Reference Minerals for the Microanalysis of Light Elements   总被引：2，自引：0，他引：2  

M. Darby Dyar  Michael Wiedenbeck  David Robertson  Laura R. Cross  Jeremy S. Delaney  Kurt Ferguson  Carl A. Francis  Edward S. Grew  Charles V. Guidotti  Richard L. Hervig  John M. Hughes  John Husler  William Leeman  Anne V. McGuire  Dieter Rhede  Heike Rothe  Rick L. Paul  Ian Richards  Martin Yates 《Geostandards and Geoanalytical Research》2001,25(2-3):441-463

The quantitative determination of light element concentrations in geological specimens represents a major analytical challenge as the electron probe is generally not suited to this task. With the development of new in situ analytical techniques, and in particular the increasing use of secondary ion mass spectrometry, the routine determination of Li, Be and B contents has become a realistic goal. However, a major obstacle to the development of this research field is the critical dependence of SIMS on the availability of well characterized, homogeneous reference materials that are closely matched in matrix (composition and structure) to the sample being studied. Here we report the first results from a suite of large, gem crystals which cover a broad spectrum of minerals in which light elements are major constituents. We have characterized these materials using both in situ and wet chemical techniques. The samples described here are intended for distribution to geochemical laboratories active in the study of light elements. Further work is needed before reference values for these materials can be finalized, but the availability of this suite of materials represents a major step toward the routine analysis of the light element contents of geological specimens.  相似文献   

Impact of Recharge Through Residual Oil Upon Sampling of Underlying Ground Water     

William R. Wise  Chi-Chung Chang  Rick A. Klopp  Philip B. Bedient 《Ground Water Monitoring & Remediation》1991,11(2):93-100

At an aviation gasoline spill site in Traverse City, Michigan, historical records indicate a positive correlation between significant rainfall events and increased concentrations of slightly soluble organic compounds in the monitoring wells of the site. To investigate the recharge effect on ground water quality due to infiltrating, water percolating past residual oil and into the saturated zone, an in situ infiltration experiment was performed at the site. Sampling cones were set at various depths below a circular test area, 13 feet (4 meters) in diameter. Rainfall was simulated by sprinkling the test area at a rate sufficiently low to prevent runoff. The sampling cones for soil-gas and ground water quality were installed in the unsaturated and saturated zones to observe the effects of the recharge process. At the time of the test, the water table was below the residual oil layer. The responses of the soil-gas and ground water quality were monitored during the recharge and drainage periods, which resulted from the sprinkling.
Infiltrated water was determined to have transported organic constituents of the residual oil, specifically benzene, toluene, ethylbenzene, and ortho-xylene (BTEX), into the ground water beneath the water table, elevating the aqueous concentrations of these constituents in the saturated zone. Soil-gas concentrations of the organic compounds in the unsaturated zone increased with depth and time after the commencement of infiltration. Reaeration of the unconfined aquifer via the infiltrated water was observed. It is concluded that water quality measurements are directly coupled to recharge events for the sandy type of aquifer with an overlying oil phase, which was studied in this work. Ground water sampling strategies and data analysis need to reflect the effect of recharge from precipitation on shallow, unconfined aquifers where an oil phase may be present.  相似文献   

Smithsonian Institution's Global Volcanism Network     

Rick Wunderman 《Bulletin of Volcanology》2002,64(8):564-565

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A Geostatistically Based Ground Water Monitoring Study of Nonpoint Source No₃^--N Concentrations     

Rick A. Carlson  James L. Osiensky 《Ground Water Monitoring & Remediation》2002,22(4):109-115

Geostatistical interpretations of ground water monitoring data are presented to define the spatial distributions of NO₃^--N in the ground water at two demonstration test sites in the Idaho Snake River Plain. Sequential Gaussian simulation was used to delineate monthly ground water NO₃^--N changes during and after implementation of a prescribed crop rotation at test site 1. Trend surface analyses were used to illustrate monthly ground water NO₃^--N changes during and after a prescribed irrigation practice was implemented at test site 2. These evaluations suggest that geostatistically based ground water monitoring can be effective in the delineation of changes in ground water quality in shallow, unconfined aquifers in agricultural areas such as those in southern Idaho. Geostatistical methods showed spatial and temporal changes in ground water NO₃^--N inferred to be a result of the agricultural practices implemented.  相似文献   

Ground-Water Contaminant Plume Differentiation and Source Determination Using BTEX Concentration Ratios     

Y. Jeffrey Yang  Rick D. Spencer  Mark A. Mersmann  Todd M. Gates 《Ground water》1995,33(6):927-935

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Alpha-decay damage in minerals of the pyrochlore group     

Gregory R. Lumpkin  Rodney C. Ewing 《Physics and Chemistry of Minerals》1988,16(1):2-20

X-ray diffraction analysis and transmission electron microscopy have been used to study the effects of alpha-decay damage in pyrochlore group minerals, characterized by the general formula A _1?m B ₂O₆(O,OH,F)_1?n ·pH₂O. As defined by the XRD intensity ratio I/I ₀ , both the saturation dose (for which I/I ₀ =0.1?0.0) and the dose which signifies the initial loss of crystallinity (for which I/I ₀ =1.0?0.8) increase as a function of geologic age. The increase is attributed to annealing of isolated alpha-recoil tracks back to the original crystalline structure. The tracks have calculated mean lives, τ_a, on the order of 10⁸ years. In contrast, minerals which remain crystalline (e.g., uraninite, UO₂) despite doses of up to 10¹⁸ alpha-events/mg have mean alpha-recoil track lives ≈10⁴ years (Eyal and Fleischer 1985). After correcting the calculated dose for annealing of alpha-recoil damage, I/I ₀ is observed to decrease exponentially to zero over the dose range 0.02–1.0 × 10¹⁶ alpha-events/mg. The relationship between I/I ₀ and “corrected” dose was used to calculate an average alpha-recoil track diameter of 4.6 nm, in which < 2600 atoms are displaced. XRD line broadening due to strain dominates the first half of the crystalline-to-metamict transition, reaching a maximum of 0.003, then decreasing to < 0.001. Line broadening due to decreasing crystallite size dominates the latter half of the transition. Estimated crystallite dimensions decrease from 450 nm to < 15 nm prior to reaching the fully metamict state. With increasing dose HRTEM images of microlites from the Harding pegmatite sequentially exhibit: 1) mottled diffraction contrast, 2) isolated 1–5 nm aperiodic areas, 3) coexisting aperiodic and crystalline areas, 4) relict “islands” of crystalline material in an aperiodic matrix, and 5) complete loss of lattice fringe periodicity. With no consideration given to alpha-recoil track fading, the transition covers a dose range of 0.04–1.7 × 10¹⁷ alpha-events/mg. Using a value of τ_a=10⁸ years, this dose range is corrected down to 0.02–1.2 × 10¹⁶ alpha-events/mg. The metamict state is characterized by a range of M-M and M-O distances which give rise to bands of diffuse scattering centered at 0.30 nm and 0.18 nm, respectively, in x-ray and electron diffraction patterns. Random image contrast shown by HRTEM is consistent with a random network type structure, an interpretation supported by EXAFS/XANES studies (Greegor et al. 1985a, b, 1987). The structure of metamict pyrochlore consists of an aperiodic framework of corner-sharing B-O polyhedra. Compared to the crystalline precursor, the metamict state displays a reduced M-O coordination number and mean bond length, increased distortion of the B-site, and a slight increase in the average M-M distance.  相似文献   

The groundwater management plan: in praise of a neglected ‘tool of our trade’     

Stephen Foster  Rick Evans  Oscar Escolero 《Hydrogeology Journal》2015,23(5):847-850

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Developing interactive geospatial holograms for spatial decision-making     

Sven Fuhrmann  Mark E. Holzbach  Rick Black 《制图学和地理信息科学》2015,42(4):27-33

Spatial decision-making in time-critical situations requires effective and usable two-dimensional and three-dimensional (3D) cartographic products. Holographic displays allow decision makers to work with auto-stereoscopic maps without the hassle of interacting with complex user interfaces or additional vision hardware. Holographic production processes have advanced greatly in a short period and now support timely and full integration of digital 3D models in geospatial holograms. George Mason University’s and Zebra Imaging’s research on interactive holographic motion displays showcases the leadership in moving cartography and geovisualization research in the US forward. In close cooperation with academic researchers, decision makers, and domain experts, the usability and usefulness of these cartographic products is tested and design guidelines for effective geospatial holograms are being developed.  相似文献   

Fluvial processes and environmental change A.G. BROWN and T.A. QUINE (eds) Publisher John Wiley & Sons,Chichester 1999 (413 pp) $160 ISBN 0‐471‐98548‐1     

Rick Shakesby 《第四纪科学杂志》2000,15(5):562-563

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The White Angel: A unique wollastonite‐bearing,mass‐fractionated refractory inclusion from the Leoville CV3 carbonaceous chondrite     

Catherine L. V. Caillet Komorowski  Ernst K. Zinner  Kevin D. McKeegan  Rick Hervig  Peter R. Buseck 《Meteoritics & planetary science》2007,42(7-8):1159-1182

Abstract— We report the study of an unusual compact type A refractory inclusion, named the White Angel, from the Leoville CV3 meteorite. The petrologic, mineral chemical, isotopic, and trace‐element signatures of this once‐molten Ca‐Al‐rich inclusion (CAI), which contains large, equant wollastonite crystals, indicate a short multistage history that occurred very early, before substantial decay of ²⁶Al. Magnesium in the inclusion is isotopically heavy, with F_Mg reaching 18‰/amu, in the range of fractionated and with unidentified nuclear effects (FUN) inclusions. However, the absence of any nuclear anomalies in Ca and Ti and an inferred ²⁶Al/²⁷Al ratio of (5.5 ± 0.9) × 10^?5 indicate that the White Angel belongs to the F inclusions. Silicon and oxygen are also mass fractionated in favor of the heavy isotopes, but to a lesser extent. The O isotopes show a range in ¹⁶O excesses. On an O three‐isotope plot, data points lie on a line parallel and to the right of the carbonaceous chondrite anhydrous mineral mixing line, with wollastonite being the most ¹⁶O‐rich phase. The chondrite‐normalized rare earth and trace‐element pattern of the whole inclusion is the complement of an ultrarefractory pattern indicating that precursor phases of the CAI must have condensed in an Al‐, heavy rare earth element (HREE)‐depleted reservoir. Melting of those precursor phases in an ¹⁶O‐rich environment and evaporation led to mass‐dependent isotopic fractionation of Mg, Si, and O. Partial isotopic exchange with a reservoir containing unfractionated Mg took place at a later stage but before any measurable decay of ²⁶Al. Some minerals (melilite and perovskite) in the White Angel equilibrated oxygen isotopes with a relatively ¹⁶O‐poor reservoir that was also mass‐fractionated toward the heavy isotopes, different from that with which the normal or FUN inclusions interacted.  相似文献