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471.
Different hypotheses have been proposed to account for the geologic evolution of the southwestern margin of Gondwana in the Early Paleozoic, involving accretion and displacement of different terranes in a protracted convergent margin. In order to constrain and understand the kinematic and paleogeographic evolution of the Pampia terrane a paleomagnetic study was carried out in different Cambrian to Devonian units of the Eastern Cordillera (Cordillera Oriental) and the Interandean Zone (Interandino) of NW Argentina. Paleomagnetic poles from the Campanario Formation (Middle to Upper Cambrian): 1.5°N 1.9°E A95 = 9.2° K = 37.46 N = 8; and Santa Rosita Formation (Lower Ordovician): 8.6°N 355.3°E A95 = 10.1° K = 26.78 n = 9, representative of the Pampia terrane, are interpreted to indicate a Late Cambrian significant displacement with respect to the Río de la Plata and other Gondwana cratons. A model, compatible with several geological evidences that explains this displacement in the framework of the final stages of Gondwana assembly is presented. We propose a simple dextral strike-slip kinematic model in which Pampia and Antofalla (? Arequipa?) blocks moved during Late Cambrian times from a position at the present southern border of the Kalahari craton into its final position next to the Rio de la Plata craton by the Early Ordovician.  相似文献   
472.
A sediment core from Guanabara Bay (Brazil) was analyzed for 210Pb dating, grain size, total organic carbon (TOC) and total nitrogen, carbon stable isotope ratio (δ13C), nitrogen stable isotope ratio (δ15N) and the metals Fe, Mn, Ni, Co, Cu, Pb, V and Zn, to assess the influence of land use changes on the aquatic system in a region for which large industrial and urban development is expected in the next few decades. To obtain baseline data for improving the monitoring of the expected increase in anthropogenic impacts from surrounding drainage basins, a multivariate analysis of data from different sediment layers was carried out to evaluate the dated sediment record. The geochemical data suggested three different sedimentary phases along the last 200 years. Before the 1880s, the highest clay and TOC contents were observed, where the C/N ratios and the δ13C values suggested a mixture of algal and terrestrial organic matter and the lowest concentrations of Co, Cu, Pb, V and Zn, for which background levels were estimated (4.6, 2.7, 14.9, 24.3 and 70.2 mg kg−1, respectively). From the 1880s to the 1950s, the metal concentrations and sand particles increased, but no change in organic matter quality was observed, reflecting a period of land use change, still without significant sewage input. After the 1950s, the sedimentation rate increased from 0.42 to 0.77 cm year−1 and increasing urban sewage input was evidenced by lower C/N ratios, higher δ15N, decrease of Fe and Mn concentrations and increased fluxes of metals and TOC, which showed a good relationship with population growth data.  相似文献   
473.
The toxicity and potential bioavailability of heavy metals were studied in sewage sludge-amended ferralsols and chernosols, using bioassays with earthworms (Eisenia andrei). Acute toxicity tests and avoidance assays were performed according to standard protocols. Potentially bioavailable concentrations of heavy metals were estimated by quantifying their concentrations in tissues of survival earthworms. The results revealed that soil properties played an important role in the toxicity and bioavailability of heavy metals. In this respect, higher levels of toxicity were detected for the ferralsol. The abundance of 2:1 clay minerals, high fertility and more basic values of pH seem to be very important in the reduction of toxicity levels for earthworms. Organisms exposed to the chernosols were able to uptake higher amount of metals. In that case, higher contents of nutrients in chernosols may have influenced such bioavailability processes. Avoidance responses were the most sensible indicator of toxicity. In the near future, such data can subsidize the establishment of toxic reference concentrations able to reflect the characteristics of important tropical pedological occurrences, supporting the definition of sustainable indicators for using sewage sludge in the tropical agriculture.  相似文献   
474.
正The Laguna Mar Chiquita,located northeast of the province of Córdoba in Argentina,is the only non-Andean place where three flamingo species regularly coexist in the southern part of South America.Two of these species,  相似文献   
475.
We have investigated the thermodynamics of mixing between aragonite (orthorhombic CaCO3) and strontianite (SrCO3). In agreement with experiment, our simulations predict that there is a miscibility gap between the two solids at ambient conditions. All SrxCa1−xCO3 solids with compositions 0.12 < x < 0.87 are metastable with respect to separation into a Ca-rich and a Sr-rich phase. The concentration of Sr in coral aragonites (x ∼ 0.01) lies in the miscibility region of the phase diagram, and therefore formation of separated Sr-rich phases in coral aragonites is not thermodynamically favorable. The miscibility gap disappears at around 380 K. The enthalpy of mixing, which is positive and nearly symmetric with respect to x = 0.5, is the dominant contribution to the excess free energy, while the vibrational and configurational entropic contributions are small and of opposite sign. We provide a detailed comparison of our simulation results with available experimental data.  相似文献   
476.
Recent developments from 2008 to 2009 in ICP-MS engineering, methods and applications are reviewed here. Of particular emphasis are advances in: (a) maximising sensitivity and reducing elemental/isotopic fractionation during laser ablation processing; (b) developing new analytical techniques to measure major, minor and trace element abundances without depending on matrix-matched calibrating materials, pre-determined internal standard concentrations and/or multiple analytical methods; (c) applying in situ and solution-based ICP-MS techniques to the analysis of forensic materials for criminal and/or nuclear investigations; and (d) improving precision and limits of detection of laser ablation multi-collector ICP-MS measurements of (ultra) trace elemental and isotopic abundances.  相似文献   
477.
In the Río Grande Valley, NW Argentina, several porphyritic panidiomorphic, ocelli-bearing dykes and sills intrude the Neoproterozoic to lower Paleozoic basement of the Eastern Cordillera. New petrographical and geochemical data permit us to classify these rocks as ocellar-analcime monchiquites, a feldspar-free variety of alkaline lamprophyre composed of Ti-rich-diopside/augite, Ti-rich biotite/phlogopite, forsteritic olivine, titanian-pargasite and analcime, with abundant ocelli filled with analcime/carbonate. In terms of geochemical compositions they are characterized by LILE and LREE enrichment and lack of Nb-Ta and Eu anomalies. The 87Sr/86Sr and 143Nd/144Nd initial ratios range between 0.70377 to 0.70781 and 0.512506 and 0.512716 respectively, and TDM model ages vary between 0.25–0.64 Ga. A K-Ar age of 163?±?9 Ma suggests that these rocks are related to the pre-rifting stage of the Mesozoic-Cenozoic continental Salta Rift in NW Argentina. Partial melting of a heterogeneous enriched metasomatized lithospheric mantle, magma mixing and fractionation are envisaged to explain the petrographic, geochemical and isotope characteristics of these magmas.  相似文献   
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480.
Ocean Dynamics - Accurate simulations of significant wave height (Hs) are extremely important for the safety of navigation, port operations, and oil and gas exploration. Thus, accurate forecasts of...  相似文献   
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