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81.
Michele Zema Mark D. Welch Roberta Oberti 《Contributions to Mineralogy and Petrology》2012,163(5):923-937
The thermoelastic behaviour of a natural gedrite having the crystal-chemical formula ANa0.47
B(Na0.03 Mg1.05 Fe0.862+ Mn0.02 Ca0.04) C(Mg3.44 Fe0.362+ Al1.15 Ti0.054+) T(Si6.31 Al1.69)O22
W(OH)2 has been studied by single-crystal X-ray diffraction to 973 K (Stage 1). After data collection at 973 K, the crystal was heated to 1,173 K to induce dehydrogenation, which was registered by significant
changes in unit-cell parameters, M1–O3 and M3–O3 bond lengths and refined site-scattering values of M1 and M4 sites. These changes and the crystal-chemical formula calculated from structure refinement show that all Fe2+ originally at M4 migrates into the ribbon of octahedrally coordinated sites, where most of it oxidises to Fe3+, and there is a corresponding exchange of Mg from the ribbon into M4. The resulting composition is that of an oxo-gedrite with an inferred crystal-chemical formula ANa0.47
B(Na0.03 Mg1.93 Ca0.04) C(Mg2.56 Mn0.022+ Fe0.102+ Fe1.223+ Al1.15 Ti0.054+) T(Si6.31 Al1.69) O22
W[O1.122− (OH)0.88]. This marked redistribution of Mg and Fe is interpreted as being driven by rapid dehydrogenation at the H3A and H3B sites, such that all available Fe in the structure orders at M1 and M3 sites and is oxidised to Fe3+. Thermoelastic data are reported for gedrite and oxo-gedrite; the latter was measured during cooling from 1,173 to 298 K
(Stage 2) and checked after further heating to 1,273 K (Stage 3). The thermoelastic properties of gedrite and oxo-gedrite are compared with each other and those of anthophyllite. 相似文献
82.
Matthew R. M. IZAWA Roberta L. FLEMMING Neil R. BANERJEE Philip J. A. McCAUSLAND 《Meteoritics & planetary science》2011,46(5):638-651
Abstract– A new method for assessing the shock stage of enstatite chondrites has been developed, using in situ micro‐X‐ray diffraction (μXRD) to measure the full width at half maximum (FWHMχ) of peak intensity distributed along the direction of the Debye rings, or chi angle (χ), corresponding to individual lattice reflections in two‐dimensional XRD patterns. This μXRD technique differs from previous XRD shock characterization methods: it does not require single crystals or powders. In situ μXRD has been applied to polished thin sections and whole‐rock meteorite samples. Three frequently observed orthoenstatite reflections were measured: (020), (610), and (131); these were selected as they did not overlap with diffraction lines from other phases. Enstatite chondrites are commonly fine grained, stained or darkened by weathering, shock‐induced oxidation, and metal/sulfide inclusions; furthermore, most E chondrites have little olivine or plagioclase. These characteristics inhibit transmitted‐light petrography, nevertheless, shock stages have been assigned MacAlpine Hills (MAC) 02837 (EL3) S3, Pecora Escarpment (PCA) 91020 (EL3) S5, MAC 02747 (EL4) S4, Thiel Mountains (TIL) 91714 (EL5) S2, Allan Hills (ALHA) 81021 (EL6) S2, Elephant Moraine (EET) 87746 (EH3) S3, Meteorite Hills (MET) 00783 (EH4) S4, EET 96135 (EH4–5) S2, Lewis Cliff (LEW) 88180 (EH5) S2, Queen Alexandra Range (QUE) 94204 (EH7) S2, LaPaz Icefield (LAP) 02225 (EH impact melt) S1; for the six with published shock stages, there is agreement with the published classification. FWHMχ plotted against petrographic shock stage demonstrates positive linear correlation. FWHMχ ranges corresponding to shock stages were assigned as follows: S1 < 0.7°, S2 = 0.7–1.2°, S3 = 1.2–2.3°, S4 = 2.3–3.5°, S5 > 3.5°, S6—not measured. Slabs of Abee (EH impact‐melt breccia), and Northwest Africa (NWA) 2212 (EL6) were examined using μXRD alone; FWHMχ values place both in the S2 range, consistent with literature values. Micro‐XRD analysis may be applicable to other shocked orthopyroxene‐bearing rocks. 相似文献
83.
Wang-Ye Li Fang-Zhen Teng Shan Ke Roberta L. Rudnick Fu-Yuan Wu 《Geochimica et cosmochimica acta》2010,74(23):6867-6884
High-precision Mg isotopic data are reported for ∼100 well-characterized samples (granites, loess, shales and upper crustal composites) that were previously used to estimate the upper continental crust composition. Magnesium isotopic compositions display limited variation in eight I-type granites from southeastern Australia (δ26Mg = −0.25 to −0.15) and in 15 granitoid composites from eastern China (δ26Mg = −0.35 to −0.16) and do not correlate with SiO2 contents, indicating the absence of significant Mg isotope fractionation during differentiation of granitic magma. Similarly, the two S-type granites, which represent the two end-members of the S-type granite spectrum from southeastern Australia, have Mg isotopic composition (δ26Mg = −0.23 and −0.14) within the range of their potential source rocks (δ26Mg = −0.20 and +0.15) and I-type granites, suggesting that Mg isotope fractionation during crustal anatexis is also insignificant. By contrast, δ26Mg varies significantly in 19 A-type granites from northeastern China (−0.28 to +0.34) and may reflect source heterogeneity.Compared to I-type and S-type granites, sedimentary rocks have highly heterogeneous and, in most cases, heavier Mg isotopic compositions, with δ26Mg ranging from −0.32 to +0.05 in nine loess from New Zealand and the USA, from −0.27 to +0.49 in 20 post-Archean Australian shales (PAAS), and from −0.52 to +0.92 in 20 sedimentary composites from eastern China. With increasing chemical weathering, as measured by the chemical index of alternation (CIA), δ26Mg values show a larger dispersion in shales than loess. Furthermore, δ26Mg correlates negatively with δ7Li in loess. These characteristics suggest that chemical weathering significantly fractionates Mg isotopes and plays an important role in producing the highly variable Mg isotopic composition of sedimentary rocks.Based on the estimated proportions of major rock units within the upper continental crust and their average MgO contents, a weighted average δ26Mg value of −0.22 is derived for the average upper continental crust. Our studies indicate that Mg isotopic composition of the upper crust is, on average, mantle-like but highly heterogeneous, with δ26Mg ranging from −0.52 to +0.92. Such large isotopic variation mainly results from chemical weathering, during which light Mg isotopes are lost to the hydrosphere, leaving weathered products (e.g., sedimentary rocks) with heavy Mg isotopes. 相似文献
84.
85.
Roberta LasagnaMonica Montefalcone Giancarlo AlbertelliNicola Corradi Marco FerrariCarla Morri Carlo Nike Bianchi 《Estuarine, Coastal and Shelf Science》2011,94(3):255-262
While coastal management activities have long been known to exert a strong influence on the health of marine ecosystems, neither scientists nor administrators have realized that small interventions may lead to disproportionately larger impacts. This study investigated the broad and long-lasting environmental consequences of the construction of an ill-planned, although small (only 12 m long) jetty for pleasure crafts on the hydrodynamic conditions and on the meadow of the seagrass Posidonia oceanica of an embayed cove in the Ligurian Sea (NW Mediterranean). There, P. oceanica used to develop on a high (>1.5 m) matte (a lignified terrace causing seafloor elevation) in which the leaves reach the surface and form a compact natural barrier to waves in front of the beach. Such a so-called ‘fringing reef’ of P. oceanica is today recognized of high ecological value and specific conservation efforts are required. The construction of the jetty implied the cutting of the matte, which directly destroyed part of the fringing reef. In addition, meadow mapping and sedimentological analyses coupled with morphodynamic modelling showed that the ecosystem of the whole cove had been greatly altered by the jetty. We used the geometric planform approach, a proper tool in the study of headland-controlled embayment, both to characterise the present situation of Prelo cove and to simulate the original one, before the jetty was built. In the long term, such a small jetty completely altered the configuration and the hydrodynamic conditions of the whole cove, splitting the original pocket beach into two smaller ones and creating strong rip-currents flowing seaward along the jetty. These rip-currents enhanced erosion of residual shallow portions of the meadow and further modified the sedimentary fluxes in shallow waters. A century after the construction of the jetty, an irreversible environmental damage has occurred, as the slow growing rate of P. oceanica implies that the high matte terrace and the fringing reef will hardly form again, even after the removal of the jetty. The lesson learnt from this study is that even such small, and therefore reputed intrinsically ‘innocent’, interventions on the coastal zone require accurate planning based on interdisciplinary studies to understand and respect the delicate interplay among morphological, hydrodynamic and ecological components. 相似文献
86.
87.
This paper presents information on the levels of trace elements in sediments collected at Deception and Penguin Islands and tracks the sources of natural and anthropogenic inputs of metals into this sub-Antarctic region. The results suggest that natural processes, such as volcanic activity, hydrothermal processes and sediment transport, are more important than anthropogenic inputs in accounting for the metal concentrations measured in sediments at Deception Island. The higher levels of trace metals recorded in sediments at Penguin Island seem to reflect the composition of the source rocks of the island, which are dominated by the olivine-basalt group. Our findings show that human activities in the study areas may contribute to negligible levels of trace metals associated with anthropogenic inputs (e.g., Cr and Zn) in sediments, and these results can be used in the future as background levels related to low anthropogenic impacts. 相似文献
88.
The thermoelastic behaviour of anthophyllite has been determined for a natural crystal with crystal-chemical formula ANa0.01
B(Mg1.30Mn0.57Ca0.09Na0.04) C(Mg4.95Fe0.02Al0.03) T(Si8.00)O22
W(OH)2 using single-crystal X-ray diffraction to 973 K. The best model for fitting the thermal expansion data is that of Berman
(J Petrol 29:445–522, 1988) in which the coefficient of volume thermal expansion varies linearly with T as α
V,T
= a
1 + 2a
2 (T − T
0): α298 = a
1 = 3.40(6) × 10−5 K−1, a
2 = 5.1(1.0) × 10−9 K−2. The corresponding axial thermal expansion coefficients for this linear model are: α
a
,298 = 1.21(2) × 10−5 K−1, a
2,a
= 5.2(4) × 10−9 K−2; α
b
,298 = 9.2(1) × 10−6 K−1, a
2,b
= 7(2) × 10−10 K−2. α
c
,298 = 1.26(3) × 10−5 K−1, a
2,c
= 1.3(6) × 10−9 K−2. The thermoelastic behaviour of anthophyllite differs from that of most monoclinic (C2/m) amphiboles: (a) the ε
1 − ε
2 plane of the unit-strain ellipsoid, which is normal to b in anthophyllite but usually at a high angle to c in monoclinic amphiboles; (b) the strain components are ε
1 ≫ ε
2 > ε
3 in anthophyllite, but ε
1 ~ ε
2 ≫ ε
3 in monoclinic amphiboles. The strain behaviour of anthophyllite is similar to that of synthetic C2/m
ANa B(LiMg) CMg5
TSi8 O22
W(OH)2, suggesting that high contents of small cations at the B-site may be primarily responsible for the much higher thermal expansion
⊥(100). Refined values for site-scattering at M4 decrease from 31.64 epfu at 298 K to 30.81 epfu at 973 K, which couples with similar increases of those of M1 and M2 sites. These changes in site scattering are interpreted in terms of Mn ↔ Mg exchange involving M1,2 ↔ M4, which was first detected at 673 K. 相似文献
89.
90.
It is a widely accepted idea that hydrologically triggered deep-seated landslides are initiated by an increase in pore-water pressure on potential slip surface induced by rising groundwater level after prolonged period of intense rainfall although the process is not fully understood. In order to contribute to better understanding, the rainfall–groundwater relationships, hydrogeological monitoring and repeated geoelectrical imaging were carried out from March 2007 to April 2011 in large deep-seated landslide near ?ubietová (Western Carpathians) catastrophically reactivated at the end of February 1977. Based on our observations, groundwater level (GWL) response to precipitation differs considerably with respect to both overall hydrological conditions and GWL mean depth. While the rate of GWL increase up to 25 cm/day were measured after some rainfall events during wet periods, noticeably lower recharge rate (up to 1–2 cm/day) and delayed GWL response to rainfall (usually from 2 weeks to 2–4 months) were observed at the beginning of the wet season after considerable depression of GWLs due to previous effective rainfall deficit. Likewise, slow GWL fluctuations without short-term oscillations are typical for deeper GWLs. Thus, long-term (several seasons to several years) hydrological conditions affect markedly groundwater response to rainfall events in the studied landslide and can be crucial for its behaviour. Comparison of hydrological conditions characterising the analysed period with those that accompanied the landslide reactivation in 1977 allow us to assume that slightly above-average rainy season following the prolonged wet period can be far more responsible for movement acceleration (and possibly failure initiation) in deep landslides than the isolated season of extreme precipitation following a longer dry period. This is true especially for landslides in regions with significant seasonal temperature changes where potential effective precipitation (PEP), calculated as excess of precipitation (P) over potential evapotranspiration (PET), may be efficiently used for estimation of slope saturation condition. 相似文献