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71.
A random, hydrogen-free, assembly of microscopic sp2 carbon chips, forming a macroscopically homogeneous and isotropic solid, is proposed as a model carrier for the ultraviolet (UV) interstellar extinction band. The validity of this model is based on the calculation of the Bruggeman average dielectric function of a mixture of the known parallel and perpendicular dielectric functions of graphite. The π absorption feature of Rayleigh-sized spheres of this mixture falls near  4.6 μm−1  (2175 Å), but its width is  1.5 μm−1  , somewhat larger than the astronomically observed average,  1 μm−1  . This is confirmed by measurements of the reflectance of an industrial material, polycrystalline graphite. A better fit to the interstellar feature position and width is obtained with a hypothetical material, having the same dielectric functions as natural graphite, except for less extended wings of the π resonance. Physically, this could result from changes in the electronic band structure due to previous thermal histories. In this model, the Frölich feature central wavelength depends only on the π resonance frequency, while its width depends only on the damping constant of the same resonance. This explains the range of observed feature widths at constant feature wavelength.  相似文献   
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73.
A relative water-depth model for the Chalk of the Paris Basin is proposed, based on the lateral variations of the high-frequency metre-scale cycles, which are characteristic features easily identified in the field. The studied outcrops are the Cenomanian–Middle Coniacian cliffs of Normandy. The main result of this study is to highlight the importance of storm activity in the deposition of the Chalk. The relative water-depth model is based on storm-induced shell concentrations observed within the two components of the metre-thick cycles: the depositional interval itself and the top hiatal surface.Six types of shell concentrations are defined, along with seven types of depositional facies making up the depositional units, as well as eight types of hiatal surface. Three cycle associations, differing in their thickness and the amount and type of non-carbonate constituents, can be identified in the Lower to Upper Cenomanian, the Upper Cenomanian to Lower Turonian and the Middle Turonian to Middle Coniacian.A relative water-depth profile model for all these cycles is based on the shell concentrations and a “water-depth equivalence” is proposed between the three cycle associations (lateral “facies” substitution diagram). This model is tested using palaeocological data (irregular echinoids) and by correlating field sections in terms of stacking patterns. Most of the studied deposits accumulated above the storm wave base (upper offshore zone or mid ramp).  相似文献   
74.
Open-cast mining for Ni, Cr and Co was conducted in the south-west part of New Caledonia during the 20th century. Abandoned mining and prospecting sites were severely affected by erosion, resulting in an increase in the load of terrigenous particles transported to the coral reef lagoon. This article assesses the impact of a typical small catchment area (La Coulée River, 85 km2 watershed) on two bays (Boulari and Sainte Marie) located near Noumea, New Caledonia's main city. This multi-disciplinary study combines geochemical, sedimentological, and hydrodynamic approaches. Ni and Cr concentrations contained in the geochemical matrix phase of the pelitic fraction were determined. The study of the geochemical signatures together with sedimentological data and 3D numerical simulations of the transport of non-settling particles throughout the lagoon demonstrated that terrigenous inputs from the Coulée River were mainly transported and deposited along the shoreline, reaching areas as distant as Sainte Marie Bay. Although quantitatively low (about 3% of the pelite mass of the bay sediments), the terrigenous inputs in Sainte Marie Bay originating from the Coulée River could be traced. The metal content in suspended matter was over 7000 mg kg(-1) for Ni and 4200 mg kg(-1) for Cr.  相似文献   
75.
Quantifying photosynthetic activity at the regional scale can provide important information to resource managers, planners and global ecosystem modelling efforts. With increasing availability of both hyperspectral and narrow band multispectral remote sensing data, new users are faced with a plethora of options when choosing an optical index to relate to their chosen or canopy parameter. The literature base regarding optical indices (particularly chlorophyll indices) is wide ranging and extensive, however it is without much consensus regarding robust indices. The wider spectral community could benefit from studies that apply a variety of published indices to differing sets of species data. The consistency and robustness of 73 published chlorophyll spectral indices have been assessed, using leaf level hyperspectral data collected from three crop species and a variety of savanna tree species. Linear regression between total leaf chlorophyll content and bootstrapping were used to determine the leafpredictive capabilities of the various indices. The indices were then ranked based on the prediction error (the average root mean square error (RMSE)) derived from the bootstrapping process involving 1000 iterative resampling with replacement. The results show two red-edge derivative based indices (red-edge position via linear extrapolation index and the modified red-edge inflection point index) as the most consistent and robust, and that the majority of the top performing indices (in spite of species variability) were simple ratio or normalised difference indices that are based on off-chlorophyll absorption centre wavebands (690–730 nm).  相似文献   
76.
The major function of underground nuclear waste disposal is to avoid the migration of radionucleides towards the biosphere during their active period. This function can be deteriorated by the EDZ (excavated damaged zone) around the excavation. The EDZ analysis is therefore crucial in the performance assessment of the storage. The paper deals with the determination of the EDZ around a nuclear waste storage cavity using borehole ultrasonic imaging (azimuthal tomography). Indeed, before processing experimental data obtained with this tool, it is necessary to establish that data can be satisfactorily inverted. This analysis is based on a method that is able to sound and image the rock mass velocity field. The velocity field is numerically simulated (3D geomechanical modeling) based on an assumption on the relationship between stress and velocity fields. In order to evaluate a radial velocity profile starting from inter-sensor distance and their corresponding traveltimes, different ray tracing algorithms are tested using synthetic data. These tests led to a simple and fast approach (implemented in a Mathematica package) to process a large quantity of data.  相似文献   
77.
Authigenic minerals can form in the water column and sediments of lakes, either abiotically or mediated by biological activity. Such minerals have been used as paleosalinity and paleoproductivity indicators and reflect trophic state and early diagenetic conditions. They are also considered potential indicators of past and perhaps ongoing microbial activity within sediments. Authigenic concretions, including vivianite, were described in late glacial sediments of Laguna Potrok Aike, a maar lake in southernmost Argentina. Occurrence of iron phosphate implies specific phosphorus sorption behavior and a reducing environment, with methane present. Because organic matter content in these sediments was generally low during glacial times, there must have been alternative sources of phosphorus and biogenic methane. Identifying these sources can help define past trophic state of the lake and diagenetic processes in the sediments. We used scanning electron microscopy, phosphorus speciation in bulk sediment, pore water analyses, in situ ATP measurements, microbial cell counts, and measurements of methane content and its carbon isotope composition (δ13CCH4) to identify components of and processes in the sediment. The multiple approaches indicated that volcanic materials in the catchment are important suppliers of iron, sulfur and phosphorus. These elements influence primary productivity and play a role in microbial metabolism during early diagenesis. Authigenic processes led to the formation of pyrite framboids and revealed sulfate reduction. Anaerobic oxidation of methane and shifts in pore water ion concentration indicated microbial influence with depth. This study documents the presence of active microbes within the sediments and their relationship to changing environmental conditions. It also illustrates the substantial role played by microbes in the formation of Laguna Potrok Aike concretions. Thus, authigenic minerals can be used as biosignatures in these late Pleistocene maar sediments.  相似文献   
78.
Water availability and management issues related to the supply of drinking water in northern communities are problematic in Canada. While rivers and lakes are abundant, they are vulnerable to contamination and may become dry in winter due to freezing. Groundwater can often provide a more secure and sustainable water source, however its availability is limited in northern Canada due to the presence of permafrost. Moreover, the exploitation of northern aquifers poses a dual challenge of identifying not only permafrost-free areas, but also permeable areas which will allow groundwater recharge and exploitation. Suitable aquifers are not as common in northern Canada since the shallow subsurface is mostly composed of low-permeability crystalline rocks or unconsolidated sediments of glacial origin that are highly heterogeneous. In order to investigate groundwater occurrence and associated geological contexts in Nunavik (northern Quebec, Canada), along with exploring how these resources will evolve in response to climate change, field and compilation work were conducted in the surroundings of the four villages of Salluit, Kuujjuaq, Umiujaq and Whapmagoostui-Kuujjuarapik. These villages are located in different permafrost zones, ranging from continuous to discontinuous, as well as in different geological environments. It was found that despite the ubiquitous presence of permafrost, unfrozen aquifers could be identified, which suggests that groundwater may be available as a source of drinking water for small communities. Expected climate change, with predicted permafrost thawing and increases in temperature and precipitation, should enhance groundwater availability and may contribute to a more secure source of drinking water for northern communities.  相似文献   
79.
80.
We investigated the oxygen isotope composition (δ18O) of shell striae from juvenile Comptopallium radula (Mollusca; Pectinidae) specimens collected live in New Caledonia. Bottom-water temperature and salinity were monitored in-situ throughout the study period. External shell striae form with a 2-day periodicity in this scallop, making it possible to estimate the date of precipitation for each calcite sample collected along a growth transect. The oxygen isotope composition of shell calcite (δ18Oshell calcite) measured at almost weekly resolution on calcite accreted between August 2002 and July 2003 accurately tracks bottom-water temperatures. A new empirical paleotemperature equation for this scallop species relates temperature and δ18Oshell calcite:
t(°C)=20.00(±0.61)-3.66(±0.39)×(δ18Oshell calcite VPDB18Owater VSMOW)  相似文献   
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