Ocean anoxic events in the mid-Cretaceous simulated by a 3-D biogeochemical general circulation model     

Kazuhiro Misumi  Yasuhiro Yamanaka 《Cretaceous Research》2008,29(5-6):893

The mid-Cretaceous is well known for its ocean anoxic events. The causal mechanisms are controversial: stagnant deepwater, high biological productivity in the surface waters, and other possibilities have been suggested. Our study simulated the mid-Cretaceous ocean, using general circulation models combined with a marine biogeochemical cycle model to explore the relationship between thermohaline circulation and biogeochemical cycles and investigate the causes of ocean anoxic events. The simulated thermohaline circulation shows an unsteady inactive state. Oxygen concentrations in the deepwater decrease under the inactive state, but a horizontal gradient develops, with higher oxygen concentrations in the Tethys and lower concentrations in eastern Panthalassa. This is not due to the different ages of the deepwater but rather to the differences in biological productivity in the surface water, meaning that the relationship between thermohaline circulation and biogeochemical cycles under the inactive state is different from that in the present ocean. In the standard simulation, assuming the present level of the total amount of phosphate in the ocean, 29% of the bottom water is anoxic. The experiments increasing the amount of phosphate show its high sensitivity for extending the anoxic region with global-scale anoxia simulated under the doubled amount of phosphate. The high amount of phosphate would be reasonable because the inactive state would induce an imbalance of phosphate between riverine input and sediment output. Therefore, both the inactive thermohaline circulation and the increase in the total amount of phosphate in the ocean induce the global-scale anoxic condition in the deepwater.  相似文献   

The influence of the Jahn–Teller effect at Fe<Superscript>2+</Superscript> on the structure of chromite at high pressure     

Atsushi?KyonoEmail author  Stephen?A.?Gramsch  Takamitsu?Yamanaka  Daijo?Ikuta  Muhtar?Ahart  Bj?rn?O.?Mysen  Ho-kwang?Mao  Russell?J.?Hemley 《Physics and Chemistry of Minerals》2012,39(2):131-141

The crystal structure of chromite FeCr₂O₄ was investigated to 13.7 GPa and ambient temperature with single-crystal X-ray diffraction techniques. The unit-cell parameter decreases continuously from 8.3832 (5) to 8.2398 (11) Å up to 11.8 GPa. A fit to the Birch–Murnaghan equation of state (EoS) based on the P–V data gives: K ₀ = 209 (13) GPa, K′ = 4.0 (fixed), and V ₀ = 588 (1) ų. The FeO₄ tetrahedra and CrO₆ octahedra are compressed isotropically with pressure with their Fe–O and Cr–O bond distances decreasing from 1.996 (6) to 1.949 (7) Å and from 1.997 (3) to 1.969 (7) Å, respectively. The tetrahedral site occupied by the Fe²⁺ cation is more compressible than the octahedral site occupied by the Cr³⁺ cation. The resulting EoS parameters for the tetrahedral and the octahedral sites are K ₀ = 147 (9) GPa, K′ = 4.0 (fixed), V ₀ = 4.07 (1) ų and K ₀ = 275 (24) GPa, K′ = 4.0 (fixed), V ₀ = 10.42 (2) ų, respectively. A discontinuous volume change is observed between 11.8 and 12.6 GPa. This change indicates a phase transition from a cubic (space group Fd-[`3]{\overline{3}} m) to a tetragonal structure (space group I4₁ /amd). At the phase transition boundary, the two Cr–O bonds parallel to the c-axis shorten from 1.969 (7) to 1.922 (17) Å and the other four Cr–O bonds parallel to the ab plane elongate from 1.969 (7) to 1.987 (9) Å. This anisotropic deformation of the octahedra leads to tetragonal compression of the unit cell along the c-axis. The angular distortion in the octahedron decreases continuously up to 13.7 GPa, whereas the distortion in the tetrahedron rises dramatically after the phase transition. At the pressure of the phase transition, the tetrahedral bond angles along the c-axis direction of the unit cell begin decreasing from 109.5° to 106.6 (7)°, which generates a “stretched” tetrahedral geometry. It is proposed that the Jahn–Teller effect at the tetrahedrally coordinated Fe²⁺ cation becomes active with compression and gives rise to the tetrahedral angular distortion, which in turn induces the cubic-to-tetragonal transition. A qualitative molecular orbital model is proposed to explain the origin and nature of the Jahn–Teller effect observed in this structure and its role in the pressure-induced phase transition.  相似文献   

A preliminary analysis of the formation of travertine and travertine cones in the Jifei hot spring,Yunnan, China   总被引：3，自引：2，他引：1  

Yaping Liu  Xun Zhou  Bin Fang  Haiyan Zhou  Tsutomu Yamanaka 《Environmental Earth Sciences》2012,66(7):1887-1896

The Jifei hot spring emerges in the form of a spring group in the Tibet–Yunnan geothermal zone, southwest of Yunnan Province, China. The temperatures of spring waters range from 35 to 81°C and are mainly of HCO₃–Na·Ca type. The total discharge of the hot spring is about 10 L/s. The spring is characterized by its huge travertine terrace with an area of about 4,000 m² and as many as 18 travertine cones of different sizes. The tallest travertine cone is as high as 7.1 m. The travertine formation and evolution can be divided into three periods: travertine terrace deposition period, travertine cone formation period and death period. The hydrochemical characteristics of the Jifei hot spring was analyzed and compared with a local non-travertine hot spring and six other famous travertine springs. The results indicate that the necessary hydrochemical conditions of travertine and travertine cones deposition in the Jifei area are (1) high concentration of HCO₃ ⁻ and CO₂; (2) about 52.9% deep source CO₂ with significantly high value; (3) very high milliequivalent percentage of HCO₃ ⁻ (97.4%) with not very high milliequivalent percentage of Ca²⁺ (24.4%); and (4) a large saturation index of calcite and aragonite of the hot water.  相似文献   

A geochemical study on mud volcanoes in the Junggar Basin, China     

Ryoichi Nakada  Yoshio TakahashiUrumu Tsunogai  Guodong ZhengHiroshi Shimizu  Keiko H. Hattori 《Applied Geochemistry》2011,26(7):1065-1076

A comprehensive study was performed to characterize, for the first time, the mud, water, and gases released from onshore mud volcanoes located in the southern margin of the Junggar Basin, northwestern China. Chemical compositions of mud, along with the geology of the basin, suggest that a source of the mud is Mesozoic or Cenozoic shale. Oxygen and H isotope compositions of the released water suggest a local meteoric origin. Combined with the positive Eu anomalies of the water, a large ¹⁸O shift of the water suggests extensive interaction with rocks. Gases discharged from the mud volcanoes are predominantly thermogenic hydrocarbons, and the high δ¹³C values (>+20‰ VPDB) for CO₂ gases and dissolved carbonate in muddy water suggest secondary methanogenesis with CO₂ reduction after oil biodegradation.The enrichments of Eu and ¹⁸O in water and the low thermal gradient of the area suggest that the water-rock interactions possibly occur deeper than 3670 ± 200 m. On the other hand, considering the relationship to the petroleum reservoir around the mud volcanoes, the depth of the gases can be derived from about 3600 m, a depth that is greater than that generally estimated for reservoirs whose gas is characterized by ¹³C-enriched CO₂. Oil biodegradation with CO₂ reduction likely occurs at a shallower depth along the seepage system of the mud volcano. The results contribute to the worldwide data set of gas genesis in mud volcanoes. Moreover, they further support the concept that most terrestrial mud volcanoes release thermogenic gas produced in very deep sediments and may be early indicators of oil biodegradation, an important problem in the petroleum industry.  相似文献   

Site effects by generalized inversion technique using strong motion recordings of the 2008 Wenchuan earthquake   总被引：3，自引：1，他引：2  

Yefei Ren  Ruizhi Wen  Hiroaki Yamanaka  Toshihide Kashima 《地震工程与工程振动(英文版)》2013,12(2):165-184

The generalized inversion of S-wave amplitude spectra from the free-field strong motion recordings of the China National Strong Motion Observation Network System (NSMONS) are used to evaluate the site effects in the Wenchuan area. In this regard, a total of 602 recordings from 96 aftershocks of the Wenchuan earthquake with magnitudes of M3.7-M6.5 were selected as a dataset. These recordings were obtained from 28 stations at a hypocenter distance ranging from 30 km to 150 km. The inversion results have been verified as reliable by comparing the site response at station 62WUD using the Generalized Inversion Technique (GIT) and the Standard Spectral Ratio method (SSR). For all 28 stations, the site predominant frequency F _p and the average site amplification in different frequency bands of 1.0–5.0 Hz, 5.0–10.0 Hz and 1.0–10.0 Hz have been calculated based on the inversion results. Compared with the results from the horizontal-to-vertical spectral ratio (HVSR) method, it shows that the HVSR method can reasonably estimate the site predominant frequency but underestimates the site amplification. The linear fitting between the average site amplification for each frequency band and the V _s20 (the average uppermost-20 m shear wave velocity) shows good correlation. A distance measurement called the asperity distance D _Aspt is proposed to reasonably characterize the source-to-site distance for large earthquakes. Finally, the inversed site response is used to identify the soil nonlinearity in the main shock and aftershocks of Wenchuan earthquake. In ten of the 28 stations analyzed in the main shock, the soil behaved nonlinearly, where the ground motion level is apparently beyond a threshold of PGA > 300 cm/s² or PGV > 20 cm/s, and only one station coded 51SFB has evidence of soil nonlinear behavior in the aftershocks.  相似文献   

Formation mechanism of the Weddell Sea Polynya and the impact on the global abyssal ocean     

Mikitoshi Hirabara  Hiroyuki Tsujino  Hideyuki Nakano  Goro Yamanaka 《Journal of Oceanography》2012,68(5):771-796

An experiment using a global ocean–ice model with an interannual forcing data set was conducted to understand the variability in the Southern Ocean. A winter-persisting polynya in the Weddell Sea (the Weddell Polynya, WP) was simulated. The process of WP breaking out after no-WP years was explored using the successive WPs found in the late 1950s. The results suggested that the anomalously warm deep water, saline surface layer, and a cyclonic wind stress over the Maud polynya region in early winter are essential for the surface layer to be dense enough to trigger deep convections which maintain a winter-persisting polynya; also, the reanalyzed surface air temperature (SAT) over the observed polynya region is too high for an ocean–ice model’s bulk formula to yield sufficient upward heat fluxes to induce WP formation. Therefore the Weddell Polynya, a series of WPs observed from satellite in the mid-1970s, is reproduced by replacing the SAT with a climatological one. Subsequent to the successive WP events, density anomalies excited in the Weddell Sea propagate northward in the Atlantic deep basins. The Antarctic Circumpolar Current (ACC) is enhanced through the increased meridional density gradient. The enhanced ACC and its meandering over the abyssal ridges excite buoyancy anomalies near the bottom at the southwestern end of the South Pacific basin. The buoyancy signals propagate northward and eventually arrive in the northern North Pacific.  相似文献   

Effects of physical changes in the ocean on the atmospheric pCO2: glacial-interglacial cycles     

Takasumi Kurahashi-Nakamura  Ayako Abe-Ouchi  Yasuhiro Yamanaka 《Climate Dynamics》2010,35(4):713-719

Based on LGM experiments with an atmosphere–ocean general circulation model, we systematically investigated the effects of physical changes in the ocean and induced biological effects as well on the low atmospheric CO₂ concentration (pCO₂) at the last glacial maximum (LGM). Numerical experiments with an oceanic carbon-cycle model showed that pCO₂ was lowered by ~30 ppm in the LGM ocean. Most of the pCO₂ reduction was explained by the change in CO₂ solubility in the ocean due to lower sea surface temperature (SST) during the LGM. Moreover, we found that SST changes in the high-latitude Northern Atlantic could explain more than one-third of the overall change in pCO₂ induced by global SST change, suggesting an important feedback between the Laurentide ice sheet and pCO₂.  相似文献   

Impacts of climate change on growth, migration and recruitment success of Japanese sardine (Sardinops melanostictus) in the western North Pacific     

Takeshi Okunishi  Shin-ichi Ito  Taketo Hashioka  Takashi T. Sakamoto  Naoki Yoshie  Hiroshi Sumata  Yumiko Yara  Naosuke Okada  Yasuhiro Yamanaka 《Climatic change》2012,115(3-4):485-503

We developed a multi-trophic level ecosystem model by coupling physical, biogeochemical-plankton and fish models. An oceanic general circulation model was coupled with a lower trophic level ecosystem model and a Japanese sardine migration model, and applied to the western North Pacific. To investigate the impact of global warming on the pelagic fish ecosystem, such as Japanese sardine, we conducted numerical experiments of growth and migration of Japanese sardine using physical fields for the present day and future with a global warming scenario simulated by a high-resolution climate model. The model results demonstrated possible impacts of global warming on the growth and migration pattern of Japanese sardine. The growths of fish in the current main spawning region under the global warming scenario were significantly slower than those under the present climate scenario. Fish in this region will be at disadvantage for their recruitment under the global warming condition. Prey conditions in the spawning region were projected not to markedly change under global warming condition while water temperature increased. As a result sardine spawning ground was projected to shift towards more north areas. During the feeding migration period in summer, geographical distribution of juveniles fish was projected to shift northwards by one to two degrees latitude under the global warming condition following the change in the distribution of optimal temperature region for feeding. However, this northwards shift of the optimal temperature for feeding was minimized adjacent to the western North Pacific by the cooler water supply by the intensification of the Oyashio.  相似文献   

Determination of Abundances of Fifty‐Two Elements in Natural Waters by ICP‐MS with Freeze‐Drying Pre‐concentration     

Que D. Hoang  Tak Kunihiro  Chie Sakaguchi  Masahiro Yamanaka  Hiroshi Kitagawa  Eizo Nakamura 《Geostandards and Geoanalytical Research》2019,43(1):147-161

To precisely determine the abundances of fifty‐two elements found within natural water samples, with mass fractions down to fg g^?1 level, we have developed a method which combines freeze‐drying pre‐concentration (FDC) and isotope dilution internal standardisation (ID‐IS). By sublimation of H₂O, the sample solution was reduced to < 1/50 of the original volume. To determine element abundance with accuracy better than 10%, we found that for solutions being analysed by mass spectrometry the HNO₃ concentration should be > 0.3 mol l^?1 to avoid hydrolysis. Matrix‐affected signal suppression was not significant for the solutions with NaCl concentrations lower than 0.2 and 0.1 cg g^?1 for quadrupole ICP‐MS and sector field ICP‐MS, respectively. The recovery yields of elements after FDC were 97–105%. The detection limits for the sample solutions prepared by FDC were ≤ 10 pg g^?1, except for Na, K and Ca. Blanks prepared using FDC were at pg‐levels, except for eleven elements (Na, Mg, Al, P, Ca, Mn, Fe, Co, Ni, Cu and Zn). The abundances of fifty‐two elements in bottled drinking water were determined from five different geological sources with mass fractions ranging from the fg g^?1 to μg g^?1 level with high accuracy.  相似文献   

Application of a feedforward neural network in the search for Kuroko deposits in the Hokuroku district, Japan   总被引：3，自引：0，他引：3  

Donald A. Singer  Ryoichi Kouda 《Mathematical Geology》1996,28(8):1017-1023

A feedforward neural network with one hidden layer and five neurons was trained to recognize the distance to kuroko mineral deposits. Average amounts per hole of pyrite, sericite, and gypsum plus anhydrite as measured by X-rays in 69 drillholes were used to train the net. Drillholes near and between the Fukazawa, Furutobe, and Shakanai mines were used. The training data were selected carefully to represent well-explored areas where some confidence of the distance to ore was assured. A logarithmic transform was applied to remove the skewness of distance and each variable was scaled and centered by subtracting the median and dividing by the interquartile range. The learning algorithm of annealing plus conjugate gradients was used to minimize the mean squared error of the scaled distance to ore. The trained network then was applied to all of the 152 drillholes that had measured gypsum, sericite, and pyrite. A contour plot of the neural net predicted distance to ore shows fairly wide areas of 1 km or less to ore; each of the known deposit groups is within the 1 km contour. The high and low distances on the margins of the contoured distance plot are in part the result of boundary effects of the contouring algorithm. For example, the short distances to ore predicted west of the Shakanai (Hanaoka) deposits are in basement. However, the short distances to ore predicted northeast of Furotobe, just off the figure, coincide with the location of the Nurukawa kuroko deposit and the Omaki deposit, south of the Shakanai-Hanaoka deposits, seems to be on an extension of short distance to ore contour, but is beyond the 3 km limit from drillholes. Also of interest are some areas only a few kilometers from the Fukazawa and Shakanai groups of deposits that are estimated to be many kilometers from ore, apparently reflecting the network's recognition of the extreme local variability of the geology near some deposits.  相似文献