Evaluation of biogeochemical prospecting methods in the search for sulfide deposits in the Appalachian piedmont, Virginia, U.S.A.     

Steven W. Leavitt  H.Grant Goodell 《Journal of Geochemical Exploration》1979,11(1):89-100

Soil and stream sediment sampling have been the primary geochemical exploration tools in the Appalachian piedmont to date. However, the great thicknesses of soil and saprolite found in the region coupled with the dense vegetation frequently encountered favor biogeochemistry as an alternative or supplemental method since deep-rooted plants sample closer to bedrock. To evaluate this method, an orientation survey was performed in which soils and vegetation at 17 sites north of Mineral, Virginia, were sampled and analyzed for Ag, Cd, Cu, Pb and Zn. The traverse included stations over the host rocks of massive sulfide mineralization, as well as over apparent “barren” country rock. Samples were analyzed by atomic absorption spectrophotometry using standard digestion and analytical techniques.Both A- and B-horizon soil metals generally appear to be reliable indicators of mineralization, with soils developed over sulfides showing up to three-fold enrichment in metal content relative to the average soils developed on the country rock. Correlation of metal concentrations in vegetation to soil metal concentrations reveal plant concentrations expressed on a dry-weight basis correlate stronger and more frequently to soil metals than do ash-weight concentrations. Copper shows some promise in selected organs and species, Ag appears fair but data are limited to one organ of one species, and plant Pb seems totally unresponsive to soil metal concentrations perhaps because foliar absorption is an important plant uptake mechanism here. However, Zn and Cd in organs of the oak group, especially mature leaves and twigs of the current year's growth show the greatest promise as prospecting tools. They correlate well with soil metals and when compared directly to the geology they reliably reflect mineralization. Although results using White oak were slightly less profound than those obtained from the Black-Red oak group, White oak may be preferred as it is a single, more widespread, easily-identifiable species. Copper and especially Zn although essential elements to plants, do not appear to be “difficult” elements for biogeochemical prospecting in the Appalachian piedmont.  相似文献   

Rare earth elements in Huronian (Lower Proterozoic) sedimentary rocks: Composition and evolution of the post-Kenoran upper crust     

Scott M McLennan  B.J Fryer  Grant M Young 《Geochimica et cosmochimica acta》1979,43(3):375-388

The Huronian sequence (Lower Proterozoicl. north of Lake Huron, contains tillites and abundant fine-grained sedimentary rocks. Analyses of rare earth elements (REE) in the matrix of tillite samples from the Gowganda Formation (~ 2.3 Gal is considered to be a reasonable estimate of upper crustal REE abundances for the region north of Lake Huron at the time of Gowganda deposition. The average is characterized by a moderately steep pattern (σLREEσHREE = 9.1) and a slight negative europium anomaly ($\text{Eu}\text{Eu1}\text{= 0.89}$). This pattern is similar to estimates of the composition of the surface of the Canadian Shield and is intermediate between estimates of typical Archean and post-Archean sedimentary rocks. REE patterns for framework granitoid clasts from the tillite suggest that K-rich granites, which were apparently unimportant in the formation of Archean sedimentary rocks, were abundant in the source regions of the Gowganda Formation. This may explain the intermediate nature of the Gowganda pattern.Comparison of the tillites and associated Gowganda mudstones suggests that previous estimates of upper crustal REE abundances, which were based on the analyses of fine-grained sedimentary rocks, may be systematically high. Relative distributions, however, are the same.Analyses of mudstones from the McKim. Pecors. Serpent Gowganda Lorrain and Gordon Lake Formations suggest rapid evolution in the composition of the exposed upper crust at the close of the Kenoran orogeny. REE patterns at the base of the Huronian are similar to typical Archean sedimentary rocks. REE characteristics change up section: patterns at the top resemble typical post-Archean sedimentary rocks.It is inferred that an essentially episodic change from an early exposed upper crust dominated by a tonalite-greenstone suite to one approximating granodioritic composition is recorded in Huronian sedimentary rocks. A deviation from the evolutionary trend of the Huronian, documented in the Gowganda Formation, may be related to the glacial origin of the Gowganda.  相似文献   

Variations in Cr content of magnetite from the upper zone of the Bushveld Complex — evidence for heterogeneity and convection currents in magma chambers     

R. Grant Cawthorn  T.S. McCarthy 《Earth and Planetary Science Letters》1980,46(3):335-343

Mineral separates of pure magnetite from the upper zone of the Bushveld Complex have been analysed for Cr. Detailed sampling within layers of massive magnetite indicates that the Cr content frequently shows an extremely rapid but regular depletion with height (for example, by a factor of seven over 85 cm of massive magnetite), with sudden reversals of variable magnitude. Rayleigh Law fractionation, from a homogeneous liquid of the volume now seen as cumulate rocks overlying the sampled horizons, cannot satisfy these observed concentration gradients. A diffusion-controlled crystallization model is preferred. In another vertical section of massive magnetite the Cr content remains constant with increasing height, and is interpreted as indicating a steady state situation where the rate of depletion of Cr by magnetite fractionation is balanced by the rate of diffusive addition into the crystallization zone. Reversals in Cr content sometimes occur in the middle of pure magnetite layers and are attributed to convective overturn in the magma chamber. These results provide geochemical support for the model of convection cells and bottom crystallization in large magma reservoirs as proposed by Jackson [20]. Depletion of compatible elements in this bottom layer causes chemical inhomogeneity in the magma.Sections, composed of several layers of magnetite sandwiched between magnetite-bearing gabbro, have also been studied. In one case, a steady decrease in Cr content with increasing height in the separated magnetite was observed; in another, several irregular reversals were found. There appears to be no systematic relation between convection cycles, the depletion in Cr and the formation of pure magnetite layers, indicating that the chemical composition of the magma does not control the production of monomineralic layers. The fluctuating pressure model envisaged by Cameron [16] for the formation of such layers is entirely consistent with these data.  相似文献   

Determination of predevelopment denudation rates of an agricultural watershed (Cayaguás River, Puerto Rico) using in-situ-produced Be in river-borne quartz     

Erik Thorson Brown  Robert F. Stallard  Matthew C. Larsen  Didier L. Bourls  Grant M. Raisbeck  Franoise Yiou 《Earth and Planetary Science Letters》1998,160(3-4):723-728

Accurate estimates of watershed denudation absent anthropogenic effects are required to develop strategies for mitigating accelerated physical erosion resulting from human activities, to model global geochemical cycles, and to examine interactions among climate, weathering, and uplift. We present a simple approach to estimate predevelopment denudation rates using in-situ-produced cosmogenic ¹⁰Be in fluvial sediments. Denudation processes in an agricultural watershed (Cayaguás River Basin, Puerto Rico) and a matched undisturbed watershed (Icacos River Basin) were compared using ¹⁰Be concentrations in quartz for various size fractions of bed material. The coarse fractions in both watersheds bear the imprint of long subsurface residence times. Fine material from old shallow soils contributes little, however, to the present-day sediment output of the Cayaguás. This confirms the recent and presumably anthropogenic origin of the modern high denudation rate in the Cayaguás Basin and suggests that pre-agricultural erosional conditions were comparable to those of the present-day Icacos.  相似文献   

The isotopic composition of strontium and oxygen in lavas from St. Helena,South Atlantic     

Norman K. Grant  James L. Powell  Flora R. Burkholder  John V. Walther  Max L. Coleman 《Earth and Planetary Science Letters》1976,31(2):209-223

Strontium and oxygen isotope measurements on the alkali basalt-trachyte-phonolite suite of St. Helena show that some of the late-fractionated rocks are enriched in ⁸⁷Sr and depleted in ¹⁸O relative to the older basalts. The data rule out both the formation of the late-fractionated rocks by the partial melting of hydrothermally altered oceanic crust and the contamination of the volcanic rocks by oceanic sediment. It also appears to be incompatible with models based either on the melting of previously fractionated and crystallized liquids in the volcanic pile, or the long-term fractionation of lavas over several millions of years in a sub-volcanic magma chamber.It is concluded that hydrothermal interaction with meteoric water is the most important cause of the ¹⁸O depletion. If the interaction occurred at widely differing temperatures, and involved meteoric and seawaters, it might conceivably have caused both the oxygen and strontium isotope heterogeneities.  相似文献   

Photogrammetric survey of the structural geology of the Sudbury-McGregor Bay District,Ontario, Canada: a discussion     

Grant M. Young 《International Journal of Earth Sciences》1974,63(2):786-788

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Using Shoreline Video Assessment for coastal planning and restoration in the context of climate change in Kien Giang,Vietnam     

Van Cuong  Chu  Russell  Michael  Brown  Sharon  Dart  Peter 《Ocean Science Journal》2015,50(2):413-432

Kien Giang, bordering Cambodia in the Mekong River Delta, is one of the two most vulnerable provinces in the region to coastal erosion and flooding. Coastal protection can conflict with current land use and economic development activities. The conditions of the mangrove forest and mainland coastline of the Kien Giang province were assessed using the Shoreline Video Assessment Method (SVAM) backed up with information from satellite images. Half of the 206 km Kien Giang coastline has been eroded or is being eroded. Protective mangrove forests naturally occurred in 74% of the coastline but have been under threat from illegal cutting, erosion and coastal retreat. Accurate information on the state of the coastline and mangrove forest health provided invaluable data for developing a new coastal rehabilitation plan to guard against future sea level rise. In contrast to the current boundary management of land and natural resources, this plan divided the provincial coastline into 19 sections based on the landscape condition and exposure to erosion. Priority strategic actions for erosion management, mangrove restoration and sustainable livelihood development for local communities for each section of coast were developed based on an integrated cross sectoral approach and practical experience in the Conservation and Development of the Kien Giang Biosphere Reserve Project.

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Latin hypercube approach to estimate uncertainty in ground water vulnerability   总被引：1，自引：0，他引：1  

Gurdak JJ  McCray JE  Thyne G  Qi SL 《Ground water》2007,45(3):348-361

A methodology is proposed to quantify prediction uncertainty associated with ground water vulnerability models that were developed through an approach that coupled multivariate logistic regression with a geographic information system (GIS). This method uses Latin hypercube sampling (LHS) to illustrate the propagation of input error and estimate uncertainty associated with the logistic regression predictions of ground water vulnerability. Central to the proposed method is the assumption that prediction uncertainty in ground water vulnerability models is a function of input error propagation from uncertainty in the estimated logistic regression model coefficients (model error) and the values of explanatory variables represented in the GIS (data error). Input probability distributions that represent both model and data error sources of uncertainty were simultaneously sampled using a Latin hypercube approach with logistic regression calculations of probability of elevated nonpoint source contaminants in ground water. The resulting probability distribution represents the prediction intervals and associated uncertainty of the ground water vulnerability predictions. The method is illustrated through a ground water vulnerability assessment of the High Plains regional aquifer. Results of the LHS simulations reveal significant prediction uncertainties that vary spatially across the regional aquifer. Additionally, the proposed method enables a spatial deconstruction of the prediction uncertainty that can lead to improved prediction of ground water vulnerability.  相似文献   

Assessing the response of watersheds to catastrophic (logging) and possible secular (global temperature change) perturbations using sediment-chemical chronologies     

David T. Long  Matthew J. Parsons  Catherine H. Yansa  Sharon S. Yohn  Colleen E. McLean  Ryan G. Vannier 《Applied Geochemistry》2010

Geochemical profiles of sediment cores from two oligotrophic lakes (Elk and Mullett) in northern Lower Michigan were studied to examine the response and recovery of watersheds to large-scale logging that occurred between 1850 and 1920. Specific questions addressed were: can the impact of extensive clear-cutting of forests be recognized in the sediment-chemical chronologies, can states of system stability be identified prior to the logging, and are there indications that the systems are recovering and possibly returning to a stable state? To answer these questions, elements were put into four groups as proxies for watershed runoff or export (e.g., Al, Mg), pollution (e.g., Pb, Cu), redox (e.g., Fe, As), and productivity (e.g., Ca, P). It was observed that vertical patterns of all proxies were influenced by logging and the early increases in concentration of pollution proxies were due to increased watershed export, not pollution. System stability might be recognized by relatively symmetrical vertical patterns among all of the proxies or secular changes of slowly increasing or decreasing vertical concentration trajectories. Some pre-logging trajectories were punctuated by episodes of slightly elevated concentrations that appear to be related to comparatively warmer periods during the Little Ice Age. Iron and Mn enrichments caused by increased watershed runoff might be misinterpreted as paleo-redox horizons. Results are interpreted to indicate that (1) reference conditions may be better defined as the temporal trends among proxy groups and not individual concentrations, (2) simply assuming pre-1800 conditions as a reference may not be appropriate, (3) inter-proxy group comparisons are needed to help for interpretations of intra-proxy group patterns, (4) the possible regime shift identified here might be expected for other ecosystems because of the intensity of human disturbances and secular changes, and (5) without consideration of a possible regime shift, recovery from logging is estimated to be on the order of 75–130 a, but shorter if regime shifts are considered.  相似文献   

The geothermal potential of the basal clastics of Saskatchewan,Canada   总被引：1，自引：0，他引：1  

Grant Ferguson  Stephen E. Grasby 《Hydrogeology Journal》2014,22(1):143-150

The Winnipeg and Deadwood formations form deep clastic reservoirs in Saskatchewan, Canada, with temperatures exceeding 40 °C over most of southern Saskatchewan and reaching 100 °C in southwestern Saskatchewan. At these temperatures, the formations have geothermal potential for development of direct use and electricity generation systems. Numerous disposal wells operating at rates of 30 L/s or more are currently installed in these formations, suggesting that electricity could be generated at rates exceeding 2 megawatts of electrical output (MW_e) from individual wells. These basal clastic units, thus, could provide significant energy supply over a broad region of Saskatchewan.  相似文献