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91.
Jeroen T.M. de Jong Marie Boyé Maria D. Gelado-Caballero Klaas R. Timmermans Marcel J.W. Veldhuis Rob F. Nolting Constant M.G. van den Berg Hein J.W. de Baar 《Marine Chemistry》2007
Dissolved Fe, Mn and Al concentrations (dFe, dMn and dAl hereafter) in surface waters and the water column of the Northeast Atlantic and the European continental shelf are reported. Following an episode of enhanced Saharan dust inputs over the Northeast Atlantic Ocean prior and during the cruise in March 1998, surface concentrations were enhanced up to 4 nmol L− 1 dFe, 3 nmol L− 1 dMn and 40 nmol L− 1 dAl and returned to 0.6 nmol L− 1 dFe, 0.5 nmol L− 1 dMn and 10 nmol L− 1 dAl towards the end of the cruise three weeks later. A simple steady state model (MADCOW, [Measures, C.I., Brown, E.T., 1996. Estimating dust input to the Atlantic Ocean using surface water aluminium concentrations. In: Guerzoni. S. and Chester. R. (Eds.), The impact of desert dust across the Mediterranean, Kluwer Academic Publishers, The Netherlands, pp. 301–311.]) was used which relies on surface ocean dAl as a proxy for atmospheric deposition of mineral dust. We estimated dust input at 1.8 g m− 2 yr− 1 (range 1.0–2.9 g m− 2 yr− 1) and fluxes of dFe, dMn and dAl were inferred. Mixed layer steady state residence times for dissolved metals were estimated at 1.3 yr for dFe (range 0.3–2.9 yr) and 1.9 yr for dMn (range 1.0–3.8 yr). The dFe residence time may have been overestimated and it is shown that 0.2–0.4 yr is probably more realistic. Using vertical dFe versus Apparent Oxygen Utilization (AOU) relationships as well as a biogeochemical two end member mixing model, regenerative Fe:C ratios were estimated respectively to be 20 ± 6 and 22 ± 5 μmol Fe:mol C. Combining the atmospheric flux of dFe to the upper water column with the latter Fe:C ratio, a ‘new iron’ supported primary productivity of only 15% (range 7%–56%) was deduced. This would imply that 85% (range 44–93%) of primary productivity could be supported by regenerated dFe. The open ocean surface data suggest that the continental shelf is probably not a major source of dissolved metals to the surface of the adjacent open ocean. Continental shelf concentrations of dMn, dFe, and to a lesser extent dAl, were well correlated with salinity and express mixing of a fresher continental end member with Atlantic Ocean water flowing onto the shelf. This means probably that diffusive benthic fluxes did not play a major role at the time of the cruise. 相似文献
92.
93.
Have applications of continuous rainfall–runoff simulation realized the vision for process‐based flood frequency analysis? 下载免费PDF全文
Keith Beven was amongst the first to propose and demonstrate a combination of conceptual rainfall–runoff modelling and stochastically generated rainfall data in what is known as the ‘continuous simulation’ approach for flood frequency analysis. The motivations included the potential to establish better links with physical processes and to avoid restrictive assumptions inherent in existing methods applied in design flood studies. Subsequently, attempts have been made to establish continuous simulation as a routine method for flood frequency analysis, particularly in the UK. The approach has not been adopted universally, but numerous studies have benefitted from applications of continuous simulation methods. This paper asks whether industry has yet realized the vision of the pioneering research by Beven and others. It reviews the generic methodology and illustrates applications of the original vision for a more physically realistic approach to flood frequency analysis through a set of practical case studies, highlighting why continuous simulation was useful and appropriate in each case. The case studies illustrate how continuous simulation has helped to offer users of flood frequency analysis more confidence about model results by avoiding (or exposing) bad assumptions relating to catchment heterogeneity, inappropriateness of assumptions made in (UK) industry‐standard design event flood estimation methods, and the representation of engineered or natural dynamic controls on flood flows. By implementing the vision for physically realistic analysis of flood frequency through continuous simulation, each of these examples illustrates how more relevant and improved information was provided for flood risk decision‐making than would have been possible using standard methods. They further demonstrate that integrating engineered infrastructure into flood frequency analysis and assessment of environmental change are also significant motivations for adopting the continuous simulation approach in practice. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
94.
95.
We assessed the reproducibility of river state-of-environment (SoE) water quality measurements in the Wellington Region, New Zealand (NZ). Field staff from GWRC and NIWA conducted 29 side-by-side water sampling and in-situ measurements at six river sites of diverse water quality for 12 variables measured routinely in river SoE monitoring across NZ. Field measurements of water temperature, dissolved oxygen, electrical conductivity and visual clarity agreed closely with strong numerical similarity (within 10%). Numerical similarity ranged widely for laboratory measurements, from strong for nitrate-nitrite-nitrogen to weak for turbidity, dissolved reactive phosphorus, and ammoniacal-nitrogen. Numerical agreement was very weak for laboratory pH (which is problematic) and E. coli–which is ‘tolerable’ for many applications given good correlation (R?=?0.94) over a 2000-fold concentration range. The findings of our inter-agency comparison have contributed to quality assurance recommendations in the NZ National Environmental Monitoring Standard (NEMS) for water quality. 相似文献
96.
97.
Christian Tueckmantel Quentin J. Fisher Rob J. Knipe Henry Lickorish Samir M. Khalil 《Marine and Petroleum Geology》2010
A study of normal faults in the Nubian Sandstone Sequence, from the eastern Gulf of Suez rift, has been conducted to investigate the relationship between the microstructure and petrophysical properties of cataclasites developed along seismic-scale faults (slip-surface cataclasites) and smaller displacement faults (deformation bands) found in their damage zones. The results help to quantify the uncertainty associated with predicting the fluid flow behaviour of seismic-scale faults by analysing small faults recovered from core, a common procedure in the petroleum industry. The microstructure of the cataclasites was analysed as well as their single-phase permeability and threshold pressure. Faulting occurred at a maximum burial depth of ∼1.2 km. The permeability of deformation band and slip-surface cataclasites varies over ∼1.5 orders of magnitude for a given fault. Our results suggest that the lowest measured deformation band permeabilities provide a good estimate for the arithmetic-mean permeability of the major slip-surface cataclasites. This is because the cataclastic permeability reduction is mostly established early in the deformation history. Stress at the time of faulting rather than final strain appears to be the critical factor determining fault rock permeability. For viable predictions it is important that the slip-surface cataclasites and deformation bands originate from the same host. On the other hand, a higher uncertainty is associated with threshold pressure predictions, as the arithmetic-mean slip-surface cataclasite threshold pressure exceeds the highest measured deformation band threshold pressure by at least a factor of 4. 相似文献
98.
Linearly Organized Turbulence Structures Observed Over a Suburban Area by Dual-Doppler Lidar 总被引:1,自引:1,他引:0
Dual-Doppler lidar observations are used to investigate the structure and evolution of surface-layer flow over a suburban
area. The observations were made during the Joint Urban 2003 (JU2003) field experiment in Oklahoma City, U.S.A. in the summer
of 2003. This study focuses specifically on a 10-h sequence of scan data beginning shortly after noon local time on 7 July
2003. During this period two coherent Doppler lidars performed overlapping low elevation angle sector scans upwind and south
of Oklahoma City’s central business district. Radial velocity data from the two lidars are processed to reveal the structure
and evolution of the horizontal velocity field in the surface layer throughout the afternoon and during the evening transition
period. The retrieved velocity fields clearly show a tendency for turbulence structures to be elongated in the direction of
the mean flow throughout the entire 10-h study period. In order to quantify the observed anisotropy and its dependence on
stability, integral length scales are estimated directly from the spatially resolved velocity retrievals. As the flow became
more stably stratified the characteristic cross-stream dimension of the linear structures decreased. The streamwise component
was consistently more anisotropic than the cross-stream component, and both velocity components exhibited maximum anisotropy
under neutral conditions. The ratio of the streamwise to cross-stream length scale was estimated to be about eight for the
streamwise component, and four for the cross-stream component under neutral conditions. 相似文献
99.
Christopher J. Daughney Uwe Morgenstern Rob van der Raaij Robert R. Reeves 《Hydrogeology Journal》2010,18(2):417-428
Concentrations of tritium, chlorofluorocarbons and sulfur hexafluoride have been measured at over 100 groundwater monitoring sites across New Zealand, followed by interpretation of groundwater age distribution using the exponential-piston flow model. Interpreted mean residence times ranged from less than 1 year to more than 100 years, with the 25th, 50th (median) and 75th percentiles being approximately 10, 40 and 100 years, respectively. Classification functions derived from discriminant analysis and based on nine input variables (well depth, electrical conductivity and the concentrations of the ions Na, K, Ca, Mg, HCO3, Cl and SO4) allowed assignment of 71% of the sites to the correct of four age categories (mean residence time 10 years or less, 11–40 years, 41–100 years, or more than 100 years). The discriminant analysis classification functions were more effective than regression methods for estimating groundwater age from hydrochemistry and well depth, and can thus be used to predict the groundwater age category for any monitoring site in New Zealand. 相似文献
100.
Eduardo Zorita Anders Moberg Lotta Leijonhufvud Rob Wilson Rudolf Brázdil Petr Dobrovolný Jürg Luterbacher Reinhard Böhm Christian Pfister Dirk Riemann Rüdiger Glaser Johan Söderberg Fidel González-Rouco 《Climatic change》2010,101(1-2):143-168
Two European temperature reconstructions for the past half-millennium, January-to-April air temperature for Stockholm (Sweden) and seasonal temperature for a Central European region, both derived from the analysis of documentary sources and long instrumental records, are compared with the output of climate simulations with the model ECHO-G. The analysis is complemented by comparisons with the long (early)-instrumental record of Central England Temperature (CET). Both approaches to study past climates (simulations and reconstructions) are burdened with uncertainties. The main objective of this comparative analysis is to identify robust features and weaknesses in each method which may help to improve models and reconstruction methods. The results indicate a general agreement between simulations obtained with temporally changing external forcings and the reconstructed Stockholm and CET records for the multi-centennial temperature trend over the recent centuries, which is not reproduced in a control simulation. This trend is likely due to the long-term change in external forcing. Additionally, the Stockholm reconstruction and the CET record also show a clear multi-decadal warm episode peaking around AD 1730, which is absent in the simulations. Neither the reconstruction uncertainties nor the model internal climate variability can easily explain this difference. Regarding the interannual variability, the Stockholm series displays, in some periods, higher amplitudes than the simulations but these differences are within the statistical uncertainty and further decrease if output from a regional model driven by the global model is used. The long-term trend of the CET series agrees less well with the simulations. The reconstructed temperature displays, for all seasons, a smaller difference between the present climate and past centuries than is seen in the simulations. Possible reasons for these differences may be related to a limitation of the traditional ‘indexing’ technique for converting documentary evidence to temperature values to capture long-term climate changes, because the documents often reflect temperatures relative to the contemporary authors’ own perception of what constituted ‘normal’ conditions. By contrast, the amplitude of the simulated and reconstructed inter-annual variability agrees rather well. 相似文献