Measurements of Reaction Coefficients of NO2 and HONO on Aerosol Particles     

Roy M. Harrison  Gareth M. Collins 《Journal of Atmospheric Chemistry》1998,30(3):397-406

The reaction coefficients of nitrogen dioxide and nitrous acid with monodisperse sodium chloride and ammonium sulphate aerosols have been measured in a flow reactor at atmospheric pressure. These experiments were performed at relative humidities above and below the deliquescence points of both aerosols (r.h. 50 and 85%) at 279 K. The results for NO₂ afford a reaction coefficient in the range (2.8–10) × 10^-4 and for HONO, (2.8–4.6) × 10^-3. For both species, there appears to be an enhancement of the reaction coefficient on sodium chloride aerosol at 50% r.h. The results are compared with reaction coefficients determined by other experimental methods. A good agreement is found for both gases between this method and the coated denuder method previously developed in our research laboratories (Msibi et al., 1993) and with the majority of other published data for NO₂. In the case of HONO, our estimate of reaction coefficient is smaller than, or at the lower limits of the ranges reported by other published studies.  相似文献   

Problems in determining paleointensities from very old rocks     

J.L. Roy 《Physics of the Earth and Planetary Interiors》1977,13(4):319-324

Polyphase magnetizations are not uncommon in old rocks. To obtain reliable paleointensities, these magnetizations need to be recognized and separated so that the paleointensity determination can be derived from one of the phases of magnetization. Some of the techniques used to detect and separate (and sometimes isolate) the different phases are described by means of a few examples. Special attention is given to the chemical remanent magnetization which can be found in both sedimentary and igneous rocks. It appears that a sedimentary rock near an igneous contact is the preferferred specimen for reliable paleointensity determinations.  相似文献   

Distribution of gold and rhenium between nickel-iron and silicate melts: implications for the abundance of siderophile elements on the Earth and Moon     

Kan Kimura  Roy S Lewis  Edward Anders 《Geochimica et cosmochimica acta》1974,38(5):683-701

The distribution equilibrium of Au and Re between nickel-iron and basaltic melts was studied at 1400–1600°C, using radioactive tracers. Metal/silicate distribution coefficients were 1–3 orders of magnitude higher than earlier estimates, as follows. Mauna Loa basalt—Fe₁₀Ni₉₀: D_Au = 3.3 × 10⁴, D_Re = (2.4?89) × 10⁴. Gorda Ridge basalt—Fe₁₀Ni₉₀: D_Au = (18?75) × 10⁴. Synthetic lunar basalt—Fe₇₀ Ni₃₀: D_Au≥ 2 × 10⁴, D_Re ≥ 2 × 10³. The experimental ΔG₁₈₀₀^° for the distribution of Au between nickel-iron and Mauna Loa basalt is ?40 kcal/mole, compared to a calculated value of about ?110 kcal/mole for a reaction involving simple Au³⁺ ions. Presumably the difference represents stabilization of Au(III) by complex formation with ligands such as Cl^?, H₂O, etc.Gold abundances in lunar basalts are roughly consistent with the measured D_Au, but those in terrestrial basalts are two orders of magnitude too high. This discrepancy may reflect complexing by volatiles in the Earth's upper lithosphere, as well as oxidative destruction of metal in the final stages of accretion. In the absence of a metal phase, siderophile trace elements would remain trapped in the upper mantle and crust.  相似文献   

Oblique propagation of ion acoustic shock waves in weakly and highly relativistic plasmas with nonthermal electrons and positrons     

M. G. Hafez  N. C. Roy  M. R. Talukder  M. Hossain Ali 《Astrophysics and Space Science》2016,361(9):312

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Insights on the events surrounding the final drainage of Lake Ojibway based on James Bay stratigraphic sequences     

M. Roy  F. Dell’Oste  J.J. Veillette  A. de Vernal  J.-F. Hélie  M. Parent 《Quaternary Science Reviews》2011,30(5-6):682-692

Deglaciation of the James Bay region was highly dynamic, with the occurrence of ice (Cochrane) readvances into glacial Lake Ojibway around final deglaciation time, which culminated with the drainage of Ojibway waters into Hudson Bay and subsequent incursion of the Tyrrell Sea at ～8 ka. Renewed interest on these events comes from the possible link between the drainage of the ice-dammed Lake Agassiz-Ojibway and a major climate deterioration known as the 8.2-ka cooling event. Recent glaciological modeling suggests that this drainage may have occurred subglacially, a mechanism that can accommodate more than one lake discharge, as suggested by marine records. The exact number and timing of drainage events, as well as location of the lake discharge pathway(s) remain, however, largely unconstrained. Here we focus on the events that led to the drainage of Lake Ojibway by documenting late-glacial sedimentary sequences located east of James Bay. Our investigations indicate that the deglacial sequence consists of a readvance till, extensive Ojibway rhythmites, and thick marine sediments. The glaciolacustrine and marine units are separated by a 60 cm-thick horizon composed of laminated silt beds containing rounded clay balls and disseminated clasts resulting from the abrupt drainage of the lake. Radiocarbon dating of marine fossils lying above the drainage horizon indicates that the glaciolacustrine episode ended around 8128–8282 cal yr BP. Micropaleontological analyses reveal that freshwater ostracods (Candona sp.) and marine microfossils (foraminifers, dinocysts) occur together in the upper part of the Ojibway sediments. Analysis of oxygen isotopes (δ¹⁸O) of ostracods and foraminifers originating from the same stratigraphic position show highly contrasting values that suggest possible subglacial exchanges between Lake Ojibway and Tyrrell Sea waters prior to the final drainage event. The complexity of the deglacial events is further indicated by radiocarbon dating of marine shells retrieved from a Cochrane till that suggests that the last ice readvance occurred almost simultaneously with the final lake discharge. These results bring additional constraints on the drainage mechanism of the coalesced Lake Agassiz-Ojibway and indicate that the James Bay region formed an important drainage pathway for meltwaters at the end of the last deglaciation.  相似文献   

Diurnal timing of warmer air under climate change affects magnitude,timing and duration of stream temperature change     

Mousa Diabat  Roy Haggerty  Steven M. Wondzell 《水文研究》2013,27(16):2367-2378

Stream temperature will be subject to changes because of atmospheric warming in the future. We investigated the effects of the diurnal timing of air temperature changes – daytime warming versus nighttime warming – on stream temperature. Using the physically based model, Heat Source, we performed a sensitivity analysis of summer stream temperatures to three diurnal air temperature distributions of +4 °C mean air temperature: i) uniform increase over the whole day, ii) warmer daytime and iii) warmer nighttime. The stream temperature model was applied to a 37‐km section of the Middle Fork John Day River in northeastern Oregon, USA. The three diurnal air temperature distributions generated 7‐day average daily maximum stream temperatures increases of approximately +1.8 °C ± 0.1 °C at the downstream end of the study section. The three air temperature distributions, with the same daily mean, generated different ranges of stream temperatures, different 7‐day average daily maximum temperatures, different durations of stream temperature changes and different average daily temperatures in most parts of the reach. The stream temperature changes were out of phase with air temperature changes, and therefore in many places, the greatest daytime increase in stream temperature was caused by nighttime warming of air temperatures. Stream temperature changes tended to be more extreme and of longer duration when driven by air temperatures concentrated in either daytime or nighttime instead of uniformly distributed across the diurnal cycle. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Impact of road‐generated storm runoff on a small catchment response     

Daniel W. Woldie  Roy C. Sidle  Takashi Gomi 《水文研究》2009,23(25):3631-3638

The impact of road‐generated runoff on the hydrological response of a zero‐order basin was monitored for a sequence of 24 storm events. The study was conducted in a zero‐order basin (C1; 0·5ha) with an unpaved mountain road; an adjacent unroaded zero‐order basin (C2; 0·2 ha) with similar topography and lithology was used to evaluate the hydrological behaviour of the affected zero‐order basin prior to construction of the road. The impact of the road at the zero‐order basin scale was highly dependent on the antecedent soil‐moisture conditions, total storm precipitation, and to some extent rainfall intensity. At the beginning of the monitoring period, during dry antecedent conditions, road runoff contributed 50% of the total runoff and 70% of the peak flow from the affected catchment (C1). The response from the unroaded catchment was almost insignificant during dry antecedent conditions. As soil moisture increased, the road exerted less influence on the total runoff from the roaded catchment. For very wet conditions, the influence of road‐generated runoff on total outflow from the roaded catchment diminished to only 5·4%. Both catchments, roaded and unroaded, produced equivalent amount of outflow during very wet antecedent conditions on a unit area basis. The lag time between the rainfall and runoff peaks observed in the unroaded catchment during the monitoring period ranged from 0 to 4 h depending on the amount of precipitation and antecedent conditions, owing mainly to much slower subsurface flow pathways in the unroaded zero‐order basin. In contrast, the lag time in the roaded zero‐order basin was virtually nil during all storms. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Analyzing Radar Meteor Trail Echoes using the Fresnel Transform Technique: A Signal Processing Viewpoint     

Arnab Roy  John F. Doherty  John D. Mathews 《Earth, Moon, and Planets》2007,101(1-2):27-39

Several techniques have been proposed for measuring speeds of meteoroids observed using radars. A recent technique involves the use of Fresnel transforms to accurately determine the speed of a meteoroid producing the trail. We follow a numerical modeling approach to analyze this technique in detail. Our studies indicate that high sensitivity to background noise levels might be a possible shortcoming of the Fresnel transform method. A matched filtering approach is presented as an alternative to alleviate this sensitivity to the noise problem. Performance of the two techniques is compared using numerical modeling and data from a 30 MHz radar.  相似文献   

Some bianchi type II universes with special free-gravitational fields     

S. R. Roy  S. K. Banerjee 《Astrophysics and Space Science》1990,167(1):81-91

The paper considers a homogeneous Bianchi type II universe. Under each of the conditionsC _hijk C ^hijk =0 and^* C _hijk C ^hijk =0 different types of models have been studied and their physical and kinematical properties have been discussed.  相似文献   

Line-of-Sight Anisotropies in the Cosmic Dawn and Epoch of Reionization 21-cm Power Spectrum     

Suman?MajumdarEmail authorView author&#;s OrcID profile  Kanan?K.?Datta  Raghunath?Ghara  Rajesh?Mondal  T.?Roy?Choudhury  Somnath?Bharadwaj  Sk.?Saiyad?Ali  Abhirup?Datta 《Journal of Astrophysics and Astronomy》2016,37(4):32

The line-of-sight direction in the redshifted 21-cm signal coming from the cosmic dawn and the epoch of reionization is quite unique in many ways compared to any other cosmological signal. Different unique effects, such as the evolution history of the signal, non-linear peculiar velocities of the matter etc. will imprint their signature along the line-of-sight axis of the observed signal. One of the major goals of the future SKA-LOW radio interferometer is to observe the cosmic dawn and the epoch of reionization through this 21-cm signal. It is thus important to understand how these various effects affect the signal for its actual detection and proper interpretation. For more than one and half decades, various groups in India have been actively trying to understand and quantify the different line-of-sight effects that are present in this signal through analytical models and simulations. In many ways the importance of this sub-field under 21-cm cosmology have been identified, highlighted and pushed forward by the Indian community. In this article, we briefly describe their contribution and implication of these effects in the context of the future surveys of the cosmic dawn and the epoch of reionization that will be conducted by the SKA-LOW.  相似文献