The geology and geochemistry of the Lumwana Cu (± Co ± U) deposits, NW Zambia     

Robin Bernau  Stephen Roberts  Mike Richards  Bruce Nisbet  Adrian Boyce  James Nowecki 《Mineralium Deposita》2013,48(2):137-153

The Lumwana Cu (± Co ± U) deposits of NW Zambia are large, tabular, disseminated ore bodies, hosted within the Mwombezhi Dome of the Lufilian Arc. The host rocks to the Lumwana deposits are two mineralogically similar but texturally distinct gneisses, a granitic to pegmatitic gneiss and a banded to augen gneiss which both comprise quartz–feldspar ± biotite ± muscovite ± haematite ± amphibole and intervening quartz–feldspar ± biotite schist. The sulphide ore horizons are typically developed within a biotite–muscovite–quartz–kyanite schist, although mineralization locally occurs within internal gneiss units. Contacts between the ore and host rocks are transitional and characterized by a loss of feldspar. Kinematic indicators, such as S-C fabrics and pressure shadows on porphyroblasts, suggest a top to the north shear sense. The sulphides are deformed by a strong shear fabric, enclosed within kyanite or concentrated into low strain zones and pressure shadows around kyanite porphyroblasts. This suggests that the copper mineralization was introduced either syn- or pre-peak metamorphism. In addition to Cu and Co, the ores are also characterized by enrichments in U, V, Ni, Ba and S and small, discrete zones of uranium mineralization, occur adjacent to the hanging wall and footwall of the copper ore bodies or in the immediate footwall to the copper mineralization. Unlike typical Copperbelt mineralization, unmineralized units show very low background copper values. Whole rock geochemical analyses of the interlayered schist and ore schist, compared to the gneiss, show depletions in Ca, Na and Sr and enrichments in Mg and K, consistent with replacement of feldspar by biotite. The mineral chemistry of muscovite, biotite and chlorite reflect changes in the bulk rock chemistry and show consistent increases in X _Mg as the schists develop. δ³⁴S for copper sulphides range from +2.3?‰ to +18.5?‰, with pyrite typically restricted to values between +3.9?‰ and +6.2?‰. These values are atypical of sulphides precipitated by bacteriogenic sulphate reduction. δ³⁴S data for Chimiwungo (Cu + Co) show a broader range and increased δ³⁴S values compared to the Malundwe (Cu) mineralization. The Lumwana deposits show many characteristics which distinguish them from classical Copperbelt mineralization and which suggests that they are formed by metasomatic alteration, mineralization and shearing of pre-Katangan basement. Although this style of mineralization is reported elsewhere in the Copperbelt, sometimes associated with the more widely reported stratiform ores of the Lower Roan, none of the previously reported occurrences have so far developed the tonnages of ore reported at Lumwana.  相似文献   

Vapor Intrusion Screening at Petroleum UST Sites     

Matthew A. Lahvis  Ian Hers  Robin V. Davis  Jackie Wright  George E. DeVaull 《Ground Water Monitoring & Remediation》2013,33(2):53-67

Detailed site investigations to assess potential inhalation exposure and risk to human health associated with the migration of petroleum hydrocarbon vapors from the subsurface to indoor air are frequently undertaken at leaking underground storage tank (UST) sites, yet documented occurrences of petroleum vapor intrusion are extremely rare. Additional assessments are largely driven by low screening‐level concentrations derived from vapor transport modeling that does not consider biodegradation. To address this issue, screening criteria were developed from soil‐gas measurements at hundreds of petroleum UST sites spanning a range of environmental conditions, geographic regions, and a 16‐year time period (1995 to 2011). The data were evaluated to define vertical separation (screening) distances from the source, beyond which, the potential for vapor intrusion can be considered negligible. The screening distances were derived explicitly from benzene data using specified soil‐gas screening levels of 30, 50, and 100 µg/m³ and nonparametric Kaplan‐Meier statistics. Results indicate that more than 95% of benzene concentrations in soil gas are ≤30 µg/m³ at any distance above a dissolved‐phase hydrocarbon source. Dissolved‐phase petroleum hydrocarbon sources are therefore unlikely to pose a risk for vapor intrusion unless groundwater (including capillary fringe) comes in contact with a building foundation. For light nonaqueous‐phase liquid (LNAPL) hydrocarbon sources, more than 95% of benzene concentrations in soil gas are ≤30 µg/m³ for vertical screening distances of 13 ft (4 m) or greater. The screening distances derived from this analysis are markedly different from 30 to 100 ft (10 to 30 m) vertical distances commonly found cited in regulatory guidance, even with specific allowances to account for uncertainty in the hydrocarbon source depth or location. Consideration of these screening distances in vapor intrusion guidance would help eliminate unnecessary site characterization at petroleum UST sites and allow more effective and sustainable use of limited resources.  相似文献   

Obituary: Dorothy Urlich Cloher (1930–2011)     

Robin Kearns 《New Zealand geographer》2013,69(1):72-73

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Chronostratigraphy,composition, and origin of Ni‐rich spinel from the Late Eocene Fuente Caldera section in Spain: One impact or more?     

Eric Robin  Eustoquio Molina 《Meteoritics & planetary science》2006,41(8):1231-1248

Abstract— Here we report on the stratigraphic distribution and chemical composition of Ni‐rich spinel, a specific mineral tracer of meteorite impacts, in the Fuente Caldera section in Spain. A major peak in spinel abundance is observed in a biostratigraphic interval defined by the last occurrence of the planktic foraminifera Porticulasphaera semiinvoluta and the first occurrence of the planktic foraminifera Turborotalia cunialensis. Two other peaks of lower abundances are observed higher up in the same biostratigraphic interval, but geochemical considerations suggest that they likely originate from redeposition by turbiditic currents. Biostratigraphic correlations with the global stratotype section and point for the Eocene/Oligocene boundary of Massignano in Italy give an age of 35.4 ± 0.2 Ma (1s?) for the major peak. This age is indistinguishable from the age of the impact horizon at Massignano (35.5 ± 0.2 Ma) and within the age uncertainties for the Popigai (35.7 ± 0.2 Ma) and Chesapeake Bay (35.5 ± 0.5 Ma) craters. The Fuente Caldera spinel, as the Massignano spinel, is assumed to be a relic mineral of microkrystites, which are believed to derive from a unique source related to the Popigai impact crater. The morphologies and Cr compositions of the Fuente Caldera and Massignano spinel crystals are markedly different, however: the Fuente Caldera spinel occurs mostly as octahedral and skeletal crystals with 85% of the grains belonging to the Cr‐rich magnetite series and 15% to the Fe‐rich chromite series, whereas the Massignano spinel occurs mostly as dendritic crystals with 90% of the grains belonging to the Cr‐poor magnetite series. It is unlikely that these differences are the result of post‐depositional alteration processes because the compositions of the crystals, as well as their morphologies, are in general very similar to those reported for primary spinel crystals, i.e., spinel crystals present in meteorite fusion crust or synthetized from meteoritic material. In addition, spinel crystals have quite homogeneous compositions except for a few grains (<10%) showing Cr zonations, but these are assigned to primary crystallization processes. One possible explanation that is consistent with a single impact event producing spatial variations in spinel compositions and morphologies is that microkrystites are locally generated by the ablation in the atmosphere of impact debris. An alternative explanation is that Fuente Caldera and Massignano microkrystites derive from two closely spaced impact events, which however requires another, so‐far unknown source crater for microkrystites.  相似文献   

An improved description of soil hydraulic and thermal properties of arctic peatland for use in a GCM     

Robin L. Hall  Chris Huntingford  Richard J. Harding  Colin R. Lloyd  Peter M. Cox 《水文研究》2003,17(13):2611-2628

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Geochemical evidence of hydrothermal recharge in Lake Baringo,central Kenya Rift Valley     

Corinne Tarits  Robin W. Renaut  Jean‐Jacques Tiercelin  Alain Le Hriss  Jo Cotten  Jean‐Yves Cabon 《水文研究》2006,20(9):2027-2055

Lake Baringo, a freshwater lake in the central Kenya Rift Valley, is fed by perennial and ephemeral rivers, direct rainfall, and hot springs on Ol Kokwe Island near the centre of the lake. The lake has no surface outlet, but despite high evaporation rates it maintains dilute waters by subsurface seepage through permeable sediments and faulted lavas. New geochemical analyses (major ions, trace elements) of the river, lake, and hot spring waters and the suspended sediments have been made to determine the main controls of lake water quality. The results show that evaporative concentration and the binary mixing between two end members (rivers and thermal waters) can explain the hydrochemistry of the lake waters. Two zones are recognized from water composition. The southern part of the lake near sites of perennial river inflow is weakly influenced by evaporation, has low total dissolved species (TDS), and has a seasonally variable load of mainly detrital suspended sediments. In contrast, waters of the northern part of the lake show evidence for strong evaporation (TDS of up to eight times inflow). Authigenic clay minerals and calcite may be precipitating from those more concentrated fluids. The subaerial hot‐spring waters have a distinctive chemistry and are enriched in some elements that are also present in the lake water. Comparison of the chemical composition of the inflowing surface waters and lake water shows (1) an enrichment of some species (HCO₃^?, Cl, SO₄^2?, F, Na, B, V, Cr, As, Mo, Ba and U) in the lake, (2) a depletion in SiO₂ in the lake, and (3) a possible hydrothermal origin for most F. The rare earth element distribution and the F/Cl and Na/Cl ratios give valuable information on the rate of mixing of the river and hydrothermal fluids in the lake water. Calculations imply that thermal fluids may be seeping upward locally into the lake through grid‐faulted lavas, particularly south of Ol Kokwe Island. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Simulations of a late lunar-forming impact   总被引：3，自引：0，他引：3  

Robin M. Canup 《Icarus》2004,168(2):433-456

Results of about 100 hydrodynamic simulations of potential Moon-forming impacts are presented, focusing on the “late impact” scenario in which the lunar forming impact occurs near the very end of Earth's accretion (Canup and Asphaug, 2001, Nature 412, 708-712). A new equation of state is utilized that includes a treatment of molecular vapor (“M-ANEOS”; Melosh, 2000, in: Proc. Lunar Planet. Sci. Conf. 31st, p. 1903). The sensitivity of impact outcome to collision conditions is assessed, in particular how the mass, angular momentum, composition and origin (target vs. impactor) of the material placed into circumterrestrial orbit vary with impact angle, speed, impactor-to-target mass ratio, and initial thermal state of the colliding objects. The most favorable conditions for producing a sufficiently massive and iron-depleted protolunar disk involve collisions with an impact angle near 45 degrees and an impactor velocity at infinity <4 km/sec. For a total mass and angular momentum near to that of the current Earth-Moon system, such impacts typically place about a lunar mass of material into orbits exterior to the Roche limit, with the orbiting material composed of 10 to 30% vapor by mass. In all cases, the vast majority of the orbiting material originates from the impactor, consistent with previous findings. By mapping the end fate (escaping, orbiting, or in the planet) of each particle and the peak temperature it experiences during the impact onto the figure of the initial objects, it is shown that in the successful collisions, the impactor material that ends up in orbit is primarily that portion of the object that was heated the least, having avoided direct collision with the Earth. Using these and previous results as a guide, a continuous suite of impact conditions intermediate to the “late impact” (Canup and Asphaug, 2001, Nature 412, 708-712) and “early Earth” (Cameron, 2000, in: Canup, R.M., Righter, K. (Eds.), Origin of the Earth and Moon, pp. 133-144; 2001, Meteorit. Planet. Sci. 36, 9-22) scenarios is identified that should also produce iron-poor, ∼lunar-sized satellites and a system angular momentum similar to that of the Earth-Moon system. Among these, those that leave the Earth >95% accreted after the Moon-forming impact are favored here, implying a giant impactor mass between 0.11 and 0.14 Earth masses.  相似文献   

Reinterpretation of streamflow trends based on shifts in large‐scale atmospheric circulation     

Ming‐ko Woo  Robin Thorne  Kit K. Szeto 《水文研究》2006,20(18):3995-4003

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Placebound: Australian Feminist Geographies     

Robin Law 《New Zealand geographer》2002,58(2):80-81

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Fern species richness and abundance are indicators of climate change on high-elevation islands: evidence from an elevational gradient on Tahiti (French Polynesia)     

Robin Pouteau  Jean-Yves Meyer  Pauline Blanchard  Joel H. Nitta  Maruiti Terorotua  Ravahere Taputuarai 《Climatic change》2016,137(1-2):143-156

Coastal sector impacts from sea level rise (SLR) are a key component of the projected economic damages of climate change, a major input to decision-making and design of climate policy. Moreover, the ultimate global costs to coastal resources will depend strongly on adaptation, society’s response to cope with the local impacts. This paper presents a new open-source optimization model to assess global coastal impacts from SLR from the perspective of economic efficiency. The Coastal Impact and Adaptation Model (CIAM) determines the optimal strategy for adaptation at the local level, evaluating over 12,000 coastal segments, as described in the DIVA database (Vafeidis et al. 2006), based on their socioeconomic characteristics and the potential impacts of relative sea level rise and uncertain sea level extremes. A deterministic application of CIAM demonstrates the model’s ability to assess local impacts and direct costs, choose the least-cost adaptation, and estimate global net damages for several climate scenarios that account for both global and local components of SLR (Kopp et al. 2014). CIAM finds that there is large potential for coastal adaptation to reduce the expected impacts of SLR compared to the alternative of no adaptation, lowering global net present costs through 2100 by a factor of seven to less than $1.7 trillion, although this does not include initial transition costs to overcome an under-adapted current state. In addition to producing aggregate estimates, CIAM results can also be interpreted at the local level, where retreat (e.g., relocate inland) is often a more cost-effective adaptation strategy than protect (e.g., construct physical defenses).  相似文献