars. Potassium was released slowly and in a small relative amount. The REE, and particularly the LREE, became mobile readily and were possibly distributed over large areas before immobilization. Thorium and U dissolved more slowly than the REE and were distributed less widely.  相似文献   

Variability of Sea Surface Heights in the Baltic Sea: An Intercomparison of Observations and Model Simulations     

Kristin Novotny  Gunter Liebsch  Andreas Lehmann  Reinhard Dietrich 《Marine Geodesy》2013,36(2):113-134

Sea level changes in the Baltic Sea are dominated by internal, short-term variations that are mostly caused by the ephemeral nature of atmospheric conditions over the Baltic area. Tides are small and their influence decreases from western parts of the Baltic Sea to the Baltic Proper. Superimposed to the large short-term sea level changes (up to few decimeters from day to day) are seasonal and interannual variations (centimeters to decimeters). This study focuses on the comparison of sea surface heights obtained from observations and from a high resolution oceanographic model of the Baltic Sea. From this comparison, the accuracy of the modeled sea surface variations is evaluated, which is a necessary precondition for the further use of the oceanographic model in geodetic applications. The model reproduces all observed Baltic sea level variations very reliably with an accuracy of 5 to 9 cm (rms) for short-term variations (up to 2 months) and 8 cm (rms) for long-term variations (>2 months). An additional improvement of the model can be attained by including long-period sea level variations of the North Sea. The model performs well also in the case of extreme sea level events, as is shown for a major storm surge that occurred at the southern coast of the Baltic Sea in November 1995.  相似文献   

Pan-African strike–slip tectonics in eastern Cameroon—Magnetic fabrics (AMS) and structure in the Lom basin and its gneissic basement     

Boniface Kankeu  Reinhard O. Greiling  Jean Paul Nzenti 《Precambrian Research》2009,174(3-4):258-272

Field, microstructural, and anisotropy of magnetic susceptibility (AMS) or magnetic fabric studies were applied to identify the sequence and character of the Pan-African structures in the basement of Eastern Cameroon at both sides of the regional scale Bétaré-Oya Shear Zone (BOSZ). The NE-SW trending BOSZ separates older gneisses and migmatites towards SE (domain I) from the younger rocks of the Lom meta-volcano-sedimentary basin towards NW (domain II). In domain I, early, ductile compressional deformation occurred in two events, D1 and D2, under relatively high T conditions. During subsequent cooling, strain partitioned between the competent basement gneisses with only mild compression and the bordering shear zone (BOSZ) with intense simple shear-wrenching (D3). Strain in the less competent rocks of domain II is dominated by simple shear, strike-slip wrenching (D3), with an earlier stage of compressional deformation preserved only in some low strain pods.Magnetic fabrics (AMS) document a progressive change from oblate ellipsoids towards prolate ellipsoids in domain I, when proceeding from the south towards the BOSZ. Foliations are mostly steep but define a girdle with a pole plunging gently towards WSW. The magnetic lineations also plunge mostly towards WSW at shallow angles. These fabrics indicate a compression approximately normal to the BOSZ, which is also the SE margin of the Lom Basin. In the Lom metasediments (domain II), AMS ellipsoids are typically oblate. Foliations trend NE-SW with mostly steep dips. Magnetic lineations plunge gently NE or SW. This fabric with foliations mostly steep and subparallel with the major BOSZ, combined with generally subhorizontal lineations implies the BOSZ as a Pan-African strike–slip shear zone with a subordinate component of compression.At a larger scale, the area is part of a continent-scale shear zone, separating external Pan-African domains of compression along the northern margin of the Congo craton from internal domains dominated by high-angle strike–slip and transpressional deformation. Together with published data, the present study thus demonstrates that transpression is a regional phenomenon in the Pan-African orogen of central and eastern Cameroon.  相似文献   

Gain and loss of uranium by meteorites and rocks,and implications for the redistribution of uranium on Mars     

Gerlind DREIBUS  Reinhard HAUBOLD  Wolfgang HUISL  Bernhard SPETTEL 《Meteoritics & planetary science》2007,42(6):951-962

Abstract Terrestrial alteration of meteorites results in the redistribution, gain, or loss of uranium and other elements. We have measured the maximum U adsorption capacity of a meteorite and two geochemical reference materials under conditions resembling terrestrial ones (pH 5.8). The basaltic eucrite Sioux County adsorbs 7 ppm of U. The result for the terrestrial granite AC‐E is similar (5 ppm), while the basalt BE‐N adsorbs 34 ppm of U. We have also investigated U adsorption in the presence of phosphate (0.01 M or less) in imitation of conditions that probably occurred in the earlier history of Mars. Such a process would have alterated Martian surface material and would be noticeable in Martian meteorites from the affected surface. The experiments demonstrated the counteracting effects of phosphate, which increases U adsorption, but decreases the quantity of dissolved U that is available for adsorption. U adsorption by AC‐E increases to 7 ppm. The lowered value for BE‐N of 8 ppm results from the low quantity of dissolved U in the volume of solution used. The results from the adsorption experiments and from leaching the Martian meteorite Zagami and a terrestrial basalt imply that the aqueous redistribution of U on Mars was moderate. Acidic liquids mobilized uranium and other metals, but present phosphate impeded the dissolution of U compounds. Some mobilized U may have reached the global sinks, while most of it probably was transported in the form of suspended particles over a limited distance and then settled.  相似文献   

Book reviews     

Dieter Richter  Axel Borsdorf  Olusegun Areola  Risto Laulajainen  L. Wahlstroem  Reinhard Stewig  Jonathan B. Laronne  Gösta A. Eriksson  Cesar N. Caviedes  John Gunn  Karl Mauder  G. Kunkel  John T. Pierce  Leszek A. Kosinski  G.orge H. Kakiuchi  Reiner Herrmann  W. M. Sackinger 《GeoJournal》1982,6(6):581-588

  相似文献   

Cross-shore distribution of longshore sediment transport rates on a barred non-tidal beach     

Reinhard?LampeEmail author  Karl?F.?Nordstrom  Nancy?L.?Jackson 《Estuaries and Coasts》2003,26(6):1426-1436

This study was conducted to relate the cross-shore distribution of longshore sediment transport and grain size characteristics to cross-shore and longshore current velocities on a sandy low-energy beach in a non-tidal embayment of the Baltic Sea. Simultaneous measurements of current velocities and amount of sand caught in streamer traps were made on 31 sampling runs on 6 d in April 1999 at three fixed sites including the swash zone on the upper foreshore, the lower foreshore, and the crest of the most landward of four bars. Spilling waves broke frequently on the bar but rarely on the lower foreshore, even during onshore wind speeds up to 11.0 m s⁻¹. Waves always broke as plunging waves at the step at the base of the upper foreshore and were converted directly into swash. The greatest longshore current velocities in the swash occurred when wind speeds and water levels were greatest, but wind direction was nearly directly onshore. Longshore velocities were greater in the swash zone than at other sites except when relatively strong winds blew nearly parallel to the shoreline, causing a pronounced wind-induced current at the other two sites. Calculated longshore shear stress and rate of sediment trapped were highly correlated on the bar (r=0.90), less highly correlated in the swash zone, and least highly correlated (r=0.66) on the lower foreshore. Mean trapping rates in the swash were 14.6 times greater than on the lower foreshore and 7.2 times greater than on the bar. Greater trapping rates in the swash are attributed to the greater turbulence mobilizing sediments in the uprush and backwash. Little of the finer-grained sediment on the offshore sites was reworked under low energy conditions. The study reveals the dominance of swash transport on steep, reflective, low-energy beaches where wave energy dissipation takes place over small distances on the upper foreshore.  相似文献   

Electric-hydraulic conductivity correlation in fractured crystalline bedrock: Central Landfill, Rhode Island, USA     

Reinhard K. Frohlich  John J. Fisher  E. Summerly 《Journal of Applied Geophysics》1996,35(4):249-259

Remote sensing and geoelectrical methods were used to find water-bearing fractures in the Scituate granite under the Central Landfill of Rhode Island. These studies were necessary to evaluate the integrity of the sanitary landfill and for planning safe landfill extensions. The most useful results were obtained with fracture trace analysis using Landsat and SLAR imagery in combination with ground-based resistivity measurements using Schlumberger vertical electrical soundings based on the assumption of horizontally layered strata. Test borings and packer tests confirmed, in the presence of a lineament and low bedrock resistivity, the probable existence of high bedrock fracture density and high average hydraulic conductivity. However, not every lineament was found to be associated with high fracture density and high hydraulic conductivity. Lineaments alone are not a reliable basis for characterising a landfill site as being affected by fractured bedrock. Horizontal fractures were found in borings located away from lineaments. High values of hydraulic conductivity were correlated with low bedrock resistivities. Bedrock resistivities between 60 and 700 Ω m were associated with average hydraulic conductivities between 4 and 60 cm/day. In some cases very low resistivities were confined to the upper part of the bedrock where the hydraulic conductivity was very large. These types of fractures apparently become narrower in aperture with depth. Bedrock zones having resistivities greater than 1000 Ω m showed, without exception, no flow to the test wells. Plots of bedrock resistivity versus the average hydraulic conductivity indicate that the resistivity decreases with increasing hydraulic conductivity. This relationship is inverse to that found in most unconsolidated sediments and is useful for estimating the hydraulic conductivity in groundwater surveys in fractured bedrock. In appropriate settings such as the Central Landfill site in New England, this electric-hydraulic correlation relationship, supplemented by lineament trace analysis, can be used effectively to estimate the hydraulic conductivity in bedrock from only a limited number of resistivity depth soundings and test wells.  相似文献   

Techniques for asynchronous and periodically synchronous coupling of atmosphere and ocean models     

Robert Sausen  Reinhard Voss 《Climate Dynamics》1996,12(5):313-323

Asynchronous and periodically-synchronous schemes for coupling atmosphere and ocean models are presented. The performance of the schemes is tested by simulating the climatic response to a step function forcing and to a gradually increasing forcing with a simple zero-dimensional non-linear energy balance model. Both the initial transient response and the asymptotic approach of the equilibrium state are studied. If no annual cycle is allowed the asynchronous coupling technique proves to be a suitable tool. However, if the annual cycle is retained, the periodically synchronous coupling technique reproduces the results of the synchronously coupled runs with smaller bias. In this case it is important that the total length of one synchronous period and one ocean only period is not a multiple of 6 months.  相似文献   

Microbial microstratification, inorganic carbon photoassimilation and dark carbon fixation at the chemocline of the meromictic Lake Cadagno (Switzerland) and its relevance to the food web   总被引：3，自引：0，他引：3  

Antonio Camacho  Jonathan Erez  Alvaro Chicote  Máximo Florín  Margaret M. Squires  Christine Lehmann  Reinhard Backofen 《Aquatic Sciences - Research Across Boundaries》2001,63(1):91-106

  相似文献