Electron microscopy study of domain structure due to phase transitions in natural perovskite     

Yanbin Wang  Robert C. Liebermann 《Physics and Chemistry of Minerals》1993,20(3):147-158

Transmission electron microscopy on natural calcium metatitanate perovskite (dysanalyte) reveals the following twin laws in the orthorhombic (space group Pbnm) phase: reflection twins on the {110} and {112} planes, and 90° rotation twins about the [001] axis (referred to as [001]_90° twin). Single crystals that were heattreated and quenched from above 1585 K exhibit a dramatic change in domain structure compared with the starting material and specimens quenched from T < 1470=" k.=" mutually=" perpendicular=" {110}=" and=">_90° twins are observed throughout the crystal, forming a cross-hatched domain texture. 1/2[001] antiphase domains, which are very rarely observed in the starting material, also become dominant in the crystal. This change in domain structure is interpreted as due to a structural phase transition in perovskite at a temperature below 1585 K. From the point symmetry elements that describe the twin laws and the translational elements that relate the antiphase domains, the most likely phase near 1585 K is tetragonal with space group P4/mbm. These results are consistent with high-temperature powder X-ray diffraction study. On the other hand, density of the {112} twins is increased significantly in the crystal quenched from 1673 K. Twin domains are either bound by mutually perpendicular {110} and (001) walls, or by {112} walls with {110} twin domains within the polygonal {112} domains. Both twin density variation and domain morphology suggest that the crystal may be cubic at this temperature. Microstructure of a single crystal deformed at 1273 K and 3.5 GPa (within the orthorhombic stability field) is morphologically quite distinct from that of the heat-treated specimens. Dislocations dominate the microstructure and often interact with twin domain boundaries.A National Science Foundation Science and Technology Center  相似文献   

New paleomagnetic results from the Aegean extensional province     

Haubold  Herbert  Scholger  Robert  Kondopoulou  Despina  Mauritsch  Hermann J. 《Geologie en Mijnbouw》1997,76(1-2):45-55

Various Oligocene formations from NE Greece (ignimbrites from the Medousa area, rhyolites from Zagradenia, granodiorites from Elatia) show discordant paleomagnetic signatures, in each case indicating small cw (clockwise) rotation and also inclination flattening. Marls from Pithion were partly remagnetized in a present-day field. Samples that contain ancient magnetization components also indicate small cw rotation and inclination flattening. However, the magnetization of andesites from Peplos reflects a considerably larger rotation, likely owing to local tectonics. In the context of previous work in the area, these results are used to propose a subdivision of NE Greece into four structural zones of distinctive rotational behaviour (from east to west): sites in zone 1, east of the Kavala-Xanthi-Komotini fault (KXK), show various cw and ccw (counterclockwise) rotation angles owing to complex kinematics resulting from the interaction of the KXK and the north-Anatolian fault zone. However, zone 2, between the KXK and the Strymon valley, is structurally homogeneous ( 10° cw rotation). The paleomagnetic signature of the Vertiskos massif (zone 3) implies a larger (> 30°) cw rotation, whereas sites in the Vardar basin (zone 4) contain a paleomagnetic signature similar to that of zone 2. This suggests a motion of the Vertiscos massif, a meta-ophiolitic nappe, relative to underlying strata. Indeed, zones 2 and 4 may be parts of the same structural unit which underlies this nappe.  相似文献   

Ozone production due to emissions from vegetation burning     

Günter Helas  Jürgen Lobert  Dieter Scharffe  Luise Schäfer  Johann Goldammer  Jean Baudet  Brou Ahoua  Ayité-Lô Ajavon  Jean-Pierre Lacaux  Robert Delmas  Meinrat O. Andreae 《Journal of Atmospheric Chemistry》1995,22(1-2):163-174

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.  相似文献   

Probabilistic seismic hazard zonation of Syria     

Abdallah I. Husein Malkawi  Robert Y. Liang  Jamal H. Nusairat  Azm S. Al-Homoud 《Natural Hazards》1995,12(2):139-151

Earthquake hazard maps for Syria are presented in this paper. The Peak Ground Acceleration (PGA) and the Modified Mercalli Intensity (MMI) on bedrock, both with 90% probability of not being exceeded during a life time of 50, 100 and 200 years, respectively are developed. The probabilistic PGA and MMI values are evaluated assuming linear sources (faults) as potential sources of future earthquakes. A new attenuation relationship for this region is developed. Ten distinctive faults of potential earthquakes are identified in and around Syria. The pertinent parameters of each fault, such as theb-parameter in the Gutenberg-Richter formula, the annual rate ₄ and the upper bound magnitudem ₁ are determined from two sets of seismic data: the historical earthquakes and the instrumentally recorded earthquake data (AD 1900–1992). The seismic hazard maps developed are intended for preliminary analysis of new designs and seismic check of existing civil engineering structures.  相似文献   

Interstellar water in meteorites?   总被引：1，自引：0，他引：1  

Deloule E  Robert F 《Geochimica et cosmochimica acta》1995,59(22):4695-4706

D/H ratios of two meteorites (Renazzo CR and Semarkona LL3), which are known to exhibit the largest departures from the terrestrial hydrogen isotopic ratios, have been determined with the CRPG Nancy ion microprobe. Correlations between the D/H ratios and the chemical compositions (H2O, K, Si, C/H) of plausible hydrogen carriers were observed. From these correlations, it is possible to show that, contrary to previous interpretations, phyllosilicates are the carriers of the deuterium-rich hydrogen in Semarkona and Renazzo: 870 x 10(-6) > or = D/H > or = 670 x 10(-6) (+4600 > or = deltaD > or = 3300%) and > or = 320 x 10(-6) (deltaD > or = 1050%), respectively. Hydrogen is also present in the chondrules of these two deuterium-rich meteorites. The large differences in D/H ratios between matrix (up to 700 x 10(-6), deltaD up to +3500%) and chondrules (from 120 x 10(-6) (deltaD = -230%) to 230 x 10(-6) (deltaD = +475%)) show that hydrogen in chondrules cannot originate from the matrix by simple contamination or diffusion processes. The high D/H ratios measured in water-bearing minerals could not have been produced thermally within a dense solar nebula. Chemical reactions (i.e., involving ions or radicals), taking place in interstellar space or in the outer regions of the nebula at 110-140K are presently the only conceivable mechanisms capable of yielding such isotopic enrichments. Water in these meteorites should no longer be considered as a simple product of nebular condensation under equilibrium thermodynamic conditions at T > or = 160K.  相似文献   

Rejuvenation of Lake Erie     

Robert A. Sweeney 《GeoJournal》1995,35(1):65-66

The positive ecological changes that have occurred in Lake Erie since the mid-1970, demonstrate that an extensively degraded aquatic ecosystem can be rejuventated. This rejuvenation should provide encouragement to other who are attempting to save such habitats as the Aral Sea. This paper summarizes the problems of Lake Erie, the meassures instituted to correct the problems and the result of remediation efforts.  相似文献   

On the use of ‘first spotless day’ as a predictor for sunspot minimum     

Robert M. Wilson 《Solar physics》1995,158(1):197-204

Defining the first spotless day of a sunspot cycle as the first day without spots relative to sunspot maximum during the decline of the solar cycle, one finds that the timing of that occurrence can be used as a predictor for the occurrence of solar minimum of the following cycle. For cycle 22, the first spotless day occurred in April 1994, based on the International sunspot number index, although other indices (Boulder and American) indicated the first spotless day to have occurred earlier (September 1993). For cycles 9–14, sunspot minimum followed the first spotless day by about 72 months, having a range of 62–82 months; for cycles 15–21, sunspot minimum followed the first spotless day by about 35 months, having a range of 27–40 months. Similarly, the timing of first spotless day relative to sunspot minimum and maximum for the same cycle reveals that it followed minimum (maximum) by about 69 (18) months during cycles 9–14 and by about 90 (44) months during cycles 15–21. Accepting April 1994 as the month of first spotless day occurrence for cycle 22, one finds that it occurred 91 months into the cycle and 57 months following sunspot maximum. Such values indicate that its behavior more closely matches that found for cycles 15–21 rather than for cycles 9–14. Therefore, one infers that sunspot minimum for cycle 23 will occur in about 2–3 years, or about April 1996 to April 1997. Accepting the earlier date of first spotless day occurrence indicates that sunspot minimum for cycle 23 could come several months earlier, perhaps late 1995.The U.S. Government right to retain a non-exclusive, royalty free licence in and to any copyright is acknowledged.  相似文献   

The solar surface differential rotation from disk-integrated chromospheric fluxes     

Robert A. Donahue  Steven L. Keil 《Solar physics》1995,159(1):53-62

Disk-integrated solar chromospheric Caii K-line (3933.68 ) fluxes have been measured almost daily at Sacramento Peak Observatory since 1977. Using observing windows selected to mimic seasonal windows for chromospheric measurements of lower Main-Sequence stars such as those observed by Mount Wilson Observatory's HK Project, we have measured the solar rotation from the modulation of the Caii K-line flux. We track the change of rotation period from the decline of cycle 21 through the maximum of cycle 22. This variation in rotation period is shown to behave as expected from the migration of active regions in latitude according to Maunder's butterfly diagram, including an abrupt change in rotation period at the transition from cycle 21 to cycle 22. These results indicate the successful detection of solar surface differential rotation from disk-integrated observations. We argue that the success of our study compared to previous investigations of the solar surface differential rotation from disk-integrated fluxes lies primarily with the choice of the length of the time-series window. Our selection of 200 days is shorter than in previous studies whose windows are typically on the order of one year. The 200-day window is long enough to permit an accurate determination of the rotation period, yet short enough to avoid complications arising from active region evolution. Thus, measurements of the variation of rotation period in lower Main-Sequence stars, especially those that appear to be correlated with long-term changes in chromospheric activity (i.e., cycles), are probably evidence for stellar surface differential rotation.  相似文献   

Evaluating the mobility of137Cs,239+240Pu and210Pb from their distributions in laminated lake sediments   总被引：1，自引：0，他引：1  

John Crusius  Robert F. Anderson 《Journal of Paleolimnology》1995,13(2):119-141

Post-depositional mobility of¹³⁷Cs,^239+240Pu and²¹⁰Pb was assessed in six small lake basins by comparing sedimentary nuclide profiles with their known fallout history. Laminae couplets, when present, were determined to be varves because the¹³⁷Cs and^239+240Pu 1963 fallout peaks are present in laminae couplets corresponding to years 1962–1964. There is no evidence of mobility of²¹⁰Pb, because 1) mass accumulation rates based on²¹⁰Pb agree with those based on¹³⁷Cs and^239+240Pu peak depths and with those based on varve counts, and 2)²¹⁰Pb ages agree with varve ages. Significant mobility of¹³⁷Cs is evident from the penetration of¹³⁷Cs to depths 15–20 cm deeper than^239+240Pu. Deep penetration of¹³⁷Cs in spite of a sharp gradient below the peak is interpreted by a numerical model to suggest that¹³⁷Cs is present in two distinct forms in these sediments, 67–82% as an immobile form and 18–33% reversibly adsorbed with a K _d of approximately 5000. The profiles can be interpreted equally well assuming a small portionof the total¹³⁷Cs was present as an extremely mobile phase (K _d 5000) in the months to years following peak fallout, slowly becoming more strongly adsorbed. High NH ₄ ⁺ concentrations in porewaters may enhance diffusion of the mobile form of¹³⁷Cs, but not of the immobile form of¹³⁷Cs that defines the sharp gradient. Mobility of¹³⁷Cs is likely also enhanced by the low clay content and the high porosity of these sediments. Thus the first detection of¹³⁷Cs in the sediments cannot automatically be assumed to correspond to a date of 1952 (initial testing of thermonuclear weapons), although the depth of the peak can be assumed to correspond to 1963 (the year of maximum fallout from testing of thermonuclear weapons).^239+240Pu is a more reliable sediment chronometer than¹³⁷Cs because it is significantly less mobile.This is the sixth of a series of papers to be published by this journal following the 20 ^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P.G. Appleby is guest editing this series.  相似文献   

Cosmic ray ionization of the Jovian atmosphere     

Louis A. Capone  John Dubach  Robert C. Whitten  Sheo S. Prasad 《Icarus》1979,39(3):433-449

An approximate form of the Boltzmann equation has been used to obtain local ionization rates due to the absorption of galactic cosmic rays in the Jovian atmosphere. It is shown that the muon flux component of the cosmic ray-induced cascade may be especially importannt in ionizing the atmosphere at levels where the total number density exceeds 10¹⁹ cm^?3 (well below the ionospheric layers produced by solar euv). A model containing both positive and negative ion reactions has been employed to compute equilibrium electron and ion number densities. Peak electron number densities on the order of 10³ cm^?3 may be expected even at relatively low magnetic latitudes. The dominant positive ions are NH₄⁺ and C_nH_m⁺ cluster ions, with n ? 2; it is suggested that the absorption of galactic cosmic ray energy at such relatively high pressures in the Jovian atmosphere $\text{(M ? 10}{}^{18}\text{to}\text{10}{}^{20}\text{cm}{}^{\mathrm{?3}}\text{)}$ and the subsequent chemical reactions may be instrumental in the local formation of complex hydrocarbons.  相似文献