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131.
Claudio Territo Philippe Vieillard Dominique Righi Sabine Petit Riccardo Scalenghe 《Journal of Geochemical Exploration》2006,88(1-3):345
The aim of this study is to characterize the pedogenic clay minerals by using simple approach: mixing mineralogical and geochemical findings.The fine clay fractions (< 0.1 μm) of a Vertic Cambisol profile were studied by means of X-ray diffraction (XRD), infrared spectroscopy (FTIR) and cation exchange capacity (CEC).Qualitative and quantitative mineralogical compositions of the clay mixture were determined.Moreover, chemical equilibria and thermodynamic stabilities of minerals (calcite, gypsum, kaolinite, smectites and illites) were studied using results of ionic activities obtained from total concentration of various aqueous species in water extracts from soil-saturated pastes.XRD analysis shows a good homogeneity in the mineralogical composition of the soil material, with depth of soil profiles. The identified clay minerals are mainly illite–smectite mixed layers (I/S) and kaolinite. The chemical analysis of saturated paste extracts with clay minerals shows a slight undersaturation of the illitic phase while smectites and also calcite and gypsum reach the thermodynamic equilibrium along the soil profile. 相似文献
132.
Roberto Sabadini Riccardo E. M. Riva Giorgio Dalla Via 《Geophysical Journal International》2007,171(1):231-243
Polar motion is modelled for the large 2004 Sumatra earthquake via dislocation theory for an incompressible elastic earth model, where inertia perturbations are due to earthquake-triggered topography of density–contrast interfaces, and for a compressible model, where inertia perturbation due to compression-dilatation of Earth's material is included; density and elastic parameters are based on a multilayered reference Earth. Both models are based on analytical Green's functions, propagated from the centre to the Earth's surface. Preliminary and updated seismological solutions are considered in elucidating the effects of improving earthquake parameters on polar motion. The large Sumatra thrust earthquake was particularly efficient in driving polar motion since it was responsible for large material displacements occurring orthogonally to the strike of the earthquake and to the Earth's surface, as imaged by GRACE gravity anomalies over the earthquake area. The effects of earthquake-induced topography are four times larger than the effects of Earth's compressibility, for l = 2 geopotential components. For varying compressional Earth properties and seismic solution, modelled polar motion ranges from 8.6 to 9.4 cm in amplitude and between 117° and 130° east longitude in direction. The close relationship between polar motion direction, earthquake longitude and thrust nature of the event, are established in terms of basic physical concepts. 相似文献
133.
Avanzinelli Riccardo; Elliott Tim; Tommasini Simone; Conticelli Sandro 《Journal of Petrology》2008,49(2):195-223
We present new U-series isotope, 87Sr/ 86Sr, 143Nd/ 144Nd andtrace element data for a set of mafic, K-rich rocks from volcanoesin Central–Southern Italy. These shoshonitic to ultrapotassiclavas display strongly depleted high field strength element(HSFE) abundances with respect to other incompatible trace elementstogether with high but variable 87Sr/ 86Sr and low but variable143Nd/ 144Nd values. Such characteristics are thought to bedue to addition of subducted crust of variable amount and compositionto their mantle sources prior to magma genesis. Rocks from thenorthernmost region (i.e. Tuscan Magmatic Province and NorthernRoman Magmatic Province) display (230Th/ 238U) activity ratiosclose to radioactive equilibrium, suggesting that metasomatismof their sources occurred before 400 ka and recent melting tookplace at shallow depths, in the absence of garnet. A 238U excessof up to 27% has been measured in rocks from the NeapolitanDistrict. The occurrence of significant U excesses is a featureof arc magmas, but is typically seen in depleted lavas ratherthan in highly enriched rocks such as these (20 ppm Th). Thissignature requires a recent addition of a U-rich component tothe already strongly enriched mantle wedge beneath this regionof Italy. We suggest that a supercritical liquid, from deeplysubducted carbonate-rich sediments of the still-active Ionianslab, is responsible for generating a high-U, low-Th component,which produces the observed disequilibria. A 30% 230Th excessmeasured in a single unaltered sample from the Lucanian MagmaticProvince, along with a less marked negative HFSE anomaly, suggeststhe contribution of a deeper, garnet-bearing component in thegenesis of these magmas, plausibly related to the upwellingof asthenospheric mantle around the corner of the Ionian slab. KEY WORDS: U/Th disequilibria; potassic and ultrapotassic rocks; subduction: metasomatism; mantle melting; Central and Southern Italy 相似文献
134.
Evolution of orthogonal sets of coeval extension joints 总被引:1,自引:0,他引:1
Riccardo Caputo 《地学学报》1995,7(5):479-490
The formation of two orthogonal sets of extension joints either crossing or abutting each other is a typical product of brittle deformation. Such systems of joints, with the two joint sets being geologically coeval, have been called a fracture grid-lock. The two sets are of common genesis and thus a unique remote stress field can be inferred. This interpretation causes some perplexity if the two joint sets are purely extension fractures and formed perpendicular to the least principal stress. In the present paper a conceptual model to explain the origin and the evolution of such systems is proposed. In a volume of rock undergoing a tensional and uniform remote stress state, caused for example by a tectonic regime, two horizontal and negative (i.e. tensional) stress rates are assumed to exist. When the tensile strength of the rock is locally reached, failure occurs perpendicular to the least principal stress. Then, that direction locally experiences a positive stress drop due to the stress release. For this reason, the stress field, retaining the same principal directions, is locally distorted by a swap between the σ3 and the σ2 components in a volume of rock surrounding the fracture. As a consequence of the persisting remote stress rates, when elastic failure conditions are newly accumulated, a second fracture forms and propagates perpendicular to the previous one. Repeated failure events, stress-drops and stress swaps eventually generate a fracture grid-lock. The whole process is also described with a simplified analytical model by applying elasticity theory. 相似文献
135.
Maria Rosaria Renna Riccardo Tribuzio Massimo Tiepolo 《Contributions to Mineralogy and Petrology》2007,154(5):493-517
The post-Variscan complex of Porto consists of metaluminous to slightly peraluminous A-type biotite granites mingled with
gabbro-dioritic rocks, and late dykes with basaltic to trachyandesitic composition. U-Pb zircon dating by LA-ICP-MS on two
mafic intrusive samples constrains the time of the gabbro–granite crystallisation at 281 ± 3 Ma and 283 ± 2 Ma. Hornblende 40Ar-39Ar ages from a late trachyandesite dyke date the dyking event at 280 ± 2 Ma, which is within error the U-Pb zircon ages of
the intrusives. Biotite granites show variable major and trace element compositions and similar initial εNd (−0.3 to +0.9). Whole rock chemistry variations and trace element compositions of plagioclase and allanite indicate that
the granites are genetically linked, essentially through fractional crystallisation of feldspars and minor allanite. On the
basis of whole-rock chemistry e.g. initial εNd +4.9 to +1.7 and trace element clinopyroxene compositions, we have ascertained that the mafic intrusives and basic dykes
formed from isotopically depleted mantle source-derived melts with similar trace element signature. These basic melts experienced
slightly different evolutionary histories, controlled by fractional crystallisation and crustal contamination, mainly by the
acid magma that gave rise to the associated biotite granites, but also by the enclosing older Variscan granitoids. U-Pb zircon
data suggest that the Porto complex was affected by hydrothermal fluid circulation at 259 ± 9 Ma. 相似文献
136.
Tommasini Simone; Heumann Arnd; Avanzinelli Riccardo; Francalanci Lorella 《Journal of Petrology》2007,48(12):2407-2430
The subaerial part of the Stromboli stratovolcano was builtup in the last 100 kyr through six periods of activity; theerupted magmas record the largest compositional variation ofall the Aeolian arc volcanoes (calc-alkaline, shoshonitic, andpotassic alkaline magma series). The trace element characteristicsof the less evolved magmas of each period of activity are coherentlycorrelated with their radiogenic isotope (Sr, Nd, Pb) composition,and are typical of volcanic arc rocks. In terms of U-seriesisotopes, samples from the different magma series have both238U and 230Th excesses, and this distinctive feature providesadditional constraints on source enrichment processes withinthe mantle wedge and on the mechanism of partial melting. Overallthe complete set of data demonstrates that the genesis of thedifferent magma series at Stromboli can be accommodated in amantle source that experienced two distinct enrichment processesby different parts of the subducting oceanic crust of the Ionianslab. The first was caused by supercritical liquids originatingfrom the basaltic and sedimentary parts of the subducting slabat >5 GPa and 900°C. The second was induced by aqueousfluids, again originating from the basaltic and sedimentaryparts of the slab, released from a shallower part of the subductedIonian slab (< 5 GPa and 800°C). U–Th disequilibriaconstrain the timing of the first metasomatic event (Stage I:supercritical liquids) at >435 ka, whereas the second event(Stage II: aqueous fluids) occurred at 100 ka. The high-angledip of the Ionian slab (70°) caused the superimpositionof the metasomatizing agents of the two enrichment processesin the same volume of the mantle wedge, explaining the occurrenceof such different magma series in a single volcanic edifice.The U–Th disequilibria provide evidence for dynamic meltingof the metasomatized mantle wedge combined with an ageing effectresulting from the restoration of secular equilibrium afterthe perturbation caused by the U-rich aqueous fluids of StageII. The trace element and radiogenic isotope (U, Th, Sr, Nd,Pb) signature of the mantle source of the magmas at Stromboliis thus dependent upon the amount of supercritical liquids andaqueous fluids released by the two components of the subductedslab, whereas the distinctive 238U and 230Th excesses of themagmas result from a combination of mantle ageing and time-dependentdynamic melting. The geochemical and radiogenic isotope signatureof the mantle source beneath Stromboli places important constraintson the isotopic polarity from Southern Latium to the Aeolianarc attributed to the effect of a HIMU mantle component followingeither lateral inflow of foreland mantle material or upwellingof a mantle plume in the centre of the Tyrrhenian basin. Ourgeochemical model demonstrates that the high 206Pb/204Pb ofthe putative HIMU mantle component could be equallyformed during metasomatism of the pre-existing mantle wedgeby either the supercritical liquid (Stage I) or aqueous fluid(Stage II) released by the subducted altered basalt of the Ionianplate. KEY WORDS: radiogenic isotopes; U–Th disequilibria; mantle metasomatism; supercritical liquid; aqueous fluid; Stromboli 相似文献
137.
Maria Rosaria Renna Riccardo Tribuzio Alessio Sanfilippo Massimo Tiepolo 《Swiss Journal of Geoscience》2017,110(2):479-501
The Balagne ophiolite from central-northern Corsica represents a continent-near paleogeographic domain of the Jurassic Liguria-Piedmont ophiolitic basin. Pillow and massive basalt lavas are primarily associated with Middle–Upper Jurassic pelagic sediments (mostly radiolarites at their base), continental-derived quartzo-feldspathic clastic sediments and ophiolitic breccias containing clasts of gabbros and basalts. The basalt-sedimentary succession is tectonically associated with a slice composed of an intrusive sequence overlain by basalt lavas. A “plagiogranite” from the intrusive sequence was dated by U–Pb zircon geochronology. Although affected by some uncertainty, mainly reflecting common Pb contamination, the U–Pb zircon data suggest a crystallization age of 159 ± 3 Ma (MSWD = 6.3), which is coeval with the formation of oceanic lower crust in the Schistes Lustrés units from Alpine Corsica. The predominance of quartz grains preserving typical volcanic shape, the prevalence of prismatic zircons and the arkose whole-rock composition indicate that the continental-derived quartzo-feldspathic clastic sediments have a low degree of textural maturity. U–Pb zircon geochronology carried out on two distinct levels of quartzo-feldspathic clastic sediments identified the predominance of zircons with within error U–Pb dates at ~280 Ma; minor components at ~457, ~309 and ~262 Ma were also obtained. The U–Pb date distribution is consistent with a source magmatic material mostly developed during the Variscan orogenic collapse. 相似文献
138.
Paul R.D. Mason Kym E. Jarvis Hilary Downes Riccardo Vannucci 《Geostandards and Geoanalytical Research》1999,23(2):157-172
Incompatible trace element abundances have been determined in mantle-derived clinopyroxenes by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) in a comparative study with established microanalytical and bulk techniques. Individual clinopyroxene grains were sampled for the laser ablation study from sieved mineral separate fractions, from which similar mineral grains had been previously extracted for microprobe (SIMS) and bulk (INAA and ID-TIMS) analysis. Mineral grains were ablated with variable degrees of surface spatial resolution (50-200 μm) in order to maximise ICP-MS analyte count rates and to improve detection limits. A comparison of results from the different techniques reveals that for the most homogeneous samples LA-ICP-MS can achieve excellent levels of agreement with other techniques (10%) and good precision for most of the studied elements (1-5% RSD). Variations in calculated concentrations by LA-ICP-MS confirm inter- and intra-mineral heterogeneity determined by SIMS, reflecting changes in sample composition and texture. The long-term reproducibility of the technique is shown by the consistency of results for one sample analysed on thirteen occasions over a period of nine months. 相似文献
139.
140.
Anita Franco Riccardo Fiorin Matteo Zucchetta Patrizia Torricelli Piero Franzoi 《Journal of Sea Research》2010,64(4):457-464
Estuarine marshes are known as suitable nursery areas for many marine migrant fishes, such as flounder. The potential nursery value of such habitats was investigated in the Venice lagoon, by using growth and production of 0-group flounder as indicators. Size–frequency distribution analysis was performed on fish samples collected fortnightly, from March 2004 to June 2005, in two marsh sites, Dese and Tessera, differing in their origin and environmental conditions. Samples were mostly composed of juvenile individuals, belonging to 0- and 1-group cohorts (the latter being present in Tessera only). A higher total production, either annual or monthly, and faster growth of 0-group flounder was observed in Dese, associated to a higher ecological performance of 0-group individuals in this site, as indicated by the higher P:B ratio values. Dese is a site located in a marsh complex characterized by the relevant influence of a nearby river, and the observed higher potential nursery value of this marsh area with respect to the other is discussed in the light of the higher trophic status and other environmental conditions in this site. The production results were also compared to those from other estuarine environments commonly acknowledged as important nurseries for European flounder. 相似文献