Surfactant Enhance DLLME/FO‐LADS: Assay of Malachite Green Level in Aquatic Environment of Trout Fish     

Araz Bidari  Mohammad Reza Ganjali  Parviz Norouzi 《洁净——土壤、空气、水》2011,39(1):83-87

Malachite green (MG), a traditional agent used in aquaculture although is not approved; its low cost and high efficacy make illicit use likely. We developed a small‐scale, simple, and sensitive dispersive liquid–liquid microextraction procedure for the assay of trace amounts of MG in aquatic environment of Trout fish. Fiber optic‐linear array detection spectrophotometry with charge‐coupled device detector benefiting from a microcell was used for this purpose. The method is based on enhancement effect of an anionic surfactant on the extraction of MG in to very fine multidroplets of microextraction solvent which made assisted by disperser solvent. Under the optimum conditions, the enrichment factor 77.5 was obtained from a 5‐mL water sample. The calibration graph was linear up to 5 × 10^?7 mol L^?1 with detection limit of 1 × 10^?8 mol L^?1. The relative standard deviation for seven replicate measurements of 4 × 10^?7 and 5 × 10^?8 mol L^?1 of MG were 3.3 and 4.5%, respectively.  相似文献   

Probabilistic rainfall thresholds for flood forecasting: evaluating different methodologies for modelling rainfall spatial correlation (or dependence)   总被引：2，自引：0，他引：2  

Saeed Golian  Bahram Saghafian  Mohammad Elmi  Reza Maknoon 《水文研究》2011,25(13):2046-2055

Rainfall threshold (RT) method is one of the evolving flood forecasting approaches. When the cumulative rainfall depth for a given initial soil moisture condition intersects the threshold rainfall curve, the peak discharge is expected to be equal or greater than the threshold discharge for flooding at the target site. Besides the total rainfall depth, spatial and temporal distribution of rainfall impacts the flood peak discharge and the time to peak. To revisit a previous study conducted by the authors, in which spatially independent rainfall pattern was assumed, the spatial distribution of rainfall was simulated following a Monte Carlo approach. The structure of the spatial dependence among sub‐watersheds' rainfalls was taken into account under three different scenarios, namely independent, bivariate copula (2copula) and multivariate Gaussian copula (MGC). For each set of generated random dimensionless rainfalls, the probabilistic RT curves were derived for dry moisture condition. Results were evaluated with both historical and simulated events. For the simulated events, threshold curves were assessed by means of categorical statistics, such as hit rate, false rate and critical success index (CSI). Results revealed that the best performance based on the CSI criterion corresponded to 50% curve in 2copula and MGC scenarios as well as 90% curve in the independent scenario. The recognition of 50% curve in 2copula and MGC scenarios is in agreement with our expectations that the mean probable curve should have the best performance. Moreover, the proposed inclusion of spatially dependent rainfall scenario improved the performance of RT curves by about 25% in comparison with the presumed spatially uniform rainfall scenario. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Crustal structure of Northwest Zagros (Kermanshah) and Central Iran (Yazd and Isfahan) using teleseismic Ps converted phases     

Narges Afsari  Forogh Sodoudi  Fataneh Taghizadeh Farahmand  Mohammad Reza Ghassemi 《Journal of Seismology》2011,15(2):341-353

Receiver functions are widely employed to detect P-to-S converted waves and are especially useful to image seismic discontinuities in the crust. In this study we used the P receiver function technique to investigate the velocity structure of the crust beneath the Northwest Zagros and Central Iran and map out the lateral variation of the Moho boundary within this area. Our dataset includes teleseismic data (M _b ≥ 5.5, epicentral distance from 30° to 95°) recorded at 12 three-component short-period stations of Kermanshah, Isfahan and Yazd telemetry seismic networks. Our results obtained from P receiver functions indicate clear Ps conversions at the Moho boundary. The Moho depths were firstly estimated from the delay time of the Moho converted phase relative to the direct P wave beneath each network. Then, we used the P receiver function inversion to find the properties of the Moho discontinuity such as depth and velocity contrast. Our results obtained from PRF are in good agreement with those obtained from the P receiver function modeling. We found an average Moho depth of about 42 km beneath the Northwest Zagros increasing toward the Sanandaj-Sirjan Metamorphic Zone and reaches 51 km, where two crusts (Zagros and Central Iran) are assumed to be superposed. The Moho depth decreases toward the Urmieh-Dokhtar Cenozoic volcanic belt and reaches 43 km beneath this area. We found a relatively flat Moho beneath the Central Iran where, the average crustal thickness is about 42 km. Our P receiver function modeling revealed a shear wave velocity of 3.6 km/s in the crust of Northwest Zagros and Central Iran increasing to 4.5 km/s beneath the Moho boundary. The average shear wave velocity in the crust of UDMA as SSZ is 3.6 km/s, which reaches to 4.0 km/s while in SSZ increases to 4.3 km/s beneath the Moho.  相似文献   

Towards quantitative evaluation of gas injection using time‐lapse seismic data     

Reza Falahat  Asghar Shams  Colin MacBeth 《Geophysical Prospecting》2011,59(2):310-322

Of particular concern in the monitoring of gas injection for the purposes of storage, disposal or improved oil recovery is the exact spatial distribution of the gas volumes in the subsurface. In principle this requirement is addressed by the use of 4D seismic data, although it is recognized that the seismic response still largely provides a qualitative estimate of moved subsurface fluids. Exact quantitative evaluation of fluid distributions and associated saturations remains a challenge to be solved. Here, an attempt has been made to produce mapped quantitative estimates of the gas volume injected into a clastic reservoir. Despite good results using three accurately repeated seismic surveys, time‐delay and amplitude attributes reveal fine‐scale differences though large‐scale agreement in the estimated fluid movement. These differences indicate disparities in the nature of the two attributes themselves, which can be explained by several possible causes. Of most impact are the effects of processing and migration, wave interference effects and noise from non‐repeatability of the seismic surveys. This subject highlights the need for a more careful consideration in 4D acquisition, amplitude processing and use of true amplitude preserving attributes in quantitative interpretation.  相似文献   

Coherence among climate signals, precipitation, and groundwater     

Ghanbari RN  Bravo HR 《Ground water》2011,49(4):476-490

Climate signals may affect groundwater level at different time scales in different geographical regions, and those patterns or time scales can be estimated using coherence analysis. This study shows that the synthesis effort required to search for patterns at the physical geography scale is possible, and this approach should be applicable in other regions of the world. The relations between climate signals, Southern Oscillation Index, Pacific Decadal Oscillation, North Atlantic Oscillation, North Pacific Pattern (SOI, PDO, NAO, and NP), precipitation, and groundwater level in three geographical areas of Wisconsin are examined using a three-tiered coherence analysis. In the high frequency band (<4(-1) cycles/year), there is a significant coherence between four climate signals and groundwater level in all three areas. In the low frequency band (>8(-1) to ≤23(-1) cycles/year), we found significant coherence between the SOI and NP signals and groundwater level in the forested area, characterized by shallow wells constructed in sand and gravel aquifers. In the high frequency band, there is significant coherence between the four climate signals and precipitation in all three areas. In the low frequency band, the four climate signals have effect on precipitation in the agricultural area, and SOI and NP have effect on precipitation in the forested and driftless areas. Precipitation affects groundwater level in all three areas, and in high, low and intermediate frequency bands. In the agricultural area, deeper aquifers and a more complex hydrostratigraphy and land use dilute the effect of precipitation on groundwater level for interdecadal frequencies.  相似文献   

Supported Axisymmetric Tunnels Within Linear Viscoelastic Burgers Rocks   总被引：4，自引：2，他引：2  

Pavlos Nomikos  Reza Rahmannejad  Alexandros Sofianos 《Rock Mechanics and Rock Engineering》2011,44(5):553-564

An exact closed form solution is derived for the mechanical behaviour of a linear viscoelastic Burgers rock around an axisymmetric tunnel, supported by a linear elastic ring. Analytical formulae are provided for the displacement of the rock/lining interface and for the pressure exerted by the rock on the lining, taking into account the stiffness and its installation time. Results calculated from these formulae do validate the corresponding numerical results of a 2D finite differences code. Further, comparison to previous existing solutions for the same viscoelastic model indicates similarities and differences. A parametric study is performed to investigate the effect of the viscoelastic constants, the stiffness and installation time of the support. The derived closed form solution is used to construct the time-dependent Supported Ground Reaction Curves of the viscoelastic rock, i.e. the time contour plots on the convergence confinement diagram. The importance of the effect of the support on the restrained rock creep and the exerted pressure on the lining, during the design life of a structure, is examined.  相似文献   

Hydrochemistry, mineralogy and chemical fractionation of mine and processing wastes associated with porphyry copper mines: A case study from the Sarcheshmeh mine, SE Iran     

Mehdi Khorasanipour  Majid H. Tangestani  Reza Naseh  Hamid Hajmohammadi 《Applied Geochemistry》2011,26(5):714-730

The Sarcheshmeh is one of the largest Oligo-Miocene porphyry Cu deposits in the world. Comparative hydrochemical, mineralogical and chemical fractionation associated with mining efflorescence salts and processing wastes of this mine are discussed. Hydrochemical results showed that rock waste dumps, reject wastes and old impoundments of tailings are the main sources of acid mine drainage waters (AMD) that contain potentially toxic metals such as Cd, Co, Cu, Mn, Ni and Zn as well as Al. Episodic fluxes of highly contaminated acidic waters were produced in a tailings dam over a short period of time. Secondary soluble minerals provide important controls on the quality of AMD produced, especially in old, dry tailings impoundments. Secondary sulfate minerals such as gypsum, magnesiocopiapite, hydronium jarosite, kornelite and coquimbite were found in rock waste drainages and in old weathered reject wastes. Highly soluble secondary minerals such as gypsum, eriochalcite, and bonattite are also observed in an evaporative layer on old tailings impoundments. Chemical fractionation patterns of potentially toxic elements showed that the geochemical behavior of metals is primarily controlled by the mineralogical composition of waste samples. Elements such as Co, Cr, Cu, Mn, Ni and Zn are readily released into the water soluble fraction from efflorescence salts associated with rock waste drainages, as well as from the evaporative layer of old tailings. Potentially toxic elements, such as As, Mo and Pb, are principally adsorbed or co-precipitated with amorphous and crystalline Fe oxides, but they may also be associated with oxidizing, primary sulfides and residual fractions. Following the development of the dammed tailings pond, the secondary minerals were dissolved, producing acidic waters contaminated by Al (154 mg L⁻¹), Cu (150 mg L⁻¹), Cd (0.31 m gL⁻¹), Co (2.13 mg L⁻¹), Mn (73.7 mg L⁻¹), Ni (1.74 mg L⁻¹), Zn (20.3 mg L⁻¹) and Cl (1690 mg L⁻¹). Therefore, the potential use of recycled water from the Sarcheshmenh dammed tailings pond is diminished by the presence of corrosive ions like Cl⁻ in highly acidic fluids that promote corrosion of pipes and pumps in the water recycling system.  相似文献   

Evaluation of correlations between precipitation, groundwater fluctuations, and lake level fluctuations using spectral methods (Wisconsin, USA)   总被引：2，自引：1，他引：1  

Reza Namdar Ghanbari  Hector R Bravo 《Hydrogeology Journal》2011,19(4):801-810

Spectral methods and 2 years of daily data were used to estimate the phase lag between precipitation and groundwater-level response, and two decades of quarterly data were used to analyze the interaction between precipitation, lake levels and groundwater in the Trout Lake watershed located in Vilas County, Wisconsin, USA. The phase-lag function between precipitation and groundwater response is used to estimate recharge travel time. The recharge travel time and precipitation–groundwater–lake interactions have been traditionally studied using time-domain methods such as physically-based modeling. In this article, the innovative and efficient use of spectral methods is demonstrated to uncover the time scales that are significant in those interactions and estimate the recharge travel time, which is extracted from the underlying daily time series data. The results consistently show that precipitation leads groundwater-level response by up to 5 days in all cases. The effects of precipitation on lake and groundwater levels display strong similarities. Both the precipitation–lake level and the precipitation–groundwater level coherency functions show significant peaks at interannual and seasonal frequencies. The groundwater level–lake level coherency function shows a significant, broad peak at interannual frequencies, and no significant peak at seasonal frequencies, demonstrating the predominance of annual and lower frequencies in groundwater–lake interaction.  相似文献   

Study on infiltration rate based on primary particle size distribution data in arid and semiarid region soils     

Mahmoud Reza Mazaheri  Majid Mahmoodabadi 《Arabian Journal of Geosciences》2011,5(5):1039-1046

Soil particle size distribution (PSD) is used to estimate some soil processes, soil moisture characteristics, and infiltration rate (IR). Prediction of infiltration rate from soil texture data requires an accurate characterization of PSD. The objective of this study was to determine more important primary particle diameters that control IR. The experiments were conducted using double-ring method with constant head of 5 cm in 15 different soils and three replications. The range of measured IR for studied soils varied from 1.6 to 30.66 cm h^?1. The results indicated that the primary PSD had a significant influence on IR. In other words, most D _n fractions had significant positive effect on the final IR. Among different fractions, D ₃₀, D ₄₀, and D ₆₀ showed higher relationships with IR than the others. These diameters are attributed to particles with diameter of 0.05, 0.08, and 0.16 mm, respectively. The results also showed that increasing the percent of sand have intensified influence on increasing the final IR. Reversely, clay and silt contents showed negative effects on final IR. Furthermore, the CaCO₃ had a meaningful effect on the IR that showed the importance of lime in arid and semiarid regions. Finally, it is revealed that the role of texture was important, especially in behavior of infiltration, runoff, and production capability.  相似文献   

Composition, porosity, and reservoir potential of the Middle Jurassic Kashafrud Formation, northeast Iran   总被引：1，自引：0，他引：1  

Mehdi Reza Poursoltani  Martin R. Gibling 《Marine and Petroleum Geology》2011,28(5):1094-1110

In the Kopet-Dagh Basin of Iran, deep-sea sandstones and shales of the Middle Jurassic Kashafrud Formation are disconformably overlain by hydrocarbon-bearing carbonates of Upper Jurassic and Cretaceous age. To explore the reservoir potential of the sandstones, we studied their burial history using more than 500 thin sections, supplemented by heavy mineral analysis, microprobe analysis, porosity and permeability determination, and vitrinite reflectance.The sandstones are arkosic and lithic arenites, rich in sedimentary and volcanic rock fragments. Quartz overgrowths and pore-filling carbonate cements (calcite, dolomite, siderite and ankerite) occluded most of the porosity during early to deep burial, assisted by early compaction that improved packing and fractured quartz grains. Iron oxides are prominent as alteration products of framework grains, probably reflecting source-area weathering prior to deposition, and locally as pore fills. Minor cements include pore-filling clays, pyrite, authigenic albite and K-feldspar, and barite. Existing porosity is secondary, resulting largely from dissolution of feldspars, micas, and rock fragments, with some fracture porosity. Porosity and permeability of six samples averages 3.2% and 0.0023 mD, respectively, and 150 thin-section point counts averaged 2.7% porosity. Reflectance of vitrinite in eight sandstone samples yielded values of 0.64-0.83%, in the early mature to mature stage of hydrocarbon generation, within the oil window.Kashafrud Formation petrographic trends were compared with trends from first-cycle basins elsewhere in the world. Inferred burial conditions accord with the maturation data, suggesting only a moderate thermal regime during burial. Some fractures, iron oxide cements, and dissolution may reflect Cenozoic tectonism and uplift that created the Kopet-Dagh Mountains. The low porosity and permeability levels of Kashafrud Formation sandstones suggest only a modest reservoir potential. For such tight sandstones, fractures may enhance the reservoir potential.  相似文献