Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)     

Jan Jehli?ka  Aleš Svatoš  Filip Uhlík 《Geochimica et cosmochimica acta》2003,67(8):1495-1506

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.  相似文献   

A Laboratory Model for the Flow in Urban Street Canyons Induced by Bottom Heating   总被引：2，自引：2，他引：2  

LIU Huizhi  LIANG Bin  ZHU Fengrong  ZHANG Boyin  SANG Jianguo 《大气科学进展》2003,20(4):554-564

Water tank experiments are carried out to investigate the convection flow induced by bottom heating and the effects of the ambient wind on the flow in non-symmetrical urban street canyons based on the PIV (Particle Image Visualization) technique. Fluid experiments show that with calm ambient wind,the flows in the street canyon are completely driven by thermal force, and the convection can reach the upper atmosphere of the street canyon. Horizontal and vertical motions also appear above the roofs of the buildings. These are the conditions which favor the exchange of momentum and air mass between the street canyon and its environment. More than two vortices are induced by the convection, and the complex circulation pattern will vary with time in a wider street canyon. However， in a narrow street canyon， just one vortex appears. With a light ambient wind, the bottom heating and the associated convection result in just one main vortex. As the ambient wind speed increases, the vortex becomes more organized and its center shifts closer to the leeward building.  相似文献   

三维重力内波和对流云街的启动机制   总被引：1，自引：0，他引：1       下载免费PDF全文

桑建国  谢安  张伯寅 《大气科学》1997,21(1):10-20

在一个下部为弱不稳定层、上部为稳定层的二层模式中，求解线性化的大气动力—热力学方程组，表明一个孤立山丘所引发的重力内波，在向下游传播过程中与边界层中对流相互作用，形成大气低层的涡漩活动，其图象与观测到的对流云街结构相似。  相似文献   

大气对流边界层中的涡漩结构   总被引：4，自引：1，他引：4  

桑建国 《气象学报》1997,55(3):285-296

大气边界层中存在尺度从几百米到几十公里的大涡漩运动。它们在边界层中动量、热量、水汽等垂直输送中起重要作用。作者从边界层中对流和上部稳定层中波动相互作用的观点，发展得出大涡结构的对流波动理论。根据此理论，大涡的波谱构成主要由上、下层大气中风向、风速、层结以及两层之间的温度跃变等因素决定。本文根据卫星云图和天气资料分析了一次冷空气爆发流经暖洋面上形成云街、对流单体以及它们之间的相互演化的过程，并用对流波动理论，依据各阶段的大气条件计算出它们的波数构成，并得出了垂直速度、辐合带、界面扰动的分布，解释了云街、对流单体的形成、结构及相互转化的原因  相似文献   

Aquatic chemistry: 3rd ed. by W. Stumm and J. J. Morgan. A Wiley-Interscience Publication, John Wiley & Sons, Inc., 1996, xvi + 1022p., US $29.95 (ISBN 0-471-51184-6)     

Tomas Pa?es 《Geochimica et cosmochimica acta》1996,60(24):5158-5159

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松辽盆地第三系可地浸砂岩型铀矿找矿方向     

桑吉盛 《铀矿地质》1997,13(5):264-269

松辽盆地是在兴蒙－吉黑海西褶皱带上发育起来的中、新生代大型陆相沉积盆地，基底主要为古生界浅变质岩，盖层主要是白垩系杂砂岩－有机页岩建造和新生界疏松碎屑堆积。笔者通过对前人资料分析研究后认为：松辽盆地具有良好的成矿地质条件和找矿前景；第三系是寻找可地浸砂岩型铀矿的主要目的层之一，层间氧化带型铀矿是主要寻找类型；盆地的西部和西南部是寻找可地浸砂岩型铀矿远景区。  相似文献   

Quantitative methods in the earth sciences     

A. F?rster  D. F. Merriam 《Mathematical Geology》1997,29(2):315

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Simulation of normal distributed smooth fields by Karhunen-Loéve expansion in combination with kriging     

Nils-Otto Kitterr?d  Lars Gottschalk 《Stochastic Hydrology and Hydraulics》1997,11(6):459-482

Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function. This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the 2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the predefined covariance functions are evaluated.  相似文献   

Structure and tectonics of convergent plate margins     

Aleš Špi?ák  Ond?ej ?adek  E.Robert Engdahl 《Physics of the Earth and Planetary Interiors》2004,141(4):241

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Influence of the zone of weakness on dip angle and shear heating of subducted slabs     

Martin Kuka?ka  Ctirad Matyska 《Physics of the Earth and Planetary Interiors》2004,141(4):243-252

We study the importance of the zones of weakness and the pattern of downgoing flow in steady-state models of subducting lithosphere, which interacts mechanically and thermally with the ambient mantle. The non-linear system of governing equations consists of (i) the momentum equation in stream function formulation and (ii) the steady-state heat transfer equation including conduction and advection of heat and dissipation. A finite element method has been applied to this system. We consider the viscosity to be a non-linear function of both the temperature and the stream function. In steady-state two-dimensional (2D) flow, the stream function isolines follow material trajectories. They are used to follow the top of the subducting slab, which because of its possible increase in water content, is assumed to have a lower viscosity. The zone of weakness has been thus obtained in the self-consistent fashion since the stream function as well as the temperature are the output from our modeling and no a priori assumptions about the shape of the bending lithosphere are taken into account. It was shown that several orders decrease of viscosity in the zone of weakness is required to obtain the dip angle of about 45°. If the decrease of viscosity is not sufficient enough, the subducted slab either sinks almost vertically or does not exhibit a plate-like behavior. We have also demonstrated that shear heating can unrealistically increase at the zone of weakness for fast subductions if decrease of viscosity is underestimated.  相似文献