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21.
The contribution of terrigenous organic matter (TOM) to high molecular weight dissolved and particulate organic matter (POM) was examined along the salinity gradient of the Delaware Estuary. Dissolved organic matter (DOM) was fractionated by ultrafiltration into 1–30 kDa (HDOM) and 30 kDa–0.2 μm (VHDOM) nominal molecular weight fractions. Thermochemolysis with tetramethylammonium hydroxide (TMAH) was used to release and quantify lipids and lignin phenols. Stable carbon isotopes, fatty acids and lignin content indicated shifts in sources with terrigenous material in the river and turbid region and a predominantly algal/planktonic signal in the lower estuary and coastal ocean. Thermochemolysis with TMAH released significant amounts of short chain fatty acids (C9–C13), not seen by traditional alkaline hydrolysis, which appear to be associated with the macromolecular matrix. Lignin phenol distributions in HDOM, VHDOM and particles followed predicted sources with higher concentrations in the river and turbid region of the estuary and lower concentrations in the coastal ocean. TOM comprised 12% of HDOM within the coastal ocean and up to 73% of HDOM within the turbid region of the estuary. In the coastal ocean, TOM from high molecular weight DOM comprised 4% of total DOC. The annual flux of TOM from the Delaware Estuary to the coastal ocean was estimated at 2.0×1010 g OC year−1 and suggests that temperate estuaries such as Delaware Bay can be significant sources of TOM on a regional scale.  相似文献   
22.
Erosion of the southern Gold Coast beaches (SE Queensland, Australia) was exacerbated after the extension of the Tweed River training walls in the early 1960s. To achieve the objective of restoring and maintaining beach amenity, significant nourishment works have been undertaken in Coolangatta Bay over the past 30 years. Particularly, under the Tweed River Entrance Sand Bypassing Project (TRESBP) since 1995, a number of nourishment campaigns and the implementation of a permanent sand bypass system in 2001 have resulted in significant changes of Coolangatta Bay morphology. The present case study investigates the influence of both wave climate and nourishment works on the area extending from the updrift Snapper Rocks area to downdrift Kirra Beach. SWAN spectral wave model is implemented at Coolangatta Bay area and forced by the global wave model WW3 to estimate wave forcing and the potential natural longshore drift entering in Coolangatta. Specific transects extracted from accurate bathymetric surveys are used to investigate and quantify Coolangatta Bay sedimentation for the period 1987–2005. A network of Argus video stations provides high sample rate information on the shoreline evolution. Results show that, over the past 10 years, Coolangatta Bay has infilled rapidly. Sedimentation reached up to 6 m in some areas between 1995 and 2005, with beach width increasing by 200 m at Kirra Beach. Rapid seaward shoreline migration is consistent with the intense over-pumping of sand relative to the natural potential to move sand alongshore. The nourishment strategy used during this project has successfully delivered large amounts of sand to the southern Gold Coast embayment, although it has been up to now controversial from many community perspectives. The artificial sand bypassing process proved to be much more efficient than depositing the dredged sand in the nearshore area which requires a significant period of low energy condition in order for the deposited sediment to migrate shoreward and weld to the shore. This case study confirms that, when carefully undertaken, sand bypassing is a sustainable and flexible soft engineering approach which can work in concert with natural processes.  相似文献   
23.
Molecular organic biomarkers together with trace element composition were investigated in sediments east of Barrow Canyon in the western Arctic Ocean to determine sources and recycling of organic carbon in a continuum from the shelf to the basin. Algal biomarkers (polyunsaturated and short-chain saturated fatty acids, 24-methylcholesta-5,24(28)-dien-3β-ol, dinosterol) highlight the substantial contribution of organic matter from water column and sea-ice primary productivity in shelf environments, while redox markers such as acid volatile sulfide (AVS), Mn, and Re indicate intense metabolism of this material leading to sediment anoxia. Shelf sediments also receive considerable inputs from terrestrial organic carbon, with biomarker composition suggesting the presence of multiple pools of terrestrial organic matter segregated by age/lability or hydrodynamic sorting. Sedimentary metabolism was not as intense in slope sediments as on the shelf; however, sufficient labile organic matter is present to create suboxic and anoxic conditions, at least intermittently, as organic matter is focused towards the slope. Basin sediments also showed evidence for episodic delivery of labile organic carbon inputs despite the strong physical controls of water depth and sea-ice cover. Principal components analysis of the lipid biomarker data was used to estimate fractions of preserved recalcitrant (of terrestrial origin) and labile (of marine origin) organic matter in the sediments, with ranges of 12–79%, 14–45%, and 37–66% found for the shelf, slope, and basin cores, respectively. On average, the relative preserved terrestrial organic matter in basin sediments was 56%, suggesting exchange of organic carbon between nearshore and basin environments in the western Arctic.  相似文献   
24.
We describe a simple method for determining the time at which the meridian of a sub-auroral magnetic observatory crosses that of the Harang discontinuity—the separation of the eastward and westward electrojets which flow in the evening and morning sectors of the auroral oval. We then consider how this time, determined from examination of magnetograms from sub-auroral observatories varies with the dawn-dusk (y) component of the Interplanetary Magnetic Field. We find that the time at which the Harang discontinuity is identified in the Northern Hemisphere is earlier for By > 0 than the occasions when By < 0, and that the converse is observed in the Southern Hemisphere. Also we suggest that there is no significant seasonal variation in the relationship between the time of the discontinuity and By. The sense of the azimuthal shift of the auroral electrojet currents with changes in By is consistent with the theory of Cowley (1981). However, the magnitude of the observed shifts is approximately an order of magnitude greater than the theoretical predictions. We suggest that this difference between observation and theory arises from the use of a dipole magnetic field model at auroral zone latitudes in the theoretical estimation of azimuthal displacement.  相似文献   
25.
26.
Estimation of swell conditions in coastal regions is important for a variety of public, government, and research applications. Driving a model of the near-shore wave transformation from an offshore global swell model such as NOAA WaveWatch3 is an economical means to arrive at swell size estimates at particular locations of interest. Recently, some work (e.g. Browne et al. [Browne, M., Strauss, D., Castelle, B., Blumenstein, M., Tomlinson, R., 2006. Local swell estimation and prediction from a global wind-wave model. IEEE Geoscience and Remote Sensing Letters 3 (4), 462–466.]) has examined an artificial neural network (ANN) based, empirical approach to wave estimation. Here, we provide a comprehensive evaluation of two data driven approaches to estimating waves near-shore (linear and ANN), and also contrast these with a more traditional spectral wave simulation model (SWAN). Performance was assessed on data gathered from a total of 17 near-shore locations, with heterogenous geography and bathymetry, around the continent of Australia over a 7 month period. It was found that the ANNs out-performed SWAN and the non-linear architecture consistently out-performed the linear method. Variability in performance and differential performance with regard to geographical location could largely be explained in terms of the underlying complexity of the local wave transformation.  相似文献   
27.
Australian arid zone ephemeral rivers are typically unregulated and maintain a high level of biodiversity and ecological health. Understanding the ecosystem functions of these rivers requires an understanding of their hydrology. These rivers are typified by highly variable hydrological regimes and a paucity, often a complete absence, of hydrological data to describe these flow regimes. A daily time‐step, grid‐based, conceptual rainfall–runoff model was developed for the previously uninstrumented Neales River in the arid zone of northern South Australia. Hourly, logged stage data provided a record of stream‐flow events in the river system. In conjunction with opportunistic gaugings of stream‐flow events, these data were used in the calibration of the model. The poorly constrained spatial variability of rainfall distribution and catchment characteristics (e.g. storage depths) limited the accuracy of the model in replicating the absolute magnitudes and volumes of stream‐flow events. In particular, small but ecologically important flow events were poorly modelled. Model performance was improved by the application of catchment‐wide processes replicating quick runoff from high intensity rainfall and improving the area inundated versus discharge relationship in the channel sections of the model. Representing areas of high and low soil moisture storage depths in the hillslope areas of the catchment also improved the model performance. The need for some explicit representation of the spatial variability of catchment characteristics (e.g. channel/floodplain, low storage hillslope and high storage hillslope) to effectively model the range of stream‐flow events makes the development of relatively complex rainfall–runoff models necessary for multisite ecological studies in large, ungauged arid zone catchments. Grid‐based conceptual models provide a good balance between providing the capacity to easily define land types with differing rainfall–runoff responses, flexibility in defining data output points and a parsimonious water‐balance–routing model. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
28.
This paper describes surface hydrometeorological and spectral datasets collected from two tower sites located in the University of Melbourne's Dookie experimental farm, Victoria, Australia. The datasets were collected from different vegetation types including wheat, canola, and grazed pasture during the 2012, 2013, and 2014 cropping seasons. The dataset includes 30‐min frequency latent and sensible heat flux measurements and layer‐average soil moisture data at profile depths of 0–5, 0–30, 30–60, 60–90, and 90–120 cm. Air temperature, wind speed, wind direction, relative humidity, precipitation, and incoming and outgoing longwave and shortwave radiation data were also collected from two locations in the study area. The dataset described in this paper is available online.  相似文献   
29.
The Halley PACE HF radar has been operated in a new mode to provide very high time (10 s) and space (15 km) resolution measurements of the iono-spheric signatures of the cusp and the low-latitude boundary layer. The first data show that the iono-spheric signature of flux transfer events occur up to 300 km equatorward of regions showing the HF characteristics of the ionospheric cusp. Whilst larger flux transfer events are seen, on average, every 7 min, many much smaller and short-duration events have been identified. On one occasion DMSP data have been used to show that at least four flux transfer events are occurring simultaneously at the edge of the cusp over 2 h of MLT. There is strong, but not conclusive evidence, that reconnection at the magnetopause is both intermittent and patchy. These data also suggest that flux transfer events can be a significant contributor to the cross-polar cap potential.  相似文献   
30.
Data are presented for trace element concentrations determined in the <63 μm fraction of streambed sediment samples collected at 24 sites on the island of O‘ahu, Hawai‘i. Sampling sites were classified as urban, agricultural, mixed (urban/agricultural), or forested based on their dominant land use, although the mixed land use at selected sampling sites consisted of either urban and agricultural or forested and agricultural land uses. Forest dominated sites were used as reference sites for calculating enrichment factors.Trace element concentrations were compared to concentrations from studies conducted in the conterminous United States using identical methods and to aquatic-life guidelines provided by the Canadian Council of Ministers of the Environment. A variety of elements including Pb, Cr, Cu and Zn exceeded the aquatic-life guidelines in selected samples. All of the Cr and Zn values and 16 of 24 Cu values exceeded their respective guidelines. The potential toxicity of elements exceeding guidelines, however, should be considered in the context of strong enrichments of selected trace elements attributable to source rocks in Hawai‘i, as well as in the context of the abundance of fine-grained sediment in the streambed of O‘ahu streams.Statistical methods including cluster analysis, Kruskal–Wallis non-parametric test, correlation analysis, and principal component analysis (PCA) were used to evaluate differences and elucidate relationships between trace elements and sites. Overall, trace element distributions and abundances can be correlated to three principal sources of elements. These include basaltic rocks of the volcanic edifice (Fe, Al, Ni, Co, Cr, V and Cu), carbonate/seawater derived elements (Mg, Ca, Na and Sr), and elements enriched owing to anthropogenic activity (P, Sn, Cd, Sn, Ba and Pb). Anthropogenic enrichment gradients were observed for Ba, Cd, Pb, Sn and Zn in the four streams in which sediments were collected upstream and downstream.The findings of this study are generally similar to but differ slightly from previous work on sediments and suspended particulate matter in streams, from two urban watersheds of O‘ahu, Hawai‘i. Inter-element associations in the latter were often stronger and indicated a mixture of anthropogenic, agricultural and basaltic sources of trace elements. Some elements fell into different statistical categories in the two studies, owing in part to differences in study design and the hydrogeological constraints on the respective study areas.  相似文献   
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