Effect of the formation of EDTA complexes on the diffusion of metal ions in water   总被引：2，自引：0，他引：2  

Kenji Furukawa  Haruo Sato 《Geochimica et cosmochimica acta》2007,71(18):4416-4424

The diffusion coefficients of aquo metal ions (M^z+) and their EDTA complexes (M-EDTA^(z−4)+) were compared to understand the effect of EDTA complexation on the diffusion of metal ions by the diffusion cell method for Co²⁺, Ga³⁺, Rb⁺, Sr²⁺, Ag⁺, Cd²⁺, Cs⁺, Th⁴⁺, , and trivalent lanthanides. Most studies about ionic diffusion in water have dealt with free ion (hydrated ion). In many cases, however, polyvalent ions are dissolved as complexed species in natural waters. Hence, we need to study the diffusion behavior of complexes in order to understand the diffusion phenomenon in natural aquifer and to measure speciation by diffusive gradient in thin films (DGT), which requires the diffusion coefficients of the species examined. For many ions, the diffusion coefficients of M-EDTA^(z−4)+ are smaller than those of hydrated ions, but the diffusion coefficients of M-EDTA^(z−4)+ are larger than those of hydrated ions for ions with high ionic potentials (Ga³⁺ and Th⁴⁺). As a result, the diffusion coefficients of EDTA complexes are similar among various metal ions. In other words, the diffusion of each ion loses its characteristics by the complexation with EDTA. Although the difference is subtle, it was also found that the diffusion coefficients of EDTA complexes increase as the ionic potential increases, which can be explained by the size of the EDTA complex of each metal ion.  相似文献   

Distribution of glycerol dialkyl glycerol tetraethers, alkenones and polyunsaturated fatty acids in suspended particulate organic matter in the East China Sea     

Takahiro Nakanishi  Masanobu Yamamoto  Tomohisa Irino  Ryuji Tada 《Journal of Oceanography》2012,68(6):959-970

We investigated the spatial distribution of glycerol dialkyl glycerol tetraethers (GDGTs), alkenones, and polyunsaturated fatty acids in particulate organic matter collected at four sites along a depth transect from the continental shelf to the Okinawa Trough in the East China Sea during the spring bloom in 2008. The maximum alkenone concentration appeared in the top 25?m at all sites and the $ U_{37}^{{{\text{K}}'}} $ values were consistent with in situ water temperatures in the depth interval, suggesting that the alkenones were produced mainly in surface water. At the slope and shelf sites, GDGTs in the water column showed a concentration maximum at 74?C99?m depth, and the $ {\text{TEX}}_{86}^{\text{H}} $ agreed with in situ water temperatures, suggesting the in situ production of GDGTs in the depth interval. The low-salinity surface water above 20?m depth was characterized by low GDGT concentrations and low $ {\text{TEX}}_{86}^{\text{L}} $ -based temperatures, suggesting either the production of GDGTs in winter season or the lateral advection of GDGTs by an eastward current. At the slope and Okinawa Trough sites, TEX₈₆-based temperatures were nearly constant in the water column deeper than 300?m and corresponded to temperatures at the surface and near-surface waters rather than in situ temperatures. This observation is consistent with a hypothesis that Thaumarchaeota cells produced in surface waters are delivered to deeper water and also indicates that the residence time of suspended GDGTs in the deep-water column is large enough to mix the GDGTs produced in different seasons.  相似文献   

多传感器不同分辨率遥感数字图像的尺度转换   总被引：14，自引：0，他引：14  

布和敖斯尔  马建文  王勤学  金子正美  福山龙次 《地理学报》2004,59(1):101-110

针对日益增多的多传感器不同分辨率的遥感数字图像数据,提出其综合利用和尺度转换的有效方法。其中,作为尺度上推 (scaling-up) 技术,本研究选择IHS和小波分解变换两种数据融合方法,应用Landsat ETM+数据和IRS-1C数据进行了实例研究。发现: IHS方法操作简单,对两种待融合的图像的像元大小和像元数 (bit数) 的依赖不是很高,而对原始图像光谱信息的依赖很高,因此适用于不同传感器之间的数据融合上,其缺点就是不能够更多的保留原始多光谱数据的光谱信息。小波分解变换 (WD) 方法可以很好地保留多光谱传感器的所有光谱信息,但是在重采样中对两种待融合的图像的像元配准的要求很高,因此比较适合于对同一传感器的多光谱数据与全色光谱数据的融合上。作为尺度下退 (scaling-down) 技术,通过探讨将札幌野外实验站点数据镶嵌到高时间分辨率遥感图像的问题,提出像元级尺度扩展的具体操作方法和对NDVI图像进行扩展时出现混合像元的识别方法。应用AVHRR, MODIS, ETM+和ASTER的NDVI图像数据进行了像元尺度的扩展研究。得出: 对不同传感器的不同分辨率的数据之间进行像元级的尺度扩展后,能够较好地识别出不同地物的分布边界,较好的分辨混合像元,因此其结果可用于对不同地物分布特征的分类研究或土地覆盖变化中的时间序列变化的研究中。  相似文献   

Hydrocarbon-Degrading Bacteria and Paraffin from Polluted Seashores 9 Years after the Nakhodka Oil Spill in the Sea of Japan     

Kazue TAZAKI Hiroaki WATANABE Siti Khodijah CHAERUN Koichi SHIRAKI Ryuji ASADA 《《地质学报》英文版》2006,80(3):432-440

Pollution of petroleum hydrocarbons, in particular oil spills, has attracted much attention in the past and recent decades. Oil spills influence natural microbial community, and physical and chemical properties of the affected sites. The biodegradation of hydrocarbons by microorganisms is one of the primary ways by which oil spill is eliminated from contaminated sites. One such spill was that of the Russian tanker the Nakhodka that spilled heavy oil into the Sea of Japan on January 2, 1997. The impact of the Nakhodka oil spill resulted in a viscous sticky fluid fouling the shores and affected natural ecosystems. This paper describes the weathering of hydrocarbon-degrading bacteria （genus Pseudomonas） and crystallized organic compounds from the Nakhodka oil spill-polluted seashores after nine years. The Nakhodka oil has hardened and formed crust of crystalline paraffin wax as shown by XRD analysis （0.422, 0.377, and 0.250 nm d-spacing） in association with graphite and calcite after 9 years of bioremediation. Anaerobic reverse side of the oil crust contained numerous coccus typed bacteria associated with halite. The finding of hydrocarbon-degrading bacteria and paraffin wax in the oil crust may have a significant effect on the weathering processes of the Nakhodka oil spill during the 9- year bioremediation.  相似文献   

Eruptive history of Sundoro volcano,Central Java,Indonesia since 34 ka     

Oktory Prambada  Yoji Arakawa  Kei Ikehata  Ryuta Furukawa  Akira Takada  Haryo Edi Wibowo  Mitsuhiro Nakagawa  M. Nugraha Kartadinata 《Bulletin of Volcanology》2016,78(11):81

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Primordial and cosmogenic noble gases in the Sutter's Mill CM chondrite          下载免费PDF全文

Ryuji Okazaki  Keisuke Nagao 《Meteoritics & planetary science》2017,52(4):669-689

The Sutter's Mill (SM) CM chondrite fell in California in 2012. The CM chondrite group is one of the most primitive, consisting of unequilibrated minerals, but some of them have experienced complex processes occurring on their parent body, such as aqueous alteration, thermal metamorphism, brecciation, and solar wind implantation. We have determined noble gas concentrations and isotopic compositions for SM samples using a stepped heating gas extraction method, in addition to mineralogical observation of the specimens. The primordial noble gas abundances, especially the P3 component trapped in presolar diamonds, confirm the classification of SM as a CM chondrite. The mineralogical features of SM indicate that it experienced mild thermal alteration after aqueous alteration. The heating temperature is estimated to be <350 °C based on the release profile of primordial ³⁶Ar. The presence of a Ni‐rich Fe‐Ni metal suggests that a minor part of SM has experienced heating at >500 °C. The variation in the heating temperature of thermal alteration is consistent with the texture as a breccia. The heterogeneous distribution of solar wind noble gases is also consistent with it. The cosmic‐ray exposure (CRE) age for SM is calculated to be 0.059 ± 0.023 Myr based on cosmogenic ²¹Ne by considering trapped noble gases as solar wind, the terrestrial atmosphere, P1 (or Q), P3, A2, and G components. The CRE age lies at the shorter end of the CRE age distribution of the CM chondrite group.  相似文献   

Evidence for ocean water invasion into the Chicxulub crater at the Cretaceous/Tertiary boundary     

Kazuhisa Goto  Ryuji Tada  Eiichi Tajika  Timothy J. Bralower  Takashi Hasegawa  Takafumi Matsui 《Meteoritics & planetary science》2004,39(8):1233-1247

Abstract— The possibility of ocean water invasion into the Chicxulub crater following the impact at the Cretaceous/Tertiary boundary was investigated based on examination of an impactite between approximately 794.63 and 894.94 m in the Yaxcopoil‐1 (Yax‐1) core. The presence of cross lamination in the uppermost part of the impactite suggests the influence of an ocean current at least during the sedimentation of this interval. Abundant occurrence of nannofossils of late Campanian to early Maastrichtian age in the matrices of samples from the upper part of the impactite suggests that the carbonate sediments deposited on the inner rim margin and outside the crater were eroded and transported into the crater most likely by ocean water that invaded the crater after its formation. The maximum grain size of limestone lithics and vesicular melt fragments, and grain and bulk chemical compositions show a cyclic variation in the upper part of the impactite. The upward fining grain size and the absence of erosional contact at the base of each cycle suggest that the sediments were derived from resuspension of units elsewhere in the crater, most likely by high energy currents association with ocean water invasion.  相似文献   

Spatial variability of chemical tracers in surface snow along the traverse route from the coast to 1000 km inland at east Dronning Maud Land, Antarctica   总被引：1，自引：0，他引：1  

Toshitaka Suzuki  Yoshinori Iizuka  Teruo Furukawa  Kenichi Matsuoka  Kokichi Kamiyama  Okitsugu Watanabe 《极地研究(英文版)》2003,14(1)

1　IntroductionAntarcticicesheetisaburialgroundforatmosphericdeposition .Sincethereiscon tinuousinteractionbetweentheicesheetandtheatmosphere,variousatmosphericsub stancesareinjectedtotheicesheetsequentiallyintimeandspace.Therefore,verticalanalysesoftheicesheetprovideuswithinformationaboutpastclimaticchange (Delmas1 992 ;LegrandandMayewski 1 997)andhorizontalanalysesoftheicesheetprovideuswithknowledgeregardinglong rangetransportofairbornematerials (Kamiyamaetal.1 989;KreutzandMayewski 1 999)…  相似文献   

Co-accretion of the Earth-Moon system after the giant impact: reduction of the total angular momentum by lunar impact ejecta     

Ryuji Morishima  Sei-ichiro Watanabe 《Icarus》2004,168(1):60-79

Though the Moon is considered to have been formed by the so-called giant impact, the mass of the Earth immediately after the impact is still controversial. If the Moon was formed during the Earth's accretion, a subsequent accretion of residual heliocentric planetesimals onto the protoearth and the protomoon must have occurred. In this co-accretion stage, a significant amount of lunar-impact-ejecta would be ejected to circumterrestrial orbits, since the mean impact velocity of the planetesimals with the protomoon is much larger than the escape velocity of the protomoon. Orbital calculations of test particles ejected from the protomoon, whose semimajor axis is smaller than that of the present Moon, reveal that most of the particles escaping from the protomoon also escape from the Hill sphere of the protoearth and reduce the planetocentric angular momentum of the primordial Earth-Moon system. Using the results of the ejecta simulations, we investigate the evolution of the mass ratio and the total angular momentum (Earth's spin angular momentum + Moon's orbital angular momentum) of the Earth-Moon system during the co-accretion. We find that the mass of the protomoon is almost constant or rather decreases and the total angular momentum decreases significantly, if the random velocity of planetesimals is as large as the escape velocity of the protoearth. On the other hand, if the random velocity is the half of the escape velocity of the protoearth, the mass ratio is kept to be almost as large as the present value and the decrease of the total angular momentum is not so significant. Comparing with the results of giant impact simulations, we find that the mass of the protoearth immediately after the Moon-forming impact was 0.7-0.8 times the present value if the impactor-to-target mass ratio was 3:7, whereas the giant impact occurred almost in the end of the Earth's accretion if the impactor-to-target mass ratio was 1:9.  相似文献   

A multilayer model for thermal infrared emission of Saturn's rings: Basic formulation and implications for Earth-based observations     

Ryuji Morishima  Heikki Salo 《Icarus》2009,201(2):634-654

We present our new model for the thermal infrared emission of Saturn's rings based on a multilayer approximation. In our model, (1) the equation of classical radiative transfer is solved directly for both visible and infrared light, (2) the vertical heterogeneity of spin frequencies of ring particles is taken into account, and (3) the heat transport due to particles motion in the vertical and azimuthal directions is taken into account. We adopt a bimodal size distribution, in which rapidly spinning small particles (whose spin periods are shorter than the thermal relaxation time) with large orbital inclinations have spherically symmetric temperatures, whereas non-spinning large particles (conventionally called slow rotators) with small orbital inclinations are heated up only on their illuminated sides. The most important physical parameters, which control ring temperatures, are the albedo in visible light, the fraction of fast rotators (ffast) in the optical depth, and the thermal inertia. In the present paper, we apply the model to Earth-based observations. Our model can well reproduce the observed temperature for all the main rings (A, B, and C rings), although we cannot determine exact values of the physical parameters due to degeneracy among them. Nevertheless, the range of the estimated albedo is limited to 0-0.52±0.05, 0.55±0.07-0.74±0.03, and 0.51±0.07-0.74±0.06 for the C, B, and A rings, respectively. These lower and upper limits are obtained assuming all ring particles to be either fast and slow rotators, respectively. For the C ring, at least some fraction of slow rotators is necessary (ffast?0.9) in order for the fitted albedo to be positive. For the A and B rings, non-zero fraction of fast rotators (ffast?0.1-0.2) is favorable, since the increase of the brightness temperature with increasing solar elevation angle is enhanced with some fraction of fast rotators.  相似文献