Cooling rate variation in natural volcanic glasses from Tenerife,Canary Islands     

M. Wilding  Sharon Webb  D. Dingwell  Giray Ablay  Joan Marti 《Contributions to Mineralogy and Petrology》1996,125(2-3):151-160

 Silicate melts form glasses in a variety of geological environments. The relaxation (equilibration) of the frozen glass structure provides a means of investigating the quench rates of natural glasses, and this cooling history provides an important constraint for models of melt dynamics. Phonolite glasses from the central volcanic edifice of Tenerife, Canary Islands indicate a range of five orders of magnitude cooling rate, determined by modeling the relaxation of the structure-dependent property, enthalpy (H) across the glass transition. The relaxation of enthalpy is determined by heat capacity (c _p = ΔH/ΔT) measurement of natural glass samples by differential scanning calorimetry (DSC). Upon heating, the heat capacity curve in the vicinity of the glass transition has a geometry characteristic of the previous cooling rate. A series of thermal treatments applied to each individual sample results in a set of sample-specific parameters which are used to model the heat capacity curve of the naturally cooled glass. The cooling rate is then derived. The equivalence of shear and enthalpic relaxation enables the relaxation of enthalpy for these volcanic samples to be described by a general term for the evolution of fictive temperature. Quench rates for thirty-one glasses are calculated to be within the range 10°C s^–1 to 7°C per day. The cooling rates quoted are linear approximations across the glass transition. Within different volcanic facies cooling rates depend on several factors. The most rapidly cooled glasses occur where samples lose heat by radiation from the surface. Our analyses indicate that in certain environments, a natural annealing process results in slow quench rates. This is interpreted as either a slow initial cooling process or the reheating of a glass to an annealing temperature within the glass transition interval. The latter results in relaxation to a lower temperature structure. Controls on these processes include the initial temperature and dissipation of thermal energy from the volcanic body. Our results are consistent with an influence of volatiles on quench rates in volcanic bombs where glass adjacent to vesicular layers is relatively rapidly quenched. We interpret this as a rapid quench rate frozen into the glass resulting from a change in viscosity due to volatile degassing. In lava flows, the conduction of heat from the hot flow interior controls the cooling process and diminishes the effect of volatile exsolution. Relaxation geospeedometry can be applied to glass samples from a variety of geological environments where cooling rates cannot be measured directly. Such measurements provide a means of determining cooling rates for a variety of volcanic processes, an independent calibration for existing temperature and time data and a means for testing cooling-rate-dependent models. Received: 9 January 1996 / Accepted: 13 May 1996  相似文献   

Ostracode δ18O and δ13C evidence of Holocene environmental changes in the sediments of two Minnesota lakes     

Antje Schwalb  Sharon M. Locke  Walter E. Dean 《Journal of Paleolimnology》1995,14(3):281-296

Stable oxygen and carbon isotope geochemistry of ostracode valves, abundance and assemblages of ostracode species, and sedimentological parameters from cores taken in Williams and Shingobee Lakes in north-central Minnesota show changes in climatic and hydrologic history during the Holocene. Isotopic records are consistent with the following scenario:Before 9800 yr B.P. the two lakes were connected. Increasing evaporation through the jack/red pine period (9800-7700 yr B.P.) led to lower lake levels, leaving small separated basins. The prairie period (7700-4000 yr B.P.) reflects high aridity, and lake levels reached low stands shortly before 6500 yr B.P. Low lake levels are associated with groundwater discharge between 6500 and 6000 yr B.P. The hardwood period (4000-3200 yr B.P.) corresponds to long cold winters and warm to cool summers with lower evaporation rates and slower sedimentation. During the white pine period (<3200 yr B.P.) evaporation increased and/or precipitation shifted to the summer months.These changes can be related to shifting atmospheric circulation patterns. Zonal flow was probably dominant during the early Holocene until the end of the prairie period (c. 4000 yr B.P.). During the hardwood period a combination of zonal and meridional flow patterns caused long and cold winters and wetter summers. During the white pine period wintners were shorter and the meridional flow pattern more significant. Today meridional flow dominates the circulation pattern.This is the 6th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.  相似文献   

美国Paradox盆地盐构造新生代的拉伸活化     

戈红星  MOSHER Sharon 《高校地质学报》2008,14(1):49-63

美国科罗拉多高原Paradox盆地中的裂口盐墙和盐背斜,主要是在古生界和中生界沉积物的差异负载作用下发育起来的。盐构造顶部的平缓褶皱,通常被认为是晚白垩纪至古新世拉腊米挤压运动的产物,而其脊顶地堑与山谷,则被认为是挤压后的松弛拉伸及盐溶作用所造成的。基于野外调查、物理模拟以及现代盐构造学理论,研究认为这些平缓褶皱和脊顶地堑,主要是新生代始新世至渐新世北北东向区域拉伸作用的产物。因为岩盐较其围岩软弱,拉伸形变主要集中在早先形成的盐墙、盐背斜及其较薄的顶板中,使盐构造发生活化并形成新的拉伸构造。顶板中的拉伸构造主要包括正断层、地堑、断层滑移(断滑)褶皱以及滚动褶皱。由于区域拉伸方向斜交盐构造走向,断层分布多呈羽列状。在母盐层较厚地区,拉伸使盐刺穿在正断层之下次动上升;而在母盐层较薄地区,拉伸使盐刺穿下降。在初始盐刺穿较高地区,盐构造的侧翼下降;而在初始盐刺穿较低地区,盐构造整体下降。拉伸使盐刺穿变宽,脊顶地堑下沉,形成拉伸型下降盐刺穿特征性的尖角盐体构造。局部地区,盐体从破碎的顶板间溢出,覆盖了下沉的脊顶地堑。  相似文献   

Interactive Effects of UV-B Radiation and Chemical Contamination on Physiological Parameters in the Lichen Ramalina lacera     

Jacob Garty  Tal Levin  Haya Lehr  Sharon Tomer  Ayala Hochman 《Journal of Atmospheric Chemistry》2004,49(1-3):267-289

To assess the impact of ultraviolet B (UV-B) radiation under laboratory conditions on lichens from different biomonitoring sites, thalli of the lichen Ramalina lacera were transplanted from a clean air site to nine different polluted sites in Israel. Our objective was to determine the probability of synergistic/antagonistic effects on physiological parameters by considering two stressors: chemical contamination and UV-B. Exposure to both airborne pollutants in the field and subsequent UV-B radiation in the laboratory which led to a severe disintegration of cell membranes, followed by electrolyte leakage, indicate the probability of a synergistic effect. The impairment of the potential quantum yield of electron transfer through photosystem II (PSII) of photosynthesis indicated by a significant decrease of the ratio F_v/F_m, further demonstrated the synergistic effect of both chemical contamination and UV-B radiation. Besides enlarged amounts of stress-ethylene in lichens at contaminated sites, the reduced levels of ethylene production upon UV-B radiation in the present study suggest the likelihood of an antagonistic effect of xenobiotic elements and UV-B radiation as a result of an impaired ethylene-producing system.  相似文献   

A four-dimensional validation of a coupled physical–biological model of the Arabian Sea     

Raleigh R. Hood  Kevin E. Kohler  Julian P. McCreary  Sharon L. Smith 《Deep Sea Research Part II: Topical Studies in Oceanography》2003,50(22-26):2917

In this paper, we use a coupled biological/physical model to synthesize and understand observations taken during the US JGOFS Arabian Sea Process Study (ASPS). Its physical component is a variable-density, -layer model; its biological component consists of a set of advective–diffusive equations in each layer that determine nitrogen concentrations in four compartments, namely, nutrients, phytoplankton, zooplankton, and detritus. Solutions are compared to time series and cruise sections from the ASPS data set, including observations of mixed-layer thickness, chlorophyll concentrations, inorganic nitrogen concentrations, particulate nitrogen export flux, zooplankton biomass, and primary production. Through these comparisons, we adjust model parameters to obtain a “best-fit” main-run solution, identify key biological and physical processes, and assess model strengths and weaknesses.Substantial improvements in the model/data comparison are obtained by: (1) adjusting the turbulence-production coefficients in the mixed-layer model to thin the mixed layer; (2) increasing the detrital sinking and remineralization rates to improve the timing and amplitude of the model's export flux; and (3) introducing a parameterization of particle aggregation to lower phytoplankton concentrations in coastal upwelling regions.With these adjustments, the model captures many key aspects of the observed physical and biogeochemical variability in offshore waters, including the near-surface DIN and phytoplankton P concentrations, mesozooplankton biomass, and primary production. Nevertheless, there are still significant model/data discrepancies of P for most of the cruises. Most of them can be attributed to forcing or process errors in the physical model: inaccurate mixed-layer thicknesses, lack of mesoscale eddies and filaments, and differences in the timing and spatial extent of coastal upwelling. Relatively few are clearly related to the simplicity of the biological model, the model's overestimation of coastal P being the most obvious example. Overall, we conclude that future efforts to improve biogeochemical models of the Arabian Sea should focus on improving their physical component, ensuring that it represents the ocean's physical state as closely as possible. We believe that this conclusion applies to coupled biogeochemical modeling efforts in other regions as well.  相似文献   

Debris flow magnitude,frequency, and precipitation threshold in the eastern North Cascades,Washington, USA     

Riedel  Jon L.  Sarrantonio  Sharon M. 《Natural Hazards》2021,106(3):2519-2544

We examine the magnitude, frequency, and precipitation threshold of the extreme flood hazard on 37 low-order streams in the lower Stehekin River Valley on the arid eastern slope of the North Cascades. Key morphometric variables identify the magnitude of the hazard by differentiating debris flood from debris flow systems. Thirty-two debris flow systems are fed by basins?<?6 km² and deposited debris cones with slopes?>?10°. Five debris flood systems have larger drainage areas and debris fans with slopes 7–10°. The debris flood systems have Melton ruggedness ratios from 0.42–0.64 compared to 0.78–3.80 for debris flow basins. We record stratigraphy at seven sites where soil surfaces buried by successive debris flows limit the age of events spanning 6000 years. Eighteen radiocarbon ages from the soils are the basis for estimates of a 200 to1500-year range in recurrence interval for larger debris flows and a 450?±?50-year average. Smaller events occur approximately every 100 years. Fifteen debris flows occurred in nine drainage systems in the last 15 years, including multiple flows on three streams. Summer storms in 2010 and 2013 with peak rainfall intensities of 7–9 mm/h sustained for 8–11 h triggered all but one flow; the fall 2015 event on Canyon Creek occurred after 170 mm of rain in 78 h. A direct link between fires and debris flows is unclear because several recent debris flows occurred in basins that did not burn or burned at low intensity, and basins that burned at high intensity did not carry debris flows. All but one of the recent flows and fires occurred on the valley’s southwest-facing wall. We conclude that fires and debris flows are linked by aspect at the landscape scale, where the sunny valley wall has flashy runoff due to sparse vegetation from frequent fires.

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Non-extensivity analysis of seismicity within four subduction regions in Mexico     

Sharon M. Valverde-Esparza  Alejandro Ramírez-Rojas  E. Leticia Flores-Márquez  Luciano Telesca 《Acta Geophysica》2012,60(3):833-845

The non-extensivity approach based on the Tsallis entropy has been applied to seismicity that occurred from 1988 to 2010 along the Mexican South Pacific coast. We analyzed four different regions, characterized by different subduction patterns. Our results indicate a possible correlation between the non-extensive parameters and the seismicity pattern associated with the inclination angle of each subduction region.  相似文献   

An empirical model of water quality for use in rapid management strategy evaluation in Southeast Queensland, Australia     

de la Mare W  Ellis N  Pascual R  Tickell S 《Marine pollution bulletin》2012,64(4):704-711

Simulation models have been widely adopted in fisheries for management strategy evaluation (MSE). However, in catchment management of water quality, MSE is hampered by the complexity of both decision space and the hydrological process models. Empirical models based on monitoring data provide a feasible alternative to process models; they run much faster and, by conditioning on data, they can simulate realistic responses to management actions. Using 10 years of water quality indicators from Queensland, Australia, we built an empirical model suitable for rapid MSE that reproduces the water quality variables' mean and covariance structure, adjusts the expected indicators through local management effects, and propagates effects downstream by capturing inter-site regression relationships. Empirical models enable managers to search the space of possible strategies using rapid assessment. They provide not only realistic responses in water quality indicators but also variability in those indicators, allowing managers to assess strategies in an uncertain world.  相似文献   

Paleoclimate of Southwestern China for the Past 50,000 yr Inferred from Lake Sediment Records   总被引：5，自引：0，他引：5  

David A. Hodell  Mark Brenner  Sharon L. Kanfoush  Jason H. Curtis  Joseph S. Stoner  Song Xueliang  Wu Yuan  Thomas J. Whitmore 《Quaternary Research》1999,52(3):369

Long sediment cores (12.5 and 13.5 m) from two lakes in Yunnan Province were used to infer the paleoclimate of southwest China over the past 50,000 yr. During the Holocene and marine isotope stage (MIS 3), bio-induced carbonate precipitation and organic matter (OM) production was high, suggesting warm temperatures and high primary productivity. In contrast, sediment inorganic carbon (IC) and organic carbon (OC) concentrations were low in last glacial deposits from 38,000 to 12,000 cal yr B.P., indicating cool temperatures and low productivity. The 50,000-yr record has alternating peaks of carbonate and coarse-grain (>38 μm) quartz that reflect warm, moist interglacial or interstadial conditions alternating with cold, dry glacial or stadial conditions, respectively. Spectral analysis of the carbonate and quartz signals reveals power concentrated at periods of 7200 and 8900 cal yr, respectively, that may reflect a nonlinear climate response to precessional forcing at a time of reduced eccentricity modulation (McIntyre and Molfino, 1996). Oxygen isotope values of calcite from Yunnan lake cores indicate the summer monsoon was weak during the last glaciation from 50,000 to 12,000 cal yr B.P. The summer monsoon intensified between 12,000 and 8000 cal yr B.P., but weakened gradually in response to insolation forcing during the mid-to-late Holocene. Our results support the Overpeck et al. (1996) model that posits a weak summer monsoon during the last glaciation that responded nonlinearly to insolation forcing when its intensity was affected by Eurasian snow cover and ice-sheet extent. The summer monsoon intensified and responded linearly to seasonal insolation forcing in the Holocene when ice volume diminished.  相似文献   

Antioxidant responses to polycyclic aromatic hydrocarbons and organochlorine pesticides in green-lipped mussels (Perna viridis): do mussels "integrate" biomarker responses?   总被引：1，自引：0，他引：1  

Richardson BJ  Mak E  De Luca-Abbott SB  Martin M  McClellan K  Lam PK 《Marine pollution bulletin》2008,57(6-12):503-514

Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCs) are generally present in the marine environment in complex mixtures. The ecotoxicological nature of contaminant interactions, however, is poorly understood, with most scientific observations derived from single contaminant exposure experiments. The objective of this experiment was to examine dose-response relationships between antioxidant parameters and body contaminant levels in mussels exposed to different exposure regimes under laboratory conditions. Accordingly, the green-lipped mussel, Perna viridis, was challenged with a mixture of PAHs (anthracene, fluoranthene, pyrene, benzo[a]pyrene) and OC pesticides (alpha-HCH, aldrin, dieldrin, p,p'-DDT) over a 4 week period. Contaminants were delivered under four different dosing regimes, with all treatments receiving the same total contaminant load by the end of the exposure period. Antioxidant biomarkers were measured after 1, 2, 3 and 4 weeks, including glutathione (GSH), gluathione-S-transferase (GST), superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GPx), glutathione reductase (GR) and lipid peroxidase (LPO). GST and CAT were induced in hepatic tissues in most of the exposure regimes, with the majority of significant induction occurring in a constant exposure regime and a two-step alternate exposure regime. Significant differences among exposure regimes were detected in the body burden of contaminants after 28 days. Hepatic CAT and GSH are proposed as potentially useful biomarkers as they showed good correlation with target contaminants and were not readily affected by different dosing patterns.  相似文献